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PREPARATION THE ROSE-LIKE HYDROPHOBIC SURFACE OF WOOD BASED MATERIALS BY SOFT LITHOGRAPHY 软光刻法制备木基材料玫瑰状疏水表面
Pub Date : 2021-05-10 DOI: 10.37763/wr.1336-4561/66.2.211220
Zeyu Zhang, Bingru Shao, Fapeng Wang, J. Pang, Ling Su
To prepare hydrophobic wood with rose-like hydrophobic surface and avoid moisture damage to wood. In this paper, With polyvinyl alcohol (PVA) as the elastic mold, the microstructure of the rose petals was replicated on the wood surfaces by soft lithography. The soft lithography technique was used to modify the wood sur-face, transferring over it a rose-like topography, based on a micro/nano hierarchical structure using fresh rose as the template. The surface of poplar coated with polystyrene was reconstructed twice using 1, 3, 5, 8 and 10% PVA as templates, respectively. The results show that the average contact angle of poplar surface coated with polystyrene is more than 130°, that of fresh rose surface is about 140°, and that of untreated wood is about 60°. Therefore, the wood surface with polystyrene has obtained a similar structure to that of rose surface and has a certain hydrophobicity. In addition, the microstructures observed by means of SEM, showing rough surface structures with micro-nanopapillate hills on wood surfaces. Water droplets could easily roll down on such wood surfaces, exhibiting super-hydrophobic and low adhesion properties. The successful fabrication of rose-like wood provided a new direction for researches on the super-hydrophobic of wood, which could effectively prevent the damage of moisture to wood.
制备具有玫瑰状疏水表面的疏水木材,避免木材受潮。本文以聚乙烯醇(PVA)为弹性模,采用软光刻技术在木材表面复制玫瑰花瓣的微观结构。使用软光刻技术修改木材表面,在其上转移玫瑰状地形,基于以新鲜玫瑰为模板的微/纳米分层结构。以1、3、5、8和10% PVA为模板剂,对涂覆聚苯乙烯的杨树表面进行了两次重构。结果表明,涂覆聚苯乙烯的杨树表面的平均接触角大于130°,新鲜玫瑰表面的平均接触角约为140°,未处理木材的平均接触角约为60°。因此,用聚苯乙烯制成的木材表面获得了与玫瑰表面相似的结构,并具有一定的疏水性。此外,通过扫描电镜观察木材的微观结构,木材表面呈现出粗糙的表面结构,表面上有微纳米堆积。水滴很容易在这种木材表面滚下,表现出超疏水性和低粘附性。玫瑰木的成功制备为木材的超疏水性研究提供了新的方向,它可以有效地防止水分对木材的破坏。
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引用次数: 1
PHYSICAL AND MECHANICAL CHARACTERIZATION OF PLANCHONELLA PACHYCARPA WOOD SPECIES FOR USE IN STRUCTURAL PURPOSE 结构用厚足跖球藻木材的物理和力学特性
Pub Date : 2021-05-10 DOI: 10.37763/WR.1336-4561/66.2.267276
V. Aquino, Marcus Vinicius Pereira De Freitas, Claudia Queiroz De Vasconcelos, J. Almeida, F. Arroyo, D. H. D. Almeida, S. A. M. Silva, D. A. L. Silva, R. V. Pinheiro, F. Lahr, E. Rodrigues, A. Christoforo
This research aimed to characterize the wood species Goiabão (Planchonella pachycarpa), following the precepts set forth in the Brazilian standard ABNT NBR 7190, as well as to evaluate the possibility of estimating physical and mechanical properties, using the analysisof variance (ANOVA) as a function of apparent density, and also to estimate the stiffness properties as a function of the respective strength property. The physical and mechanical properties were considered adequate for the use of this wood for structural purposes, being classified in class C40. According to the results of the regression models, it is possible to estimate the tensile strength parallel to the fibers as a function of the apparent density. It was also possible to estimate the longitudinal elastic modulus in the compression parallel to the fibers as a function of the compressive strength parallel to the fibers.
