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New Geopolymer Adsorbents for Phosphate Removal from DilutedSolutions and their Applications 新型地聚合物吸附剂对稀释溶液中磷酸盐的去除及其应用
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.158
T. Samarina, E. Takaluoma
Extended Abstract Phosphorus (P) in the form of phosphate, phosphate esters and hydroxylapathite is an essential element for all living organism. It therefore has a non-replaceable role in fertilizers. However, some of the phosphate ends up in water bodies from field run off water in crop production. Industrial processing releases phosphate to the environment due to the high cost of its recovery. To close the nutrient loop, new and innovative ways for more efficient phosphorus cycling is therefore urgently necessary. Moreover, depletion of world phosphate deposits “Phosphorus peak” and soil contamination through cadmium and uranium contained in fertilizers produced from raw phosphate rock, eutrophication of water bodies, and P emission to the air during mining and ore processing, make the search for alternative solutions of P recycling attractive. The wellestablished removal techniques of P from waste streams are performed by physico-chemical or by biological treatment methods as well as their combinations [1], [2]. Although most of such methods are effective for large-scale industrial or domestic wastewater treatment plants (> 400 PE), implementation of these solutions to small-scale facilities or to remote applications may not be economically or logistically feasible. In this work, we present the development of a low-cost adsorptive media for phosphate removal. The work aims to find an effective solution for production of adsorbents having high capacity and selectivity towards phosphate ions, on the one hand, but possessing uniform properties and ease of manufacturing on the other. For this purpose, the series of adsorbent compositions employing industrial by-products were developed. Industrial solid wastes such as fly ash F, blast furnace slag, and paper mill sludge with high calcium content were chosen as raw materials to be a primary source of Ca, Al and Si. Geopolymerization technique with alkaline activator was used to obtain powdered and granulated forms of adsorbents[3]. Three types of geopolymer adsorbent named fly ash F (FAF-GP), blast furnace slag (BFS-GP) and fibre sludge (FSHCa-GP) were evaluated for the adsorption of phosphate in aqueous solution. XRD and XRF methods were employed to characterize physical structure and chemical composition of primary source materials and geopolymer products. To evaluate phosphate removal efficiency of geopolymers, batch and column adsorption experiments were performed. The effect of various operating conditions, i.e. initial pH, adsorbent dose, initial phosphate concentration, and adsorption time has been studied. The adsorption process was relatively fast for FAF-GP, equilibrium has been reached at 1.5h contact time, while for BFS-GP and FSHCa-GP the maximum removal rate was achieved at 5h and 24h, resp. The isotherms look differently for all three adsorbents that reflects the different adsorption mechanisms. Capacities at phosphate concentration of 100 mg L are 26 mg PO4 g for BFS-GP, 36 mg PO4 g
