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Refineries of the Future – The Refinery as an ENERGY HUB 未来的精炼厂——精炼厂作为能源枢纽
Pub Date : 2019-10-13 DOI: 10.2118/198184-ms
E. Jansen
This paper presents the study of the European Petroleum Refiners Association into various pathways to produce a low-carbon liquid fuel to reduce the greenhouse gas (GHG) intensity in European transport. The European Union has set climate goals targeting 80-95 % GHG emission reductions by 2050. There is a strong focus on reducing CO2 emissions from transport fuels. Refining industry can effectively contribute by gradually transitioning to e.g. new feedstock's hence reducing product-related CO2 emissions (in combination with more efficient vehicles); integration with chemicals; further increasing CO2 efficiency in refineries and Green Hydrogen. The Concawe study explores these so-called Low-Carbon Pathways with the potential to reduce the CO2 emissions associated with the production and the use refined oil products [Concawe, 2018]. Options for CO2 emission reduction in refining are e.g. energy efficiency, low carbon electricity and carbon-capture & storage (CCS) and carbon-capture & usage (CCU). CO2 emissions savings up to 70 % towards 2050 could be possible. Other pathways explored for future refining are e.g. the use of green hydrogen and the impact of fuel quality and bio-feedstock into the refinery. The use of advanced biofuels will play a significant role in the reduction of greenhouse gas emissions in transport. This paper being a summary of the FuelsEurope Vision 2050 [FuelsEurope, 2018] presents the latest results of the ongoing study by Concawe showing possible pathways and CO2 reduction potential for EU refining, site-specific factors will determine individual refineries preferred routes to contribute. The principles are generally applicable to refineries in other parts of the world.
本文介绍了欧洲炼油协会对生产低碳液体燃料的各种途径的研究,以减少欧洲运输中的温室气体(GHG)强度。欧盟已经制定了到2050年温室气体减排80- 95%的气候目标。减少运输燃料的二氧化碳排放是一个非常重要的重点。炼油行业可以通过逐步过渡到新的原料,从而减少与产品相关的二氧化碳排放(与更高效的车辆相结合),从而有效地做出贡献;与化学品整合;进一步提高炼油厂和绿色氢的二氧化碳效率。Concawe的研究探索了这些所谓的低碳途径,这些途径有可能减少与成品油生产和使用相关的二氧化碳排放[Concawe, 2018]。炼油中减少二氧化碳排放的选择包括能源效率、低碳电力和碳捕获与储存(CCS)以及碳捕获与使用(CCU)。到2050年,二氧化碳排放量可能减少70%。探索未来炼油的其他途径,例如绿色氢的使用以及燃料质量和生物原料对炼油厂的影响。先进生物燃料的使用将在减少交通运输中的温室气体排放方面发挥重要作用。本文是《欧洲燃料展望2050》(fueleurope, 2018)的总结,介绍了Concawe正在进行的研究的最新结果,该研究显示了欧盟炼油的可能途径和二氧化碳减排潜力,具体地点的因素将决定各个炼油厂的首选路线。这些原则一般适用于世界其他地区的炼油厂。
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引用次数: 0
Visual Analysis of SAGD with Chemical Additives 化学添加剂对SAGD的目视分析
Pub Date : 2019-10-13 DOI: 10.2118/198041-ms
Jingjing Huang, T. Babadagli
SAGD (steam assisted gravity drainage) has been proven as an effective technology to enhance heavy oil/bitumen recovery. The main shortcoming of this method is its inefficiency, a result of high water and energy consumption. As a solution to SAGD efficiency improvement, we propose the addition of chemicals resulting in higher recovery and reduced steam consumption. The objective of this paper is to screen new generation chemicals as additives and study the mechanisms and optimum injection strategies. This screening was achieved through Hele-Shaw type macroscopic visual experiments. We previously screened a wide variety of chemical additives (Bruns and Babadagli 2017, 2018) for steam flooding. As a continuation of this work, these chemicals were tested for SAGD conditions using a new visual experimental design where the optimal injection strategies were identified, eventually providing a reference for the selection of chemical additives for field applications. 11 conventional and new generation chemical additives (heptane, biodiesel, DME, LTS-18, Tween 80, Span 80, Novelfroth 190, ionic liquid (BMMMIM BF4), silicon dioxide nanoparticle, DES9, and DES11) were selected based on both their strong thermal stability and enhanced oil recovery capability. The recovery improvement mechanisms for the different chemical additives and different injection strategies were identified through flow characteristics, emulsifying ability, viscosity reduction capability, and wettability alteration. Simultaneously, the mechanisms were studied from a macro perspective via analyzing areal sweep efficiency and microscopic oil displacement efficiency together with observing the images acquired during the process. Three different injection strategies were applied for each chemical: (1) chemicals were injected at the beginning, (2) in the middle, and (3) at the end of the steam injection. The chemical additives played different roles in recovery improvement, and different chemical addition strategies yielded different mechanisms. Heptane exhibited extraordinary characteristics with maximum "steam saving" (34.52%) when the middle injection strategy was applied and maximum ultimate oil recovery (64.75%) was obtained for the end injection strategy due to the ability to reduce the viscosity of heavy oil by dissolving around the chamber edge. Steamflooding with Novelfroth 190 showed an excellent performance for the middle and end injection strategies due to its ability to develop rapid oil drainage "channels". The addition of surfactant LST-18 presented the ability to improve the EOR by forming emulsions. Additionally, the distributions of the steam chamber in the Hele-Shaw cell were different due to the changed flow characteristics when the same chemical additive was injected at different times, thus showing the ability to reduce viscosity and form emulsions with different strengths.