本研究旨在根据巴西标准ABNT NBR 7190的规定,对goiab (Planchonella pachycarpa)树种进行表征,并利用方差分析(ANOVA)作为表观密度的函数,评估估计物理和机械性能的可能性,并估计刚度特性作为各自强度特性的函数。该木材的物理和机械性能被认为足以用于结构用途,被分类为C40类。根据回归模型的结果,可以估计平行于纤维的拉伸强度作为表观密度的函数。也可以估计纵向弹性模量在平行于纤维的压缩中作为平行于纤维的抗压强度的函数。
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引用次数: 2
BENDING CHARACTERISTICS OF LAMINATED WOOD COMPOSITES CONSTRUCTED WITH BLACK PINE WOOD AND ARAMID FIBER REINFORCED FABRIC 由黑松木和芳纶纤维增强织物构成的层压木复合材料的弯曲特性
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.309320
A. Karaman, Mehmet Nuri Yıldırım, Onder Tor
The aim of this study was to determine the 4-point bending strength and modulusof elasticity in bending of Black pine wood laminated materials reinforced with aramid fiber was bonded using epoxy or polyurethane glues separately. The samples were prepared in accordance with the TS 5497 EN 408 (2006). The results of the study determined that the highest value for static bending strength was found in the laminated wood samples (83.94 N.mm-2) that were prepared using inter-layer aramid fiber reinforced polymer (AFRP) and epoxy glue. The highest value of modulus of elasticity in bending was found in the samples prepared with inter-layer epoxy and AFRP (10311.62 N.mm-2). It was observed that the samples parallel to the glue line of the laminated material showed higher performance compared to those perpendicular to the glue line. The data obtained as a result of this study demonstrated that aramid fiber reinforced Black pine wood laminated materials can be used in the building industry as building materials.
本研究的目的是测定芳纶纤维增强黑松木复合材料分别用环氧胶和聚氨酯胶粘接后的四点弯曲强度和弯曲弹性模量。样品按照TS 5497 EN 408(2006)制备。研究结果表明,采用层间芳纶纤维增强聚合物(AFRP)和环氧树脂胶制备的复合木材样品的静态抗弯强度最高(83.94 N.mm-2)。弯曲弹性模量最高的是层间环氧树脂和AFRP制备的样品(10311.62 N.mm-2)。结果表明,平行于胶合线方向的样品比垂直于胶合线方向的样品表现出更高的性能。研究结果表明,芳纶纤维增强黑松木层压材料可以作为建筑材料应用于建筑行业。
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引用次数: 4
CHANGES IN GROSS CALORIFIC VALUE OF THERMALLY TREATED SCOTS PINE (PINUS SYLVESTRIS L.) AND SESSILE OAK (QUERCUS PETRAEA L.) WOOD AND THEIR EXPLANATION USING FTIR SPECTROSCOPY 热处理后苏格兰松总热值的变化无梗橡树(栎)伍德和他们使用红外光谱的解释
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.243254
Emília Orémusová, E. Výbohová
Scots pine (Pinus sylvestris L.) and Sessile oak (Quercus petraea L.) wood were thermally treated in an oven at the temperatures of 160°C, and 200°C under atmospheric pressure inthe presence of air for 3 and 9 hrs. The mass loss and gross calorific value were determined. Non-treated wood samples achieved a gross calorific value of 22 193 J.g-1 for pine wood and 19 277 J.g-1 for oak wood. Whereas the calorific value of pine wood with increasing severity of treatment decreased, in the case of oak it increased. The mass loss increased with increasing treatment severity by both wood species. Mentioned differences in pine and oak wood behaviour using ATR-FTIR spectroscopy were explained. In the case of pine wood with increasing temperature and time of exposure a decrease of resin acids was observed. This may be contributed to decrease in GCV. In the case of oak wood, mainly at temperature of 200°C the degradation of hemicelluloses was observed that results in relative increasing in the lignin content with followed increase in the GCV.
