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Effect of Catholyte Concentration on Current Production During Chocolate Industry Wastewater Treatment by a Microbial Fuel Cell 微生物燃料电池处理巧克力工业废水时电解液浓度对电流产生的影响
Pub Date : 2020-09-01 DOI: 10.7454/mst.v24i2.418
D. R. Wulan, S. Notodarmojo
Microbial fuel cells (MFCs) use bacteria as a catalyst to oxidize organic and/or inorganic substrates and produce electric currents. Wastewater could function as an electron donor in the anode chamber and, thus, represents a very promising energy source. Catholytes, as electron acceptors, influence power production in MFCs by increasing the availability of electrons. The present research aims to determine the influence of catholyte concentration on current production in an aerobic two-chamber MFC. Aerobic treatment was carried out in the two-chamber MFC operated in an incubator at 37  1 °C with and without aeration in the cathode chamber. Wastewater from the chocolate industry was used as a substrate and oxidized by using a bacterial consortium isolated from the sludge wastewater itself. The catholytes used were 0.01, 0.05, 0.1, and 0.3 N NaCl. In the presence of NaCl, the chemical oxygen demand (COD) removal efficiency in the cathode chamber of the MFC was approximately 65%–83% without aeration and 76%–89% with aeration after 72 hours. The current density increased as the catholyte concentration increased to 0.05 N, after which the oxidation process shifted from the anode chamber to the cathode chamber. Addition of O2 to the cathode chamber influenced current production.
微生物燃料电池(MFCs)利用细菌作为催化剂氧化有机和/或无机底物并产生电流。废水可以作为阳极室中的电子供体,因此代表了一种非常有前途的能源。阴极电解质作为电子受体,通过增加电子的可用性来影响mfc中的发电。本研究旨在确定阴极电解质浓度对有氧双室MFC电流产生的影响。在371°C的培养箱中运行的双室MFC进行好氧处理,阴极室有和没有曝气。巧克力工业的废水被用作底物,并使用从污泥废水中分离出来的细菌联合体进行氧化。阴极电解质分别为0.01、0.05、0.1和0.3 N NaCl。NaCl存在下,72 h后MFC阴极室化学需氧量(COD)去除率在不曝气的情况下约为65% ~ 83%,在曝气条件下约为76% ~ 89%。当阴极液浓度增加到0.05 N时,电流密度增大,氧化过程从阳极室转移到阴极室。向阴极室添加氧气影响电流的产生。
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引用次数: 0
Performance of adhesive waterproofing as regardsof lateral water filtration 胶粘剂防水的侧向水过滤性能
Pub Date : 2020-08-31 DOI: 10.31448/mstj.02.01.2019.77-93
Gergely Dobszay, R. Nemes, F. Andriska, Dániel Heincz, K. Kovács, Richárd Reisch, T. Simon
Self-bonding layers In order to simplify construction, to decrease the amount of special auxiliaries, to decrease the damages due to faults, to increase safety and to decrease the necessary space, material producers developed such waterproofing systems which can establish mechanical or chemical working together capability with in situ reinforced concrete load bearing structures. These technologies differ significantly from customary waterproofing in practice. They participate in water displacement not as a separate layer, but as the integral part of an underground civil engineering structure. As long as a waterproofing system functions properly, any type is appropriate. The difference becomes significant only, when due to a breach a fault of the waterproofing system occurs. Only from then on increases the importance of the type of the original system. During our studies we punctured deliberately new, adhesive waterproofing systems and for reference a customary membrane all of which were applied on concrete, hence tested their performance as a structure by concentrating mainly on lateral water filtration.