SAGD(蒸汽辅助重力泄油)技术已被证明是提高稠油/沥青采收率的有效技术。这种方法的主要缺点是效率低,水和能源消耗高。作为提高SAGD效率的解决方案,我们建议添加化学品,从而提高采收率并降低蒸汽消耗。本文的目的是筛选新一代化学添加剂,并研究其机理和最佳注射策略。这种筛选是通过Hele-Shaw型宏观视觉实验实现的。我们之前筛选了多种用于蒸汽驱的化学添加剂(Bruns and Babadagli 2017, 2018)。作为这项工作的延续,使用新的视觉实验设计对这些化学品进行了SAGD条件下的测试,确定了最佳注入策略,最终为现场应用的化学添加剂选择提供了参考。11种常规和新一代化学添加剂(庚烷、生物柴油、二甲醚、LTS-18、Tween 80、Span 80、Novelfroth 190、离子液体(BMMMIM BF4)、二氧化硅纳米颗粒、DES9和DES11)具有较强的热稳定性和提高采油能力。通过流动特性、乳化能力、降粘能力和润湿性变化,确定了不同化学添加剂和不同注入策略对采收率的提高机理。同时,通过面扫效率和微观驱油效率分析,并观察过程中获取的图像,从宏观角度研究其机理。每种化学品采用了三种不同的注入策略:(1)化学品在注汽开始时注入,(2)在注汽中期注入,(3)在注汽结束时注入。化学添加剂对提高采收率的作用不同,不同的化学添加策略产生不同的机理。采用中间注入策略时,庚烷表现出非凡的“省汽”(34.52%)和最终采收率(64.75%)的特点,这是由于其能够通过在腔室边缘周围的溶解来降低稠油的粘度。Novelfroth 190蒸汽驱由于能够形成快速排油“通道”,在中端和末端注入策略中表现出优异的性能。表面活性剂LST-18的加入能够通过形成乳状液来提高提高采收率。此外,同一种化学添加剂在不同时间注入时,由于流动特性的改变,使得Hele-Shaw槽内蒸汽室的分布也不同,从而表现出降低粘度和形成不同强度乳液的能力。
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引用次数: 3
A Review of Preliminary Out-Of-Sequence Pinpoint Fracturing Field Trials in North America 北美乱序精确压裂初步现场试验综述
Pub Date : 2019-10-13 DOI: 10.2118/198023-ms
B. Jamaloei
Out-Of-Sequence (OOS) Fracturing can potentially maximize reservoir contact and fracture conductivity/connectivity by creating fracture complexity via reducing the stress anisotropy. It is initiated by fracturing two "book-end" frac stages (Outside Fracs), followed by a ‘middle" stage (Centre Frac) between them. The Center Frac is theorized to utilize the reduced stress anisotropy to activate pre-existing failure surfaces oriented at various azimuths and dip angles, thereby connecting bi-wing fractures to planes of weakness (natural fractures/fissures/faults/joints/cleats) and resulting in a complex fracture network that enhances connectivity and fracture area within the Stimulated Reservoir Volume (SRV). OOS Fracturing can mitigate possible issues in treatments aiming at creating fracture complexity, including zipper frac (fracture tip interference and blunting inhibiting fracture extension), modified zipper frac (risks of well bashing and fractures growing asymmetrically opposite of the induced stress from prior stage in the adjacent well), simultaneous frac (middle clusters experiencing larger stress interference inhibiting their growth), and high-rate fracturing (risk of cluster erosion reducing the limited entry effect and premature screenout due to inconsistent diversions inside fractures). Since its inception in early 2010s, OOS Fracturing has not gained considerable attention due to previously-existing operational limitations in fracturing out-of-sequence. It is reported to have been field tested in Western Siberia in 2014 with claimed well performance success. Operational limitations of the system employed in that trial is believed to have prevented its commercial development at that time. With the advent of Multicycle Sleeves and Shift-Frac-Close operation with a single Bottom-Hole Assembly to open and close sleeves, previous operational limitations of OOS Fracturing have been resolved. OOS Fracturing has since been trialed in three formations in Western Canada (2017/2018). This work analyzes the fracture treatment pressures and well performance of these trials. Five OOS Fracturing trials in these three formations reveal that normalized 15-month/18-month production from out-of-sequence-fractured wells outperform that of sequentially-fractured offsets, with similar formation properties and treatment designs. Instantaneous Shut-In Pressures (ISIP) of Centre Frac are generally higher than that of either Outside Fracs. Breakdown pressures for Centre Fracs exhibit a mixed trend, confirming that reducing stress anisotropy could lower the breakdown gradient (based on Kirsch Equation) if rock fabric permits. Well performance and treatment pressures appear to be more sensitive to Centre Frac proppant tonnage/fluid volumes and uneven sleeve spacing. This is the first attempt in analyzing the five OOS Fracturing trials, with encouraging well performance and operational execution in conventional reservoirs where it was deployed. Despite uneven
