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THERMO-HYDRAULIC CHARACTERISTICS OF ADDITIVELY MANUFACTURED MINI-CHANNELS 增材制造微通道的热液特性
Pub Date : 2023-06-11 DOI: 10.31472/ttpe.2.2023.3
А.А. Khalatov, І.І. Borisov, S. Kulishov
The aim of this work is to analyze the heat transfer, hydraulic resistance and thermo-hydraulic performance of a new type of heat exchange channels made by additive technology. The main factors affecting the quality of products and determining the heat transfer and hydraulic resistance of the channels are noted.  Well-known ratios for calculating hydraulic resistance and heat transfer are not suitable for such high roughness. Data on the AT resistance coefficient of the channels show that even at low Reynolds numbers there is a contribution of roughness. With increasing roughness, the intensification of resistance and heat exchange increases. The transition occurs at 700 < Re < 2000. Comparison of data on heat transfer augmentation and increase of hydraulic losses, as well as their thermo-hydraulic characteristics has been carried out. The hydraulic resistance coefficient of AT channels is significantly higher than the resistance coefficient of smooth channels. Heat transfer augmentation in wave-shaped channels is 2 times higher than augmentation in straight channels. Channels with pin fins allow to achieve a very high heat transfer augmentation (up to 8). Channels with internal grids provide high intensification, but have the highest hydraulic losses. The dependence of the Reynolds analogy factor on the resistance increase factor showed that the straight channels of all geometric forms fit on one dependence closed to the lower boundary line, and have a low hydraulic resistance. Data on channels with pin fins have a large spread. A number of points are above the upper boundary line, which refers to channels with low surface roughness.     
本文分析了一种新型增材制造的换热通道的传热特性、水力阻力和热工性能。指出了影响产品质量和决定通道传热和水力阻力的主要因素。众所周知的计算水力阻力和传热的比率不适用于如此高的粗糙度。通道的AT阻力系数数据表明,即使在低雷诺数下,粗糙度也有贡献。随着粗糙度的增加,阻力和热交换的强度增加。转变发生在700 < Re < 2000。比较了换热增大和水力损失增大的数据,以及它们的热液特性。AT通道的水力阻力系数明显高于光滑通道的阻力系数。波浪形通道的换热增益比直线通道的换热增益高2倍。带有销鳍的通道可以实现非常高的传热增强(高达8)。带有内部网格的通道提供高强化,但具有最高的水力损失。雷诺数类比因子对阻力增加因子的依赖关系表明,所有几何形式的直流道在靠近下边线的一项依赖关系上都符合,并且具有较低的水力阻力。带销钉鳍的通道的数据有很大的传播。许多点位于上边界线之上,这是指表面粗糙度较低的通道。
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引用次数: 0
THERMOPHYSICAL PROPERTIES OF POLYMER MICRO- AND NANOCOMPOSITES AND THEIR CONNECTION WITH THE STRUCTURAL CHARACTERISTICS OF THE POLYMER MATRIX 聚合物微纳米复合材料的热物理性质及其与聚合物基体结构特性的关系
Pub Date : 2022-08-31 DOI: 10.31472/ttpe.3.2022.3
N. Fialko, R. Dinzhos, Ju.V. Sherenkovskyi, V. Prokopov, N. Meranova
The results of experimental studies of the heat-conducting properties of polymer micro- and nanocomposites based on polyethylene and polycarbonate filled with carbon nanotubes and aluminum particles are presented. The dependences of the heat conductivity of the considered polymer composite materials on the content of the filler are obtained. The possibility of obtaining polymer composites based on polycarbonate with a coefficient of heat conductivity of 50.0 and 25.7 W/(m K) using carbon nanotubes and aluminum particles as fillers, respectively, has been established. The results of studies of the degree of crystallinity of polymer matrices of the considered composites are presented. Data are submitted concerning the correlation between the indicated degree of crystallinity and the heat conductivity coefficient of the studied composite materials. An interpretation of the mechanism of such a dependence is given on the basis of the laws governing the formation of percolation structures from filler particles.
