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Evaluation of a copper based gel polymer electrolyte and its performance in a primary cell 一种铜基凝胶聚合物电解质及其在原电池中的性能评价
Pub Date : 2015-01-27 DOI: 10.4038/SLJP.V15I0.6686
Y.M.C.D. Jayathilaka, K. Perera, K. Vidanapathirana, L. Bandara
Portable electronic device industry is vastly developing over the last few years. As electrochemical batteries are suitable power sources for portable devices, demand for reliable and efficient batteries have also been increased. Since liquid electrolytes can cause several safety hazards due to leaking of the electrolyte, studies on gel polymer electrolytes have been able to attract many researchers. In this research work, a gel polymer electrolyte based primary cell was fabricated and discharge characteristics were studied. To prepare the gel polymer electrolyte, Polymethylmethacrylate (PMMA), Ethylene Carbonate (EC), Propylene Carbonate (PC) and Copper trifluoromethanesulfonate (Cu(CF 3 SO 3 ) 2 - CuTf) were used. Gel polymer electrolyte sample which contained 22.5% PMMA: 30% EC: 30% PC: 17.5% CuTf showed a conductivity of 2.34 10 -3 S cm -1 at room temperature with an appreciable mechanical stability. Primary cell with Cu and Mg electrodes showed 1.73 V open circuit potential, 131 µA h capacity and 1.13 mA short circuit current. DOI: http://dx.doi.org/10.4038/sljp.v15i0.6686 Sri Lankan Journal of Physics, Vol. 15 (2014) 45-51
近几年来,便携式电子设备行业得到了极大的发展。由于电化学电池是便携式设备的合适电源,对可靠、高效的电池的需求也在增加。由于液态电解质的泄漏会造成多种安全隐患,因此对凝胶聚合物电解质的研究一直备受关注。本研究制备了一种基于凝胶聚合物电解质的原电池,并对其放电特性进行了研究。以聚甲基丙烯酸甲酯(PMMA)、碳酸乙烯酯(EC)、碳酸丙烯(PC)和三氟甲烷磺酸铜(Cu(cf3so3) 2 - CuTf)为原料制备凝胶聚合物电解质。含有22.5% PMMA: 30% EC: 30% PC: 17.5% CuTf的凝胶聚合物电解质样品在室温下的电导率为2.34 10 -3 S cm -1,具有良好的机械稳定性。铜和镁电极原电池的开路电位为1.73 V,容量为131µA h,短路电流为1.13 mA。DOI: http://dx.doi.org/10.4038/sljp.v15i0.6686斯里兰卡物理杂志,卷15 (2014)45-51
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引用次数: 1
Sodium nickel oxide nanoporous cathodes used for sodium-ion rechargeable batteries 用于钠离子可充电电池的氧化镍钠纳米多孔阴极
Pub Date : 2015-01-27 DOI: 10.4038/SLJP.V15I0.8021
R.C.L. De Silva, M. Jayaweera, V. Perera, I. Jayarathna, S. Rosa
The initial research on rechargeable batteries started focusing on both Lithium and Sodium but Lithium was more attracted because of its higher energy density. Later considering the cost of lithium, research has been directed to explore the possibility of using Sodium for rechargeable batteries because of its high abundance and low cost compared to Lithium. In this study we focuses on sodium Nickel oxide as the cathode material of the sodium iron rechargeable battery and tests were carried out to find the formation of crystal structure. Synthesis of Na x NiO 2 nonporous active material were made using solid state reactions at 700 ° C and the material development was studied by XRD characterizing technique. The developed Na x NiO 2 was used as the active cathode material in a rechargeable half cell. The characterization confirmed the crystal structure of NaNiO 2 to be monoclinic, and also its surface