无序压裂(OOS)可以通过降低应力各向异性来增加裂缝复杂性,从而最大限度地提高储层接触和裂缝导流性/连通性。首先是压裂两个“书端”压裂段(Outside fras),然后是中间压裂段(Centre frac)。从理论上讲,中心裂缝利用减小的应力各向异性来激活不同方位和倾角的预先存在的破坏面,从而将双翼裂缝连接到薄弱面(天然裂缝/裂缝/断层/节理/理缝),从而形成复杂的裂缝网络,从而提高增产储层体积(SRV)内的连性和裂缝面积。OOS压裂可以减轻压裂过程中可能出现的问题,包括拉链压裂(裂缝尖端干扰和钝化抑制裂缝延伸)、改良拉链压裂(井击和裂缝生长不对称的风险,与相邻井的前一阶段诱导应力相反)、同步压裂(中间簇经历较大的应力干扰,抑制裂缝生长)、高速率压裂(簇蚀的风险降低了有限的进入效果和由于裂缝内部不一致的转向而过早筛出)。自2010年代初问世以来,由于之前存在的压裂失序的操作限制,OOS压裂并没有得到足够的关注。据报道,该系统已于2014年在西伯利亚西部进行了现场测试,并取得了成功。据信,在那次试验中使用的系统的操作限制当时阻碍了它的商业发展。随着多循环滑套和shift -压裂关闭作业的出现,一个底部钻具组合就可以打开和关闭滑套,解决了以前OOS压裂的操作局限性。自2017/2018年以来,在加拿大西部的三个地层中进行了OOS压裂试验。本文分析了这些试验的压裂压力和井况。在这三种地层中进行的5次OOS压裂试验表明,在相同的地层性质和处理设计下,序外压裂井15 /18个月的正常产量优于序外压裂井。中心压裂的瞬时关井压力(ISIP)通常高于任何一个外部压裂。中心裂缝的破裂压力呈现混合趋势,证实如果岩石组构允许,减小应力各向异性可以降低破裂梯度(基于Kirsch方程)。井的性能和处理压力似乎对Centre Frac支撑剂吨位/流体体积和不均匀滑套间距更为敏感。这是第一次对5次OOS压裂试验进行分析,在常规油藏中,该试验取得了令人鼓舞的油井性能和作业执行情况。尽管滑套间距不均匀,由于邻井生产造成的损耗,以及不太有利的地质力学特性(高泊松比和低杨氏模量),但现场试验取得了良好的结果。在非常规油藏中,非顺序压裂的真正潜力可能更大,因为地层性质更有利于形成复杂裂缝。
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引用次数: 1
Advanced Surveillance Technique for Multi-Phase Sweep Efficiency Monitoring 多相扫描效率监测的先进监控技术
Pub Date : 2019-10-13 DOI: 10.2118/197985-ms
Abdulaziz Alqasim, M. Sheshtawy, S. Kokal, Noureddine Benlakhdar
With maturing oil fields there is an increasing focus on improving the oil recovery factor and pushing the envelope toward a 70% target. This target is indeed very challenging and depends on a number of factors including enhanced oil recovery (EOR) methods, reservoir heterogeneities, displacement efficiency, and reservoir sweep. Other factors also play a role including vertical sweep due to flow behind the casing, well integrity issues, presence of conductive faults, or fractures. Proper surveillance performed to evaluate the injectant plume front, reservoir conformance, well connectivity, assessment of the integrity of wells, and other factors can be crucial for the success of the project and its future development. The paper discusses special downhole logging techniques including a set of conventional multiphase sensors alongside high precision temperature (HPT) and high-definition spectral noise logging (SNL-HD). It was run to provide complete assessment of the injection – production distribution and any associated well integrity issues that might impair the lateral sweep of injectants into the target layer. This will be done for an injector and producer pair near the wellbore area. The operation was carried out with a tool string that contained no mechanical parts and was not affected by downhole fluid properties. It was conducted under flowing and shut-in conditions to identify flow zones and check fracture signatures. It also provided multiphase fluid velocity profiles. The results of the survey allowed for in-depth assessment of borehole and behind casing flow, confirming lateral continuity, and provided an assessment of production-injection outside the pay zone. Results will allow for better well planning and anticipation of possible loss of well integrity that might impair production in the future. Combining the behind casing flow assessment with borehole multiphase flow distribution can be used for production optimization by sealing unwanted water contributing zones.