本文介绍了碳纳米管和铝颗粒填充聚乙烯和聚碳酸酯聚合物微纳米复合材料导热性能的实验研究结果。得到了所考虑的聚合物复合材料的导热性与填料含量的关系。以碳纳米管和铝颗粒为填料,制备导热系数分别为50.0和25.7 W/(m K)的聚碳酸酯基聚合物复合材料。给出了所考虑的复合材料的聚合物基体结晶度的研究结果。提交了有关所研究的复合材料的指示结晶度与导热系数之间的相关性的数据。根据填料颗粒形成渗透结构的规律,对这种依赖的机理进行了解释。
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引用次数: 0
PEAT IS AN EFFECTIVE ALTERNATIVE FUEL 泥炭是一种有效的替代燃料
Pub Date : 2022-08-30 DOI: 10.31472/ttpe.3.2022.1
Yurii Sniezhkin, D. Korinchuk
The article considers peat as an effective alternative fuel. Its reserves and directions of use in the world and in Ukraine presented and analyzed. The analysis showed that the geological reserves of peat in Ukraine are equivalent to 600 billion cubic meters of natural gas. The main reserves of peat are concentrated in the districts of Polissia. Industrial peat extraction can take place in 12 regions: Volyn, Rivne, Zhytomyr, Kyiv, Cherkasy, Poltava, Sumy, Chernihiv, Khmelnytskyi, Ternopil, Lviv, and Ivano-Frankivsk. It has been shown that, compared to traditional energy carriers, peat fuel has a lower heat of combustion and a fairly high ash content, but during combustion it emits almost no toxic substances and, accordingly, pollutes the environment much less. In home furnaces, peat fuel burned with a higher efficiency than coal, and the ash used as fertilizer. The estimated cost of 1Gj of lower heat of combustion of various types of fuel according to the data of recent years shows a noticeable advantage of peat fuels. The cost of thermal energy obtained from burning 1 ton of peat briquettes is 2 times cheaper than when using coal, 3 times cheaper than gas, and 4 times cheaper than fuel oil. Peat fuel is suitable for use in all types of modern solid fuel combustion devices, which increases the prospect of its implementation on the domestic and foreign fuel markets. The technology for using plant biomass as a filler in peat briquettes and granules developed. Special attention paid to wood, buckwheat husk, sunflower and other grain crops, which have a lower ash content and a higher heat of combustion, the potential of which waste is significant, and the fuel characteristics are able to increase the heat of combustion of composite peat briquettes or peat granules and reduce their ash content. Taking into account that peat used in large quantities as fertilizer for agriculture, a technology developed according to which humic substances first removed from peat for fertilizer, and then biomass added to this peat and a composite peat fuel obtained. This technology involves the integration of technology and extraction of humic substances into the production cycle of a peat briquette plant for the production of composite fuel. The wide implementation of the developed technology of composite peat briquettes at peat briquette factories will allow to increase the production of briquettes by almost 2 times without increasing the consumption of peat raw materials and to produce peat fuel in the range of 0.18-0.2% of geological reserves, which is equivalent to the replacement of more than 1 billion m3 of natural gas. All this allows us to draw a conclusion about the positioning of peat fuel as an effective local type of fuel, which is an alternative to gas and coal.