苏格兰松(Pinus sylvestris L.)和无柄橡树(Quercus petaea L.)木材在160°C和200°C的大气压下在空气存在下进行热处理3和9小时。测定了质量损失和总热值。未经处理的木材样品的总热值为22 193 J.g-1的松木和19 277 J.g-1的橡木。松木的热值随着处理程度的增加而降低,而橡木的热值则增加。两种木材的质量损失均随处理程度的增加而增加。用ATR-FTIR光谱解释了松树和橡树木材行为的上述差异。在松木的情况下,树脂酸随着暴露温度和时间的增加而减少。这可能是GCV降低的原因之一。以橡木为例,主要在200°C温度下观察到半纤维素的降解,导致木质素含量随着GCV的增加而相对增加。
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引用次数: 0
ELIMINATION OF ADHESIVE IMPURITIES OF THE RECOVERED PAPER IN FLOTATION PROCESS 回收纸浮选过程中胶黏剂杂质的去除
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.221230
V. Kuňa, J. Balberčák, Š. Boháček, V. Ihnát
The article presents results of the elimination of sticky impurities from recovered paperin laboratory flotation of three pulp suspensions with different whiteness, obtained directly from the production line before entering flotation. A combination of commercial agents releasing undesirable substances from recovered paper and means for regulation and stabilization of froth and modified micronized bentonit was used. In the flotation purification of pulp suspension with a whiteness of 53%, the combination of Prodeink Extra, Prodeink AS10 and Hydrocol OT reduced the macrostickies content by 58%, the ash content decreased from 18.5% to 4.5%, the whiteness increased from 53% to 56.4% and the residual color content was reduced from 385 ppm to 294 ppm. The pulp suspension with a whiteness of 64% showed a reduction in the content of macrostickies by 66%, a reduction in the ash content by 23.2%, an increase in whiteness by 1.4% and a reduction in the residual color content from 245 ppm to 194 ppm. The pulp suspension with a whiteness of 68.3% showed a decrease in the content of macrostickies by 58.1%, the ash content decreased from 35.7% to 6.3%, the whiteness increased by 1.1% and the content of residual color decreased from 157 ppm to 117 ppm.
本文介绍了在进入浮选前直接从生产线上获得的三种不同白度的矿浆悬浮液在实验室浮选中去除回收纸中的粘性杂质的结果。从回收纸中释放不良物质的商业药剂与调节和稳定泡沫和改性微粉膨润土的方法相结合。在白度为53%的矿浆悬浮液浮选提纯中,Prodeink Extra、Prodeink AS10和Hydrocol OT组合可使矿浆宏观黏合剂含量降低58%,灰分由18.5%降至4.5%,白度由53%提高至56.4%,残色含量由385 ppm降至294 ppm。白度为64%的纸浆悬浮液,宏观黏合剂含量降低66%,灰分含量降低23.2%,白度提高1.4%,残色含量从245ppm降至194ppm。白度为68.3%的纸浆悬浮液宏观黏合剂含量下降58.1%,灰分含量由35.7%下降到6.3%,白度提高1.1%,残色含量由157 ppm下降到117 ppm。
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引用次数: 1
INTERNAL CAUSE ANALYSIS OF DAMAGE OF WOODEN COMPONENTS IN DANXIA TEMPLE ANCIENT ARCHITECTURES: TREE SPECIES 丹霞寺古建筑木质构件损坏的内因分析:树种
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.297308
Yan Yang, He Sun, Shuangmao Yang, Aifeng Wang, Rui Zhao, Wen Wang, Yiming He, Bin Li, Binxin Zhang, Qian Wu
In the study, part of degraded wooden components of Danxia Temple ancient architectures in China were indentified through the bright field microscope, and chemical compositions in cell walls were observed using polarized and fluorescence lights, respectively. The results showed that samples were belonged to Quercus spp., Ulmus spp., Salix spp., and Populus spp., respectively. Cellulose composition in Quercus spp. was seriously consumed by brown decay fungi, cellulose and lignin compositions in Ulmus spp. were consumed by white decay fungi under polarized and fluorescence light observations. All of these four kind of tree species themselves were easily vulnerable to be attacked by insects.