随着油田的成熟,人们越来越关注提高采收率,并将其推向70%的目标。这一目标确实非常具有挑战性,并且取决于许多因素,包括提高采收率(EOR)方法、油藏非均质性、驱油效率和油藏波及范围。其他因素也起作用,包括套管后流动造成的垂直波及、井完整性问题、导电断层或裂缝的存在。进行适当的监测,以评估注入液柱前缘、储层一致性、井连通性、井完整性评估以及其他因素,对于项目的成功和未来的开发至关重要。本文讨论了特殊的井下测井技术,包括一套常规的多相传感器、高精度温度(HPT)和高分辨率频谱噪声测井(SNL-HD)。该方法的目的是对注采分布和相关的井完整性问题进行全面评估,这些问题可能会影响注入物进入目标层的横向波及。这将用于靠近井筒区域的注入器和生产器对。该作业使用的工具柱不含机械部件,不受井下流体特性的影响。在流动和关井条件下进行,以识别流动区域并检查裂缝特征。它还提供了多相流体速度分布图。调查结果允许对井眼和套管后流进行深度评估,确认横向连续性,并对产层以外的生产注入进行评估。研究结果将有助于更好地进行井计划,并预测可能影响未来生产的井完整性损失。将套管后流评价与井内多相流分布相结合,可以通过封堵不需要的产水层来进行生产优化。
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引用次数: 0
An Integrated Study of Probabilistic Formation Evaluation and Geomechanical Analysis to Investigate the Potential of Hydraulic Fracture Stimulation in Najmah Unconventional Shale Reservoirs 基于概率地层评价和地质力学分析的Najmah非常规页岩储层水力压裂潜力综合研究
Pub Date : 2019-10-13 DOI: 10.2118/198103-ms
Tingyin He, J. Hornbrook, B. Dharanidharan, M. Al-Bahar, A. Al-Sane, Vandana Suresh, J. Hickey
The Najmah Shale, an organic-rich marl, is generally considered the primary source rock for hydrocarbons in Kuwait’s Jurassic and Cretaceous reservoirs. The purpose of this study was to estimate the original hydrocarbons in place (OHIP) and the geomechanical properties of the Najmah reservoir to aid in the design of a hydraulic fracture stimulation program in West Kuwait. An integrated petrophysical evaluation utilized conventional and sidewall core measurements, and standard and advanced open-hole logs were used to estimate net pay, porosity, oil saturation, and geomechanical properties. Formation evaluation of the Najmah Shale as a potential unconventional reservoir posed numerous challenges. These challenges included the ambiguous effects that high total organic carbon (TOC) has on conventional porosity logs and resistivity logs and the associated shale volume estimations. In this study, a probabilistic multi-mineral model was developed to more accurately assess the TOC of the rock and the associated porosity, saturation, and clay volume. Advanced well logs, including spectral gamma ray and elemental spectroscopy logs, were used to improve the mineralogical model of the complex formation. Routine core analysis, programmed pyrolysis, and X-ray diffraction (XRD) analyses were used to verify and calibrate the multi-mineral model results. Since a dual-porosity system was present in the formation, the Simandoux saturation equation was used to evaluate the fluid saturations. Anisotropic horizontal stress profiles were developed for specific wells based on analysis of dipole sonic logs, resulting in a greater regional understanding of the target interval. Based on the results of the multi-mineral modeling, the average TOC of the Najmah Shale varies from well to well throughout West Kuwait, with values as high as 14.8%. The effective porosity of the Najmah Shale ranges from 1 to 8%. Water saturation is low for these organic-rich formations. Water zones may occur above or below the organic-rich interval depending on the location. The geomechanical properties of the Najmah Shale are conducive to hydraulic fracture stimulation, by analogy to proven productive shale plays. The Sargelu interval, below the Najmah Shale, exhibits distinctly higher minimum horizontal stress gradients while the limestone above the Najmah Shale presents a weaker stress barrier. The results of the probabilistic formation evaluation of the Najmah Shale indicated that a significant volume of hydrocarbons is present in the formation. The geomechanical properties of the Najmah and adjacent units are conducive to successful hydraulic fracture stimulation. The evaluation of water-bearing zones adjacent to the target formation is critical to the investigation of the formation’s stimulation potential.
Najmah页岩是一种富含有机物的泥灰岩,通常被认为是科威特侏罗纪和白垩纪储层的主要烃源岩。本研究的目的是评估Najmah储层的原始油气储量(OHIP)和地质力学特性,以帮助设计科威特西部的水力压裂增产方案。综合岩石物理评价采用常规岩心和侧壁岩心测量,采用标准和先进的裸眼测井来估计净产层、孔隙度、含油饱和度和地质力学性质。Najmah页岩作为一种潜在的非常规储层,其储层评价面临诸多挑战。这些挑战包括高总有机碳(TOC)对常规孔隙度测井和电阻率测井以及相关页岩体积估算的模糊影响。在这项研究中,开发了一个概率多矿物模型,以更准确地评估岩石的TOC以及相关的孔隙度、饱和度和粘土体积。利用伽马能谱测井和元素能谱测井等先进测井技术,改进了复杂地层的矿物学模型。常规岩心分析、程序热解和x射线衍射(XRD)分析用于验证和校准多矿物模型结果。由于地层中存在双重孔隙系统,因此使用Simandoux饱和度方程来评估流体饱和度。基于偶极子声波测井分析,开发了特定井的各向异性水平应力剖面,从而对目标层段有了更深入的了解。根据多矿物建模的结果,在整个西科威特,Najmah页岩的平均TOC随井而异,最高可达14.8%。Najmah页岩的有效孔隙度为1% ~ 8%。这些富含有机物的地层含水饱和度很低。根据地点的不同,水区可能出现在富有机质区间的上方或下方。Najmah页岩的地质力学性质有利于水力压裂增产,与已探明的页岩生产区类似。Najmah页岩下方的Sargelu段表现出明显较高的最小水平应力梯度,而Najmah页岩上方的石灰岩则表现出较弱的应力屏障。Najmah页岩的概率地层评价结果表明,该地层中存在大量的油气。Najmah及邻近单元的地质力学特性有利于水力压裂增产。目标地层附近含水带的评价对于研究该地层的增产潜力至关重要。
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引用次数: 0