这篇文章认为泥炭是一种有效的替代燃料。介绍并分析了其在世界和乌克兰的储量和使用方向。分析表明,乌克兰泥炭的地质储量相当于6000亿立方米的天然气。泥炭的主要储量集中在波兰的地区。工业泥炭提取可以在12个地区进行:沃林、里夫纳、日托米尔、基辅、切尔卡西、波尔塔瓦、苏梅、切尔尼耶夫、赫梅利尼茨基、捷尔诺波尔、利沃夫和伊万诺-弗兰科夫斯克。研究表明,与传统的能源载体相比,泥炭燃料的燃烧热较低,灰分含量相当高,但在燃烧过程中几乎不排放有毒物质,因此对环境的污染要小得多。在家庭炉中,泥炭燃料比煤燃烧效率更高,灰烬用作肥料。根据近年来的数据,对各类燃料较低燃烧热1Gj的估算成本表明,泥炭燃料具有明显的优势。燃烧1吨泥煤型煤获得的热能成本比使用煤炭便宜2倍,比使用天然气便宜3倍,比燃料油便宜4倍。泥炭燃料适用于各种现代固体燃料燃烧装置,增加了其在国内外燃料市场上的应用前景。开发了利用植物生物质作为泥炭型煤和颗粒填料的技术。特别关注木材、荞麦壳、向日葵等粮食作物,这些作物灰分含量较低,燃烧热较高,废弃物潜力显著,燃料特性能够提高复合泥炭型煤或泥炭颗粒的燃烧热,降低其灰分含量。考虑到泥炭被大量用作农业肥料,开发了一种技术,根据该技术,首先从泥炭中去除腐殖物质作为肥料,然后将生物质添加到泥炭中并获得复合泥炭燃料。这项技术涉及将技术和腐殖质物质的提取整合到泥炭型煤厂的生产周期中,以生产复合燃料。开发的复合泥炭型煤技术在泥炭型煤工厂的广泛应用,可以在不增加泥炭原料消耗的情况下,将煤型煤的产量提高近2倍,生产的泥炭燃料占地质储量的0.18-0.2%,相当于替代超过10亿立方米的天然气。所有这些都使我们得出一个结论,泥炭燃料的定位是一种有效的地方类型的燃料,它是天然气和煤炭的替代品。
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引用次数: 0
RESEARCH OF BURNING OF AGRICULTURAL PELLETS IN BOILERS WITH CAPACITY UP TO 25 kW 25千瓦以下锅炉中农业颗粒燃烧的研究
Pub Date : 2022-08-17 DOI: 10.31472/ttpe.3.2022.10
O. Lysenko, H. M. Veremiichuk, O. Siryi
The main purpose of this research is to determine the main dependence’s of the agricultural pellets combustion process and to study the influence of regime parameters on the distribution of temperatures in the combustion chamber, as well as to analyze the biofuels productivity characteristics. Research methods: experimental and theoretical. Results. The research of biofuel combustion process was carried out at the experimental facility of solid fuel boiler with a pellet burner for a passive type house heating. During experimental researches samples of wood pellets, rapeseed pellets and beets pulp were used. On the received graphs the changes in the temperature state of the combustion chamber at the stage of pelletʼs ignition, burning and fading were reflected. It was found that the largest increase in temperature occurs near the wall of the boiler, which is opposite to the burner. As can be seen on the graphs, temperature fluctuations occur as a result of the periodic burning of biofuel in the burner and the arrival of a new portion of pellet from the hopper. As the experiments showed, the temperature level at burning of rapeseed pellets is much lower than in comparison with wood pellets, and to go to the established mode of burning of beet pulp pellets is generally problematic. It is obvious that when setting up the fuel supply system and modes of operation of the fuel it is necessary to take into account heat physical characteristics of fuel, first of all moisture and heat capacity, as well as yield of volatile combustible components. For this purpose, a gas analysis was carried out when burning wood pellets. The selection of combustion products was done in the wild immediately after the boiler. As a result, the NOx and CO concentrations of the appropriate temperature were obtained at the sample site. The nitrogen oxide concentrations should be considered moderate, which cannot be argued about the concentration of carbon monoxide, which requires further research. The obtained results can be used to increase the efficiency of combustion process at burning biofuel in boilers of low power communal and industrial heat power, social-budget sphere and individual-household sector.
