首页 > 最新文献

World of Oil products the Oil Companies Bulletin最新文献

英文 中文
How to certify reference materials: by voting or by exact weights 如何认证参考材料:通过投票还是通过精确的权重
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-20-26
A. B. Kopiltsova, B. Tarasov, U. A. Kopiltsov
The problems of using reference materials (RM) of oil and petroleum products humidity is discussed for different programs of certification: according to accuracy of the preparation procedure (RM-PP), according to the results of the interlaboratory studies (RM-INTERLAB) and using reference methods (RM-RM). Similar NIST samples (SRM 2271 and 272) were used for comparison. The problem of using CO-INTERLAB for control the accuracy of standard methods is the absence of the true value, this task is not even raised. "Accuracy control" has a different emphasis in this situation: RM-INTERLAB allow to select, "voting by majority" among the general population of the laboratory and cut the others. Therefore, their main application is qualification tasks. This approach is basically incorrect for analyzers. In the case of RM-PP and RM-RM, the main problem is the difference in the composition of real samples and ideal matrices of RM’s. Their main application is the control the accuracy of the analyzers in the absence of interfering influences. The "cheap" RM’s production technologies do not allow the omprehensive control of the real oil samples. The complication of oil technologies and the use of heavy oils in refining could provide the progress in RM’s.
针对不同的认证方案:根据制备程序的准确性(RM- pp),根据实验室间研究的结果(RM- interlab)和使用参考方法(RM-RM),讨论了使用石油和石油产品湿度标准物质(RM)的问题。相似的NIST样本(SRM 2271和272)用于比较。使用CO-INTERLAB来控制标准方法的准确度的问题是没有真实值,这个任务甚至没有被提出。“准确性控制”在这种情况下有不同的重点:RM-INTERLAB允许选择,在实验室的一般人群中“多数投票”,并削减其他人。因此,它们的主要应用是鉴定任务。对于分析器来说,这种方法基本上是不正确的。在RM- pp和RM-RM的情况下,主要问题是RM的实际样本和理想矩阵的组成不同。它们的主要应用是在没有干扰影响的情况下控制分析仪的精度。“廉价”RM的生产技术不允许对真实的油样进行全面控制。炼油技术的复杂性和重油在炼制中的应用为炼油技术的发展提供了动力。
{"title":"How to certify reference materials: by voting or by exact weights","authors":"A. B. Kopiltsova, B. Tarasov, U. A. Kopiltsov","doi":"10.32758/2071-5951-2021-1-4-20-26","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-1-4-20-26","url":null,"abstract":"The problems of using reference materials (RM) of oil and petroleum products humidity is discussed for different programs of certification: according to accuracy of the preparation procedure (RM-PP), according to the results of the interlaboratory studies (RM-INTERLAB) and using reference methods (RM-RM). Similar NIST samples (SRM 2271 and 272) were used for comparison. The problem of using CO-INTERLAB for control the accuracy of standard methods is the absence of the true value, this task is not even raised. \"Accuracy control\" has a different emphasis in this situation: RM-INTERLAB allow to select, \"voting by majority\" among the general population of the laboratory and cut the others. Therefore, their main application is qualification tasks. This approach is basically incorrect for analyzers. In the case of RM-PP and RM-RM, the main problem is the difference in the composition of real samples and ideal matrices of RM’s. Their main application is the control the accuracy of the analyzers in the absence of interfering influences. The \"cheap\" RM’s production technologies do not allow the omprehensive control of the real oil samples. The complication of oil technologies and the use of heavy oils in refining could provide the progress in RM’s.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82529736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of technology for producing base oil and environmentally friendly petroleum plasticizer 基础油及环保型石油增塑剂生产技术的发展
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-26-30
V. I. Zuber, V. R. Nigmatullin, R. Nigmatullin, D. A. Perkhutkin
The article relates to the field of chemical technology and can be used in oil refining. The article reveals a method for producing base oils with a low sulfur content, environmentally friendly aromatic fillers and plasticizers of rubber and rubber, including selective purification of oil fractions of oil with a selective solvent, separation of the extract and raffinate solutions of the first stage, while the extract solution of the first stage is cooled, followed by separation in the settling tank of the pseudo-raffinate solution of the first stage, a raffinate solution of the first stage after solvent regeneration is dewaxed and oxidized, followed by extraction of the oxidized dewaxed oil to obtain raffinate and extract solutions of the second stage, from the raffinate solution of the second stage after solvent regeneration and subsequent adsorption or hydrotreatment, a base oil of group II with a low sulfur content is obtained, while the extract solution of the second stage is mixed with a pseudo-paraffinate solution of the first stage to obtain after solvent regeneration, an environmentally friendly aromatic filler and plasticizer of rubber and rubber with a polyaromatic hydrocarbon content of less than 2.9%.