morphology. Electron transition status test revealed the specific energy band gap to be 5.16 eV. Charge transfer resistance of the cathode material obtained was 13,121 Ω. The further investigations on charge discharge revealed the maximum efficient charging rate per gram as 7.5 mA for 0.12 hours and maximum rate of discharge for maximum charge retention as 25 mA rate of charge per gram of Na x NiO 2 which was the active material of the rechargeable cell. The charge discharge cyclability was tested for Sodium Nickel Oxide with 0.2 mA constant current for both charging and discharging. A voltage of 2.34 V was observed as the open voltage (no load) at the beginning and the half cell showed more than 180 charge-discharge cycles in performance including a rest time of one minute for each cycle. This confirmed that the battery is able to hold a fairly high reversibility. DOI: http://dx.doi.org/10.4038/sljp.v15i0.8021 Sri Lankan Journal of Physics, Vol. 15 (2014) 19-29
对可充电电池的最初研究主要集中在锂电池和钠电池上,但锂电池因其更高的能量密度而更受欢迎。后来考虑到锂的成本,研究人员开始探索将钠用于可充电电池的可能性,因为与锂相比,钠的丰度高,成本低。本研究以氧化镍钠作为铁钠可充电电池的正极材料,并对其晶体结构的形成进行了测试。在700℃下采用固相反应合成了Na x nio2无孔活性材料,并采用XRD表征技术对材料的发育进行了研究。在可充电半电池中,将所制备的Na x nio2用作活性正极材料。表征证实了纳米二氧化硅的晶体结构和表面形貌均为单斜晶。电子跃迁状态测试表明,比能带隙为5.16 eV。所得正极材料的电荷转移电阻为13121 Ω。进一步的充放电研究表明,每克电池的最大有效充电速率为7.5 mA,充电时间为0.12小时,最大电荷保留率为25 mA,每克电池的活性材料Na x nio2的充电速率为25 mA。在0.2 mA恒流条件下,对氧化镍钠的充放电循环性能进行了测试。开始时的开电压为2.34 V(空载),半电池的充放电循环次数超过180次,每次循环休息时间为1分钟。这证实了电池能够保持相当高的可逆性。DOI: http://dx.doi.org/10.4038/sljp.v15i0.8021斯里兰卡物理杂志,Vol. 15 (2014) 19-29
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引用次数: 4
Synthesis, characterization and ethanol vapor sensing performance of SnO2/Graphene composite film SnO2/石墨烯复合薄膜的合成、表征及乙醇气敏性能
Pub Date : 2015-01-26 DOI: 10.4038/SLJP.V15I0.6345
M. Jayaweera, R.C.L. De Silva, I. Kottegoda, S. Rosa
High performing sensor consisting of SnO 2 /Gn nanocomposite was fabricated using a novel one-step in-situ sonochemical method. The reducing properties of SnCl 2 was used to reduce graphite oxide (GO) so that SnCl 2 could be transformed to SnO 2 on the basal plane of graphene. The combined characterizations including X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transformed Infra-Red spectroscopic data (FTIR) indicated the successful formation of SnO 2 /Gn composites. Current-voltage (I-V) characteristics of the gas sensor showed ideal ohmic behavior having low resistance. To demonstrate the product on sensing application, gas sensors were fabricated using SnO 2 /Gn composites and used in detecting ethanol vapor at room temperature (27°C).The results indicate that the SnO 2 /Gn composite exhibits a considerably high sensing performance of 17.54% response at 150 ppm ethanol vapor, rapid response and reproducibility. Furthermore, the performance of the gas sensor based on SnO 2 /Gn is very stable for a long period of time under normal operating conditions. Therefore, it is suggested that SnO 2 /Gn can be considered as an excellent sensing material which also has a potential for wider range of applications on sensors.
