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Eco-Friendly Microwave Assisted Green Synthesis, Characterization and Antibacterial Activity of Silver Nanoparticles 纳米银的微波辅助绿色合成、表征及抗菌活性研究
Pub Date : 2019-06-11 DOI: 10.30799/JNST.246.19050402
D. Kumar, A. Tiwari, Neelam
This paper deals a novel method for the synthesis of silver nanoparticles (AgNPs) by microwave assisted approach using silver nitrate and trisodium citrate. The formation of nanoparticles was confirmed by UV-visible spectral studies. Particle size and morphology was determined by P-XRD and HR-TEM studies which revealed the average particle size of synthesized nanoparticles 21.49 and 20.08 nm respectively with spherical shape. The synthesized nanoparticles were screened for antibacterial activity in vitro against gram-positive bacteria Staphylococcus aureus and Bacillus subtilis and gram-negative bacteria Escherichia coli and Klebsiella pneumoniae by adopting disk diffusion method. The results of antibacterial studies exhibited that AgNPs were potential antibacterial agent.
研究了以硝酸银和柠檬酸三钠为原料,微波辅助合成纳米银的新方法。紫外可见光谱研究证实了纳米颗粒的形成。通过P-XRD和HR-TEM研究了纳米颗粒的粒径和形貌,结果表明,合成的纳米颗粒平均粒径分别为21.49 nm和20.08 nm,呈球形。采用圆盘扩散法对合成的纳米颗粒体外对革兰氏阳性菌金黄色葡萄球菌和枯草芽孢杆菌以及革兰氏阴性菌大肠杆菌和肺炎克雷伯菌的抑菌活性进行了筛选。抗菌研究结果表明,AgNPs是潜在的抗菌药物。
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引用次数: 1
Green Synthesis and Characterization of Silver Nanoparticles using Ethanol Extract of Myristica fragrans (Nutmeg) and Its Biological Applications 肉豆蔻乙醇提取物绿色合成纳米银及其生物学应用研究
Pub Date : 2019-06-08 DOI: 10.30799/JNST.S02.19050309
P. Malini, V. Premalatha, S. Rani
Silver nanoparticles have been synthesized from the ethanol extract of Myristica fragrans seed. The synthesized nanoparticles were characterized by UV-visible, FT-IR, XRD, SEM, TEM and AFM spectral studies. Formation of silver nanoparticles conform through colour change from pale yellow to brown when ethanol extract of Myristica fragrans was added dropwise to silver nitrate. The appearance of brown color in aqueous solution is due to excitation of surface plasmon vibrations of silver nanoparticles observed between 400 – 450 nm. Peak corresponding to 1741 cm -1 confirms the presence of aldehyde groups in the ethanol extract of Myristica fragrans which is responsible for the capping and stabilization of biosynthesised. AEM images of silver nanoparticles exhibit uniformly distributed, well defined regular nanostructures. Silver nanoparticles showed significant antibacterial action on both the gram classes of gram-negative Escherichia coli and gram-negative bacteria Bacillus cereus .