本研究通过明场显微镜对中国丹霞寺古建筑的部分木质构件进行了鉴定,并分别利用偏振光和荧光观察了细胞壁的化学成分。结果表明,样品分别属于栎属、榆属、柳属和胡杨属。在偏光和荧光观察下,栎属植物的纤维素成分主要被棕色腐烂真菌消耗,榆属植物的纤维素和木质素成分主要被白色腐烂真菌消耗。这四种树种本身都很容易受到昆虫的攻击。
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引用次数: 3
DEVELOPMENT AND VALIDATION OF AN ANALYTICAL METHOD FOR CONDENSED TANNIN EXTRACTS OBTAINED FROM THE BARK OF FOUR TREE SPECIES USING HPLC 四种树种树皮浓缩单宁提取物的高效液相色谱分析方法的建立与验证
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.171182
Faustino Ruiz Aquino, Rossy Feria Reyes, J. R. Quiñones, Wenceslao Santiago García, Mario Ernesto Suárez Mota, Héctor Hugo Esquivel Reyes
Herein, we evaluated the content of condensed tannins present in the bark of four tree species that are Quercus laurina Humb. & Bonpl., Quercus crassifolia Humb. & Bonpl., Arbutus xalapensis Kunth, and Prunus serotina Ehrn. An analytical method using high-performance liquid chromatography (HPLC) for condensed tannin extracts was developed and validated. Also,the aqueous extracts were analyzed by Fourier transform infrared spectroscopy (FTIR). Based on the Stiasny number, A. xalapensis, and Q. laurina represent an important source of condensed tannins, which may be subject to exploitation. Using infrared spectroscopy, it was observed that tannins do not show an important signal of carbonyl groups (aromatic esters) with respectto high purity catechin. Furthermore, the band of the hydroxyl group is less pronouncedin tannins, because various hydroxyl are interacting with each other. However, it can be seen that the method of extraction of wood tannins developed in this work, presents satisfactory results.
在这里,我们评估了浓缩单宁的含量存在于四种树种的树皮是栎下叶。& Bonpl。柏树(Quercus assifolia Humb)& Bonpl。杨梅、胡杨梅、樱李。建立了高效液相色谱法测定浓缩单宁提取物的方法,并进行了验证。并用傅里叶变换红外光谱(FTIR)对水提物进行了分析。从Stiasny数量上看,xalapensis和laurina是浓缩单宁的重要来源,具有开发利用的潜力。红外光谱分析表明,相对于高纯度儿茶素,单宁中不存在羰基(芳香酯)的重要信号。此外,在单宁中羟基的带不太明显,因为不同的羟基相互作用。然而,可以看出,本工作所开发的提取木材单宁的方法,取得了令人满意的结果。
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引用次数: 4
MECHANICAL PROPERTIES OF POLISH-GROWN PINUS SYLVESTRIS L. STRUCTURAL SAWN TIMBER FROM THE BUTT, MIDDLE AND TOP LOGS 波兰生长的西尔山松结构锯木的机械性能
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.231242
S. Krzosek, M. Grześkiewicz, Izabela Burawska Kupniewska, P. Mańkowski, M. Wieruszewski
The research consisted in testing Polish sawn timber dedicated for construction applications made of pines (Pinus sylvestris L.) that grew in the Silesian Forestry Region, taking into account three parts of the log: butt, middle and top. The boards had the same cross section, a nominal thickness of 40 mm and width of 138 mm, typical for Polish structural timber. The mean nominal length of the boards under research amounted to 3500 mm. Each set was composed of 70 boards. Before the tests, boards were dried in an industrial drier until reaching the moisture content of 12%, and they were planed on 4 sides. First of all, the sawn timber was graded into strength classes, and their dynamic modulus of elasticity (MOE_dyn) was tested with a non-destructive method, with the use of a portable MTG device. The next step consisted in a bending test with four points of support, according to the EN 408 standard, and with the use of the TiraTest 2300 machine, in order to determine the global modulus of elasticity (MOE_EN-408) and the static bending strength, also referred to as modulus of rupture (MOR). Finally, the average growth ring width was determined for each board (PN-D-94021), as well as wood density accordingto EN-408. The hereby paper presents the test results for all the tested sawn timber boards, taking into account the part of log that each board came from: butt, middle or top. The hereby paper presents the influence of density on the mechanical properties of wood, taking into account the location on the round timber. The analysis does not include the influence of the width of annual growth rings and the proportion of latewood on the wood properties under research.
