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MODELING FIELD DIFFUSION EXPERIMENTS IN CLAY ROCK: INFLUENCE OF NUMERICAL REPRESENTATION OF BOREHOLE AND ROCK INTERFACE 粘土岩模拟场扩散试验:井岩界面数值表征的影响
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.2.63
T. Gimmi
Argillaceous rocks are considered in Switzerland and in other countries as potential host rocks for the deep geologic disposal of radioactive waste. Opalinus Clay, a formation of Jurassic age, is at present the most favored candidate in Switzerland. It has a low hydraulic conductivity, no or only few active fractures, and a large retention capacity for sorbing solutes, which make this sediment well suited as an additional barrier for the spreading of contaminants. Transport through Opalinus Clay is typically dominated by diffusion. Accordingly, the diffusion of tracers through this material is intensively studied. In the underground research facility at Mont Terri in Switzerland, field experiments are performed that aim at investigating the diffusion and retention of sorbing tracers at intermediate scales and under relevant in-situ conditions. The field experiments use a borehole, from which tracers diffuse into the surrounding rock. The tracer cocktail in the borehole is continuously circulated, which allows to monitor the tracer decrease over time. When modeling these experiments, care has to be taken to correctly represent the inlet system. In this paper, it is shown how the numerical representation of the borehole and inlet system and the spatial discretization affect the simulation results of mobile and sorbing tracers. For mobile tracers, it is generally sufficient to use an effective diffusion coefficient for the circulated fluid about 30 times larger than that in the rock to mimic the continuous mixing. In contrast, for sorbing tracers even a 7000 times larger diffusion coefficient may, at early times, not lead to homogeneous borehole concentrations. This is because the equilibrium sorption on the rock quickly and drastically reduces the tracer concentrations at the interface. As a consequence, the simulated flux into the rock becomes too small, and the calculated average decrease of the borehole concentration is much too slow even for larger times. The slow decrease can be similar to that simulated for a much less sorbing solute, which of course would critically affect parameter estimation when fitting the model to observed data. Increasing the borehole diffusion coefficient to very large values to obtain a complete mixing can lead to a too fast simulated concentration decrease, if the spatial discretization is insufficient. Thus, a careful checking of the numerical results is required for the strongly sorbing tracers.
在瑞士和其他国家,泥质岩石被认为是放射性废物深层地质处置的潜在宿主岩石。Opalinus Clay是一种侏罗纪时期的地层,目前是瑞士最受青睐的候选。它具有较低的水力导电性,没有或只有很少的活动裂缝,并且具有很大的吸附溶质的保留能力,这使得这种沉积物非常适合作为污染物扩散的额外屏障。通过蛋白石粘土的运输通常以扩散为主。因此,对示踪剂在该材料中的扩散进行了深入研究。在瑞士蒙特特里的地下研究设施中,进行了实地实验,目的是研究吸附示踪剂在中等尺度和有关的原位条件下的扩散和保留。现场实验使用钻孔,示踪剂从中扩散到周围的岩石中。在井眼中连续循环示踪剂混合物,从而可以监测示踪剂随时间的减少。在对这些实验进行建模时,必须注意正确地表示进气系统。本文给出了井眼和进气系统的数值表示和空间离散化如何影响可移动和可吸收示踪剂的模拟结果。对于可移动示踪剂,通常使用比岩石中有效扩散系数大30倍左右的循环流体有效扩散系数来模拟连续混合就足够了。相比之下,对于吸附示踪剂,即使扩散系数大7000倍,在早期也可能导致井内浓度不均匀。这是因为岩石上的平衡吸附迅速而急剧地降低了界面处的示踪剂浓度。因此,模拟进入岩石的通量变得太小,即使在较大的时间内,计算出的钻孔浓度的平均下降速度也太慢。这种缓慢的下降可能类似于对吸收量小得多的溶质的模拟,这当然会严重影响模型与观测数据拟合时的参数估计。如果空间离散化不够充分,将钻孔扩散系数增大到非常大的值以获得完全混合可能导致模拟浓度下降过快。因此,需要对强吸附示踪剂的数值结果进行仔细的检查。
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引用次数: 2
AGRICULTURAL AND WATERSHED MODELING WITH EPIC, APEX, AND SWAT: COMPUTATIONAL TOOLS FOR INVESTIGATING, PLANNING, AND UNDERSTANDING THE FUTURE 史诗、顶点和swat的农业和流域建模:用于调查、规划和理解未来的计算工具
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.10.MR06
J. Wolfe, Jaehak Jeong, Kara Paulk, A. Farley
