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Design of New Composites Nano-Catalysts for Naphtha Reforming Process: Experiments and Process Modeling 石脑油重整过程新型复合纳米催化剂的设计:实验和过程建模
Q3 Environmental Science Pub Date : 2023-05-14 DOI: 10.25130/tjes.30.2.6
A. Jarullah, A. N. Ahmed, Banafsha Ahmed, Abdullah M. Ahmed
The naphtha catalytic reforming process is evaluated by designing new composite nano-catalysts. Three catalysts were prepared for this process. The first catalyst was molybdenum carbide composite with platinum over HY zeolite (Mo2C.Pt/HY zeolite), the second catalyst was molybdenum carbide composite with platinum over modified zeolite by cerium nitrate (Mo2C.Pt/CeY zeolite), and the last catalyst was bimetallic titanium and platinum with a titanium content of 1% and platinum content of 0.11% over HY zeolite (Pt.Ti/HY zeolite). All catalysts were tested with several tests, mainly X-Ray Diffraction (XRD), BET surface area, and pore volume. All these substances were applied as catalysts for the reforming process of Iraqi heavy naphtha at the following operating conditions: reaction temperature (480, 500, and 520 ), reaction pressure (10, 12.5, and 15 bar), liquid hourly space velocity (LHSV) at 2 hr-1, and constant hydrogen to hydrocarbon ratio (H2/ HC) of 4. All the reforming reactions occurred in a packed bed pilot plant reactor to investigate its stability and activity during the reforming process. All the developed catalyst samples showed sensational stability even at operating under difficult circumstances. The best catalyst was Pt.Ti/HY zeolite based on the results obtained with respect to the octane number (86.2) at 520  and 15 bar. Also, a mathematical model to describe the reforming process with high accuracy was built and simulated using gPROMS software. The results were very satisfying since the most significant error with the wt% of reformate was 4.9% (the experimental aromatics content was 23.94 wt.%, while the predicted result was 21.67 wt.%), while Research Octane Number (RON) error was 4.7% (the experimental RON was 81, whereas the predicted value of RON was 85) among all the results meaning that the simulating was valid to describe the process.
通过设计新型复合纳米催化剂对石脑油催化重整过程进行了评价。为该工艺制备了三种催化剂。第一种催化剂是在HY沸石上的碳化钼与铂的复合物(Mo2C.Pt/HY沸石),第二种催化剂是用硝酸铈改性的沸石(Mo2C.Pt/CeY沸石)制备的碳化钼和铂的复合材料,最后一种催化剂是双金属钛和铂,其钛含量为1%,铂含量为0.11%。所有催化剂都进行了多次测试,主要是X射线衍射(XRD)、BET表面积和孔体积。所有这些物质在以下操作条件下用作伊拉克重质石脑油重整过程的催化剂:反应温度(480、500和520)、反应压力(10、12.5和15巴)、2小时-1下的液体小时空速(LHSV)和恒定的氢烃比(H2/HC)为4。所有的重整反应都发生在填充床中试装置反应器中,以研究其在重整过程中的稳定性和活性。所有开发的催化剂样品即使在困难的环境下操作也显示出惊人的稳定性。基于在520和15巴下获得的辛烷值(86.2)的结果,最好的催化剂是Pt.Ti/HY沸石。此外,还建立了一个高精度描述重整过程的数学模型,并使用gPROMS软件进行了模拟。结果是非常令人满意的,因为重整产物的wt%的最显著误差为4.9%(实验芳烃含量为23.94wt%,而预测结果为21.67wt%),在所有结果中,研究辛烷值(RON)误差为4.7%(实验RON为81,而RON的预测值为85),这意味着模拟是描述该过程的有效方法。
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引用次数: 4
A Genetic Algorithm Optimization Model for Stability of an Inclined Cutoff with Soil-Embedded Depth 含埋深倾斜路堑稳定性的遗传算法优化模型
Q3 Environmental Science Pub Date : 2023-05-13 DOI: 10.25130/tjes.30.2.4
Rafea Al-Suhili, R. Karim