本文涉及化工技术领域,可用于石油炼制。本文揭示了一种生产低硫含量基础油、环保型芳香填料和橡胶增塑剂的方法,包括用选择性溶剂对油的油馏分进行选择性纯化,将第一级萃取液和萃余液分离,同时将第一级萃取液冷却,然后在第一级伪萃余液沉淀池中分离。将溶剂再生后的第一级萃余液进行脱蜡氧化,将氧化后的脱蜡油进行萃取,得到第二级萃余液和萃取液,由溶剂再生后的第二级萃余液进行吸附或加氢处理,得到含硫量低的II族基础油。而将第二期的萃取液与第一期的伪石蜡溶液混合,经溶剂再生后得到多芳烃含量小于2.9%的环保型橡胶和橡胶芳香族填料和增塑剂。
{"title":"Development of technology for producing base oil and environmentally friendly petroleum plasticizer","authors":"V. I. Zuber, V. R. Nigmatullin, R. Nigmatullin, D. A. Perkhutkin","doi":"10.32758/2071-5951-2021-0-3-26-30","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-0-3-26-30","url":null,"abstract":"The article relates to the field of chemical technology and can be used in oil refining. The article reveals a method for producing base oils with a low sulfur content, environmentally friendly aromatic fillers and plasticizers of rubber and rubber, including selective purification of oil fractions of oil with a selective solvent, separation of the extract and raffinate solutions of the first stage, while the extract solution of the first stage is cooled, followed by separation in the settling tank of the pseudo-raffinate solution of the first stage, a raffinate solution of the first stage after solvent regeneration is dewaxed and oxidized, followed by extraction of the oxidized dewaxed oil to obtain raffinate and extract solutions of the second stage, from the raffinate solution of the second stage after solvent regeneration and subsequent adsorption or hydrotreatment, a base oil of group II with a low sulfur content is obtained, while the extract solution of the second stage is mixed with a pseudo-paraffinate solution of the first stage to obtain after solvent regeneration, an environmentally friendly aromatic filler and plasticizer of rubber and rubber with a polyaromatic hydrocarbon content of less than 2.9%.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"60 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79578645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Digital monitoring system of equipment for the analysis of fuel and lubricants quality 燃油和润滑油质量分析设备数字监控系统
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-54-59
V. R. Nigmatullin, I. R. Nigmatullin, R. Nigmatullin, A. Migranov
Currently, to increase the efficiency of industrial production, high-performance and expensive technological equipment is increasingly used, in which the weakest link, from the point of view of efficiency and reliability, is the components and parts of heavily loaded tribo – couplings operating both at significantly different temperatures (conditionally under lighter conditions, the temperature difference can be 100-120 degrees) and climatic conditions (high humidity, the presence of abrasives and other chemical elements in the atmosphere). As the results of the analysis of the frequency of failures of friction units and, accordingly, the cost of their restoration reach 9-20 percent of the cost of all equipment, without taking into account significant losses of income (profit) of the enterprise from downtime. The solution of this problem is based on the study of the wear rate of friction units by the wear products accumulated in working oils, cooling lubricants, and greases. A digital equipment monitoring system (DSMT) has been developed and implemented, which includes dynamic recording of the number of wear products and oil temperature by original modern recording devices, followed by the technology of their processing and use. The system also includes methods for finding the necessary information in large data sets useful and necessary in theoretical and practical terms with a similar technique controlled by a digital monitoring system. The advantages of SMT are the ability to predict the reliability of the equipment; reduce production risks and significantly reduce inefficient costs.