World's Largest Yard Testing of a Thixotropic Polymer Sealant for Chemical Annular Plug Applications in Low-temperature Horizontal Wellbores 世界上最大的触变聚合物密封胶测试,用于低温水平井的化学环空塞
Pub Date : 2019-10-13 DOI: 10.2118/198085-ms
K. Matar, Y. Santin, Khan Taku, Jesper Koldig
Forming a retrofit annular plug on controlled acid jet (CAJ) liners in horizontal wells can be challenging. Several conformance technologies have been tested with mixed results; optimal chemical placement is problematic, and results show that conventional treatments either slump or float along horizontal sections, fail to withstand the desired differential pressure, or are not achievable at low temperatures. This paper describes laboratory improvements and a large-scale yard test of a thixotropic polymer sealant (TPS). The TPS system is composed of an organically crosslinked polymer combined with optimized rheological modifiers, which enable predictable and controllable crosslinking times. This allows precise TPS placement into the horizontal or deviated wellbores to help control unwanted water or gas. Extensive laboratory testing was conducted on the TPS system to formulate the optimal rheology at low temperatures. A specialized laboratory-scaled test cell was purposely built to verify the development of the thixotropic blend at low temperatures of 35 to 40°C. After successful laboratory testing, a 520-ft long yard test was conducted to mimic a field trial. It consisted of centralized 4 1/2-in. tubing run horizontally inside a 7-in. casing. Four predrilled holes of 4-mm diameter were located midway along the tubing to represent the perforations, providing communication to the annulus of the tubing and casing. A 2.25-in. outer diameter (OD) high-pressure hose, representing coiled tubing, was placed inside the 4 1/2-in. tubing and used to deliver the TPS fluid to the perforations. The entire setup was pressure-tested to 5,000 psi and heated to 40°C using an insulated heating blanket. A high-pressure pump was used to pump and displace 6 bbl of TPS, which was sufficient to form a 300-ft annular plug. The chemical was allowed to crosslink and set for 45 hours. Results of this yard test showed that a 300-ft TPS annular plug is capable of withstanding up to 4,620-psi differential pressure. The setup was then cut at various locations, both treated and untreated, to confirm, assess, and observe TPS placement in the cross-section of the tubulars. It was observed that the TPS can flow in the smaller spaces between the tubing and the centralizer, helping ensure optimal sealing. The TPS system described here can be used to help reduce unwanted water or gas production in long horizontal wells with CAJ liners. The open annulus between the preperforated liner and the formation makes selective isolation for the presence of thief zones, high-permeability zones, or fractures extremely challenging. Left untreated, this can eventually result in a large increase in water production and eventually a reduction in the economic life of the field.
在水平井中,在可控酸射流(CAJ)尾管上形成改造环空塞是一项具有挑战性的工作。已经测试了几种一致性技术,结果好坏参半;最佳的化学药剂放置是有问题的,结果表明,常规的处理方法要么沿着水平段滑塌,要么漂浮,无法承受预期的压差,或者在低温下无法实现。本文介绍了触变聚合物密封胶(TPS)的实验室改进和大规模现场试验。TPS体系由有机交联聚合物和优化的流变改性剂组成,可以预测和控制交联时间。这使得TPS可以精确地定位到水平井或斜井中,以帮助控制不需要的水或气。对TPS体系进行了大量的实验室测试,以确定低温下的最佳流变性。专门建立了一个实验室规模的测试单元,在35至40°C的低温下验证触变共混物的发展。在实验室测试成功后,进行了520英尺长的测试,以模拟现场试验。它由集中的4 1/2-in组成。油管在7-in内水平下入。套管。4个直径为4mm的预钻孔位于油管的中间位置,代表射孔,为油管和套管的环空提供连通。——2.25。外径(OD)高压软管,代表连续油管,放置在4 1/2-in。用于将TPS流体输送到射孔。整个装置进行了5000 psi的压力测试,并使用绝缘加热毯加热到40°C。使用高压泵泵送并置换了6桶TPS,这足以形成一个300英尺的环空塞。化学物质被允许交联并放置45小时。现场测试结果表明,300英尺TPS环空桥塞能够承受高达4,620 psi的压差。然后在不同的位置进行切割,包括处理过的和未处理过的,以确认、评估和观察TPS在管截面上的位置。研究人员观察到,TPS可以在油管和扶正器之间较小的空间内流动,有助于确保最佳密封。本文介绍的TPS系统可以帮助使用CAJ尾管的长水平井减少不必要的水或气产量。预射孔尾管与地层之间的开放环空,使得对漏失层、高渗透层或裂缝的选择性隔离极具挑战性。如果不加以处理,最终会导致产水量的大幅增加,并最终降低油田的经济寿命。
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引用次数: 0
Root Cause Analysis for Iron Sulfide Deposition in Sour Gas Wells 含硫气井硫化铁沉积的根本原因分析
Pub Date : 2019-10-13 DOI: 10.2118/198187-ms
Tao Chen, Qiwei Wang, F. Chang, Jairo Leal, Mauricio Espinosa