为了简化施工,减少特殊助剂的用量,减少因故障造成的破坏,提高安全性和减少必要的空间,材料生产商开发了这种防水系统,可以与现场钢筋混凝土承重结构建立机械或化学协同工作能力。这些技术在实践中与传统的防水技术有很大的不同。它们不是作为一个单独的层参与水位移,而是作为地下土木工程结构的组成部分。只要防水系统功能正常,任何类型都是合适的。只有当由于防水系统的破坏而发生故障时,差异才会变得显著。只有从那时起,原始系统类型的重要性才会增加。在我们的研究中,我们特意设计了新的粘合防水系统,并参考了一种传统的膜,所有这些都应用在混凝土上,因此通过主要集中在横向水过滤上来测试它们作为结构的性能。
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引用次数: 0
Ethylene Carbonate and Polyethylene Glycol as Efficient Plasticizers in CMC-PVA-NH4NO3-Based Polymer Electrolyte 碳酸乙烯和聚乙二醇在cmc - pva - nh4no3基聚合物电解质中的高效增塑剂
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3833
Noor Saadiah Mohd Ali, Y. Nagao, A. S. Samsudin
This study investigated the influence of plasticizers (polyethylene glycol [PEG] and ethylene carbonate [EC]) on the ionic conduction of CMC-PVA-NH4NO3. Blended biopolymer electrolytes (BBEs) based on carboxymethyl cellulose– polyvinyl alcohol (CMC-PVA) doped with ammonium nitrate (NH4NO3) were obtained via casting solution technique incorporated with PEG and EC, which acted as plasticizers. Electrical impedance spectroscopy (EIS) was conducted to evaluate the effect of plasticization on the ionic conduction properties. The ionic conductivity improved from 1.70 × 10 S/cm for un-plasticized BBEs to 3.92 × 10 S/cm for plasticized BBEs with EC and 3.00 × 10 S/cm for plasticized BBEs with PEG. The improvement indicated that the plasticizers weakened the Coulombic force and promoted further dissociation in the ionic dopant. The highest ionic conductivity was achieved for BBEs plasticized with EC, thereby suggesting the suitability of EC as plasticizer in this present system. The BBE system showed the Arrhenius characteristic at elevated temperatures and demonstrated increasing ionic conductivity. Dielectric properties of all BBE systems were found to improve upon the addition of EC and PEG, demonstrating their correlation with ionic conductivity.
研究了增塑剂(聚乙二醇[PEG]和碳酸乙烯[EC])对CMC-PVA-NH4NO3离子传导的影响。以聚乙二醇(PEG)和EC为增塑剂,采用铸液法制备了羧甲基纤维素-聚乙烯醇(CMC-PVA)掺杂硝酸铵(NH4NO3)的共混生物聚合物电解质(BBEs)。利用电阻抗谱(EIS)评价了塑化对离子导电性能的影响。离子电导率由未塑化的1.70 × 10 S/cm提高到EC塑化的3.92 × 10 S/cm, PEG塑化的3.00 × 10 S/cm。结果表明,增塑剂削弱了离子掺杂剂的库仑力,促进了离子掺杂剂的进一步解离。用EC塑化的BBEs获得了最高的离子电导率,从而表明EC在本体系中作为增塑剂的适用性。BBE体系在高温下表现出阿伦尼乌斯特性,离子电导率提高。所有BBE体系的介电性能都在加入EC和PEG后得到改善,证明了它们与离子电导率的相关性。
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引用次数: 4
Effects of Collision Damage on the Ultimate Strength of FPSO Vessels 碰撞损伤对FPSO船舶极限强度的影响
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3732
M. Alie, Dian Ramasari, T. Rachman, R. Adiputra
Floating production storage offloading (FPSO) vessels are movable offshore structures. These structures are designed with large dimensions, and their decks are loaded with several types of equipment. During collision damage, the hull and deck parts loaded with equipment are severely affected. Therefore, the ultimate strength of FPSO vessels should be thoroughly checked and evaluated. The objective of the present study is to analyze the ultimate strength of FPSO vessels against collision damage characterized by hogging and sagging under longitudinal bending. The cross section of an FPSO vessel is modeled with elements composed of stiffened and unstiffened plates. The vessel length is assumed to occupy one frame space. The ultimate strength of FPSO vessels against collision damage is determined by performing a numerical analysis under hogging and sagging conditions. Multipoint constraint is applied to both sides of the cross section, and the material properties are set to be constant. Collision damage is represented by the loss of element stiffness, and it represents the percentage of the ship’s depth. For the extent of transversal damage, B/16 is set to be constant. The minimum and maximum collision damages are taken as 10% and 60% of the ship’s depth, respectively. Numerical results show that the ultimate strength of FPSO vessels and their bending stiffness decrease under collision.