and the – the mid-1960’s, computer models describing agricultural, environmental, and hydrological processes have been developed by scientists at BRC. Today BRC scientists continue to refine and support numerous modeling products that are used world-wide by researchers, environmental managers, and government policy makers. The Environmental Policy and Integrated Climate (EPIC) model, the Agricultural Policy and Environmental eXtender (APEX) model, and the Soil and Water Assessment Tool (SWAT) are the most prominent and heavily used. This paper briefly describes their history, general organization, usage tools, support and availability, and three example uses. In the first example, the EPIC model was used to evaluate irrigation control methods on an urban landscape. The uncalibrated results suggested that scheduled irrigation was more efficient than sensor-based. This was unexpected but explained by poor plant growth under water-saturated soil conditions. In another example, a calibrated SWAT model was used to determine sediment sources and evaluate a detention pond management strategy in a heavily developed urban watershed. Stream channel erosion was found to be higher than upland erosion and the implementation of a sediment detention pond showed that sediment exports could be reduced by up to 14%. the APEX model was used to examine two irrigation strategies in cascading rice paddy fields. Data from Okayama, Japan was used to develop a terraced hydrology model and predict irrigation management practice effects on water useage and soil and nitrogen exports to downstream waterbodies. The uncalibrated model showed that constant flooding irrigation produced higher crop yields but also increased sediment exports. Cycled flooding however showed reduced nitrogen exports. Determining the optimial management strategy depends upon user goals. Mini-review
20世纪60年代中期,BRC的科学家开发了描述农业、环境和水文过程的计算机模型。今天,BRC的科学家们继续完善和支持众多的建模产品,这些产品被世界各地的研究人员、环境管理者和政府决策者所使用。环境政策与综合气候(EPIC)模型、农业政策与环境扩展器(APEX)模型和水土评价工具(SWAT)是最突出和使用最多的模型。本文简要描述了它们的历史、一般组织、使用工具、支持和可用性,以及三个示例使用。在第一个例子中,使用EPIC模型对城市景观的灌溉控制方法进行了评价。未经校准的结果表明,定时灌溉比基于传感器的灌溉更有效。这是出乎意料的,但可以解释为在水分饱和的土壤条件下植物生长不良。在另一个例子中,在一个高度发达的城市流域,使用校准的SWAT模型来确定沉积物来源并评估滞留池管理策略。河道侵蚀被发现比高地侵蚀更严重,泥沙滞留池的实施表明泥沙出口可以减少高达14%。利用APEX模型对两种灌溉策略进行了分析。来自日本冈山的数据被用于开发一个梯田水文模型,并预测灌溉管理实践对水利用和土壤和氮向下游水体出口的影响。未经校准的模型显示,持续的洪涝灌溉提高了作物产量,但也增加了沉积物的出口。然而,循环淹水减少了氮的输出。确定最佳管理策略取决于用户目标。本文着重
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引用次数: 0
NITROUS OXIDE AND CARBON DIOXIDE EMISSIONS FROM PADDY SOIL TREATED WITH RICE HUSK PRODUCTS AT DIFFERENT MOISTURE CONTENTS IN A SHORT-TERM EXPERIMENT 不同含水率稻壳制品处理水稻土的氮氧化物和二氧化碳排放短期试验
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.7.9
T. Ha, M. Maeda, T. Fujiwara, H. Nagare, S. Akao, Quoc Thinh Tran
1 Graduate School of Environmental and Life Science, Okayama University (3-1-1, Tsushima-Naka, Kita-Ku, Okayama 700-8530, Japan) E-mail: hathanh1211@gmail.com 2* Associate Professor, Graduate School of Environmental and Life Science, Okayama University (3-1-1, Tsushima-Naka, Kita-Ku, Okayama 700-8530, Japan) Corresponding author E-mail: mun@cc.okayama-u.ac.jp 3 Professor, Agriculture Unit, Research and Education Faculty, Kochi University, Japan (200 Monobe Otsu, Nankoku, Kochi 783-8502, Japan) E-mail: fujiwarat@kochi-u.ac.jp 4 Associate Professor, Graduate School of Environmental and Life Science, Okayama University (3-1-1, Tsushima-Naka, Kita-Ku, Okayama 700-8530, Japan) E-mail: nagare-h@okayama-u.ac.jp 5 Associate Professor, Faculty of Science and Engineering, Doshisha University (1-3, Tatara Miyakodani, Kyotanabe, Kyoto 610-0394, Japan) E-mail: sakao@mail.doshisha.ac.jp 6 Graduate School of Environmental and Life Science, Okayama University (3-1-1, Tsushima-Naka, Kita-Ku, Okayama 700-8530, Japan) E-mail: tranquocthinh89@gmail.com
1冈山大学环境与生命科学研究生院(3-1-1,Tsushima-Naka, kitama 700-8530,日本)E-mail: hathanh1211@gmail.com 2*冈山大学环境与生命科学研究生院副教授(3-1-1,Tsushima-Naka, kitama 700-8530,日本)通讯作者E-mail:mun@cc.okayama-u.ac.jp 3日本高知大学研究与教育学部农业部教授(高知市南国大津单部200号,高知783-8502,日本)E-mail: fujiwarat@kochi-u.ac.jp 4冈山大学环境与生命科学研究生院副教授(日本冈山市北区中对中3-1-1,冈山市700-8530)E-mail:nagare-h@okayama-u.ac.jp 5社社大学理工学学院副教授(京都京都610-0394宫古谷达原1-3)E-mail: sakao@mail.doshisha.ac.jp 6冈山大学环境与生命科学研究生院(日本冈山700-8530北区对岛中3-1-1)E-mail: tranquocthinh89@gmail.com
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引用次数: 0
Program of Debrief Session of the Project Researches on Environmental Rehabilitation in Asia FY2020 2020财年亚洲环境修复项目研究报告会计划
Pub Date : 1900-01-01 DOI: 10.3107/jesss.10.collo1