A coupled artificial neural network model with a genetic algorithm optimization model is developed for a practical case of a single cutoff. The proposed cutoff is of a soil-embedded vertical part with an inclined extension. The model successfully found the optimum dimensions of the vertical and inclined parts, the optimum angle of inclination, and the optimum length of protection downstream of the cutoff for a factor of safety of 3 against piping. Two thousand one hundred cases are modeled first using Geo-studio software to find the required length of downstream protection against piping for different lengths of the vertical, inclined lengths of the cutoff, its angle of inclination, soil layer depth, and degree of anisotropy. Then the created data set was used to develop an Artificial Neural Network (ANN) model for finding the length of protection required. The ANN model showed high performance with a determination coefficient of (0.922). The genetic algorithm model needs a minimum number of randomly generated populations of 100000 and three crossover iterations to produce a stable optimum solution. Running the model for different practical cases showed that the optimum angle variation was low and fluctuated around 30o. This low angle variation was due to its lower effect on the downstream soil protection length compared to the other decision variables. At the same time, the other dimensions varied with input variables, such as the depth of the soil layer, the seepage driving head, and the degree of isotropy. For a degree of anisotropy (ratio of vertical to horizontal hydraulic gradient) less than 0.5, the results showed no need for protection against piping; hence it is recommended to use minimum dimensions for such a case. The coupled model can easily obtain the optimum dimensions for any given input. Importance analysis showed that the optimum length of the downstream protection was highly affected by the vertical and inclined length of the cutoff, while it was less affected by the angle of inclination. Correlation analysis supported the importance analysis. 
针对单个截断的实际情况,建立了人工神经网络与遗传算法的耦合优化模型。拟建截水沟为土壤嵌入的垂直部分,具有倾斜延伸部分。该模型成功地找到了垂直和倾斜部分的最佳尺寸、最佳倾斜角度和截流下游的最佳保护长度,针对管道的安全系数为3。首先使用Geo studio软件对2100个案例进行建模,以找到不同垂直长度、倾斜截水长度、倾斜角度、土层深度和各向异性程度的管道下游保护所需长度。然后,使用创建的数据集来开发人工神经网络(ANN)模型,以找到所需的保护长度。神经网络模型具有较高的性能,决定系数为(0.922)。遗传算法模型需要最少100000个随机生成的种群和三次交叉迭代才能产生稳定的最优解。模型在不同的实际情况下运行表明,最佳角度变化较小,在30°左右波动。这种低角度变化是由于与其他决策变量相比,其对下游土壤保护长度的影响较小。同时,其他维度随着输入变量的变化而变化,如土层深度、渗流驱动水头和各向同性程度。对于各向异性程度(垂直与水平水力梯度之比)小于0.5的情况,结果表明不需要对管道进行保护;因此建议在这种情况下使用最小尺寸。耦合模型可以很容易地获得任何给定输入的最佳尺寸。重要性分析表明,下游保护的最佳长度受截水垂直和倾斜长度的影响较大,而受倾斜角度的影响较小。相关性分析支持重要性分析。
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引用次数: 1
Study the Mechanical Properties and Fatigue Effect of Multilayer Woven E-Glass/Epoxy Composite under Constant and Variable Loading 多层机织E-玻璃/环氧树脂复合材料在恒载和变载下的力学性能和疲劳效应研究
Q3 Environmental Science Pub Date : 2023-05-03 DOI: 10.25130/tjes.30.2.3
Saif-Aldeen Ghafel, N. Namer, Abduljabar H. Ali
The present work studies the effect of adding woven E-glass fibers [0°/90°], 16 layers with 50% weight fraction to pure epoxy (matrix) on fatigue behavior under constant and variable loadings. The CNC water jet cutting machine was used to cut the composite samples with five fiber direction angles, such as (0°, 5°, 15°, 30°, and 45°). The tensile test was used to determine the composite material’s mechanical properties. The results showed that the composite material with 5° of fiber direction had the highest ultimate tensile stress, i.e., 353 MPa, and the highest Young's Modulus, i.e., 11940 