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First Report of Field Remediation of Contaminated Tailings from the Collapsed Fundão Dam in Brazil 巴西fundo溃坝污染尾矿现场修复首次报道
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.163
M. Scotti, S. Avila, L. Mendes, Tomás J Lacerda, S. Silva, Arthur Antão, Alessandra R Gomes, Mirelli B Medeiros, Stael Alvarenga, C. H. Santos, E. Rigobelo
The failure of the Fundão dam in Brazil spilled contaminated sediments to the Doce river basin with high levels of pH,ether-amine and sodium. In the present study, it was established a riparian forest over contaminated sediment using two main remediation strategies: phytoremediation with native species to the Atlantic Forest, previously selected for tolerance to the sediment toxicity, and physico-chemical remediation by management of the sediment with incorporation of OM. In the experimental site (ES), 12 native species were cultivated under two treatments: T1management of the sediments with incorporation of OM and T2nonmanaged sediment + superficial deposition of OM. The results were compared with a degraded site (DS) affected by the contaminated sediments and a preserved site (PS) composed of a fragment of preserved Atlantic Forest. After 6 month of transplanting, plants from T1 showed a better height growth performance (up to 3m) and survival index in relation to T2, as well as a significant decline of etheramine and sodium contents. Besides the improvement of soil fertility, the amendment with OM promoted a pH reduction, favoring ether-amine destabilization, sodium sequestration and improvement of soil microbial populations. Soil nitrification was improved as revealed by the significant increase of nitrate which seems to have favoured the rampant growth of tolerant plant species after 6 months of planting. Therefore, it is recommended the incorporation of OM to the sediment and phytoremediation with selected tolerant species to remediate sodium and ether-amine toxicity.
巴西fund o大坝的故障将受污染的沉积物泄漏到多塞河流域,这些沉积物的pH值、醚胺和钠含量都很高。在本研究中,通过两种主要的修复策略,在受污染的沉积物上建立了一个河岸森林:利用大西洋森林的本地物种进行植物修复,之前选择了对沉积物毒性的耐受性,以及通过结合OM管理沉积物进行物理化学修复。在试验点(ES),对12种本地植物进行了2种处理:1种是有机质管理,2种是有机质非管理+表层沉积。结果与受污染沉积物影响的退化样地(DS)和由大西洋森林保存片断组成的保存样地(PS)进行了比较。移栽6个月后,与T2相比,T1植株的高生长性能(最高可达3m)和成活指数均有所提高,醚胺和钠含量显著下降。除了提高土壤肥力外,OM的添加还促进了pH的降低,有利于醚胺的不稳定、钠的固存和土壤微生物数量的增加。种植6个月后,硝态氮显著增加,土壤硝化作用得到改善,这似乎有利于耐受性植物的猖獗生长。因此,建议在沉积物中掺入OM,并选择耐受性强的物种进行植物修复,以修复钠和醚胺毒性。
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引用次数: 0
Atomic Layer Deposition of High-k Films on Graphene Surface 高k薄膜在石墨烯表面的原子层沉积
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.136
Hyeok Jae Lee, Kangtaek Lee, Sang Woon Lee