目前,为了提高工业生产的效率,越来越多地使用高性能和昂贵的技术设备,从效率和可靠性的角度来看,其中最薄弱的环节是重载摩擦联轴器的组件和部件,它们在明显不同的温度(有条件地在较轻的条件下,温差可达100-120度)和气候条件(高湿,高温和高温)下运行。(大气中磨料和其他化学元素的存在)。根据对摩擦单元故障频率的分析结果,相应的,其修复成本达到所有设备成本的9- 20%,而不考虑企业因停机而造成的重大收入(利润)损失。这一问题的解决是基于对工作油、冷却润滑剂和润滑脂中积累的磨损产物对摩擦单元磨损率的研究。开发并实现了一套数字设备监测系统(DSMT),该系统包括由原始的现代记录设备动态记录磨损产品的数量和油温,然后对其进行处理和使用技术。该系统还包括在理论和实践方面有用和必要的大型数据集中查找必要信息的方法,采用由数字监测系统控制的类似技术。SMT的优点是能够预测设备的可靠性;降低生产风险,显著降低低效成本。
{"title":"Digital monitoring system of equipment for the analysis of fuel and lubricants quality","authors":"V. R. Nigmatullin, I. R. Nigmatullin, R. Nigmatullin, A. Migranov","doi":"10.32758/2071-5951-2021-1-4-54-59","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-1-4-54-59","url":null,"abstract":"Currently, to increase the efficiency of industrial production, high-performance and expensive technological equipment is increasingly used, in which the weakest link, from the point of view of efficiency and reliability, is the components and parts of heavily loaded tribo – couplings operating both at significantly different temperatures (conditionally under lighter conditions, the temperature difference can be 100-120 degrees) and climatic conditions (high humidity, the presence of abrasives and other chemical elements in the atmosphere). As the results of the analysis of the frequency of failures of friction units and, accordingly, the cost of their restoration reach 9-20 percent of the cost of all equipment, without taking into account significant losses of income (profit) of the enterprise from downtime. The solution of this problem is based on the study of the wear rate of friction units by the wear products accumulated in working oils, cooling lubricants, and greases. A digital equipment monitoring system (DSMT) has been developed and implemented, which includes dynamic recording of the number of wear products and oil temperature by original modern recording devices, followed by the technology of their processing and use. The system also includes methods for finding the necessary information in large data sets useful and necessary in theoretical and practical terms with a similar technique controlled by a digital monitoring system. The advantages of SMT are the ability to predict the reliability of the equipment; reduce production risks and significantly reduce inefficient costs.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"161 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72865875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Overview of modern multifunctional gasoline additives. Market, key components, and methods for evaluating their effectiveness 现代多功能汽油添加剂综述。市场,关键组成部分,以及评估其有效性的方法
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-42-53
M. Ershov, V. D. Savelenko, N. Shvedova, D. V. Tokareva, D. Potanin, I. Khabibullin, I. V. Klokova
The article provides an analysis of scientific and technical publications (articles and patents) on the components of multifunctional additives for gasoline, their chemistry and development companies. According to the detergent component, for the first time, based on the analysis of these documents, an integral assessment of the effectiveness of active substances on various elements of the fuel system is given. The article summarizes the current requirements for the content of detergent additives in gasoline of the leading manufacturers, provides standards and currently used methods for evaluating the effectiveness of detergent components. The issues of the market of multifunctional additives are considered by summarizing the marketing statements of the leading Russian and world oil companies, which allows us to draw conclusions about the principal component composition of additives used in commercial branded gasoline. The cost and quantitative assessment of the market of multifunctional additives and branded gasoline is given. The relevance of the topic and this review is high because it given the almost complete absence of gasoline with domestic multifunctional additives on the Russian market. The review will be useful both for specialists involved in the development and testing of multifunctional additives and branded gasoline, and for employees of oil companies (regional sales departments) responsible for promoting new branded fuels to the market.