本研究的主要目的是确定农业颗粒燃烧过程的主要依赖性,研究制度参数对燃烧室温度分布的影响,并分析生物燃料的生产力特征。研究方法:实验与理论。结果。在被动式住宅供暖用固体燃料锅炉颗粒燃烧器实验装置上,对生物燃料燃烧过程进行了研究。实验采用木屑颗粒、油菜籽颗粒和甜菜粕为样品。接收到的图像反映了颗粒着火、燃烧和褪色阶段燃烧室温度状态的变化。结果表明,温度升高幅度最大的是与燃烧器相对的锅炉壁面。从图中可以看出,由于生物燃料在燃烧器中周期性燃烧和从料斗中到达新颗粒的一部分,温度波动会发生。实验表明,油菜籽颗粒燃烧时的温度水平远低于木屑颗粒,而进入甜菜浆颗粒的既定燃烧模式通常是有问题的。显然,在设置燃料供应系统和燃料的操作方式时,必须考虑燃料的热物理特性,首先是水分和热容量,以及挥发性可燃组分的产量。为此,在燃烧木屑颗粒时进行了气体分析。燃烧产物的选择在锅炉建成后立即在野外进行。结果,得到了样品现场适当温度下的NOx和CO浓度。氮氧化物的浓度应该被认为是适中的,这不能与一氧化碳的浓度争论,这需要进一步的研究。所得结果可用于提高低功率公共和工业热电锅炉、社会预算领域和个人家庭部门燃烧生物燃料的燃烧过程的效率。
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引用次数: 0
APPLICATION OF DIMPLES AND HELICAL GROOVES ON THE OUTTER SURFACE OF TUBES TO INCREASE THERMAL-HYDRAULIC EFFICIENCY OF TUBE BUNDLES AT CROSS FLOW 在管壁外表面采用凹窝和螺旋槽提高管束横向流动的热工效率
Pub Date : 2022-07-25 DOI: 10.31472/ttpe.3.2022.11
А.А. Khalatov, І.І. Borisov, G. Kovalenko, M. Muliarchuk
The flow structure and thermo-hydraulic efficiency of cross flow of tube bundles with dimples and helical grooves have been analyzed. The Reynolds number range (103-104) was typical for industrial heat exсhangers. It was found that dimples and grooves decrease scientifically the cylinder wake area and reduces the hydraulic losses. The heat transfer augmentation in five-row tube bundle by dimples is 35-40% while pressure drop increase by 10-15%. The hydraulic resistance of two-row bundle of tube with helical grooves is 20% lower than that of a smooth tube bundle, while heat transfer augmentation is absent. The value of Reynolds analogy factor for tube bundles with dimples and helical grooves exceeds unity. The high thermo-hydraulic efficiency of tube bundles with dimples and helical grooves, allows us to recommend it for practical use in the development of modern heat exchange equipment of the tubular type.
分析了带凹窝和螺旋槽的管束交叉流的流动结构和热工效率。雷诺数范围(103-104)是典型的工业换热器。结果表明,凹窝和凹槽能科学地减小缸尾面积,降低水力损失。五排管束的增热效果为35 ~ 40%,压降提高10 ~ 15%。螺旋槽双排管束的水力阻力比光滑管束低20%,且没有强化传热作用。带凹窝和螺旋槽的管束的雷诺数类比系数大于1。具有凹窝和螺旋槽的管束具有很高的热工效率,因此我们推荐它在现代管式热交换设备的开发中实际使用。
{"title":"APPLICATION OF DIMPLES AND HELICAL GROOVES ON THE OUTTER SURFACE OF TUBES TO INCREASE THERMAL-HYDRAULIC EFFICIENCY OF TUBE BUNDLES AT CROSS FLOW","authors":"А.А. Khalatov, І.І. Borisov, G. Kovalenko, M. Muliarchuk","doi":"10.31472/ttpe.3.2022.11","DOIUrl":"https://doi.org/10.31472/ttpe.3.2022.11","url":null,"abstract":"The flow structure and thermo-hydraulic efficiency of cross flow of tube bundles with dimples and helical grooves have been analyzed. The Reynolds number range (103-104) was typical for industrial heat exсhangers. It was found that dimples and grooves decrease scientifically the cylinder wake area and reduces the hydraulic losses. The heat transfer augmentation in five-row tube bundle by dimples is 35-40% while pressure drop increase by 10-15%. The hydraulic resistance of two-row bundle of tube with helical grooves is 20% lower than that of a smooth tube bundle, while heat transfer augmentation is absent. The value of Reynolds analogy factor for tube bundles with dimples and helical grooves exceeds unity. The high thermo-hydraulic efficiency of tube bundles with dimples and helical grooves, allows us to recommend it for practical use in the development of modern heat exchange equipment of the tubular type.","PeriodicalId":23079,"journal":{"name":"Thermophysics and Thermal Power Engineering","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79628721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
METHANATION TECHNOLOGIES FOR PRODUCING SYNTHETIC RENEWABLE METHANE 生产合成可再生甲烷的甲烷化技术
Pub Date : 2022-07-22 DOI: 10.31472/ttpe.3.2022.6
V. M. Klimenko, T. Suprun
Methanation, or the generation of synthetic methane through the combination of carbon dioxide and hydrogen, has been attracting more and more attention of researchers and energy scientists in recent years due to the fact that the development of an effective and economically feasible technology for the implementation of this process will allow solving a number of energy and environmental problems. First, it is the accumulation of excess renewable electricity from solar and wind power plants by using it in the creation of another energy-intensive product, namely synthetic natural gas, which removes the problem of coordinating unstable sources of electricity with energy networks. Secondly, methanation becomes another technology for enriching biogas and turning it into biomethane, which will allow it to be used through existing gas networks and contribute to solving the problem of natural gas shortage. The development and improvement of methanation technologies are engaged in many organizations of the world - Germany, Denmark, France, the USA, Japan and