Extended Abstract Graphene has received considerable attentions because of its unique band structure and high electron mobility (>20,000 cm/Vs). Especially, the electronic characteristics of graphene is suitable as a channel material for the high performance metal-oxide-semiconductor field effect transistor. A growth of high-k film is necessary on graphene surface for top-gated graphene transistor.[1] However, graphene has no surface functional groups such as hydroxyl groups (-OH group) except for defects and graphene edges, which caused a failure of high-k film deposition on graphene surface even using state-of-the-art thin film deposition technique, i. e., atomic layer deposition (ALD). Thus, various methods were proposed to deposit dielectric films uniformly on graphene. For example, a growth of dielectric thin film by oxidation treatment after forming a metal seed layer using physical vapor deposition (PVD). In addition, a use of perylene-tetracarboxylic acid (PTCA), and preH2O treatment were attempted. Unfortunately, impurities such as the perylene molecules remain on the graphene surface and the pre-H2O treatment and post-oxidation treatment become somewhat complicated.[2, 3] In the meantime, enhancement of nucleation sites on graphene surface using ozone degraded the chemical state of graphene because of a defect formation on the graphene.[4] However, the chemical and electrical properties of the graphene must be preserved after the growth of highk films.[5] Here, we propose a novel graphene surface treatment method that allows an enhanced nucleation and growth of high-k thin films by ALD via a graphene surface treatment using trimethylaluminum (TMA) and H2O prior to the deposition of HfO2 film on the graphene. Then, high-k thin films such as Al2O3 and HfO2 were deposited on the surface-treated graphene sample using ALD. These graphene surface treatment methods generate Al2O3 nuclei through physical adsorption on the surface of graphene, which enhanced the growth and nucleation of high-k film through ALD on the graphene surface. As a result, additional defects were not created after surface treatment on graphene and HfO2 ALD. And significant amount of Hf-C bond was observed after HfO2 ALD, which was decreased substantially with surface treatment. Nucleation delay in HfO2 ALD decreases from 70 to 10 ALD cycles with graphene surface treatment and dielectric constant of HfO2 film is higher using the surface treatment (k ~14.5) than that without the surface treatment (k ~5.6). Also, a leakage current (with a capacitor fabrication) was decreased by a factor of 10 compared to without surface treatment. The graphene surface treatment method enhanced the nucleation and the electrical properties of the HfO2 film without deteriorating the properties of graphene, thus providing promising opportunities in graphene electronics.
石墨烯因其独特的能带结构和高电子迁移率(>20,000 cm/Vs)而受到广泛关注。特别是石墨烯的电子特性适合作为高性能金属氧化物半导体场效应晶体管的沟道材料。在石墨烯表面生长高k薄膜是顶门控石墨烯晶体管的必要条件。[1]然而,石墨烯除了缺陷和石墨烯边缘外,表面没有羟基(-OH基团)等官能团,这导致即使使用最先进的薄膜沉积技术,即原子层沉积(ALD),也无法在石墨烯表面沉积高k薄膜。因此,提出了各种方法来均匀地在石墨烯上沉积介电膜。例如,在使用物理气相沉积(PVD)形成金属种子层后,通过氧化处理来生长介电薄膜。此外,还尝试了使用苝-四羧酸(PTCA)和prepre2o处理。不幸的是,像苝分子这样的杂质仍然留在石墨烯表面,并且预h2o处理和后氧化处理变得有些复杂。[2,3]同时,使用臭氧增强石墨烯表面的成核位点,由于石墨烯上形成缺陷而降低了石墨烯的化学状态[4]。然而,石墨烯的化学和电学性质必须在高薄膜生长后保持不变。[5]在这里,我们提出了一种新的石墨烯表面处理方法,在HfO2薄膜沉积在石墨烯上之前,通过三甲基铝(TMA)和水对石墨烯进行表面处理,可以增强ALD的高k薄膜的成核和生长。然后,用ALD在表面处理过的石墨烯样品上沉积Al2O3和HfO2等高k薄膜。这些石墨烯表面处理方法通过物理吸附在石墨烯表面产生Al2O3核,通过ALD在石墨烯表面增强高k膜的生长和成核。因此,在石墨烯和HfO2 ALD表面处理后不会产生额外的缺陷。HfO2 ALD后观察到大量Hf-C键,经过表面处理后明显减少。经过石墨烯表面处理后,HfO2 ALD的成核延迟从70个ALD循环减少到10个ALD循环,并且经过表面处理(k ~14.5)的HfO2膜的介电常数高于未经过表面处理(k ~5.6)的HfO2膜。此外,与未进行表面处理相比,泄漏电流(与电容器制造相比)减少了10倍。石墨烯表面处理方法增强了HfO2薄膜的成核和电学性能,而不破坏石墨烯的性能,从而为石墨烯电子学提供了有前途的机会。