以香肉豆蔻种子乙醇提取物为原料合成了纳米银。通过紫外可见光谱、红外光谱、XRD、SEM、TEM和原子力显微镜对合成的纳米颗粒进行了表征。在硝酸银中滴入香豆汁乙醇提取物后,其颜色由淡黄色变为褐色,从而形成纳米银颗粒。水溶液中棕色的出现是由于在400 - 450 nm之间观察到的银纳米粒子表面等离子激元振动的激发。对应于1741 cm -1的峰证实了香豆蔻醇提取物中醛基团的存在,醛基团对生物合成的封顶和稳定起作用。银纳米粒子的AEM图像显示出均匀分布、定义良好的规则纳米结构。银纳米颗粒对革兰氏阴性大肠杆菌和革兰氏阴性蜡样芽孢杆菌均有明显的抗菌作用。
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引用次数: 3
CO2 Sequestration by Thermophiles with Ethanol Production 嗜热菌在乙醇生产中的CO2固存作用
Pub Date : 2019-06-08 DOI: 10.30799/JESPR.162.19050203
Bhatia Ruchi, Kataria Rosy, B. Tripti
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引用次数: 0
Biosynthesis of Cobalt Oxide Nanoparticles - A Short Review 氧化钴纳米颗粒的生物合成研究进展
Pub Date : 2019-06-07 DOI: 10.30799/JNST.S01.19050308
S. Alwin David, V. Veeraputhiran, C. Vedhi
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引用次数: 8
Effect of Laser Induced Potassium Oxalate (C2K2O4) Nanopowder 激光诱导草酸钾纳米粉体的制备效果
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S22.19050302
J. Thabithal, N. Ravi
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引用次数: 0
Synthesis and Characterization of CdS/Polypyrrole Core/Shell Nanocomposites with Controlled Grain Size 可控粒径CdS/聚吡咯核/壳纳米复合材料的合成与表征
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S09.19050306
G. Manohari, M. D. Sweetlin
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 04 June 2019 Many challenges of core/shell nanostructures for various applications still exist. The structure including the diameter, length, spacing and the thickness of the core or shell is difficult to control precisely. Metal nanoparticles used as various types of catalysts adsorbents and sensors. They have applications in optical, electronic and magnetic devices. Majority of these applications significantly depend on the size of the nanoparticles. Therefore, the synthesis of nanoparticles with controlled grain size is important. In the present work, Cadmium sulfide (CdS) was used as the core material which coated by the polypyrrole (PPy). To form the core and the shell set, the diameter fixed and measured theoretically. The calculated amount is used to prepare the shell which is formed by addition polymerization. The XRD studies are used to determine the particle size of the core shell nanocomposite. The average particle size of CdS and CdS/PPy is 13 nm and 15 nm respectively. Fourier transform infrared (FTIR) spectra and UV-Vis spectra are used to characterize the structure and to calculate the band gap of the core/shell nanocomposite. The AFM studies give the surface morphology of the samples.
文章历史:收到2019年3月20日接受2019年4月29日在线提供2019年6月4日核/壳纳米结构在各种应用中的许多挑战仍然存在。芯或壳的直径、长度、间距和厚度等结构难以精确控制。金属纳米颗粒用作各种类型的催化剂、吸附剂和传感器。它们在光学、电子和磁性设备中都有应用。这些应用中的大多数很大程度上取决于纳米颗粒的大小。因此,合成具有可控粒径的纳米颗粒具有重要的意义。本文以硫化镉(cd)为芯材,采用聚吡咯(PPy)包覆。为了形成芯和壳的集合,对直径进行了理论上的固定和测量。计算出的量用于制备加成聚合形成的壳。采用XRD研究确定了核壳纳米复合材料的粒径。CdS和CdS/PPy的平均粒径分别为13 nm和15 nm。利用傅里叶变换红外光谱(FTIR)和紫外可见光谱(UV-Vis)表征了核/壳纳米复合材料的结构,并计算了其带隙。原子力显微镜研究给出了样品的表面形貌。
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引用次数: 4
Single Step Synthesis of Poly(o-Anisidine) Lignosulfonate Composite Protected Silver Nanoparticles and Study of Their Application on Reduction of Nitrophenol and Textile Dyes 聚(o-茴香胺)木素磺酸酯复合保护纳米银的一步合成及其在还原硝基酚和纺织染料中的应用研究
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S23.19050303
D. M. Soundari, K. Pandian
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 04 June 2019 Lignosulfonate doped poly(o-anisidine) and poly(o-anisidine)/lignosulfonate polymer composite protected silver nanoparticles (AgNPs) were synthesized by interfacial polymerization method by mixing of an equal molar ratio of o-anisidine and lignosulfonate using silver nitrite as oxidizing agent. The polymerization reaction was carried out under reflux condition at 80 °C for 3 hours. The resulting AgNPs nanocomposite was isolated and then characterized by using various instrument method including UV-visible spectroscopy, FT-IR, and FE-SEM analysis. The catalytic behaviour of the polymer protected silver nanoparticle was studied for the reduction of 4-nitrophenol (4-NP) and textile dyes like methylene blue (MB) and Congo Red. The reduction of 4-nitrophenol using AgNPs/poly(o-anisidine) nanocomposite reaction follow the pseudo first order kinetics and the resulting rate constant was found to be 10 min-1 for 4.0×10-4 M concentration of 4-NP using 10 mg/L of catalyst. On the other hand, the catalytic behaviour of the nanocomposite was investigated toward the degradation of some of the textile dyes such as MB and Congo Red. The percentage of degradation of dye was monitored by UV-visible spectral studies and found to be superior to the other catalyst used for the degradation studies. The present method was employed for the effective removal of textile dyes and reduction of 4-nitrophenol with a minimum amount of catalyst.