others. Research is conducted in two main directions: catalytic methanation and biological methanation. In the first direction, methanation is carried out through the Sabatier reaction using catalysts. The problems of such methanation are: the development of catalysts with high activity, selectivity and resistance to the heat of reaction, the provision of optimal reaction modes, in particular temperature and pressure, through the use of various methods of reactor cooling, control of the reaction mechanism, the use of three-phase reactors, changing their structure, and so on. Biological methanation is carried out using of biological methanogens - so-called archaea, which act as a kind of catalyst. The methanation is carried out either directly in the biomass anaerobic digestion reactor (in-situ methanation) or in a separate reactor into which biogas and hydrogen are fed separately (ex-situ methanation). One of the main problems of in-situ methanation is the simultaneous provision of optimal conditions for both acetoclastic and hydrogenotrophic methanogens. This problem is solved by ex-situ methanation, in which the optimal conditions for anaerobic digestion and methanation processes are provided separately. It is clear that optimal conditions are also provided for biomethanation of pure CO2 and H2, when the «broth» for archaea is created separately. A comparison of catalytic and biological methanation technologies shows that catalytic methanation provides higher energy efficiency and requires much smaller reactor sizes than biological methanation for the same methane yield. However, the latter has a higher resistance to harmful impurities than the catalytic one.
甲烷化,或通过二氧化碳和氢气的结合产生合成甲烷,近年来已经吸引了越来越多的研究人员和能源科学家的关注,因为开发一种有效的和经济上可行的技术来实施这一过程将允许解决许多能源和环境问题。首先,利用太阳能和风能发电厂产生的多余可再生电力来制造另一种能源密集型产品,即合成天然气,从而消除了不稳定电力来源与能源网络协调的问题。其次,甲烷化成为另一种富集沼气并将其转化为生物甲烷的技术,这将使其能够通过现有的天然气网络使用,有助于解决天然气短缺的问题。德国、丹麦、法国、美国、日本等世界上许多组织都在从事甲烷化技术的开发和改进。研究方向主要有两个:催化甲烷化和生物甲烷化。在第一个方向上,甲烷化是通过使用催化剂的Sabatier反应进行的。这种甲烷化的问题是:开发具有高活性、选择性和抗反应热的催化剂,提供最佳的反应模式,特别是温度和压力,通过使用各种反应器冷却方法,控制反应机理,使用三相反应器,改变其结构,等等。生物甲烷化是利用生物产甲烷菌——所谓的古细菌——作为一种催化剂来进行的。甲烷化可以直接在生物质厌氧消化反应器中进行(原位甲烷化),也可以在单独的反应器中进行,其中沼气和氢气分别进料(非原位甲烷化)。原位甲烷化的主要问题之一是同时为丙酮裂解菌和氢营养型甲烷菌提供最佳条件。非原位甲烷化解决了这一问题,其中厌氧消化和甲烷化过程分别提供了最佳条件。很明显,当古菌的“肉汤”单独产生时,也为纯CO2和H2的生物甲烷化提供了最佳条件。催化甲烷化和生物甲烷化技术的比较表明,催化甲烷化提供了更高的能源效率,并且在相同的甲烷产量下需要的反应器尺寸要小得多。然而,后者对有害杂质的抗性比催化型高。
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引用次数: 1
DEVELOPMENTS TO INCREASE THE EFFICIENCY OF HEAT SUPPLY IN THE THERMAL POWER INDUSTRY 在火电工业中提高供热效率的发展
Pub Date : 2022-07-22 DOI: 10.31472/ttpe.3.2022.7
V. Demchenko, A. Konyk, N. D. Pogorelova
In the conditions of military operations taking place on the territory of Ukraine, the reliability of the heat supply system is of particular importance. The destruction of engineering infrastructure, targeted destruction of energy supply sources and fuel blackmail carried out by the Russian Federation leads to the emergence of significant problems of providing heat to urban agglomerations. At the state level, heat supply should be considered as an integral part of national energy security. Ukraine has a unique chance to transform the heat supply system and bring it up to modern European requirements. Therefore, choosing the right strategy for the development of a reliable and stable heat supply system of the country is an urgent scientific and technical problem. The modern and post-war reconstruction of the Ukrainian energy sector is, above all, the implementation of initiatives that are already being implemented in the EU countries. It should be noted that Europe seeks to reduce dependence on Russian fossil fuels by rapidly transitioning to clean energy and joining efforts to achieve a more sustainable energy system. The purpose of this work is to conduct an analysis and substantiation of proposals for ensuring a stable heat supply of infrastructure facilities and urban agglomerations in the conditions of hostilities, emergency situations and further transformation of the heat energy industry of Ukraine in accordance with the standards of the European Union. An assessment of factors affecting energy security and operational reliability of centralized heat supply systems was carried out. Technical solutions are proposed, which allow to ensure the coordinated and stable operation of heat supply systems with the involvement of the latest developments of equipment and technologies of the ITTF of the National Academy of Sciences of Ukraine. Application of these developments can be implemented in heat supply systems in a short period of time. Suggestions and rationale for their use are also provided.