Iron sulfide (FeS) deposition is a ubiquitous phenomenon in sour oil and gas wells, especially for these producing from high temperature and high pressure reservoirs. Hydrogen sulfide (H2S) gas is highly soluble in water and readily reacts with carbon steel and dissolved iron once in contact, which leads to the formation of FeS scale. The surface deposition or bulk precipitation of FeS scale is detrimental to flow assurance, such as flow restriction, pitting corrosion and stabilized emulsion. Compared to the conventional carbonate and sulphate scales, the mitigation of iron sulfide deposition is notoriously difficult. It is essential to understand its root causes in order to develop a suitable strategy to manage the problem effectively. By combining laboratorial tests and model simulations, new progresses have been made on the FeS root cause analysis for high temperature high H2S gas wells. The iron sources were determined over different stages of well life from drilling, completion, acidizing to production. Results from this study demonstrate that the iron contributed by the sour reservoir connate water is limited and is not the major cause to FeS deposition on downhole tubular in sour gas wells. Carbon steel corrosion during production stage is one source of FeS deposition. However, the rate of iron sulfide deposition during production is minor and far less than the deposit observed in the field. Other sources of iron sulfide deposition should be further investigated. Another major source is the iron released from tubing due to acid corrosion during acidizing stimulation, which potentially leads to severe formation damage and associated deposition problems in the production tubing and equipment. In addition, the iron contamination in the drilling fluid could contribute to FeS scaling problem. This paper presents a fundamental study to understand the sources of iron for FeS deposition in high H2S sour wells producing from carbonate reservoirs. Appropriate mitigation strategies are recommended accordingly.
硫化铁沉积是含硫油气井中普遍存在的现象,特别是高温高压油气井。硫化氢(H2S)气体极易溶于水,一旦与碳钢和溶解的铁接触就容易发生反应,从而形成FeS结垢。FeS水垢的表面沉积或大块沉淀不利于流动保证,如流动限制、点蚀和稳定乳液。与传统的碳酸盐和硫酸盐垢相比,减缓硫化铁沉积是出了名的困难。为了制定有效管理问题的合适策略,了解其根本原因是至关重要的。通过室内试验与模型模拟相结合,在高温高硫化氢气井FeS成因分析方面取得了新的进展。从钻井、完井、酸化到生产的不同井寿命阶段确定了铁源。研究结果表明,含硫气藏原生水对铁的贡献是有限的,并不是导致含硫气井井下FeS沉积的主要原因。碳钢在生产过程中的腐蚀是FeS沉积的来源之一。然而,在生产过程中,硫化铁的沉积速度很小,远远低于现场观察到的矿床。硫化铁沉积的其他来源有待进一步研究。另一个主要来源是在酸化增产过程中,由于酸腐蚀,从油管中释放出铁,这可能导致严重的地层损害,并导致生产油管和设备的沉积问题。此外,钻井液中的铁污染也可能导致FeS结垢问题。本文为了解碳酸盐储层高硫化氢酸井中FeS沉积的铁源进行了基础性研究。因此,建议采取适当的缓解战略。
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引用次数: 0
Overview of Tracer Applications in Oil and Gas Industry 示踪剂在油气工业中的应用综述
Pub Date : 2019-10-13 DOI: 10.2118/198157-ms
Deena Tayyib, Abdulaziz Alqasim, S. Kokal, O. Huseby
Tracer technology is an efficient and effective monitoring and surveillance tool with many useful applications in the oil and gas industry. Some of these applications include improving reservoir characterization, waterflood optimization, remaining oil saturation (Sor) determination, fluid pathways, and connectivity between wells. Tracer surveys can be deployed inter-well between an injector and offset producer(s) or as push-and-pull studies in a single well. Tracers can be classified several ways. (a) Based on their functionality: partitioning and passive tracers. Partitioning tracers interact with the reservoir and thus propagate slower than passive tracers do. The time lag between the two types can be used to estimate Sor, to ultimately assess and optimize EOR operations. (b) Based on their carrying fluid: water and gas tracers. These can be used in IOR or EOR operations. All gas tracers are partitioning tracers and the most common are perfluorocarbons; they are thermally stable, environmentally friendly, have high detectability and low natural occurrence in the reservoir. On the other hand, water tracers are passive tracers and the most commonly used ones are fluorinated acids. (c) Based on radioactivity: radioactive and non-radioactive tracers. Selecting a tracer to deploy in the field depends on a number of factors including their solubility, fluid compatibility, background concentration, stability, detectability, cost, and environmental impact. This paper provides an overview of various tracer applications in the oil and gas industry. These will include the single-well tracer test (SWCT), inter-well tracer test (IWTT), nano tracers, gas tracers and radioactive tracers. Their use will be highlighted in different scenarios. Field case studies will be reviewed for all types of tracers. Lessons learnt for all the applications, including what works and what does not work, will be shared. Specific cases and examples will include the optimization of waterflood operations, remaining oil saturation determination, flow paths and connectivity between wells, and IOR/EOR applications. The current state-of-the-art will be presented and novel emerging methods will be highlighted. This paper will showcase how the tracer technology has evolved over the years and how it shows great potential as a reservoir monitoring and surveillance tool.