本文对汽油多用添加剂的成分及其化学和开发公司的科技出版物(文章和专利)进行了分析。根据去污剂成分,在对这些文献进行分析的基础上,首次对活性物质对燃料系统各元件的有效性进行了综合评价。本文综述了目前主要生产厂家对汽油中洗涤剂添加剂含量的要求,提供了评价洗涤剂成分有效性的标准和目前常用的方法。通过总结俄罗斯和世界领先的石油公司的营销声明,考虑了多功能添加剂市场的问题,这使我们能够得出关于商业品牌汽油中使用的添加剂的主要成分组成的结论。给出了多功能添加剂和牌号汽油市场的成本和定量评价。鉴于俄罗斯市场上几乎完全没有使用国产多功能添加剂的汽油,本课题和本综述的相关性很高。对于参与开发和测试多功能添加剂和品牌汽油的专家,以及负责向市场推广新品牌燃料的石油公司(区域销售部门)的雇员来说,这项审查将是有用的。
{"title":"Overview of modern multifunctional gasoline additives. Market, key components, and methods for evaluating their effectiveness","authors":"M. Ershov, V. D. Savelenko, N. Shvedova, D. V. Tokareva, D. Potanin, I. Khabibullin, I. V. Klokova","doi":"10.32758/2071-5951-2021-1-4-42-53","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-1-4-42-53","url":null,"abstract":"The article provides an analysis of scientific and technical publications (articles and patents) on the components of multifunctional additives for gasoline, their chemistry and development companies. According to the detergent component, for the first time, based on the analysis of these documents, an integral assessment of the effectiveness of active substances on various elements of the fuel system is given. The article summarizes the current requirements for the content of detergent additives in gasoline of the leading manufacturers, provides standards and currently used methods for evaluating the effectiveness of detergent components. The issues of the market of multifunctional additives are considered by summarizing the marketing statements of the leading Russian and world oil companies, which allows us to draw conclusions about the principal component composition of additives used in commercial branded gasoline. The cost and quantitative assessment of the market of multifunctional additives and branded gasoline is given. The relevance of the topic and this review is high because it given the almost complete absence of gasoline with domestic multifunctional additives on the Russian market. The review will be useful both for specialists involved in the development and testing of multifunctional additives and branded gasoline, and for employees of oil companies (regional sales departments) responsible for promoting new branded fuels to the market.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"102 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78228359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Energy efficiency is the future 能源效率是未来
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-53-56
S. L. Egorov, D. S. Balyuk
The share of energy costs in the structure of specific costs for the production of oil refining enterprises comprises about 25–30%, which means that increasing energy efficiency is a real opportunity to significantly reduce costs and, accordingly, increase competitiveness. Therefore, the implementation of the energy saving program at such a large industrial enterprise as Slavneft-YANOS PJSC saves hundreds of millions of rubles a year.
在炼油企业生产的具体成本结构中,能源成本所占的份额约为25-30%,这意味着提高能源效率是一个真正的机会,可以显著降低成本,从而提高竞争力。因此,在Slavneft-YANOS PJSC这样的大型工业企业实施节能计划每年节省数亿卢布。
{"title":"Energy efficiency is the future","authors":"S. L. Egorov, D. S. Balyuk","doi":"10.32758/2071-5951-2021-0-4-53-56","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-0-4-53-56","url":null,"abstract":"The share of energy costs in the structure of specific costs for the production of oil refining enterprises comprises about 25–30%, which means that increasing energy efficiency is a real opportunity to significantly reduce costs and, accordingly, increase competitiveness. Therefore, the implementation of the energy saving program at such a large industrial enterprise as Slavneft-YANOS PJSC saves hundreds of millions of rubles a year.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72980871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Repair department of the enterprise: today and tomorrow 维修部门的企业:今天和明天
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-30-35
D. Kuchin, L.V. Lypko
this article reviews the development of the repair and mechanical department of SLAVNEFT-YANOS PJSC since the foundation of the enterprise to the present day. Thanks to its own repair production, expansion of its functionality, reliable, trouble-free and uninterrupted operation of all units of the oil refinery is ensured.