该研究包括测试波兰锯材,用于由生长在西里西亚林区的松树(Pinus sylvestris L.)制成的建筑应用,考虑到原木的三个部分:尾部、中部和顶部。木板具有相同的横截面,标称厚度为40毫米,宽度为138毫米,典型的波兰结构木材。所研究的板的平均标称长度为3500mm。每组由70块木板组成。试验前,将板材在工业干燥机中干燥至含水率12%,并进行4面刨平。首先,对锯材进行强度分级,利用便携式MTG装置对锯材的动态弹性模量(MOE_dyn)进行无损检测。下一步是根据EN 408标准,使用TiraTest 2300机器进行四个支点的弯曲测试,以确定整体弹性模量(MOE_EN-408)和静态弯曲强度,也称为断裂模量(MOR)。最后,根据EN-408确定每块板的平均生长环宽度(PN-D-94021)以及木材密度。本文给出了所有被测试的锯木板的测试结果,考虑到每块木板的原木部分:对接、中间或顶部。本文研究了密度对木材力学性能的影响,同时考虑了木材在圆木上的位置。分析未考虑年轮宽度和后期木材比例对研究木材性能的影响。
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引用次数: 3
NUMERICAL STUDY ON EFFECTS OF TENON SIZES ON WITHDRAWAL LOAD CAPACITY OF MORTISE AND TENON JOINT 榫尺寸对榫卯连接拔载能力影响的数值研究
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.321330
Tianxing Zhang, Wengang Hu
The effect of tenon length and tenon width on withdrawal load capacity of mortise and tenon (M-T) joint was studied based on the finite element method (FEM), and the relationship of withdrawal load capacity relating to tenon length and tenon width was regressed using response surface method. The results showed that the tenon length and tenon width had remarkable effects on withdrawal load capacity of M-T joint T-shaped sample. The effect of tenon length on withdrawal load capacity was greater than tenon width. The regression equation used to predict the withdrawal load capacity was capable of optimizing the tenon sizes of M-T joint with R-square of 0.926. Using FEM can get more knowledge of M-T joint visually, and reduce the costs of materials and time of experiments.
基于有限元法研究了榫卯长度和宽度对M-T节点的抽拔承载力的影响,并利用响应面法回归了榫卯长度和宽度与抽拔承载力的关系。结果表明:榫头长度和榫头宽度对M-T接头t形试件的抗拔承载力有显著影响;榫头长度对抽拔承载力的影响大于榫头宽度。预测拔载能力的回归方程能够优化M-T节点的榫尺寸,其r平方为0.926。采用有限元法可以直观地了解M-T接头,减少材料成本和试验时间。
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引用次数: 6
INFLUENCE OF THE ENVIRONMENTAL POLLUTION ON THE DISTRIBUTION AND POLYMERIZATION DEGREE OF CELLULOSE IN BARK AND WOOD FROM SCOTS PINE(PINUS SYLVESTRIS L.) STEM 环境污染对苏格兰松树皮和木材中纤维素分布和聚合度的影响阀杆
Pub Date : 1900-01-01 DOI: 10.37763/wr.1336-4561/66.2.203210
D. Krutul, A. Radomski, A. Antczak, M. Drożdżek, T. Kłosińska, D. Szadkowska, J. Zawadzki
The pine stems were cut from three different polluted environments – Ist trees degradation degree (weak pollution), IInd trees degradation degree (strong pollution) and IIIrd trees degradation degree (connected with very strong pollution). On the basis of obtained results it was stated that environmental pollution caused changes in late wood participation, as well as distribution of cellulose on the stem cross- and longitudinal section. It also changed cellulose contentin bark from the butt-end section, which was about 26% regardless the degradation degree.The environmental pollution caused also an increase of viscometric average polymerization degree of cellulose in heartwood in relation to heartwood adjacent sapwood and sapwood frombutt-end section. Regardless the degradation degree, cellulose polymerization degree in heartwood adjacent sapwood from the middle part of the stem was higher in comparison to sapwood and heartwood. Moreover, the environmental pollution caused the increase of viscometric average polymerization degree of cellulose in bark. The polymerization degree of cellulose in bark from the butt-end section of IIIrd degradation degree stems was 22% and 23% higher in comparisonto the Ist and IInd degradation degree.
在1级树木退化程度(弱污染)、2级树木退化程度(强污染)和3级树木退化程度(强污染)3种不同污染环境中采伐松材。在此基础上指出,环境污染引起了后期木材参与的变化,以及纤维素在茎横截面和纵截面上的分布。它还改变了树皮后端部分的纤维素含量,无论降解程度如何,纤维素含量都在26%左右。环境污染还导致心材中纤维素的粘度平均聚合度相对于心材邻近边材和对端边材有所增加。无论降解程度如何,茎中部邻近边材的心材中纤维素聚合度高于边材和心材。此外,环境污染导致树皮中纤维素的粘度平均聚合度增加。降解度为IIIrd的茎秆尾段树皮中纤维素的聚合度比降解度为i和IInd的分别高22%和23%。
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引用次数: 0
期刊
WOOD RESEARCH 66(2): 2021
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