示踪剂技术是一种高效的监测工具,在油气行业中有着广泛的应用。其中一些应用包括改善储层特征、水驱优化、剩余油饱和度(Sor)测定、流体路径和井间连通性。示踪剂测量可以部署在注入器和邻井采油器之间的井间,也可以在单井中进行推拉研究。示踪剂可以按几种方式分类。(a)根据其功能:分划和被动示踪剂。分割示踪剂与储层相互作用,因此传播速度比被动示踪剂慢。两种类型之间的时间差可用于估计Sor,最终评估和优化EOR操作。(b)根据其携带流体:水和气体示踪剂。这些可用于IOR或EOR操作。所有的气体示踪剂都是分割示踪剂,最常见的是全氟碳化合物;它们具有热稳定、环境友好、可探测性高、在储层中自然存在率低等特点。另一方面,水示踪剂是被动示踪剂,最常用的是氟化酸。(c)根据放射性:放射性和非放射性示踪剂。选择在现场部署的示踪剂取决于许多因素,包括它们的溶解度、流体相容性、本底浓度、稳定性、可探测性、成本和环境影响。本文概述了各种示踪剂在石油和天然气工业中的应用。这些测试包括单井示踪剂测试(SWCT)、井间示踪剂测试(IWTT)、纳米示踪剂、气体示踪剂和放射性示踪剂。它们的使用将在不同的场景中突出显示。将审查所有类型示踪剂的现场案例研究。所有应用程序的经验教训,包括哪些可行,哪些不可行,都将被分享。具体案例包括水驱作业的优化、剩余油饱和度的确定、井间流动路径和连通性,以及IOR/EOR应用。将介绍当前的最先进的技术,并强调新的新兴方法。本文将展示示踪剂技术多年来的发展,以及它如何显示出作为油藏监测工具的巨大潜力。
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引用次数: 15
Turning Threat into Opportunity: NORM Management Helps to Recoup the Deferred Production from North Kuwait 化威胁为机遇:规范管理有助于弥补北科威特延期生产
Pub Date : 2019-10-13 DOI: 10.2118/198117-ms
N. Saleh, H. Chetri, M. Al-Mutawa
North Kuwait has a vision to produce about 1 million BOPD within next couple of year. As a part of this strategy, all efforts & opportunities are being synchronized to maximize the production. A serious threat to this plan was confronted by observation of Naturally occurring radioactive materials (NORM) at some of the producers, a new challenge for which the asset did not anticipate or had any plan earlier. The paper proposal covers how this threat was converted into an opportunity. A comprehensive review of the wells with NORM was done to understand the link to specific reservoir related issues or zone's mineralogy. As this kind of production problem has been faced for the first time in North Kuwait, brainstorming and technical pros & cons were investigated with internal as well as external consultants. A due diligence was conducted to existing rules & procedures within KOC and Kuwait. Case histories from different parts of the world were reviewed as to how such issues had been resolved. Measurement of NORM, accuracy & validity was also looked into, which varied from vendor to vendor. Thus the gathered knowledge was shared with all stake holder teams. As almost 30-40 MBOPD was the locked in potential, fast track actions have been taken to create a contract to manage wells suffering from NORM. After going through a fast track identification of suitable vendor, contract was awarded to one of the international vendor. Accordingly, workover rigs were made ready to handle NORM remediation operations professionally. Simultaneously, technical evaluation of the performance of wells infected with NORM was done to understand the phenomenon and the relationship with the changes in reservoir pressure / stimulation. A workover schedule was prepared and implemented to revive the shut-in production potential to the GCs, resulting in a bump in oil production for North Kuwait. As a result of the strategy adopted, deferment of oil production due to NORM, which hovered to more than 1.5 years in the past, is prevented, thus helping production target requirements for the Asset. Performance evaluation of wells indicated that there is a strong relationship of reservoir pressure and stimulation with the NORM level. NORM management requires an integrated team approach, ranging from working units to the organization level and a proactive analytical approach to understand the impact of ongoing sub-surface operations on NORM tendencies. The proper understanding and analysis done in overcoming the NORM has aided in enhancing and sustaining the production via having extended productive life for the wells.