本文回顾了SLAVNEFT-YANOS PJSC公司自成立至今的维修机械部的发展历程。由于其自身的维修生产,扩大了其功能,确保了炼油厂所有装置的可靠,无故障和不间断运行。
{"title":"Repair department of the enterprise: today and tomorrow","authors":"D. Kuchin, L.V. Lypko","doi":"10.32758/2071-5951-2021-0-4-30-35","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-0-4-30-35","url":null,"abstract":"this article reviews the development of the repair and mechanical department of SLAVNEFT-YANOS PJSC since the foundation of the enterprise to the present day. Thanks to its own repair production, expansion of its functionality, reliable, trouble-free and uninterrupted operation of all units of the oil refinery is ensured.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86131604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mixed esters of xanthogenic acids containing carbonyl, dithiocarbamine and thiocyane group and their research as additives improving tribological characteristics 含羰基、二硫代氨基和硫代氰基的黄原酸混合酯及其作为改善摩擦学特性添加剂的研究
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-60-64
B. Musayeva, V. Farzaliyev, G. G. Ismayilova, N. Novotorzhina, M. Šafářová
On the basis of environmentally friendly raw materials of glycerol, by its interaction with monochloroacetic acid, 1,2,3-(trichloroacetyl)triglyceride was synthesized, which is used for further syntheses of xanthogenic acid derivatives containing a number of functional groups  dithiocarbamic, thiocyanic. The reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium alkylxanthate in a ratio of 1:1 and 1:2 gave 1-butylxanthogenatoacetoxy-2,3-(dichloroacetoxy) propane and 1,3-di(alkylxanthogenatoacetoxy)-2-chloroacetoxypropane. Mixed esters of xanthogenic acid containing dithiocarbamic and thiocyanic groups were synthesized by the interaction of 1,2,3-(trichloroacetyl) triglyceride in the corresponding sequence, first with sodium diethyl dithiocarbamate, with potassium butylxanthate, as a result 1-butylxanthogenatoacetoxy-2-chloracetoxy-3-(diethyldithiocarbamatoacetoxy) propane. Sequential reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium rhodanide with potassium butylxanthate gave 1-butylxanthogenatoacetoxy-2-chloroacetoxy-3-(thiocyanatoacetoxy)propane. The structure of the synthesized compounds has been proven by IR spectroscopy. The compounds have been tested as additives to improve the tribological characteristics of oils and have been shown to be effective.