文章历史:收到20 2019年3月接受2019年6月29日2019年4月网上04木质素磺酸盐掺杂聚(o-anisidine)和聚(o-anisidine) /木质素磺酸盐聚合物复合保护银纳米粒子(AgNPs)合成了混合界面聚合方法的相同摩尔比率的o-anisidine和木质素磺酸盐使用银亚硝酸盐作为氧化剂。聚合反应在80℃回流条件下进行,反应时间为3小时。分离得到的AgNPs纳米复合材料,并利用紫外可见光谱、FT-IR和FE-SEM等多种仪器方法对其进行了表征。研究了聚合物保护银纳米粒子对4-硝基苯酚(4-NP)和亚甲基蓝(MB)、刚果红等纺织染料的还原作用。AgNPs/聚o-茴香胺纳米复合还原4-硝基苯酚的反应符合准一级动力学,当4-NP浓度为4.0×10-4 M、催化剂用量为10 mg/L时,反应速率常数为10 min-1。另一方面,研究了纳米复合材料对MB和刚果红等纺织染料的降解催化性能。通过紫外可见光谱研究监测了染料的降解率,发现其优于用于降解研究的其他催化剂。本方法在催化剂用量最少的情况下,对纺织染料进行了有效的脱除和4-硝基酚的还原。
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引用次数: 1
Synthesis and Characterization of Pure and Gd-Doped CeO2 Nanoparticles 纯CeO2纳米颗粒的合成与表征
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S10.19050305
M. Sridaran, K. Dhanasekar, M. Arivanandhan
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引用次数: 6
Photocatalytic and Antimicrobial Activities of Polyaniline Nanocomposites with Molybdates 钼酸盐聚苯胺纳米复合材料的光催化及抗菌活性
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S11.19050304
S. Balamurugan, D. Sathya, S. Kalyanaraman, A. Pushparaj, R. Murugesan
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 04 June 2019 The present study describes the process for the formation of PANI nanocomposite incorporated with metal (Cd, Bi, Ba) molybdates of binary metal oxide. The PANI and its nanocomposites were prepared by 0.1 M aniline in 100 mL of 1 M sulphuric acid in the presence or absence of 50 mg of metal molybdate by chemical polymerization using 0.1 M APS as oxidant in 100 mL of 1 M sulphuric acid. The polymerisation yields are increased due to incorporation of metal molybdates. The growth of polymerization is also enhanced. The interaction of metal molybdates into PANI matrix leads to increase in very high conductivity, heavy interaction between the two-polymer chain lead to increase in stability of the polymer. In the incorporation of metal molybdate into the polymer matrix leads to increase in conductivity of about 5, 4 and 2 times with respect to the original sample (PANI) as in PANI-CdMoO4, PANI-BiMoO4 and PANI-BaMoO4 respectively. The incorporation of metal molybdates is confirmed by XRD and UV-VIS spectral studies. The XRD studies are also suggested the presence of chemical interaction between polymer chain and incorporated metal molybdates. The antimicrobial activity of the synthesized material PANI and PANI-nanocomposites were tested against four bacteria, Escherichia coli, Staphylococcus aureus, P. aeruginosa and Proteus vulgaris using disc diffusion method. The nanocomposite doped polymer possesses excellent antibacterial property. The results on MB dye degradation showed that PANI-SO4/CdMoO4 photocatalyst, under visible light degraded 80.2 % of MB dye after 180 min. The photo-degradation study, thus, suggests that the light absorption of PANI and catalytic role of CdMoO4 could be coupled for high photo-catalytic functionality. This work opens a new avenue for the design of new modified photo-catalysts with high activity for the large-scale water treatment and other applications.