MPa, compared to other samples with angles of (0°, 15°, 30°, 45°) of fiber direction. The sample with 5° angle was adopted in constant and variable fatigue loading tests. The fatigue test results under constant loading showed a 24.8 times fatigue strength improvement for composite material at 107 cycles compared to pure epoxy. The fatigue test under variable loading was conducted with two types of sequence loading program tests at a constant number of cycles at each stress level: high-low sequence loading with stress of 170-130 MPa with 10,000 and 20,000 cycles for each stress level and low-high sequence loading with stress 130-170 MPa with 10,000 and 20,000 cycle for each stress level loading and so on to failure. The results showed that the fatigue life under high-low sequence loading for both 10,000 and 20,000 cycles was less than that of the low-high sequence loading. Also, the results showed that Miner's rules were safe to calculate the damage of composite material used in this work where the damage was above one (D > 1).
本工作研究了在纯环氧树脂(基体)中添加0°/90°编织e -玻璃纤维,16层,重量分数为50%,对恒定和可变载荷下疲劳性能的影响。采用数控水射流切割机对复合材料样品进行(0°、5°、15°、30°、45°)5种纤维方向角的切割。通过拉伸试验确定复合材料的力学性能。结果表明:与纤维方向为(0°、15°、30°、45°)的复合材料相比,纤维方向为5°的复合材料的极限拉伸应力最高,为353 MPa,杨氏模量最高,为11940 MPa;恒、变疲劳载荷试验采用5°角试样。恒载疲劳试验结果表明,复合材料在107次循环时的疲劳强度比纯环氧树脂提高了24.8倍。变载荷下的疲劳试验采用两种顺序加载程序,在每个应力水平下进行等次循环试验:高-低顺序加载,应力为170-130 MPa,每个应力水平进行1万次和2万次循环;低-高顺序加载,应力为130-170 MPa,每个应力水平进行1万次和2万次循环,以此类推直至失效。结果表明:1万次和2万次高-低顺序载荷下的疲劳寿命均小于低-高顺序载荷下的疲劳寿命;结果表明,当复合材料的损伤值大于1时,Miner规则对于计算复合材料的损伤是安全的。
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引用次数: 1
The Influence of Angled Electrodes on Various Characteristics in EDM Process - Review Article 角度电极对电火花加工各种特性的影响-综述
Q3 Environmental Science Pub Date : 2023-04-27 DOI: 10.25130/tjes.30.2.1
Ahmed E Abbas, A. A. Khleif
Electric discharge machining (EDM) is considered one of the most energy-efficient production methods for the highly accurate processing of any electrically conductive materials, regardless of mechanical characteristics. EDM is a non-contact method used in a diverse range of industries, including aerospace, industrial, instruments, molds and dies, and medical tools, particularly for hard materials with simple or intricate geometries and shapes. This review investigated EDM research in process, material, operational parameter selection, the influence on outputs, numerous process varieties, and innovative strategies to improve performance. The present study presented an overview of the EDM process with different angled electrode geometry, optimization, and modeling of method parameters, and the effect of parameters such as material removal rate (MRR), pulse shape, and surface roughness. This review (1) organized the published literature in a specific way, with an emphasis on both theoretical and experimental findings investigations to enhance the process performance, such as the rate of material removal and quality of surface, among others, and tool wear; (2) investigated assessment methods and procedures used to evaluate process circumstances; and (3) examined the EDM improvements and predicted future trends study. The article's conclusion section extracts specific points and gaps in each part. As a result, the article is straightforward to comprehend and incredibly beneficial to the scientific community.