磷(P)以磷酸盐、磷酸酯和羟基磷灰石的形式存在,是所有生物必需的元素。因此,它在肥料中具有不可替代的作用。然而,在作物生产过程中,一些磷酸盐最终会从农田径流中进入水体。由于回收成本高,工业加工向环境中释放磷酸盐。因此,为了关闭养分循环,迫切需要新的和创新的方法来更有效地循环磷。此外,世界磷矿“磷峰”的耗竭、原磷矿生产的肥料中含有的镉和铀对土壤的污染、水体的富营养化以及采矿和矿石加工过程中向空气中排放的磷,使得寻找磷循环利用的替代解决方案具有吸引力。废液中磷的成熟去除技术是通过物理化学或生物处理方法及其组合来实现的[1],[2]。虽然大多数此类方法对大型工业或家庭污水处理厂(> 400 PE)有效,但将这些解决方案实施到小型设施或远程应用可能在经济上或物流上都不可行。在这项工作中,我们提出了一种低成本的磷酸盐去除吸附介质的开发。这项工作的目的是找到一种有效的方法来生产吸附剂,一方面对磷酸盐离子具有高容量和选择性,另一方面具有均匀的性质和易于制造。为此,开发了一系列利用工业副产物的吸附剂组合物。选取高钙工业固体废弃物如粉煤灰F、高炉炉渣、造纸厂污泥等为原料,作为钙、铝、硅的主要来源。采用碱性活化剂地聚合技术制备粉状和粒状吸附剂[3]。研究了粉煤灰F (FAF-GP)、高炉矿渣(BFS-GP)和纤维污泥(FSHCa-GP)三种地聚合物吸附剂对水溶液中磷酸盐的吸附性能。采用x射线衍射(XRD)和x射线荧光(XRF)等方法对原料和产物的物理结构和化学成分进行了表征。为了评价地聚合物对磷酸盐的去除效果,进行了间歇吸附和柱吸附实验。研究了初始pH、吸附剂剂量、初始磷酸盐浓度和吸附时间等操作条件对吸附效果的影响。FAF-GP的吸附速度较快,在接触时间1.5h时达到平衡,而BFS-GP和FSHCa-GP的最大去除率分别在接触时间5h和24h时达到。三种吸附剂的等温线不同,反映了不同的吸附机制。磷酸盐浓度为100 mg L时,BFS-GP的容量为26 mg PO4 g, FAF-GP的容量为36 mg PO4 g, FSHCa-GP的容量为43 mg PO4 g。FAF-GP和FSHCa-GP的吸附剂用量为2 g L, BFS-GP的吸附剂用量为4 g L,去除率超过98%。在所有情况下,地聚合物去除磷酸盐离子的能力随着pH值的增加而增加,直到pH值为9,然后下降到pH值为12。通过固定床连续塔实验,考察了颗粒大小、流速、吸附层长对吸附塔操作条件的影响。在实验规模应用中处理了两个野外径流水样品,两个水样的去除率都在95%以上。浸出试验结果表明,废吸附剂可以安全处理或进一步重复利用。该研究是WaterPro项目(编号A74635 EAKR, Keski-Pohjanmaan/Kainuun Liitto)的一部分。
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引用次数: 2
Digest the Lignocellulosic Degradation Mechanism in White-Rot Fungi to Guide the Design of Efficient Bioprocessing For Biomass Conversion 研究白腐真菌对木质纤维素的降解机制,指导生物质转化的高效生物工艺设计
Pub Date : 2019-08-01 DOI: 10.11159/ICBB19.119
Su Sun, Jialong Zhang, Fei Li, Fuying Ma, Shangxian Xie, Xiaoyu Zhang
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引用次数: 0
Synthetic Bacterial Cell Factory for Highly Efficient Protein Secretion and Consolidated 合成细菌细胞工厂高效的蛋白质分泌和巩固
Pub Date : 2019-08-01 DOI: 10.11159/ICBB19.118
Shangxian Xie, Su Sun, Xiaoyu Zhang, Joshua S. Yuan
Shangxian Xie, Su Sun, Xiaoyu Zhang, Joshua Yuan Department of Biotechnology, College of Life Science and Technology, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, 43004, China shangxian _xie@hust.edu.cn; sunsu@hust.edu.cn; zhangxiaoyu@hust.edu.cn Department of Plant pathology and Microbiology, Texas A&M University 2123 TAMU, College Station, 77843, United States syuan@tamu.edu
华中科技大学生命科学与技术学院生物技术系,武汉市罗宇路1037号,43004,尚贤_xie@hust.edu.cn;sunsu@hust.edu.cn;zhangxiaoyu@hust.edu.cn美国德州农工大学植物病理与微生物学系2123 TAMU,美国大学城77843 syuan@tamu.edu
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引用次数: 0
Bacterial Protein Mediated Synthesis of Antibacterial AgNPs and Protein Crystallization for Time-dependent Growth Studies of AgNPs 细菌蛋白介导的抗菌AgNPs合成及AgNPs生长的蛋白结晶研究
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.115
Noreen Ashraf, F. Ahmad, Yin Dachuan
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引用次数: 0
Simultaneous Removal of Nutrients by Geopolymers Made From Industrial By-Products 利用工业副产品制成的地聚合物同时去除营养物质
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.169
T. Samarina, E. Takaluoma
An effective way to recover phosphate and ammonium from contaminated waters is of great demand. Nutrients can be reused and applied to land as valuable fertilizers. Composite adsorbents were prepared from industrial waste materials and calcined natural clay. The ability of the new adsorbents to simultaneously remove phosphate and ammonium from diluted solutions was evaluated. Paper mill sludge or blast furnace slag together with kaolinite clay were used as raw materials to produce inorganic polymers by alkaline activation. All raw materials and composites have been characterized by XRF and XRD. The influence of clay and waste material in the adsorbent composition, the adsorbent dose, and time of adsorption characteristics have been investigated at static conditions by bench-top tests. For the best identified composition (metakaolin and blast furnace slag composite), the phosphate adsorption increases from 0.05 mg-P/g for pure clay up to 8.5 mg-P/g for composite with blast furnace slag content of 60 wt.%, while a decrease on the ammonium sorption capacity from 15 mg-N/g to 7 mg-N/g is observed. Phosphate removal was enhanced when ammonium was present, while ammonium removal was slightly varied whether phosphate ions in the system or not. In case of ammonium, ion exchange is the likely mechanism of removal, whereas in the case of phosphate surface precipitation in form of hydroxyapatite appears to occur.