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引用次数: 0
EVALUATION OF WASTE TREATMENT STRATEGIES IN CHINESE CITIES FROM VIEWPOINTS OF GHG EMISSION 温室气体排放视角下中国城市垃圾处理策略评价
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.5.27
Jinmei Yang, T. Fujiwara, Y. Matsuoka, Wei Wang
Recent years have witnessed increased attention being given to the evaluation and selection of alternative waste treatment strategies from the view of reduction of greenhouse gas (GHG) emissions. However, a long period of waste records is necessary for getting acceptably accurate results, especially in calculating GHG emission from disposal site. Therefore, in this paper, applying the systematic approach we have developed in the previous work, the back-casting and ex-post forecasting of the waste quantity by composition in the past is conducted. Then, current GHG emissions in five Chinese metropolitan cities are investigated and analyzed; thereafter, a scenario analysis is carried out in Shanghai based on the forecasts of waste generation and the corresponding waste category in 2015. Methane (CH 4 ), carbon dioxide (CO 2 ) and nitrous oxide (N 2 O) are mainly taken into account in GHG emission due to significant amount emitted from waste treatment. The results confirm that the per capita CO 2 emission factor (kg CO 2 -eq/kg waste-treated) in Shanghai, Guangzhou, Hangzhou, Wuhan and Chengdu in 2007 is 0.48, 0.59, 0.57, 0.41 and 0.48 respectively, thereby demonstrating that economic growth is the main driving force of GHG emissions currently observed in Chinese cities. Further, through the scenario analysis, composting and integrated waste management are considered as effective attempts at reducing GHG emissions in Shanghai.
近年来,人们越来越重视从减少温室气体排放的角度评价和选择替代性废物处理战略。然而,要获得可接受的精确结果,特别是在计算处置场地的温室气体排放量时,需要长时间的废物记录。因此,在本文中,应用我们在以前的工作中开发的系统方法,对过去的废物量进行了反推算和事后预测。然后,对中国5个特大城市的温室气体排放现状进行了调查分析;之后,根据2015年上海市的垃圾产生量和相应的垃圾类别进行情景分析。在温室气体排放中,主要考虑的是甲烷(ch4)、二氧化碳(CO 2)和氧化亚氮(n2o),因为废物处理产生了大量的排放。结果表明,2007年上海、广州、杭州、武汉和成都的人均二氧化碳排放系数(kg CO 2 -当量/kg废弃物处理量)分别为0.48、0.59、0.57、0.41和0.48,表明经济增长是中国城市温室气体排放的主要驱动力。此外,通过情景分析,认为堆肥和废物综合管理是减少上海温室气体排放的有效尝试。
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引用次数: 2
GEOCHEMISTRY OF THE RIVER RHINE AND THE UPPER DANUBE: RECENT TRENDS AND LITHOLOGICAL INFLUENCE ON BASELINES 莱茵河和多瑙河上游的地球化学:最近的趋势和对基线的岩性影响
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.1.39
J. Hartmann, N. Jansen, S. Kempe, H. Dürr
Human pressure is now severe on most of the rivers worldwide. The long term fluxes of dissolved geogenic and biogenic matter are changing dramatically, causing notable changes in aquatic bioactivity. Typical patterns of anthropogenic pressure that influence eutrophication, salinization and chemical contamination are discussed. The heavily influenced rivers Rhine and upper Danube will be used as examples, also considering their geological settings. In the past decade sewage treatment reduced nitrate and orthophosphate loads in both basins. This influenced bioactivity in the rivers, causing less silica depletion due to diatom blooms in the Rhine. Therefore a notable increase in minima concentrations of dissolved silica can be observed. In the upper Danube, however, an increase in orthophosphate concentration since 2003 is noticeable; breaking the former decreasing trend, despite treatment efforts. The hydrochemistry of major ions in both basins is strongly influenced by the ratios of carbonate, siliciclastic sediment and igneous or metamorphic rock outcrops. In addition Mesozoic evaporites and salt mining were responsible for extremely high levels of Cl, Na and SO4 in the Rhine, peaking in the 70s and 80s at concentrations of 350, 180 and 140 mg/l, respectively. Water basin management efforts cut former high levels to less than a half. Heavy metals and persistent organic pollutant concentrations are declining in the Rhine as well. A combination of climate change and anthropogenic water inputs resulted in an increase of water temperature of the Rhine by 3.5 °C during the past 50 years. In the upper Danube such a trend in water temperature can not be observed.