在乌克兰领土上进行军事行动的情况下,供热系统的可靠性尤为重要。俄罗斯联邦对工程基础设施的破坏、对能源供应来源的有针对性的破坏和对燃料的讹诈导致出现了向城市聚集区提供热能的重大问题。在国家层面,供热应被视为国家能源安全的重要组成部分。乌克兰有一个独特的机会来改造供热系统,使其达到现代欧洲的要求。因此,选择合适的战略发展一个可靠稳定的国家供热系统是一个迫切需要解决的科学技术问题。乌克兰能源部门的现代和战后重建首先是实施欧盟国家已经实施的倡议。应当指出的是,欧洲正在寻求通过迅速过渡到清洁能源和共同努力实现更可持续的能源系统来减少对俄罗斯化石燃料的依赖。这项工作的目的是对在敌对行动和紧急情况下确保基础设施和城市群的稳定供热的建议进行分析和证实,并根据欧洲联盟的标准进一步改造乌克兰的热能工业。对集中供热系统能源安全和运行可靠性的影响因素进行了评估。提出了技术解决方案,以确保供热系统的协调和稳定运行,并参与乌克兰国家科学院国际乒联设备和技术的最新发展。这些发展的应用可以在短时间内在供热系统中实施。还提供了使用它们的建议和理由。
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引用次数: 0
DETERMINATION OF KINETIC CHARACTERISTICS OF SOLID FUEL. 固体燃料动力学特性的测定。
Pub Date : 2022-07-21 DOI: 10.31472/ttpe.3.2022.9
V. Chmel, I. Novikova
The combustion process begins with the ignition of the fuel - bringing it to the auto-ignition temperature, which is one of the important components of the kinetic characteristics of the fuel. Fuel ignition does not occur immediately - but after a certain period, during which activation energy is accumulated: heat or active centers, depending on the mechanism of the process - thermal-kinetic or chain-kinetic, sufficient to overcome the potential barrier. At the same time, the period of reaching the self-ignition temperature is the induction period of this reactive system: for self-ignition or the ignition time during ignition. The purpose of the work is to substantiate the kinetic characteristics of the fuel: self-ignition temperature and induction period, methods of their experimental determination for solid fossil fuels and biomass waste. According to the methodology, an installation was created for the experimental determination of the self-ignition temperature and the induction period of solid fuel in the layer. Studies of such fuels as anthracite, hard coal, buckwheat husk, millet, oats, flax husks, birch wood, peat, and paper showed the dependence of the self-ignition temperature on the degree of metamorphosis and volatiles. With an increase in the degree of metamorphism and a decrease in volatiles in solid fuel, the self-ignition temperature increases. However, the self-ignition temperature does not depend on the size of its particles, their number in the layer and the temperature of the oxidizer. The above allows us to conclude that the self-ignition temperature depends only on the conditions of heat exchange (accordingly, on aerodynamics), and the absolute value of the auto-ignition temperature for an infinite space, in the absence of a jet stream, is a constant value, and only then, in the presence of heat exchange (with velocity gradients) , takes one or another value. It was found that the induction period depends only on the initial temperature of the process, the induction period decreases with increasing temperature. This is due to the more intensive transfer of heat to the fuel particles due to the increase in the temperature gradient and the acceleration of the development of the oxidation reaction. The induction period, as shown by the conducted experiments, does not depend on the size of the particles. This can be explained only by the fact that the rate of thermal destruction of the fuel is close to the rate of its heating. The burning time of coal particles, on the contrary, depends on the size of its particles. Expressions for determining the autoignition temperature and the induction period were obtained based on the processing of the results of the conducted experiments. The results of the work can be used in combustion technologies, in which self-ignition of fuel is one of the main components of the process - it ensures combustion in the self-ignition mode of fuel when in contact with an oxidizer.