浮式生产储存卸载船(FPSO)是一种可移动的海上结构。这些结构的设计尺寸很大,甲板上装载了几种类型的设备。在碰撞损坏中,船体和装载设备的甲板部位受到严重影响。因此,应该对FPSO船的极限强度进行彻底的检查和评估。本研究的目的是分析FPSO船在纵向弯曲下的碰撞损伤的极限强度。FPSO船的横截面由加筋板和非加筋板组成。假定容器长度占用一个帧空间。FPSO船抗碰撞损伤的极限强度是通过对其在占用和下垂条件下的数值分析来确定的。将多点约束应用于横截面的两侧,并将材料属性设置为常数。碰撞损伤用单元刚度损失来表示,它代表船舶深度的百分比。对于横向损伤程度,设B/16为常数。最小和最大碰撞损伤分别取船舶深度的10%和60%。数值计算结果表明,FPSO船舶在碰撞作用下的极限强度和抗弯刚度降低。
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引用次数: 4
Ionic Conductivity and Electrochemical Properties of Alginate–NN4NO3-Based Biopolymer Electrolytes for EDLC Application 海藻酸盐- nn4no3基EDLC生物聚合物电解质的离子电导率和电化学性能
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3832
Norfatihah Mazuki, N. M. J. Rasali, B. Sahraoui, A. S. Samsudin
In this work, alginate doped with various contents of ammonium nitrate (NH4NO3) as a solid biopolymer electrolyte (SBE) was prepared via casting by using distilled water as a solvent. Impedance studies on alginate–NH4NO3 SBE films were conducted via impedance spectroscopy. The lowest bulk resistance (Rb) showed that the maximum ionic conductivity of the sample containing 25 wt.% NH4NO3 at ambient temperature (303 K) was 5.56 × 10 S cm. The temperature dependence of ionic conductivity was evaluated, and results confirmed that electrolytes followed an Arrhenius behavior. The highest conducting sample was fabricated into an electrical double-layer capacitor and characterized in terms of its electrochemical properties through cyclic voltammetry (CV) and galvanostatic charge– discharge (GCD) measurement. CV analysis indicated that specific capacitance decreased as the scan rate increased. Conversely, GCD analysis showed that specific capacitance almost remained unchanged for up to 5000 cycles.
本研究以蒸馏水为溶剂,采用浇铸法制备了掺杂不同含量硝酸铵(NH4NO3)的海藻酸盐作为固体生物聚合物电解质(SBE)。采用阻抗谱法对海藻酸盐- nh4no3 SBE薄膜进行了阻抗研究。最小体积电阻(Rb)表明,含25 wt.% NH4NO3的样品在室温(303 K)下的最大离子电导率为5.56 × 10 S cm。对离子电导率的温度依赖性进行了评估,结果证实了电解质遵循Arrhenius行为。采用循环伏安法(CV)和恒流充放电法(GCD)对其电化学性能进行了表征。CV分析表明,比电容随扫描速率的增加而减小。相反,GCD分析表明,在5000次循环中,比电容几乎保持不变。
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引用次数: 2
Comparison of Phytoremediation and Filtration for Diamond-mine-tailings Water Treatment 植物修复与过滤处理金刚石尾矿水的比较研究
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3821
M. Noor, Mijani Rahman, Akhmad Gazali, N. Kania, A. Rahma, E. L. Rampun, A. E. Pratiwi, M. Elma
The water pollution caused by diamond mine activities can kill aquatic life. In this work, we used phytoremediation and filtration to treat pond water polluted by the tailings of a diamond mine located in South Kalimantan, Indonesia. Einchhornia crassipes (water hyacinth) was utilized as the biomass for the phytoremediation process. Gravel (10–15 mm) and sand (0.1–1 mm) were used as filter media in the simple filtration setup, using an up-flow system (bottom to top). In the experiment, 16 L of diamond tailing water was poured into five phytoremediation reactors (each 60 L in volume), which were then tested over seven days. A pretreatment analysis of the tailings water showed that its biochemical oxygen demand (BOD) of 8.9 mg L and chemical oxygen demand (COD) of 22 mg L exceeded the national maximum standards of 2 mg L and 10 mg L, respectively. The experimental results demonstrate that both phytoremediation and filtration could increase the dissolved oxygen concentration (4.7 mg.L) and reduce the BOD (3.2 mg.L), COD (6.5 mg.L), Fe (0.6 mg.L), Mn (0.16 mg.L), and ammonia (0.63 mg.L) concentrations from those measured in the raw diamond-mine-tailings water. The phytoremediation performance was better than that of filtration. The COD values were successfully reduced to the permissible limit, although the other parameters still failed to meet the government water quality regulation requirements.