采用一种新型的一步原位声化学方法,制备了由二氧化硅/氮化镓纳米复合材料组成的高性能传感器。利用SnCl - 2的还原性对氧化石墨烯(GO)进行还原,使SnCl - 2在石墨烯基面上转化为sno2。通过x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)的综合表征表明,SnO 2 /Gn复合材料的合成成功。该气体传感器的电流-电压(I-V)特性具有理想的欧姆特性和低电阻。为了验证该产品在传感方面的应用,采用sno2 /Gn复合材料制作了气体传感器,并将其用于室温(27℃)下的乙醇蒸汽检测。结果表明,在150 ppm乙醇蒸汽条件下,sno2 /Gn复合材料具有较高的传感性能,响应速度快,重现性好,达到17.54%。此外,在正常工作条件下,基于sno2 /Gn的气体传感器的性能在很长一段时间内都非常稳定。因此,sno2 /Gn可以被认为是一种优秀的传感材料,在传感器上也有更广泛的应用潜力。
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引用次数: 11
Simultaneous analysis of non-strange negative parity baryon Properties in large Nc QCD 大型Nc QCD中非奇异负宇称重子性质的同时分析
Pub Date : 2013-04-21 DOI: 10.4038/SLJP.V13I2.5443
S. Premaratne, C. Jayalath
Non-strange  excited baryons are analyzed within the Large  QCD framework. The Large  approach is used as an effective theory to simultaneously fit the masses and decays with corrections up to . Values of the mixing angles for the  and  nucleon mass eigenstates are obtained within the simultaneous analysis. The observed effective operator hierarchy is consistent with the previous studies conducted in this sector and improved results are obtained. DOI: http://dx.doi.org/10.4038/sljp.v13i2.5443 Sri Lankan Journal of Physics, Vol. 13 ( 2 ) ( 2012 ) 27 - 38
在大QCD框架内对非奇激重子进行了分析。Large方法是一种有效的理论,可以同时拟合质量和衰减,修正量可达。在同步分析中得到了和核子质量本征态的混合角值。观察到的有效经营者层次与以往在该领域的研究结果一致,并得到了改进的结果。DOI: http://dx.doi.org/10.4038/sljp.v13i2.5443斯里兰卡物理杂志,Vol. 13 (2) (2012) 27 - 38
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引用次数: 0
Fractal Nature of Simulated Lightning Channels 模拟闪电通道的分形性质
Pub Date : 2013-04-19 DOI: 10.4038/SLJP.V13I2.5433
M.M.N. Perera, D. Sonnadara
Cloud-to-ground lightning discharges in 2D and 3D domains were simulated using a stochastic dielectric breakdown model. The dependency between fractal dimension of the discharge patterns and the power of the local electric field η was critically evaluated. An exponential decrease in fractal dimension was observed as η increases. Fractal dimension of simulated 3D discharge patterns and 2D images of lightning discharges were compared by taking projections of simulated patterns. Discharge patterns similar to actual lightning were obtained when η ≈ 5.2. Influence of ground objects on simulated lightning discharges was also studied by introducing additional boundary conditions to the ground plane.  It was observed that pointed structures on the ground have a higher probability of attracting simulated lightning discharges. An extension was introduced to dielectric breakdown model to simulate the development of upward connecting positive leader discharges that occur during the decent of a downward moving negative leader. It was found that the height of the stepped leader tip above the ground (at the time when the upward connecting leader initiation occurs) is dependent on the initial breakdown voltage threshold. The height of the point of interception was found to decrease exponentially as the breakdown threshold is increased. DOI: http://dx.doi.org/10.4038/sljp.v13i2.5433 Sri Lankan Journal of Physics, Vol. 13 ( 2 ) ( 2012 ) 09 - 25
采用随机电介质击穿模型对二维和三维云地闪电放电进行了模拟。分析了放电模式的分形维数与局部电场功率η之间的关系。随着η的增大,分形维数呈指数减小。通过模拟闪电放电模式的投影,比较了模拟闪电放电模式的三维分形维数和模拟闪电放电模式的二维分形维数。当η≈5.2时,得到与实际闪电相似的放电模式。通过在地面上引入附加边界条件,研究了地物对模拟雷击放电的影响。据观察,地面上的尖状结构更有可能吸引模拟闪电放电。对介电击穿模型进行了扩展,模拟了负极引线向下移动时向上连接的正极引线放电的发展过程。研究发现,梯级引线尖端离地高度(向上连接引线起始时)与初始击穿电压阈值有关。随着击穿阈值的增加,拦截点的高度呈指数下降。DOI: http://dx.doi.org/10.4038/sljp.v13i2.5433斯里兰卡物理杂志,Vol. 13 (2) (2012) 09 - 25