放电加工(EDM)被认为是对任何导电材料进行高精度加工的最节能的生产方法之一,无论其机械特性如何。EDM是一种非接触式方法,用于各种行业,包括航空航天、工业、仪器、模具和医疗工具,尤其是几何形状和形状简单或复杂的硬质材料。本文综述了电火花加工在工艺、材料、操作参数选择、对产量的影响、多种工艺以及提高性能的创新策略方面的研究。本研究概述了不同角度电极几何形状的电火花加工工艺、方法参数的优化和建模,以及材料去除率(MRR)、脉冲形状和表面粗糙度等参数的影响。这篇综述(1)以一种特定的方式组织了已发表的文献,重点是理论和实验研究结果,以提高工艺性能,如材料去除率和表面质量等,以及工具磨损;(2) 调查了用于评估过程环境的评估方法和程序;以及(3)研究了EDM的改进并预测了未来的趋势研究。文章的结论部分摘录了每个部分的具体观点和差距。因此,这篇文章通俗易懂,对科学界非常有益。
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引用次数: 1
Utilizing LPG as an Additive to Enhance the Properties of Iraqi Diesel Oil 利用LPG作为添加剂提高伊拉克柴油的性能
Q3 Environmental Science Pub Date : 2023-04-27 DOI: 10.25130/tjes.30.2.2
Davan Abdulqadir, Fakhri Hamdullah Ibraheem
For environmental and economic purposes, it is necessary to search for methods that reduce gas emission by flare from the oil refineries. It causes environmental pollution and warmup. All laboratory tests have been completed at Koya University, with the contribution of the Institute of Technology in Koya, to check some readings and verify their accuracy. Increasing the absorptivity of the gases by heavy oil will have expected to improve oil burning characteristics. This research aims to determine the best operating conditions that leads for higher absorption. In this research the diesel oil is considered as a heavy cut and LPG as a light gas. A lab scale unit was installed for that purpose. The amount of changes in oil weight before and after atomizing was determines as well as, the properties of the diesel oil like flash point, cetane number, and diesel index. The effect of a wide range of atomizing time (10, 20, 30, 40, 50, 60, and 90) minutes at different temperatures (0, 10, 20, 30, 40, and 50) °C was considered. The data is discussed and graphically analyzed.  The optimum operating conditions is achieved by, 9 liters/minute gas Atomizing flowrate of LPG for one liter of diesel oil, atomizing Temperature is 30 ᵒC, atomizing Time is 30 minutes’ minimum till 60 minutes’ maximum. The produced Diesel Flash Point is 55 ᵒC, and the amount of gas absorption is 24 gm per 850 gm of diesel oil which represent 2.8 % of diesel weight and 5% of LPG gas flowrate.