从污染水体中回收磷酸盐和铵的有效方法是迫切需要的。养分可以重复利用,并作为有价值的肥料施用于土地。以工业废料和煅烧的天然粘土为原料制备复合吸附剂。评价了新型吸附剂同时从稀释溶液中去除磷酸盐和铵的能力。以造纸厂污泥或高炉炉渣与高岭石粘土为原料,采用碱活化法制备无机聚合物。用XRF和XRD对原料和复合材料进行了表征。在静态条件下,通过台架试验研究了粘土和废弃物对吸附剂组成、吸附剂用量和吸附时间的影响。对于鉴定出的最佳组合物(偏高岭土和高炉渣复合材料),当炉渣含量为60 wt.%时,对磷酸盐的吸附量从纯粘土的0.05 mg-P/g增加到复合材料的8.5 mg-P/g,而对铵的吸附量从15 mg-N/g下降到7 mg-N/g。当系统中有铵离子存在时,对磷酸盐的去除率提高,而当系统中是否有磷酸离子存在时,对铵的去除率略有不同。在铵的情况下,离子交换是可能的去除机制,而在磷酸盐的情况下,表面沉淀以羟基磷灰石的形式出现。
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引用次数: 1
Smart Alginate-Based Magnetic Platforms for Drug Delivery 基于海藻酸盐的磁性药物传递平台
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.120
C. Ilie, Angela Spoială, Laura Moise, Maria Anghelache, D. Ficai, I. Ardelean, R. Trusca, A. Ficai, Manuela Calin, Anca Gagencu, E. Andronescu
Cornelia Ioana Ilie, Angela Spoiala, Laura Moise, Maria Anghelache, Denisa Ficai, Ioana Lavinia Ardelean, Roxana Doina Trusca, Anton Ficai, Manuela Calin, Anca Gafencu, Ecaterina Andronescu Faculty of Applied Chemistry and Materials Science, University POLITEHNICA of Bucharest Polizu Street no 1-7, 011061, Bucharest, Romania denisaficai@rahoo.ro Academy of Romanian Science Splaiul Independentei Street, No 54, Bucharest, Romania Institute of Cellular Biology and Pathology “N. Simionescu” of Romanian Academy 8, BP Hasdeu Street, 050568, Bucharest, Romania
Cornelia Ioana Ilie, Angela Spoiala, Laura Moise, Maria Anghelache, Denisa Ficai, Ioana Lavinia Ardelean, Roxana Doina Trusca, Anton Ficai, Manuela Calin, Anca Gafencu, Ecaterina Andronescu,罗马尼亚布加勒斯特POLITEHNICA大学应用化学与材料科学学院,布加勒斯特Polizu街1-7号,011061,罗马尼亚布加勒斯特,独立街54号,罗马尼亚细胞生物学和病理学研究所罗马尼亚布加勒斯特哈德乌街BP号,050568,罗马尼亚学院8号
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引用次数: 0
A Study on the Evaluation of the Core Disinfection Facility in South Korea 韩国核心消毒设施评价研究
Pub Date : 2019-08-01 DOI: 10.11159/ICBB19.107
Wooseog Jeong
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引用次数: 0
Graphene Oxide Based Nanocomposite for Crop Protection 基于氧化石墨烯的作物保护纳米复合材料
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.142
Z. Bytešníková, J. Pečenka, L. Richtera
Zuzana Bytešníková, Jakub Pečenka, Lukáš Richtera, Dorota Tekielska, Aleš Eichmeier, Vojtěch Adam Department of Chemistry and Biochemistry Mendel University in Brno, Zemědělská 1, 613 00 Brno, Czech Republic zuzana.bytesnikova@mendelu.cz; lukas.richtera@mendelu.cz Central European Institute of Technology, Brno University of Technology Purkyňova 656/123, 612 00 Brno, Czech Republic Mendeleum – Institute of Genetics, Faculty of Horticulture, Mendel University in Brno Valticka 337, 69144 Lednice, Czech Republic jakub.pecenka@mendelu.cz
{"title":"Graphene Oxide Based Nanocomposite for Crop Protection","authors":"Z. Bytešníková, J. Pečenka, L. Richtera","doi":"10.11159/ICNFA19.142","DOIUrl":"https://doi.org/10.11159/ICNFA19.142","url":null,"abstract":"Zuzana Bytešníková, Jakub Pečenka, Lukáš Richtera, Dorota Tekielska, Aleš Eichmeier, Vojtěch Adam Department of Chemistry and Biochemistry Mendel University in Brno, Zemědělská 1, 613 00 Brno, Czech Republic zuzana.bytesnikova@mendelu.cz; lukas.richtera@mendelu.cz Central European Institute of Technology, Brno University of Technology Purkyňova 656/123, 612 00 Brno, Czech Republic Mendeleum – Institute of Genetics, Faculty of Horticulture, Mendel University in Brno Valticka 337, 69144 Lednice, Czech Republic jakub.pecenka@mendelu.cz","PeriodicalId":265434,"journal":{"name":"Proceedings of the 5th World Congress on New Technologies","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116898173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Application of Taq DNA Polymerase for Electrochemical Detection of Sexually Transmitted Pathogenic DNA Taq DNA聚合酶在性传播致病DNA电化学检测中的新应用