燃烧过程从燃料点火开始,使其达到自燃温度,这是燃料动力学特性的重要组成部分之一。燃料点火不是立即发生,而是经过一段时间,在此期间,活化能积累:热量或活性中心,取决于过程的机制-热动力学或链动力学,足以克服势垒。同时,达到自燃温度的时间即为该反应体系的诱导期,即为自燃或着火时的着火时间。这项工作的目的是证实燃料的动力学特性:自燃温度和诱导期,以及固体化石燃料和生物质废物的实验测定方法。根据该方法,建立了一个装置,用于实验测定层内固体燃料的自燃温度和诱导期。对诸如无烟煤、硬煤、荞麦壳、小米、燕麦、亚麻壳、桦木、泥炭和纸张等燃料的研究表明,自燃温度与变质程度和挥发物有关。随着变质程度的增加和固体燃料中挥发物的减少,自燃温度升高。然而,自燃温度并不取决于其颗粒的大小,它们在层中的数量和氧化剂的温度。以上可以使我们得出结论,自燃温度仅取决于热交换条件(相应地,取决于空气动力学),并且在没有急流的无限空间中,自燃温度的绝对值是一个恒定值,只有在存在热交换(具有速度梯度)时,才取一个或另一个值。结果表明,诱导期仅与工艺初始温度有关,随着温度的升高,诱导期逐渐减小。这是由于温度梯度的增加和氧化反应发展的加速使热量更密集地传递到燃料颗粒。所进行的实验表明,诱导期不取决于颗粒的大小。这只能用燃料的热破坏率接近其升温率这一事实来解释。相反,煤颗粒的燃烧时间取决于其颗粒的大小。在对实验结果进行处理的基础上,得到了自燃温度和引燃周期的确定表达式。这项工作的结果可以用于燃烧技术,其中燃料自燃是该过程的主要组成部分之一-它确保燃料在与氧化剂接触时以自燃模式燃烧。
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引用次数: 0
KINETIC CHARACTERISTICS OF DRYING DROPLETS OF APPLE JUICE AND COMPOSITIONS BASED ON THEM WITH MILK PROTEINS 苹果汁干燥液滴的动力学特性及其与乳蛋白的合成
Pub Date : 2022-07-11 DOI: 10.31472/ttpe.3.2022.4
K. Maletska, L.Yu. Avdieieva, T.Ya. Turchyna, A. Makarenko
Recently, the demand for concentrates and dry powders from natural fruit and berry raw materials has been growing in the food industry. Spray drying is a method that is widely used to increase the shelf life of food products. However, obtaining dry concentrates from clarified, unclarified juices, as well as juices with pulp, by the spraying method has certain difficulties. This is due to the fact that apple juices and purees contain a complex of organic acids (malic, citric, etc.) in combination with a large number of simple carbohydrates. These substances are the main factors of the viscoplastic state of the dried particles in the heated air in the drying chamber. Thermoplastic (adhesive) properties of the material to be dried in the chamber of the spray dryer and hygroscopic in the state of dried powders complicate the conditions for their timely removal from the chamber, separation, unloading, and storage. As a result, the presence of such properties worsens the organoleptic and physicochemical characteristics of dry powders, reduces product yield, and also complicates the operating conditions of drying equipment. The use of structuring additives of various types, which include protein products of various origins, contributes to the improvement of drying conditions. The aim of the work was to study the kinetic characteristics of dehydration of drops of apple juice and compositions with milk proteins in order to determine the feasibility of their use as structuring additives for the preparation of powdered health products based on apple juice by spraying. The research results showed the expediency of using a complex of skim milk proteins and whey protein concentrate as structuring additives. It has been proven that their use improves the structuring and vapor-conducting properties of the material during drying, due to which it is possible to obtain powder products with minimal final moisture while preserving valuable bioactive components.  