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引用次数: 0
Bioremediation of Silver and Recovery of AgNPs for the Fabrication of AgNPs Functionalized Antibacterial Polycaprolactone Membrane 银的生物修复及AgNPs的回收制备AgNPs功能化抗菌聚己内酯膜
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.113
F. Ahmad, Noreen Ashraf, Yin Dachuan
Extended Abstract Heavy metals denote a group of hazardous environmental contaminants due to their toxic effects on human health in concentrations higher than the permissible limits which cause widespread concerns [1]. Silver is a precious as well as toxic heavy metal; hence, its remediation and recovery are essential for environmental sustainability and biomedical applications. So far, conventional methods, i.e., precipitation, coagulation, and ion exchange are less efficient at low metal concentrations and expensive in comparison with bioremediation of heavy metal pollutants. Therefore, the isolation of heavy metal resistant bacteria from metal contaminated sites and their use for the remediation and recovery of metals is documented [2, 3]. However, there are very few or no reports of simultaneous remediation and recovery of silver in the form of silver nanoparticles (AgNPs). Due to the chemical stability, bactericidal and optical properties of AgNPs, they are widely used in many biomedical and environmental applications [4]. In this study, we have isolated three potential bacterial strains from silver mining site (Zhashui, Shaanxi Province, China) for their potential use in silver remediation and its recovery in the form of AgNPs. The synthesized biogenic AgNPs were characterized and utilized to fabricate antibacterial membrane filter using nanofibers of polycaprolactone (PCL) functionalized with AgNPs by dissolved electrospinning method for their potential use in biomedical filtration devices. The novel bacterial strains were isolated from soil and water showing a long history of silver contamination and identified using restriction fragment length polymorphism, and through 16S DNA sequencing followed by NCBI Blast analysis. Based on preliminary experimental results, one (SMP1) out of three bacterial strains was selected for further studies. The detection and quantification of silver removal and recovery of AgNPs from spiked aqueous medium were measured by using atomic absorption spectroscopy (AAS). Synthesized AgNPs were purified through centrifugation and by the application of external voltage directly from the reaction mixture. Biogenic AgNPs were characterized by using UVspectrophotometer, dynamic light scattering (DLS), SEM and TEM. Diethyl ether was used to dissolve PCL followed by mixing of AgNPs to prepare AgNPs and PCL (AgNPs-PCL) composite, and an antibacterial AgNPs-PCL filter membrane was fabricated by using electrospinning technique. Disc diffusion method was used to access the antibacterial potential of the developed membrane filter. Results obtained showed that potentially all three isolated bacterial strains identified as Enterobacter cloacae (SMP1), Cupriavidus necator (SMP2), and Bacillus megaterium (SMP3) were highly efficient with more than 95% silver remediation efficiency. However, SMP1 was selected for further studies based on its quick and highest remediation of silver as well as high efficiency of AgNPs recovery. The