文章历史:2019年3月20日接收2019年4月29日接受2019年6月4日在线提供2019年6月4日本研究描述了与金属(Cd, Bi, Ba)钼酸盐的二元金属氧化物结合的聚苯胺纳米复合材料的形成过程。以0.1 M苯胺为氧化剂,在100 mL 1 M硫酸中,以0.1 M APS为氧化剂,在50 mg钼酸盐存在或不存在的情况下,在100 mL 1 M硫酸中进行化学聚合,制备聚苯胺及其纳米复合材料。由于金属钼酸盐的掺入,聚合收率提高了。聚合的生长也得到了增强。金属钼酸盐与聚苯胺基体的相互作用增加了聚合物的高导电性,双聚合物链之间的相互作用增加了聚合物的稳定性。金属钼酸盐掺入聚合物基体后,其电导率比原样品(PANI)分别提高了约5倍、4倍和2倍,如PANI- cdmoo4、PANI- bimoo4和PANI- bamoo4。通过XRD和UV-VIS光谱研究证实了金属钼酸盐的掺入。XRD研究表明,聚合物链与掺入的金属钼酸盐之间存在化学相互作用。采用圆盘扩散法测定合成的聚苯胺及其纳米复合材料对大肠杆菌、金黄色葡萄球菌、铜绿假单胞菌和寻常变形杆菌的抑菌活性。纳米复合掺杂聚合物具有优异的抗菌性能。对MB染料的降解结果表明,PANI- so4 /CdMoO4光催化剂在可见光下180 min后对MB染料的降解率为80.2%。因此,光降解研究表明,PANI的光吸收和CdMoO4的催化作用可以耦合在一起,从而获得较高的光催化功能。本研究为设计新型改性高活性光催化剂用于大规模水处理及其他应用开辟了新的途径。
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引用次数: 0
Photocatalytic Activity of Pure and Nickel Doped Cadmium Sulphide Nanoparticles Synthesized via Co-Precipitation Method 共沉淀法合成纯和掺杂镍的硫化镉纳米颗粒的光催化活性
Pub Date : 2019-06-06 DOI: 10.30799/JNST.S21.19050301
A. Leena, K. Raji
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 04 June 2019 Cadmium sulfide is an important group of II-VI semiconducting nanomaterials with excellent physical properties and wide bandgap energy, are successful in the utilization of photocatalytic application. Photo technology is one of important technology to solve environmental and energy issues. Incorporating a transition metal ion dopant into CdS nanocrystalline is a convenient way to tailor its physical properties. In this present work, we have synthesized transition metal ion nickel doped CdS nanocrystals via coprecipitation method. The objective of this research is to investigate the photocatalytic activity of pure and nickel doped CdS nanocrystals for the degradation of methylene blue and to provide an experimental base for further study and practical application in textile effluent and wastewater treatment processes. Many factors can influence the performance of photocatalytic activity such as phase composition, crystallite size, morphology, and energy gap. The structural and optical properties of as-synthesized materials were studied by XRD, EDAX, SEM, UV, PL, and FTIR. Photocatalytic degradation of methylene blue was performed by using nickel doped CdS nanoparticles in a photoreactor vessel irradiated by visible light from the tungsten lamp (λmax=400 nm).
硫化镉是一类重要的II-VI型半导体纳米材料,具有优异的物理性能和宽能带能,在光催化应用中得到了成功的利用。光技术是解决环境和能源问题的重要技术之一。在CdS纳米晶体中加入过渡金属离子掺杂剂是调整其物理性质的一种方便方法。本文采用共沉淀法合成了过渡金属离子镍掺杂的CdS纳米晶体。研究纯镉纳米晶和掺杂镍镉纳米晶在降解亚甲基蓝中的光催化活性,为进一步研究和在纺织废水处理中的实际应用提供实验基础。影响光催化活性的因素很多,如相组成、晶粒大小、形貌和能隙等。通过XRD、EDAX、SEM、UV、PL和FTIR等手段对合成材料的结构和光学性能进行了研究。在可见光(λmax=400 nm)照射下,利用掺杂镍的CdS纳米颗粒在光反应器容器中进行了亚甲基蓝的光催化降解。
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引用次数: 2
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