为了环境和经济的目的,有必要寻找减少炼油厂火炬气体排放的方法。它会造成环境污染和升温。在Koya技术研究所的协助下,在Koya大学完成了所有实验室测试,以检查一些读数并核实其准确性。提高重油对气体的吸收率有望改善油的燃烧特性。本研究旨在确定最佳的操作条件,导致更高的吸收。在本研究中,柴油被认为是重油,液化石油气被认为是轻气。为此目的安装了一个实验室规模的装置。测定了雾化前后油品质量的变化量以及柴油闪点、十六烷值、柴油指数等特性。考虑了不同温度(0、10、20、30、40、50、60和90)下雾化时间(10、20、20、30、40和50)min的影响。对数据进行了讨论和图形化分析。最佳工况为:1升柴油用LPG雾化流量为9升/分钟,雾化温度为30℃,雾化时间最短为30分钟,最长为60分钟。生产的柴油闪点为55℃,每850克柴油的气体吸收量为24克,占柴油重量的2.8%,LPG气体流量的5%。
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引用次数: 0
Flood Risk Analysis: The Case of Tigris River (Tikrit /Iraq) 洪水风险分析:以底格里斯河(提克里特/伊拉克)为例
Q3 Environmental Science Pub Date : 2023-03-31 DOI: 10.25130/tjes.30.1.11
Wesam Mohammed-Ali, R. S. Khairallah
The study of flood risks has a fundamental role in ensuring the safety of cities near rivers and drawing up plans to protect them during future floods. This study aims to manage potential flood risks, and Tikrit city was used as a case study. The daily discharge of the Tigris River in the study area was provided by the Iraqi Ministry of Water Resources from 2019 to 2022. The HEC-RAS software was utilized to build a 2-D flood model to simulate potential flood scenarios. First, the model was calibrated by adjusting the value of Manning's coefficient (n), and it was found that n = 0.031 reflects the nature of the region because the Nash-Sutcliff Error (NSE) was 0.93. Then, the efficiency of the 2-D flood model was verified by comparing the model’s results with the study area’s satellite images, and the results showed a great match. Following that, the 2-D model was used under different flooding scenarios. The results showed that the size of areas exposed to flooding increased with the discharges passing through the Tigris River. For instance, increasing the discharge to 800m3/s increased the flooded areas by 13.7%, while increasing the discharge to 1500 m3/s increased the flooded areas by 90.7 % compared to the river’s normal flow. Also, the results showed that the eastern regions of the riverbanks are more vulnerable to flooding than the western side because the ground levels are low on the eastern side compared to the western part of the riverbanks.
洪水风险的研究对于确保河流附近城市的安全以及制定在未来洪水期间保护它们的计划具有根本作用。本研究旨在管理潜在的洪水风险,并以提克里特市为例进行了研究。从2019年到2022年,研究区域的底格里斯河每天的流量由伊拉克水利部提供。利用HEC-RAS软件建立二维洪水模型,模拟潜在洪水情景。首先,通过调整Manning系数(n)的值对模型进行校准,发现由于Nash-Sutcliff误差(NSE)为0.93,因此n = 0.031反映了该地区的性质。然后,将二维洪水模型的结果与研究区域的卫星图像进行对比,验证了模型的有效性,结果显示出较好的匹配性。然后,在不同的洪水情景下使用二维模型。结果表明,随着底格里斯河流量的增加,暴露在洪涝灾害中的面积逐渐增大。例如,将流量增加到800m3/s时,淹没面积增加了13.7%,而将流量增加到1500m3 /s时,淹没面积比河流正常流量增加了90.7%。结果还表明,由于东岸的地面水平比西岸低,东岸比西岸更容易发生洪水。
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引用次数: 2
Improving IoT Security using Lightweight Based Deep Learning Protection Model 使用基于轻量级的深度学习保护模型提高物联网安全性
Q3 Environmental Science Pub Date : 2023-03-31 DOI: 10.25130/tjes.30.1.12
Mahmood Subhy Mahmood, Najla Badie Al Dabagh
The Internet of Things (IoT) has recently become an essential ingredient of human life. The main critical challenges that confront IoT are security and protection. Several methods have been developed to protect the IoT; among these methods is Intrusion Detection System (IDS) Deep Learning-based. On the other hand, these types of IDS have a complex operation that takes a long time when applied on IoT devices and is inconvenient for a massive system that includes many connected devices. Thus, this paper suggested a Lightweight Intrusion Detection System (LIDS) IoT model that depends on deep learning using a Multi-Layer Perceptron (MLP) network. LIDS has the following characteristics lightweight, high accuracy, high speed in detection, and deals with a few features in MQTT protocol. The MQTTset dataset was used in training, validating, and testing the proposed model to investigate the performance of the proposed LIDS. The achieved performance ratios for the proposed LIDS, as measured by accuracy and F1-score. The experiment results showed that for the balanced MQTTset dataset, the number of obtained features was 15 with accuracy (95.06) and F1_score (95.31). Also, for the imbalanced MQTTset, the number of obtained features was 12 with accuracy (96.97) and F1-score (98.24). The obtained results have shown the deep learning efficiency role in improving the accuracy of an intrusion detection model by approximately 3.5% compared to other methods in the literature. In addition, the proposed methods reduced the number of features by around 50% of the total number of features, leading to a LIDS operating in a constrained environment.