重金属是指一组有害的环境污染物,其浓度超过允许限值对人体健康产生毒性影响,引起广泛关注[1]。银是一种珍贵而有毒的重金属;因此,其修复和恢复对环境可持续性和生物医学应用至关重要。迄今为止,与重金属污染物的生物修复相比,沉淀、混凝和离子交换等传统方法在低金属浓度下效率较低,成本较高。因此,从金属污染场地中分离重金属抗性细菌及其用于金属修复和回收的研究有文献记载[2,3]。然而,很少或没有报道同时修复和回收银纳米粒子(AgNPs)的形式。由于AgNPs的化学稳定性、杀菌性能和光学性能,它们被广泛应用于许多生物医学和环境应用中[4]。在这项研究中,我们从陕西柞水的银矿区分离到了三株潜在的细菌菌株,它们可能以AgNPs的形式用于银的修复和回收。对合成的生物源AgNPs进行了表征,并利用溶解静电纺丝法将AgNPs功能化的聚己内酯(PCL)纳米纤维用于制备抗菌膜过滤器,为其在生物医学过滤装置中的潜在应用提供了技术支持。该菌株从银污染历史较长的土壤和水体中分离得到,通过限制性内切片段长度多态性、16S DNA测序和NCBI Blast分析进行鉴定。根据初步实验结果,从3株细菌中选择1株(SMP1)进行进一步研究。采用原子吸收光谱法(AAS)对加标水介质中AgNPs的除银和回收率进行了检测和定量。通过离心和直接从反应混合物中施加外部电压纯化合成的AgNPs。采用紫外分光光度计、动态光散射(DLS)、扫描电镜(SEM)和透射电镜(TEM)对AgNPs进行了表征。采用乙醚溶解PCL,再与AgNPs混合制备AgNPs和PCL (AgNPs-PCL)复合材料,并采用静电纺丝技术制备AgNPs-PCL抗菌过滤膜。采用圆盘扩散法测定膜过滤器的抑菌潜能。结果表明,阴沟肠杆菌(SMP1)、necator铜杆菌(SMP2)和megaterium芽孢杆菌(SMP3)对银的修复效率均在95%以上。然而,SMP1由于其对银的快速和最高的修复以及AgNPs的高效回收而被选中进行进一步的研究。AgNPs在1小时内的修复效率为100%。菌株(SMP1)能够在细胞表面和细胞外合成10 ~ 20 nm大小的球形和部分立方AgNPs。制备的AgNP-PCL膜过滤器对铜绿假单胞菌和大肠杆菌具有显著的杀菌潜力,且可重复使用。这种方法可能被用于修复不同的重金属污染地点和回收的纳米颗粒,这些纳米颗粒可用于各种生物医学和环境应用。
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引用次数: 0
Sewage Water as Resources for Green Energy by Using Hydro Turbines, Pumped Energy Storage, Waste and Bio Systems 利用水力涡轮机、抽水蓄能、废物和生物系统将污水作为绿色能源的资源
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.186
R. Glick
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引用次数: 0
Evaluation the Antimicrobial Activity of LDPE Nanocomposites Based on TiO2 Nanostructure for Food Packaging Applications 基于TiO2纳米结构的LDPE纳米复合材料在食品包装中的抗菌性能评价
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.122
Nasser A Al-Tayya, A. M. Youssef, R. Al-Hindi
Extended Abstract This work aims to prepare and characterize novel nanocomposite materials based on low density polyethylene (LDPE) and titanium dioxide (TiO2) nanostructure for food packaging applications. The fabricated nanocomposites films were examined by X-ray diffraction pattern (XRD) and mechanical properties. The XRD results confirmed that the formation of LDPE nanocomposites films containing different concentrations of TiO2 nanostructure. The mechanical properties of the prepared LDPE/TiO2 nanocomposites were investigated. Moreover, the thermal properties of the prepared films displayed that the good enhancement of the thermal stability of the prepared film after addition of TiO2 nanostructure. Furthermore, the permeability of oxygen transmission rate (GTR) and water vapor transmission rate (WVTR) of the prepared LDPE nanocomposites were evaluated. Moreover, the antimicrobial activity of the prepared films against gram positive (Staphylococcus aureus) bacteria and gram negative (Pseudomonas aeruginosa) bacteria were investigated.