Pub Date : 2019-08-01 DOI: 10.11159/ICBB19.127
Hyowon Jang, Hyo Yong Kim, Seoyoung Lee, H. Park
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引用次数: 0
Reduction of Dioxins and Furans Emission in Air and Soil Samples after Renovation Works at Ararat Dumpsite 阿拉拉特垃圾场翻新工程后空气及土壤样本中二恶英及呋喃排放量的减少
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.144
A. Aleksandryan, A. Khachatryan, P. Kukučka, P. Příbylová, P. Čupr, K. Sebková
Due to the lack of sanitary landfills in Armenia, general unseparated wastes are disposed to dumpsites. Then in order to reduce their amounts and volumes uncontrolled burning of wastes occurs. As known, low-temperature burning of waste generates emissions of unintentionally produced dioxins and furans. At the selected pilot dumpsite of Ararat (Republic of Armenia) renovation works were performed, then followed infrastructure development, as well as implementation of best available technique and best environmental practice. The paper deals with data obtained through 2 monitoring campaigns, including analyses of samples of air and soil taken at the dumpsite area before and after renovation works. For PCDDs/PCDFs determination passive sampling was arranged and done using passive samplers installed at the selected site of Ararat urban dumpsite before and after renovation works. Collection of samples was done for the evaluation of the environmental situation (2 monitoring campaigns). The samples were analysed for PCDD/PCDFs at the laboratory of RECETOX (Masaryk University, Brno, Czech Republic) as an external laboratory. The entire procedure was executed in accordance to SOP provided by the RECETOX. Considering findings of the First and Second Monitoring Campaigns, we identified some sampling points that can be compared. Thus, air samples 10001, 10002 and 10003 can be compared with 20001, 20002 and 20003 accordingly. The following observations were done. For air samples decrease of PCDDs/PCDFs concentration made from 28 to 65 times. For soil samples PCDDs/PCDFs concentration decreased 304-393 times.
由于亚美尼亚缺乏卫生填埋场,一般未经分类的废物被处置到垃圾场。然后,为了减少它们的数量和体积,发生了不受控制的废物燃烧。众所周知,废物的低温燃烧会产生无意中产生的二恶英和呋喃。在选定的阿拉拉特(亚美尼亚共和国)试点垃圾场进行了翻新工程,然后进行了基础设施建设,并实施了现有的最佳技术和最佳环境做法。本文涉及通过两次监测活动获得的数据,包括对修复工程前后在垃圾场采集的空气和土壤样本的分析。对于pcdd /PCDFs的测定,采用安装在Ararat城市垃圾场改造工程前后选定地点的被动采样器进行被动采样。为评价环境状况收集了样本(2次监测活动)。在RECETOX实验室(捷克共和国布尔诺马萨里克大学)作为外部实验室对样品进行了PCDD/ pcdf分析。整个过程按照RECETOX提供的SOP执行。考虑到第一次和第二次监测活动的结果,我们确定了一些可以比较的抽样点。因此,10001、10002和10003的空气样本可以与20001、20002和20003进行比较。进行了以下观察。空气样本的多氯联苯/多氯联苯浓度由28%下降至65%。土壤样品PCDDs/PCDFs浓度降低304 ~ 393倍。
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引用次数: 0
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Proceedings of the 5th World Congress on New Technologies
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