在环保原料甘油的基础上,通过其与一氯乙酸的相互作用,合成了1,2,3-(三氯乙酰)甘油三酯,该甘油三酯用于进一步合成含有多个官能团的黄原酸衍生物。1,2,3-(三氯乙酰基)甘油三酯与烷基黄药钾按1:1和1:2的比例反应得到1-丁基黄原乙酰氧基-2,3-(二氯乙酰氧基)丙烷和1,3-二(烷基黄原乙酰氧基)-2-氯乙酰氧基丙烷。采用1,2,3-(三氯乙酰基)甘油三酯依次与二乙基二硫代氨基甲酸钠、丁基黄药钾相互作用,合成了含二硫代氨基和硫氰基的黄原酸混合酯,得到1-丁基黄原乙酰氧基-2-氯乙酰氧基-3-(二乙基二硫代氨基乙氧基)丙烷。1,2,3-(三氯乙酰基)甘油三酯与rhodanide钾和丁基黄药钾序贯反应得到1-丁基黄药乙氧基-2-氯乙氧基-3-(硫氰酸乙氧基)丙烷。所合成化合物的结构经红外光谱分析证实。这些化合物已被测试作为添加剂,以改善油的摩擦学特性,并已被证明是有效的。
{"title":"Mixed esters of xanthogenic acids containing carbonyl, dithiocarbamine and thiocyane group and their research as additives improving tribological characteristics","authors":"B. Musayeva, V. Farzaliyev, G. G. Ismayilova, N. Novotorzhina, M. Šafářová","doi":"10.32758/2071-5951-2021-1-4-60-64","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-1-4-60-64","url":null,"abstract":"On the basis of environmentally friendly raw materials of glycerol, by its interaction with monochloroacetic acid, 1,2,3-(trichloroacetyl)triglyceride was synthesized, which is used for further syntheses of xanthogenic acid derivatives containing a number of functional groups  dithiocarbamic, thiocyanic. The reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium alkylxanthate in a ratio of 1:1 and 1:2 gave 1-butylxanthogenatoacetoxy-2,3-(dichloroacetoxy) propane and 1,3-di(alkylxanthogenatoacetoxy)-2-chloroacetoxypropane. Mixed esters of xanthogenic acid containing dithiocarbamic and thiocyanic groups were synthesized by the interaction of 1,2,3-(trichloroacetyl) triglyceride in the corresponding sequence, first with sodium diethyl dithiocarbamate, with potassium butylxanthate, as a result 1-butylxanthogenatoacetoxy-2-chloracetoxy-3-(diethyldithiocarbamatoacetoxy) propane. Sequential reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium rhodanide with potassium butylxanthate gave 1-butylxanthogenatoacetoxy-2-chloroacetoxy-3-(thiocyanatoacetoxy)propane. The structure of the synthesized compounds has been proven by IR spectroscopy. The compounds have been tested as additives to improve the tribological characteristics of oils and have been shown to be effective.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"35 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88231208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A study of thermal and antiwear properties of the oil compositions involving a condensed alkylphenol detergent additive 含缩合烷基酚洗涤剂添加剂的油组合物的热性能和抗磨性能的研究
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-22-25
A. S. Medzhibovskiy, A. Kolokolnikov, S.N. Zibrova
The current paper presents further studies of the oils’ operational properties (detergent properties mostly) of those oils which contain a highly alkaline condensed alkylphenol detergent additive. In this text thermal and antiwear properties of oils containing various detergents were discussed. Thermal properties of different oil compositions were evaluated when heated in a Q-derivatograph (under a dynamic mode). Weight loss of the oil sample due to its evaporation and the temperature of the end of evaporation were estimated. It was revealed that the most stable is sample 3, containing K-38 additive. This sample had the highest evaporation start temperature (275°C compared to 269, 286, 262°C of the samples 4,1,2 respectively) as well as the highest end of evaporation temperature (579°C compared to 558°C (samples 1 and 4) and 555°C of sample 2). The antiwear properties were studied on a friction machine (roller-block type). The test results have shown a high efficiency of the oils containing a new highly alkaline K-38 additive.