钻石矿活动造成的水污染会杀死水生生物。在这项工作中,我们采用植物修复和过滤的方法处理了位于印度尼西亚南加里曼丹的一个钻石矿的尾矿污染的池塘水。利用水葫芦(inchhornia crassipes)作为植物修复的生物量。在简单的过滤装置中,使用砾石(10-15 mm)和沙子(0.1-1 mm)作为过滤介质,使用自下而上的向上流动系统。在实验中,将16 L的钻石尾矿水倒入5个植物修复反应器中(每个反应器的体积为60 L),然后进行为期7天的测试。对尾矿水进行预处理分析,其生化需氧量(BOD)为8.9 mg L,化学需氧量(COD)为22 mg L,分别超过国家最高标准2 mg L和10 mg L。实验结果表明,植物修复和过滤均能提高原钻尾矿水中溶解氧浓度(4.7 mg.L),降低BOD (3.2 mg.L)、COD (6.5 mg.L)、Fe (0.6 mg.L)、Mn (0.16 mg.L)和氨(0.63 mg.L)浓度。植物修复效果优于过滤修复。COD值成功降至允许限值,但其他参数仍未达到政府水质监管要求。
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引用次数: 0
Current Status of Hydrothermal Treatment for Energy and Material Recovery Toward a Sustainable Post-consumer Material Cycle 面向可持续消费后材料循环的水热处理能源和材料回收的现状
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3885
Baskoro Lokahita, M. Aziz, F. Takahashi
The demand for energy-efficient and environmentally friendly municipal solid waste (MSW) processing has increased in developing countries. The thermochemical process offers a fast and reliable solution to reutilize or reduce the volume of MSW. Hydrothermal treatment is a novel MSW treatment technology that is compatible with high-moisture-content feedstock. It involves the thermal degradation of MSW in pressurized water or steam, which promotes the disintegration of cellulosic and polymer materials. Recent advances have shown effective MSW conversion into homogenous solid hydrochar with higher energy density. Alkali and chlorine content, which causes issues in combustors, was successfully removed due to the washing effect of hydrothermal treatment. The possibility of activated carbon production also exists because the surface area is significantly increased after the treatment. This paper presents an overview of the latest development of hydrothermal treatment in the field of post-consumer waste and MSW treatment, with particular focus on the operating conditions and physicochemical characteristics of the hydrochar. Several experimental results from post-consumer waste feedstock were compiled and interpreted using principal component analysis to observe the effect of different operating conditions and feedstock during the hydrothermal process.
发展中国家对节能和无害环境的城市固体废物处理的需求有所增加。热化学处理提供了一种快速可靠的解决方案来再利用或减少城市生活垃圾的体积。水热处理是一种适用于高含水率原料的新型城市生活垃圾处理技术。它涉及城市生活垃圾在加压水或蒸汽中的热降解,这促进了纤维素和聚合物材料的分解。近年来的研究进展表明,生活垃圾可以有效地转化为具有较高能量密度的均质固体碳氢化合物。由于水热处理的洗涤作用,成功地去除了引起燃烧器问题的碱和氯含量。活性炭生产的可能性也存在,因为处理后的表面积显着增加。本文综述了水热处理在生活后垃圾和城市生活垃圾处理领域的最新进展,重点介绍了水热处理的操作条件和烃类的物理化学特性。利用主成分分析对消费后废原料的实验结果进行了整理和解释,观察了不同操作条件和不同原料对水热过程的影响。
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引用次数: 0
Liquefaction Potential Analysis Based on Nonlinear Ground Response on the Coastline of Bengkulu City, Indonesia 基于非线性地面响应的印尼Bengkulu市海岸线液化潜力分析
Pub Date : 2020-04-29 DOI: 10.7454/MST.V24I1.3778
L. Z. Mase
This paper presents the study of the seismic response and liquefaction potential of the coastal area of Bengkulu City during the September 2007 Sumatra earthquake. The study is conducted by collecting site investigation data (standard penetration test) and applying input motion to observe soil response. Synthetic ground motion is generated by considering the important aspects of earthquakes, including focal depth, epicenter, earthquake source, and site classification. The synthetized ground motion is then used as the input motion in the seismic response analysis. The results of this analysis are spectral acceleration and peak ground acceleration at each depth. The resulting spectral acceleration is compared with that specified in the seismic design code of Indonesia (SNI 03-1726-2012). Liquefaction potential analysis is performed on the basis of the results of the seismic response analysis. Results show that spectral acceleration depends on soil type. A high soil density equates to a low spectral response. The designed spectral acceleration may still be considered for each borehole, especially for T (period) < 1. However, for T > 1, spectral acceleration should be prioritized, especially for high-rise building construction. The liquefaction analysis reveals that a shallow depth is vulnerable to liquefaction. In general, this study could give a better understanding on the implementation of seismic ground response for liquefaction potential analysis.