物联网(IoT)最近已成为人类生活的重要组成部分。物联网面临的主要关键挑战是安全和保护。已经开发了几种方法来保护物联网;其中基于深度学习的入侵检测系统(IDS)就是其中之一。另一方面,这些类型的IDS具有复杂的操作,在物联网设备上应用时需要很长时间,并且对于包括许多连接设备的大型系统来说是不方便的。因此,本文提出了一种基于多层感知器(MLP)网络的深度学习的轻量级入侵检测系统(LIDS)物联网模型。LIDS具有以下特点:重量轻、精度高、检测速度快,并处理了MQTT协议中的一些特性。MQTTset数据集用于训练、验证和测试所提出的模型,以研究所提出的LIDS的性能。通过精度和F1分数测量的所提出的LIDS实现的性能比率。实验结果表明,对于平衡的MQTset数据集,获得的特征数量为15个,准确率为95.06,F1_score为95.31,所获得的特征数量为12个,准确度(96.97),F1得分(98.24)。所获得的结果表明,与文献中的其他方法相比,深度学习效率在将入侵检测模型的准确度提高约3.5%方面发挥了作用。此外,所提出的方法将特征数量减少了特征总数的50%左右,导致LIDS在受限环境中运行。
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引用次数: 3
Surface Area Model to Assess the Plastic Aggregate Concrete Properties 评估塑性骨料混凝土性能的表面积模型
Q3 Environmental Science Pub Date : 2023-03-31 DOI: 10.25130/tjes.30.1.13
Frya Shawkat Jafr, A. Mohammed, Hemn M. Ahmed
In this study, a model was proposed based on calculating the total surface area of aggregate to assess fresh density, compressive, and splitting tensile strengths of plastic aggregate (PA) recycled concrete. The key factor is the change in the total surface area of the natural aggregate by the PA. For a given PA volume, the change in the property could be assessed. The prediction well depends on the natural and plastic aggregates distribution size, specific gravity, and bulk density. The proposed model prediction was accurate when applied to high-strength, and lightweight concretes. The reason is attributed to the relatively good bond between PA and hardened cement paste in these concretes. However, for the majority of concrete mixes investigated, the model moderately underestimated strength loss, and this underestimation could be attributed to the PA- hardened cement paste bond deficiency. An attempt was made to assess the bond deficiency parameter for a more accurate prediction.
在这项研究中,提出了一个基于计算骨料总表面积的模型,以评估塑料骨料(PA)再生混凝土的新鲜密度、抗压强度和劈裂抗拉强度。关键因素是PA对天然骨料总表面积的改变。对于给定的PA体积,可以评估属性的变化。预测的好坏取决于天然和塑性骨料的分布、粒径、比重和容重。当应用于高强轻质混凝土时,所提出的模型预测是准确的。其原因是这些混凝土中PA与硬化水泥浆体的粘结性相对较好。然而,对于所研究的大多数混凝土混合料,该模型适度低估了强度损失,这种低估可能归因于PA硬化水泥浆粘结不足。为了得到更准确的预测,我们尝试对键缺陷参数进行评估。
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引用次数: 0
Insulation Materials Based on Recycled Feather Waste: A Review 基于再生羽毛废料的隔热材料:综述
Q3 Environmental Science Pub Date : 2023-03-31 DOI: 10.25130/tjes.30.1.10
Recently, the world has been moving towards reusing wastes in many industrial applications, such as buildings and automotive, to eliminate the environmental pollution impact due to increasing waste worldwide. Besides, waste reuse also leads to cost savings and improves sustainability. Therefore, this short review aims to present and discuss the recently used methods of utilizing feather waste as sustainable and renewable insulation instead of traditional petroleum-derived materials. The father's low thermal conductivity ranges from 0.024 W/(m. K) to 0.034 W/(m. K), and it's chemical composition and microstructure effectively trap air and produce a good barrier. So, feather waste fibers can be used as an effective thermal and acoustic insulation material with the same or better performance than commercially available products. However, several significant barriers and limitations associated with the manufacturing process of feathers insulations were identified in this review. These limitations make the commercial development of insulation materials based on feather waste a challenge. They need to be appropriately addressed to realize the potential of feather waste as a reliable insulation material.