本文进一步研究了含高碱性浓缩烷基酚洗涤剂添加剂的油品的操作性能(主要是洗涤剂性能)。本文讨论了含各种洗涤剂的油品的热性能和抗磨性能。在q衍生仪(动态模式下)加热时,评估了不同油组分的热性能。估计了油样蒸发后的失重量和蒸发结束时的温度。结果表明,含K-38添加剂的样品3最稳定。该样品具有最高的蒸发起始温度(275℃,而样品4、1、2的蒸发起始温度分别为269、286、262℃)和最高的蒸发结束温度(579℃,而样品1和4的蒸发起始温度为558℃,样品2的蒸发结束温度为555℃)。在摩擦机上(滚轮式)研究了其抗磨性能。试验结果表明,新型高碱性K-38添加剂对油品的收率较高。
{"title":"A study of thermal and antiwear properties of the oil compositions involving a condensed alkylphenol detergent additive","authors":"A. S. Medzhibovskiy, A. Kolokolnikov, S.N. Zibrova","doi":"10.32758/2071-5951-2021-0-3-22-25","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-0-3-22-25","url":null,"abstract":"The current paper presents further studies of the oils’ operational properties (detergent properties mostly) of those oils which contain a highly alkaline condensed alkylphenol detergent additive. In this text thermal and antiwear properties of oils containing various detergents were discussed. Thermal properties of different oil compositions were evaluated when heated in a Q-derivatograph (under a dynamic mode). Weight loss of the oil sample due to its evaporation and the temperature of the end of evaporation were estimated. It was revealed that the most stable is sample 3, containing K-38 additive. This sample had the highest evaporation start temperature (275°C compared to 269, 286, 262°C of the samples 4,1,2 respectively) as well as the highest end of evaporation temperature (579°C compared to 558°C (samples 1 and 4) and 555°C of sample 2). The antiwear properties were studied on a friction machine (roller-block type). The test results have shown a high efficiency of the oils containing a new highly alkaline K-38 additive.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78020143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Public joint stock company Slavneft-YANOS. Development history 公共股份公司Slavneft-YANOS。发展历史
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-5-12
T. P. Shmeleva, A. Morozov, E. A. Zaiko, I. S. Budakhina, V. S. Stanyulis
the article reviews the stages of enterprise establishment, its modern achievements, as well as deve-lopment prospects and plans for the modernization of production. Currently, the public joint-stock company slavneft yaroslavnefteorgsintez (SLAVNEFT-YANOS PJSC; YANOS) is one of the largest oil refineries in russia. The structure of the enterprise includes main and auxiliary production. The main activity of SLAVNEFT-YANOS PJSC is a production of high-quality commercial oil products and petrochemicals by means of efficient processing of crude oil. the plant produces more than 40 types of products: motor gasolines and disel fuel of euro 5 standard, fuel for jet engines, a wide range of oils (industrial, turbine, compressor, base oils), bitumen (road, roofing, construction), tar, asphalt, paraffin-wax products, aromatic hydrocarbons, liquefied fuel gases and heating fuel oil. High technological level of production, the use of the latest russian and foreign achievements in the field of oil refining, continuous modernization of equipment ensure the competitiveness of SLAVNEFT-YANOS petroleum products in russian and foreign markets.
文章回顾了企业成立的各个阶段、取得的现代化成就以及生产现代化的发展前景和规划。目前,公共股份公司slavneft yaroslavnefteorgsintez (slavneft - yanos PJSC;YANOS是俄罗斯最大的炼油厂之一。企业结构分为主辅两部分。SLAVNEFT-YANOS PJSC的主要业务是通过原油的有效加工生产高质量的商业石油产品和石化产品。该工厂生产40多种产品:欧5标准的汽车汽油和柴油,喷气发动机燃料,各种油(工业,涡轮,压缩机,基础油),沥青(道路,屋顶,建筑),焦油,沥青,石蜡产品,芳烃,液化燃料油和加热燃料油。高技术水平的生产,使用最新的俄罗斯和国外在炼油领域的成就,不断现代化的设备,确保SLAVNEFT-YANOS石油产品在俄罗斯和国外市场的竞争力。
{"title":"Public joint stock company Slavneft-YANOS. Development history","authors":"T. P. Shmeleva, A. Morozov, E. A. Zaiko, I. S. Budakhina, V. S. Stanyulis","doi":"10.32758/2071-5951-2021-0-4-5-12","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-0-4-5-12","url":null,"abstract":"the article reviews the stages of enterprise establishment, its modern achievements, as well as deve-lopment prospects and plans for the modernization of production. Currently, the public joint-stock company slavneft yaroslavnefteorgsintez (SLAVNEFT-YANOS PJSC; YANOS) is one of the largest oil refineries in russia. The structure of the