人类活动对世界上大多数河流造成了严重的压力。溶解的地成因和生物成因物质的长期通量正在发生巨大变化,引起水生生物活性的显著变化。讨论了影响富营养化、盐碱化和化学污染的人为压力的典型模式。受严重影响的莱茵河和多瑙河上游将作为例子,同时考虑到它们的地质环境。在过去的十年中,污水处理降低了两个流域的硝酸盐和正磷酸盐负荷。这影响了河流中的生物活性,莱茵河中硅藻的大量繁殖减少了二氧化硅的消耗。因此,可以观察到溶解二氧化硅的最低浓度显著增加。然而,在多瑙河上游,自2003年以来正磷酸盐浓度的增加是明显的;打破了之前的下降趋势,尽管治疗努力。两个盆地主要离子的水化学性质受碳酸盐岩、硅质碎屑沉积物和火成岩或变质岩露头比例的强烈影响。此外,中生代的蒸发岩和盐矿开采是莱茵河中Cl、Na和SO4含量极高的原因,在70年代和80年代分别达到350、180和140毫克/升的峰值。流域管理的努力将以前的高水位降至不到一半。莱茵河中的重金属和持久性有机污染物浓度也在下降。在过去50年里,气候变化和人为水输入的共同作用导致莱茵河水温上升了3.5℃。在多瑙河上游,没有观察到这种水温变化趋势。
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引用次数: 39
POPS CONTAMINATED SOIL TREATMENT WITH "REDUCTIVE HEATING AND SODIUM DISPERSION METHOD" AND ITS RECYCLING FOR MATERIAL OF GREEN PLANTING 采用“还原加热分散钠法”处理Pops污染土壤,并将其回收为绿色种植材料
Pub Date : 1900-01-01 DOI: 10.3107/JESSS.1.11
Y. Ishii, T. Kawai, Nobuaki Hiranaka, Hisato Takehara, H. Yara, Y. Tokashiki
"RH-SP Process" is a combined process of reductive heating for reduction of POPs (Persistent Organic Pollutants: Such as PCB, Dioxins, and Organic Chlorinate Agricultural Chemicals) from contaminated soil, and sodium dispersion for the decomposition of POPs material. We investigated the applicability of the process for three characteristic soils at Okinawa region.  BHC (Benzene Hexachloride) is reduced from 10mg/kg to lower than 0.001mg/kg in each soil and PCB is also reduced from 53mg/kg to lower than 0.5μg/kg by reductive heating. Dioxins in discharged gas shows lower than 0.1ng-TEQ/m3. From the result of green planting test with treated soil, the growth rate is same as that of normal soil, and it is also confirmed that treated soil is able to be recycled for green planting.
“RH-SP工艺”是通过还原加热减少污染土壤中的持久性有机污染物(持久性有机污染物:如多氯联苯、二恶英和有机氯酸农药)和分散钠分解持久性有机污染物的组合工艺。研究了该方法对冲绳地区三种典型土壤的适用性。通过还原加热,各土壤中六氯化苯(BHC)由10mg/kg降至0.001mg/kg以下,PCB由53mg/kg降至0.5μg/kg以下。排放气体中二恶英含量低于0.1ng-TEQ/m3。从处理过的土壤进行绿植试验的结果来看,其生长速度与正常土壤相同,也证实了处理过的土壤可以循环利用进行绿植。
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引用次数: 0
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Journal of Environmental Science for Sustainable Society
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