本工作旨在制备和表征基于低密度聚乙烯(LDPE)和二氧化钛(TiO2)纳米结构的新型食品包装纳米复合材料。对制备的纳米复合材料薄膜进行了x射线衍射图(XRD)和力学性能测试。XRD结果证实,LDPE纳米复合材料薄膜中含有不同浓度的TiO2纳米结构。研究了所制备的LDPE/TiO2纳米复合材料的力学性能。此外,所制备薄膜的热性能表明,TiO2纳米结构的加入使所制备薄膜的热稳定性得到了较好的增强。此外,还对制备的LDPE纳米复合材料的透氧率(GTR)和水蒸气透过率(WVTR)进行了评价。此外,还研究了制备的膜对革兰氏阳性(金黄色葡萄球菌)细菌和革兰氏阴性(铜绿假单胞菌)细菌的抑菌活性。
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引用次数: 0
The Synthesis of Renewable Hydrocarbons from Vegetable Oil Feedstock In The Presence Of Ni-Supported Catalysts 镍负载催化剂催化植物油合成可再生碳氢化合物的研究
Pub Date : 2019-08-01 DOI: 10.11159/ICERT19.117
K. Malins
The effects of commercial Ni65%/SiO2-Al2O3 and prepared Ni10%/SiO2-Al2O3-135I Ni-supported catalysts and their amount (1.5-10%) on hydrocarbon production from rapeseed oil/it fatty acid (RO/RFA, weight ratio 1/1) feedstock were investigated. The textural properties of catalysts were characterized by N2 sorption analysis and active metal loading by XRF. The activity of catalysts was evaluated by minimum oxygen removal reaction time determined from pressure-time profiles at studied operating temperature 340 oC and initial H2 pressure of 100 bar. GC analysis of obtained hydrocarbon mixtures was used for determination of dominant hydrocarbon n-pentadecane, n-hexadecane, n-heptadecane and n-octadecane composition. Both catalyst have proper activity for complete conversion of RO/RFA into marketable hydrocarbon mixture with high yield (76.1%-83.2%), calorific value (47.20-47.24 MJ/kg) and energy recovery (ER) (90.7%-99.1%) produced at residence time ~35-52 min. Ni65%/SiO2Al2O3 has higher activity, but Ni10%/SiO2-Al2O3-135I deliver elevated yield of hydrocarbons. Both catalysts with different selectivity have a potential for practical application in hydrotreated vegetable oil production processes.
研究了Ni65%/SiO2-Al2O3工业催化剂和制备的Ni10%/SiO2-Al2O3- 135i ni负载催化剂及其用量(1.5 ~ 10%)对菜籽油/it脂肪酸(RO/RFA,重量比为1/1)产烃的影响。通过N2吸附分析和XRF负载活性金属表征催化剂的结构特性。在研究的操作温度为340℃,初始H2压力为100 bar时,通过压力-时间曲线确定最小脱氧反应时间来评价催化剂的活性。用气相色谱法测定了所制混合物中优势烃正十五烷、正十六烷、正十七烷和正十八烷的组成。两种催化剂均具有良好的活性,可将RO/RFA完全转化为可销售的烃类混合物,在35 ~ 52 min的停留时间内产生较高的产率(76.1% ~ 83.2%)、热值(47.20 ~ 47.24 MJ/kg)和能量回收率(ER)(90.7% ~ 99.1%)。Ni65%/SiO2Al2O3具有较高的活性,但Ni10%/SiO2-Al2O3-135I具有较高的烃类收率。这两种催化剂具有不同的选择性,在加氢植物油生产过程中具有实际应用的潜力。
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引用次数: 1
Inoculation of Soil Cyanobacteria Improves Fertility of a Soil Mixed With Copper Tailing Sands 接种土壤蓝藻提高铜尾矿砂混合土壤肥力
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.179
C. Ortiz, Uro Ledesma, Darlyng Pontigo
Industrial activities such as mining provoke soil degradation which can be restored by applying cyanobacteria as inoculants to promote biocrust development. However, previous to the field applications, there is a need to determine the cyanobacterial suitable species under laboratory conditions. In this investigation, a culture of Trichormus sp. isolated from environmental samples was inoculated on a soil mixed with copper tailing sands. The establishment of the cyanobacteria on the substrate was determined by confocal microscopy, and germination and growth of Polypogon australis, a tailing storage facility (TSF) natural colonizer were determined. In addition, the total nitrogen content (N), phosphorus available (P) and organic matter (OM) content of the inoculated substrates was measured after 30 days. The results showed that the cyanobacterial culture increases the speed but not the cumulative germination of P. australis, and generates an increase of available P, total N and OM of the mixed soil. The improvement in soil fertility and stability of tailing sands supports the use of cyanobacteria to restore degraded or mining polluted soils.