enterprise includes main and auxiliary production. The main activity of SLAVNEFT-YANOS PJSC is a production of high-quality commercial oil products and petrochemicals by means of efficient processing of crude oil. the plant produces more than 40 types of products: motor gasolines and disel fuel of euro 5 standard, fuel for jet engines, a wide range of oils (industrial, turbine, compressor, base oils), bitumen (road, roofing, construction), tar, asphalt, paraffin-wax products, aromatic hydrocarbons, liquefied fuel gases and heating fuel oil. High technological level of production, the use of the latest russian and foreign achievements in the field of oil refining, continuous modernization of equipment ensure the competitiveness of SLAVNEFT-YANOS petroleum products in russian and foreign markets.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89281382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of reaction time on the process of upgrading heavy oils in the presence and in the absence of oil soluble catalysts at 250 ° C 250℃条件下油溶性催化剂存在和不存在情况下反应时间对重油提质过程的影响
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-29-34
M. Suwaid, A. Al-Muntaser, N.I. Abdaljalil, M. Varfolomeev, R. Djimasbe, M. M. Saleh, A. Alfarttoosi
This work presents the possibility of improving the quality of heavy oil during in-situ upgrading using oil-soluble catalysts based on copper (copper oleate) at 250 ° C under high pressure for 12, 24, 48 and 72 hours using a 300 ml stainless steel batch reactor. Different technique analyzes for heavy oil befor and after upgrading were carried out: Analysis of the evolved gas components by gas chromatography, determination of the group composition of oil (SARA analysis), measurement of viscosity, gas chromatographic analysis of saturated hydrocarbons. The results showed that with an increase in the time of experiments and the use of oil-soluble catalysts, the content of saturated fractions increases due to a decrease in the content of resins and asphaltenes, which leads to a decrease in viscosity of heavy oil from 2073.7 to 1290.5 mPa.s. According to the obtained results, it can be said that reaction time and the use of an oil-soluble catalyst increase the efficiency of the in-situ upgrading.
这项工作展示了在原位升级过程中使用基于铜(油酸铜)的油溶性催化剂在250°C高压下使用300 ml不锈钢间歇式反应器进行12、24、48和72小时提高重油质量的可能性。对改造前后的稠油进行了不同的技术分析:气相色谱法分析演化出的气体组分,测定油的族组成(SARA分析),粘度测量,饱和烃气相色谱分析。结果表明:随着实验时间的延长和油溶性催化剂的使用,树脂和沥青质含量降低,饱和馏分含量增加,稠油粘度从2073.7降低到1290.5 mPa.s;根据得到的结果,可以说反应时间和油溶性催化剂的使用提高了原位升级的效率。
{"title":"Effect of reaction time on the process of upgrading heavy oils in the presence and in the absence of oil soluble catalysts at 250 ° C","authors":"M. Suwaid, A. Al-Muntaser, N.I. Abdaljalil, M. Varfolomeev, R. Djimasbe, M. M. Saleh, A. Alfarttoosi","doi":"10.32758/2071-5951-2021-1-4-29-34","DOIUrl":"https://doi.org/10.32758/2071-5951-2021-1-4-29-34","url":null,"abstract":"This work presents the possibility of improving the quality of heavy oil during in-situ upgrading using oil-soluble catalysts based on copper (copper oleate) at 250 ° C under high pressure for 12, 24, 48 and 72 hours using a 300 ml stainless steel batch reactor. Different technique analyzes for heavy oil befor and after upgrading were carried out: Analysis of the evolved gas components by gas chromatography, determination of the group composition of oil (SARA analysis), measurement of viscosity, gas chromatographic analysis of saturated hydrocarbons. The results showed that with an increase in the time of experiments and the use of oil-soluble catalysts, the content of saturated fractions increases due to a decrease in the content of resins and asphaltenes, which leads to a decrease in viscosity of heavy oil from 2073.7 to 1290.5 mPa.s. According to the obtained results, it can be said that reaction time and the use of an oil-soluble catalyst increase the efficiency of the in-situ upgrading.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89597330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
World of Oil products the Oil Companies Bulletin
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1