本文介绍了2007年9月苏门答腊岛地震期间明古鲁市沿海地区的地震反应和液化潜力的研究。采用现场调查数据(标准贯入试验)和输入运动观测土体响应的方法进行研究。合成地震动是通过考虑地震的重要方面产生的,包括震源深度、震中、震源和场地分类。然后将合成的地震动作为地震反应分析的输入运动。这一分析的结果是频谱加速度和峰值地面加速度在每个深度。将得到的谱加速度与印度尼西亚抗震设计规范(SNI 03-1726-2012)的规定进行了比较。在地震反应分析结果的基础上进行了液化势分析。结果表明,光谱加速度与土壤类型有关。高土壤密度等于低光谱响应。对于每个井眼,特别是当T(周期)< 1时,仍然可以考虑设计的谱加速度。但对于t>1,应优先考虑谱加速,特别是高层建筑施工。液化分析表明,浅层深度易发生液化。总的来说,本研究可以更好地理解液化潜力分析中地震地面反应的实施。
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引用次数: 1
Acute Toxicitystudy of Choline Based Ionic Liquids Towards Danio rerio fish and the Aggregation Behavior of Their Binary Mixtures 胆碱离子液体对斑马鱼的急性毒性研究及其二元混合物的聚集行为
Pub Date : 2020-02-27 DOI: 10.7454/mst.v23i3.3858
Mansoor ul Hassan Shah, N. Nasruddin, S. Yusup, M. Moniruzzaman
Marine oil spills are effectively controlled by chemical dispersants. However, the toxicity associated with it reduce its employment in marine environment. To overcome this limitation, the acute toxicity of choline based ionic liquids was evaluated as a potential low toxic variant for oil spill remediation. Further, the aggregation behavior of the individual as well as their binary mixtures was also evaluated by employing tensiometry technique. The half-lethal concentration, LC50on zebrafish (Danio rerio) of three choline based ionic liquids showed that the studied ionic liquids (ILs) fall in the range of “practically nontoxic” ( 100-1000 mg L).Various micellar properties showed that a synergistic interaction existed between all the binary mixtures (β < 0, f1and f2 <1). Moreover, the produced micelles were found to be spontaneous and thermodynamically stable with respect to all the mole ratio of ILs. Overall, these results showed the safe nature of the studied ILs for various application including oil dispersants.
化学分散剂可以有效地控制海洋石油泄漏。然而,与之相关的毒性减少了其在海洋环境中的使用。为了克服这一限制,我们对胆碱离子液体的急性毒性进行了评估,认为胆碱离子液体是一种潜在的低毒石油泄漏补救方法。此外,聚合行为的个人以及他们的二元混合物也被评估采用张力测量技术。三种胆碱离子液体对斑马鱼(Danio rerio)的半致死浓度lc50表明,所研究的离子液体(ILs)在“几乎无毒”(100-1000 mg L)范围内。各种胶束性质表明,所有二元混合物(β < 0, f1和f2 <1)之间存在协同相互作用。此外,发现所产生的胶束是自发的,并且相对于所有il的摩尔比都是热力学稳定的。总的来说,这些结果表明了所研究的il在包括油分散剂在内的各种应用中的安全性。
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引用次数: 0
Influence of NH4F in Dextran Based Biopolymer Electrolytes: Conductivity and Electrical Analysis NH4F对葡聚糖基生物聚合物电解质的影响:电导率和电学分析
Pub Date : 2020-02-10 DOI: 10.7454/mst.v23i3.3729
M. H. Hamsan, M. Kadir, S. B. Aziz, Muhammad Amirul Solihin Azha, Saifful K Muzakir
Dextran polymer host was doped with different concentrations of ammonium fluoride (NH4F) via casting technique. In this present work, dextran-NH4F film has been employed to investigate the ionic conductivity using electrochemical impedance spectroscopy from 50 to 5 MHz. The highest room temperature conductivity is achieved at (2.33 ± 0.76) × 10 S cm with 40 wt.% NH4F. The electrolyte is found to obey Arrhenius rule at high temperature with activation energy of 0.21 eV. Dielectric analysis has been performed to obtain better understanding on the conductivity pattern. The dielectric parameters e.g. ɛreal, ɛimag, Mreal, and Mimag have been tested as a function of frequency at various temperature. The potential stability obtained for the highest electrolyte in this study is 1.58 V.
采用浇铸法制备了不同浓度的氟化铵掺杂的葡聚糖聚合物载体。在本研究中,利用50 ~ 5 MHz的电化学阻抗谱研究了右旋糖酐- nh4f膜的离子电导率。在40 wt.% NH4F条件下,室温电导率最高,为(2.33±0.76)× 10 S cm。该电解质在高温下符合阿伦尼乌斯定律,活化能为0.21 eV。为了更好地理解电导率模式,进行了介电分析。在不同温度下,测试了介电参数如:_ real, _ imag, _ Mreal和_ Mimag作为频率的函数。本研究获得的最高电解质电位稳定性为1.58 V。
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引用次数: 3
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Theory of Computing Systems \/ Mathematical Systems Theory
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