近年来,食品工业对天然水果和浆果原料的浓缩物和干粉的需求不断增长。喷雾干燥是一种被广泛用于增加食品保质期的方法。然而,用喷雾法从澄清的、未澄清的果汁和有果肉的果汁中获得干浓缩物有一定的困难。这是因为苹果汁和苹果汁含有一种复合的有机酸(苹果酸、柠檬酸等)和大量的简单碳水化合物。这些物质是干燥室内加热空气中干燥颗粒粘塑性状态的主要因素。在喷雾干燥机的腔室中干燥的物料的热塑性(粘接)特性和干燥粉末状态下的吸湿性使其及时从腔室中取出、分离、卸载和储存的条件复杂化。因此,这些性质的存在恶化了干粉的感官和物理化学特性,降低了产品收率,也使干燥设备的操作条件复杂化。使用各种类型的结构添加剂,其中包括各种来源的蛋白质产品,有助于改善干燥条件。本研究的目的是研究苹果汁滴剂和乳蛋白组成物的脱水动力学特性,以确定其作为结构添加剂用于以苹果汁为基础的粉状保健品喷雾制备的可行性。研究结果表明,采用脱脂乳蛋白和浓缩乳清蛋白的复合物作为结构添加剂是方便的。事实证明,它们的使用改善了干燥过程中材料的结构和导汽性能,因此有可能以最小的最终水分获得粉末产品,同时保留有价值的生物活性成分。
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引用次数: 0
LOW CARBON ENERGY 2. Hydrogen energy: problems, achievements, possible risks (review) 低碳能源2。氢能:问题、成就、可能存在的风险(回顾)
Pub Date : 2022-06-15 DOI: 10.31472/ttpe.3.2022.5
B. Basok, Ye.T. Baseyev
Ways to reduce the carbon capacity of Ukraine's economy through the active use of energy efficiency measures in energy, extensive use of renewable energy sources, in particular hydrogen, with possible problems and risks of transition to low-carbon energy. The aim of the work is to assess the contribution of hydrogen use in the perspective of achieving decarbonized energy of Ukraine, taking into account the advantages, available achievements and obstacles to the movement of the economy on this path. To this end, estimates of energy efficiency of primary energy resources according to the EROEI indicator, in particular, renewable energy sources; indicators of environmental friendliness of basic energy resources according to specific (per unit of energy) greenhouse gas emissions are given; IEA data on the volume of global investments in energy efficiency are presented. The main scientific and technical results of recent times in the field of research on the processes of production, transportation and end use of hydrogen, obtained by teams from a number of institutes of the National Academy of Sciences of Ukraine. The problems of hydrogen energy are in the focus of close attention of scientists in the country. The use of Ukrainian nuclear power plants for hydrogen production is considered. Particular attention is paid to the materials of the draft Hydrogen Strategy of Ukraine until 2050, according to which the volume of hydrogen production in the final period of implementation will be up to 330 billion nm3 annually. The risks of formation and development of energy at RES are assessed, the optimal scenarios of the country's economic development are considered.
通过积极使用能源效率措施,广泛使用可再生能源,特别是氢,减少乌克兰经济碳容量的方法,以及向低碳能源过渡可能存在的问题和风险。这项工作的目的是在考虑到经济在这条道路上发展的优势、现有成就和障碍的情况下,从实现乌克兰脱碳能源的角度评估氢使用的贡献。为此目的,根据EROEI指标估计初级能源的能源效率,特别是可再生能源;根据单位能源温室气体排放量给出了基础能源环境友好性指标;本文介绍了国际能源机构关于全球能源效率投资量的数据。最近在氢气生产、运输和最终使用过程研究领域的主要科学和技术成果,由乌克兰国家科学院的一些研究所的团队获得。氢能问题是全国科学家密切关注的焦点。考虑使用乌克兰核电站生产氢气。特别关注乌克兰到2050年氢战略草案的材料,根据该草案,在实施的最后阶段,氢气产量将达到每年3300亿立方米。对可再生能源的形成和开发风险进行了评估,并考虑了该国经济发展的最佳方案。
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Thermophysics and Thermal Power Engineering
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