北科威特的目标是在未来几年内生产约100万桶/天。作为该战略的一部分,所有的努力和机会都是同步的,以最大限度地提高产量。在一些生产商观察到自然产生的放射性物质(NORM),这对该计划构成了严重威胁,这是该资产没有预料到或之前没有任何计划的新挑战。这份书面建议书涵盖了这种威胁是如何转化为机遇的。对使用NORM的井进行了全面审查,以了解与特定油藏相关问题或区域矿物学的联系。由于这种生产问题在北科威特是第一次遇到,因此与内部和外部顾问进行了集思广益和技术利弊调查。对科威特石油公司和科威特的现行规则和程序进行了尽职调查。审查了世界不同地区的历史案例,以了解这些问题是如何解决的。规范,准确性和有效性的测量也被研究,这是不同的供应商。因此,收集到的知识与所有利益相关者团队共享。由于潜在产能锁定在30-40万桶/天,因此采取了快速行动来签订合同,以管理受NORM影响的油井。在通过快速通道识别合适的供应商后,合同被授予一家国际供应商。因此,修井机可以专业地处理NORM修复作业。同时,对受NORM影响的油井进行了技术评价,以了解该现象及其与油藏压力/增产变化的关系。制定并实施了修井计划,以恢复gc的关井生产潜力,从而提高了北科威特的石油产量。由于采用了该策略,避免了过去因NORM而导致的石油生产延迟,从而有助于实现该资产的生产目标要求。井的动态评价表明,油藏压力和增产与规范水平有很强的关系。规范管理需要一个集成的团队方法,从工作单位到组织层面,以及一个积极的分析方法,以了解正在进行的地下作业对规范趋势的影响。在克服规范方面所做的正确理解和分析有助于通过延长油井的生产寿命来提高和维持产量。
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引用次数: 0
The Synergy of Surfactant and Nanoparticles: Towards Enhancing Foam Stability 表面活性剂和纳米颗粒的协同作用:增强泡沫稳定性
Pub Date : 2019-10-13 DOI: 10.2118/198190-ms
Z. Alyousef, D. Schechter
Gas injection has been widely used for enhancing oil recovery in petroleum reservoirs. One of the major challenges facing this technique is the high mobility of gas caused by its lower viscosity compared to reservoir fluids. Injecting the gas in a foam phase can solve the mobility challenge by increasing the gas apparent viscosity. Surface active agents such as surfactants are usually used to generate foams. However, the long-term stability of the surfactants is challenging. The synergistic effect of surfactants and nanoparticles may offer a novel technique to solve the foam stability issue and generate stronger foams. This study evaluates the role of nanoparticles on stabilizing surfactant foams in porous media. Anionic surfactant and surface modified silica nanoparticles were used in this assessment. Dynamic foam tests were conducted to study the foam stability and strength in porous media. The major parameter used to evaluate the foam strength in this study is the mobility reduction factor (MRF). The experiments were conducted using nitrogen gas at elevated pressure. The influence of nanoparticles on surfactant foam strength was conducted at different nanoparticles concentrations and fixed surfactant concentration. The results demonstrated that the presence of nanoparticles in surfactant solution resulted in a more stable foam compared to surfactant alone. The nanoparticles used in this study seem to enhance the foam stability by either one or two mechanisms: particle arrangement during film drainage or increasing the capillary pressure of coalescence. Based on the dynamic foam tests, higher pressure drops were reported for the mixtures of nanoparticles and surfactant compared to surfactant alone. This clearly indicated the higher resistance to gas flow caused by the foam generated using the mixture. The results also showed that as the nanoparticles concentration increased, MRF increased, too. The MRF for the sample contains only surfactant was 72. However, the addition of 0.50 and 1.00 wt% of nanoparticles to the surfactant solution resulted in higher MRF: 75 and 85, respectively. The need for generating strong foam is very important to ensure the long term stability of foam and, consequently, reducing the gas mobility in porous media. The addition of solid nanoparticles to surfactant solutions might strengthen the aqueous film between gas bubbles and, eventually, enhancing the foam stability.
注气技术在提高油藏采收率方面得到了广泛的应用。该技术面临的主要挑战之一是,与储层流体相比,由于粘度较低,气体具有高流动性。在泡沫相中注入气体可以通过增加气体表观粘度来解决流动性问题。表面活性剂如表面活性剂通常用于产生泡沫。然而,表面活性剂的长期稳定性是一个挑战。表面活性剂和纳米颗粒的协同作用可能为解决泡沫稳定性问题和产生更强的泡沫提供一种新技术。研究了纳米颗粒对多孔介质中表面活性剂泡沫的稳定作用。使用阴离子表面活性剂和表面改性二氧化硅纳米颗粒进行评价。通过动态泡沫试验研究了多孔介质中泡沫的稳定性和强度。在本研究中,用来评价泡沫强度的主要参数是迁移率降低系数(MRF)。实验是用高压氮气进行的。在不同纳米颗粒浓度和固定表面活性剂浓度下,研究了纳米颗粒对表面活性剂泡沫强度的影响。结果表明,表面活性剂溶液中纳米颗粒的存在比单独使用表面活性剂的泡沫更稳定。本研究中使用的纳米颗粒似乎通过一种或两种机制来增强泡沫稳定性:在膜排水过程中颗粒排列或增加聚并的毛细压力。根据动态泡沫测试,纳米颗粒和表面活性剂的混合物比单独的表面活性剂的压降更高。这清楚地表明,使用混合物产生的泡沫对气体流动的阻力更高。结果还表明,随着纳米颗粒浓度的增加,磁流变系数也随之增加。仅含表面活性剂的样品的MRF为72。然而,在表面活性剂溶液中加入0.50 wt%和1.00 wt%的纳米颗粒会导致更高的MRF:分别为75和85。为了确保泡沫的长期稳定性,从而降低多孔介质中的气体流动性,产生强泡沫的需求是非常重要的。在表面活性剂溶液中加入固体纳米颗粒可能会加强气泡之间的水膜,最终提高泡沫的稳定性。
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引用次数: 4
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Day 2 Mon, October 14, 2019
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