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引用次数: 10
A model for Thundercloud Charge Separation 雷云电荷分离模型
Pub Date : 2013-04-19 DOI: 10.4038/SLJP.V13I2.5432
K. Tennakone, P. Hewageegana
A theoretical model of thundercloud charge separation is presented. The model assume that  moisture in  the updraft moving  as a stream with uniform velocity condenses into particles of graupel  in reaching cooler regions of the atmosphere.  Falling graupels acquire a negative charge by shedding the inductive positive charge which is carried away by the updraft. Charged graupels moves downward subjected to gravity, force due to the collective electric field and air resistance. Non-linear equations governing the dynamics of the system demonstrate existence of a stable equilibrium electric field of the order of magnitude needed for dielectric breakdown of air. Model also shows that thundercloud electric field could undergo pulsations at infrasonic frequencies and synchronously emit acoustic waves at the same frequency.  Preferential positive inductive charging of graupel is explained as a consequence of the proton conductivity of ice. DOI: http://dx.doi.org/10.4038/sljp.v13i2.5432 Sri Lankan Journal of Physics, Vol. 13(2) (2012) 01-07
提出了雷云电荷分离的理论模型。该模型假设上升气流中的水分以匀速流的形式在到达大气较冷的区域时凝结成霰颗粒。下落的霰通过脱落被上升气流带走的感应正电荷而获得负电荷。带电的霰在重力的作用下向下移动,重力是由集体电场和空气阻力引起的。控制系统动力学的非线性方程证明了空气介电击穿所需数量级的稳定平衡电场的存在。模型还表明,雷云电场可以在次声波频率上发生脉动,并同步发射同一频率的声波。霰的优先正感应电荷被解释为冰的质子电导率的结果。DOI: http://dx.doi.org/10.4038/sljp.v13i2.5432斯里兰卡物理杂志,Vol. 13(2) (2012) 01-07
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引用次数: 0
Polarizability of a metallic nanosphere: Local random-phase approximation (LRPA) 金属纳米球的极化率:局部随机相近似(LRPA)
Pub Date : 2012-07-19 DOI: 10.4038/SLJP.V13I1.4211
P. Hewageegana
We develop a method for calculating the polarizability of a spherical nano particle by taking in to account the temporal and spatial dispersion where dispersion due to the Landau damping. To describe these phenomena, we developed analytical theory based on local random-phase approximation. Our theory is very general in the sense that it can be applied to any material which can be characterized by a bulk dielectric function of the form e(κ,ω) . The theory is applied to calculate the polarizabilities of dielectric and metallic nanospheres. Keywords: metallic nanosphere; polarizability; random-phase approximation DOI:  http://dx.doi.org/10.4038/sljp.v13i1.4211 Sri Lankan Journal of Physics, Vol. 13(1) (2012) 41-47
我们开发了一种计算球形纳米粒子极化率的方法,该方法考虑了由朗道阻尼引起的时空色散。为了描述这些现象,我们发展了基于局部随机相位近似的解析理论。我们的理论是非常普遍的,因为它可以应用于任何可以用e(κ,ω)形式的体介电函数来表征的材料。应用该理论计算了电介质和金属纳米球的极化率。关键词:金属纳米球;极化率;随机相位近似DOI: http://dx.doi.org/10.4038/sljp.v13i1.4211斯里兰卡物理杂志,Vol. 13(1) (2012) 41-47
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引用次数: 0
Transformation of Surface Charge Density in Mixed Number Lorentz Transformation 混合数洛伦兹变换中表面电荷密度的变换
Pub Date : 2012-07-19 DOI: 10.4038/SLJP.V13I1.3546
S. Rafiq, M. S. Alam
We know that the electric charge of an isolated system is relativistically invariant. We have studied the transformation of surface charge density in Special, Most general, Mixed number Lorentz transformation. As the formula of length contraction is not the same in these types of Lorentz transformation, the transformation equation of surface charge density will be different in the above mentioned transformations. Keywords: Special Lorentz Transformation; Surface charge density DOI: http://dx.doi.org/10.4038/sljp.v13i1.3546 Sri Lankan Journal of Physics, Vol. 13(1) (2012) 17-25