采矿等工业活动引起土壤退化,可以通过应用蓝藻作为接种剂来促进生物结皮的发育来恢复土壤退化。然而,在现场应用之前,有必要在实验室条件下确定合适的蓝藻种类。在本研究中,从环境样品中分离出毛霉菌培养物,接种于含铜尾矿砂的土壤中。用共聚焦显微镜测定了底物上蓝藻的建立情况,并测定了尾矿储存库(TSF)天然定植菌南方多棱菌(Polypogon australis)的萌发和生长情况。此外,接种30 d后测定基质的总氮含量(N)、速效磷含量(P)和有机质含量(OM)。结果表明,蓝藻培养提高了南洋蓟的萌发速度,但没有提高其累积萌发量,并增加了混合土壤的有效磷、全氮和OM。尾矿砂的土壤肥力和稳定性的改善支持利用蓝藻来恢复退化或采矿污染的土壤。
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引用次数: 2
Energy Refurbishment of a School Building in Ceprano, Italy 意大利塞普拉诺一所学校建筑的能源改造
Pub Date : 2019-08-01 DOI: 10.11159/ICERT19.122
C. Aureli, Claudia Rampini, A. D’Angelo
Among the adaptation measures against the climate change, energy saving in buildings is a crucial point. Detailed analysis to keep the operation of the building as well as its architectural features when listed is required. A school is selected as case study for its age of construction and potential of replicability due to its similarities for many other schools which make it an archetype. Building envelope and energy systems are the area of intervention supported by an experimental campaign to assess the status quo. Furthermore, the design complies with minimum environmental requirements by current regulation for public buildings. For the new proposed design, the target of high-efficient building is reachable even for so constrained existing building.
在适应气候变化的措施中,建筑节能是一个关键问题。详细的分析,以保持建筑物的运作,以及它的建筑特点,当上市时是必要的。一所学校被选为案例研究,因为它的建筑年代和可复制性的潜力,因为它与许多其他学校相似,使其成为一个原型。建筑围护结构和能源系统是由评估现状的实验活动支持的干预领域。此外,该设计符合现行公共建筑法规的最低环境要求。对于新提出的设计,即使现有建筑受到如此大的限制,也可以达到高效建筑的目标。
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引用次数: 0
3D Tailored Design as a Bioremediation Strategy for a Lagoon in Matanza-Riachuelo Basin 3D定制设计作为Matanza-Riachuelo盆地泻湖的生物修复策略
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.121
P. Marconi, A. Trentini, M. D. Groppa, M. Zawoznik, Carlos Nadra
Patricia Laura Marconi, Andrea Trentini, María Daniela Groppa, Myriam Zawoznik, Carlos Nadra CONICET, CEBBAD , Univ. Maimónides, Hidalgo 775, Buenos Aires, Argentina ; marconi.patricialaura@maimonides.edu; trentini.andrea@maimonides.edu CONICET, FFyB, Universidad de Buenos Aires, Junin 954, Buenos Aires, Argentina danielagroppa@gmail.com FFyB, Universidad de Buenos Aires, Junin 954, Buenos Aires, Argentina; myriamz@ffyb.uba.ar ACUMAR Esmeralda 225, Buenos Aires, Argentina cnadra@acumar.gov.ar
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引用次数: 0
Chemical Characterization of Landfill Leachate and Its Impact on the Receiving Natural Water-Body Surrounding the Naboro Landfill, Suva, Fiji Island 斐济岛苏瓦纳博罗垃圾填埋场渗滤液的化学特性及其对接收水体的影响
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.128
F. Mani, Esha Chetty, M. Maata, S. Chand
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引用次数: 0
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