最近,世界正朝着在许多工业应用中重复使用废物的方向发展,如建筑和汽车,以消除全球范围内日益增加的废物对环境污染的影响。此外,废物再利用还可以节省成本并提高可持续性。因此,这篇简短的综述旨在介绍和讨论最近使用的利用羽毛垃圾代替传统石油衍生材料作为可持续可再生隔热材料的方法。该父亲的低热导率范围为0.024W/(m.K)至0.034W/(m.K),其化学成分和微观结构有效地捕获了空气并产生了良好的屏障。因此,羽毛废料纤维可以作为一种有效的隔热和隔音材料,其性能与商用产品相同或更好。然而,在这篇综述中,发现了与羽毛绝缘材料制造过程相关的几个重大障碍和局限性。这些限制使得基于羽毛废料的绝缘材料的商业开发成为一个挑战。它们需要得到适当的解决,以实现羽毛废料作为可靠绝缘材料的潜力。
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引用次数: 0
Evaluation of Synthesized Pt/HY-H- Mordenite Composite Catalyst for Isomerization of Light Naphtha 合成Pt/HY-H-丝光沸石复合轻油异构化催化剂的评价
Q3 Environmental Science Pub Date : 2023-03-26 DOI: 10.25130/tjes.30.1.9
A. Jarullah, Abdullah M. Ahmed, Halla Hussein, A. Ahmed, Hamin J. Mohammed
This work deals with a composite catalyst preparation, Pt/HY-H-Mordenite, for isomerization of Iraqi light naphtha produced from Baiji North Refinery in a pilot plant fixed bed reactor under operating conditions with the following ranges: temperature 150–250 °C, LHSV 2.46–4.7 hr-1, pressure 6 bar, and hydrogen to hydrocarbon ratio 3.7 mol/mol. The prepared nano-silica, Na-mordenite, H-mordenite, and Pt/HY-H-Mordenite catalysts were described by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FTIR), and Brunauer-Emmett-Teller (BET) surface area analysis. The investigation results showed that the light naphtha isomerization conversion and yield increased with increasing the temperature and decreasing the liquid-hour space velocity. The highest conversion and yield, obtained at 250 °C and LHSV of 2.46 hr-1, were 89.38% and 76.36%, respectively.
本文研究了Pt/ hy - h -丝光沸石复合催化剂的制备,用于在固定床反应器中试装置中,在温度150 ~ 250℃,LHSV 2.46 ~ 4.7 hr-1,压力6 bar,氢烃比3.7 mol/mol的条件下,对Baiji北炼油厂生产的伊拉克轻油进行异构化反应。采用x射线衍射(XRD)、场发射扫描电镜(FE-SEM)、傅里叶变换红外光谱(FTIR)和布鲁诺尔-埃米特-泰勒(BET)表面积分析对制备的纳米二氧化硅、na -丝光石、h -丝光石和Pt/ hy - h -丝光石催化剂进行了表征。研究结果表明,轻质油异构化转化率和产率随温度的升高和液时空速的降低而提高。在250°C和LHSV为2.46 hr-1时,转化率和产率分别为89.38%和76.36%。
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引用次数: 5
期刊
Tikrit Journal of Engineering Sciences
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