我们知道孤立系统的电荷是相对不变的。研究了特殊、一般、混合数洛伦兹变换中表面电荷密度的变换。由于这几种洛伦兹变换中长度收缩的公式不一样,因此在上述变换中,表面电荷密度的变换方程也会不同。关键词:特殊洛伦兹变换;表面电荷密度DOI: http://dx.doi.org/10.4038/sljp.v13i1.3546斯里兰卡物理杂志,Vol. 13(1) (2012) 17-25
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引用次数: 2
Gross Alpha and Gross Beta Activities of Tap Water Samples from Different Locations of Dhaka City 达喀市不同地点自来水样本的总α和总β活性
Pub Date : 2012-07-19 DOI: 10.4038/SLJP.V13I1.3917
M. Ferdous, M. Rahman, A. Begum
Gross alpha and gross beta activities were determined for twenty tap water samples collected from different locations in Dhaka city. The instrumentations used to count the gross alpha and gross beta activities were ZnS scintillation detector and gas proportional counter, respectively. Concentrations ranging from 1.88 ± 0.03 mBq / l to 8.16 ± 0.03 mBq / l with an average 3.76 ± 1.50 mBq / l and from 29.305 ± 0.06 mBq/ l to 115.74 ± 0.16 mBq / l with an average 60.41 ± 23.57 mBq /l were observed for the gross alpha and gross beta activities, respectively. The results showed that the natural activities of alpha and beta emitting radionuclides in tap water samples did not exceed WHO recommended levels and were comparable with the data available in other parts of the world. It suggests that the radioactivity in tap water for the people residing in Dhaka city is not yet a problem. To ensure the safe level of radioactivity in drinking water, however, periodic monitoring of water quality for compliance is necessary. DOI: http://dx.doi.org/10.4038/sljp.v13i1.3917 Keywords: Gross Alpha; Gross beta; Tap water; ZnS Scintillation Counter and Gas Proportional Counter Sri Lankan Journal of Physics, Vol. 13(1) (2012) 01-08
测定了从达卡市不同地点收集的20个自来水样品的总α和总β活性。测定总α活度和总β活度的仪器分别是ZnS闪烁检测器和气体比例计数器。总α和总β活性的浓度范围分别为1.88±0.03 mBq/ l ~ 8.16±0.03 mBq/ l,平均为3.76±1.50 mBq/ l和29.305±0.06 mBq/ l ~ 115.74±0.16 mBq/ l,平均为60.41±23.57 mBq/ l。结果表明,自来水样品中释放α和β的放射性核素的自然活性没有超过世卫组织建议的水平,并与世界其他地区的现有数据相当。这表明,对居住在达卡市的人们来说,自来水中的放射性还不是一个问题。然而,为了确保饮用水中的放射性达到安全水平,必须定期监测水质是否符合规定。关键词:Gross Alpha;总β;自来水;ZnS闪烁计数器与气体比例计数器斯里兰卡物理学报Vol. 13(1) (2012) 01-08
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引用次数: 18
Bound state solutions of the Klein - Gordon equation for deformed Hulthen potential with position dependent mass 具有位置依赖质量的变形Hulthen势的Klein - Gordon方程的束缚态解
Pub Date : 2012-07-19 DOI: 10.4038/SLJP.V13I1.3780
A. Antia, A. Ikot, E. Ituen, I. Akpan
We solve approximately the bound state solutions of the Klein - Gordon equation for deformed Hulthen potential with unequal scalar and vector potential for arbitrary l -state. We obtain explicitly the energy eigenvalues and the corresponding wave function expressed in terms of the Jacobi polynomials. We also discuss the energy eigenvalues of our result for three cases with equal and unequal scalar and vector potentials. Keywords: Klein-Gordon equation; Hulthen potential; bound state DOI:  http://dx.doi.org/10.4038/sljp.v13i1.3780 Sri Lankan Journal of Physics, Vol. 13(1) (2012) 27-40
对任意l态具有不等标量势和不等矢量势的变形Hulthen势的Klein - Gordon方程的束缚态解进行了近似求解。我们显式地得到了能量特征值和相应的以雅可比多项式表示的波函数。我们还讨论了标量势和矢量势相等和不等的三种情况下我们的结果的能量特征值。关键词:Klein-Gordon方程;Hulthen潜能;DOI: http://dx.doi.org/10.4038/sljp.v13i1.3780斯里兰卡物理杂志,Vol. 13(1) (2012) 27-40
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引用次数: 8
期刊
Sri Lankan Journal of Physics
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