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VALIDATION METHOD OF DETERMINATION OF Cd (II) IN NPK FERTILIZER BY FLAME ATOMIC ABSORPTION SPECTROPHOTOMETRY AT THE QUALITY CONTROL LABORATORY, PT. PUPUK KALIMANTAN TIMUR 加里曼丹PUPUK质量控制实验室火焰原子吸收分光光度法测定NPK肥料中Cd (II)的验证方法
Pub Date : 2021-11-30 DOI: 10.30872/jkm.v19i1.898
Leonardus Lewo Hayon, A. Alimuddin, A. S. Panggabean
The research about validation method of determination of Cd (II) in NPK fertilizer by Flame Atomic Absorption Spectrophotometry at the Quality Control Laboratory, PT. Pupuk Kaltim has been done. Determination of Cd (II) was done by referring to the Indonesian National Standard (SNI) 2803:2012. Based on the research results obtained by the correlation coefficient (r) was 0.9991; reproducibility with a relative standard deviation (RSD) value was 4.502 % less than 2/3 CV Horwitz was 9.757 and  repeatability with a relative standard deviation (RSD) value was 5.225% less than 2/3 CV Horwitz was 9.695; % recovery was in the range of 80-110 % with an average was 98.56 %; limit of detection was 0.056 mg/kg and limit of quantitation was 0,066 mg/kg; uncertainty estimation of measurement with uncertainty components of concentration, volume, mass, precision and purity of the standard solution, obtained the expanded uncertainty value with a 95 % confidence level was  ± 0.197 mg/kg and uncertainty percentage value was 10.43 %.
在Pupuk Kaltim质量控制实验室对火焰原子吸收分光光度法测定NPK肥料中Cd(II)的验证方法进行了研究。Cd(II)的测定参照印尼国家标准(SNI)2803:2012进行。根据研究结果得出的相关系数(r)为0.9991;相对标准偏差(RSD)值的再现性为4.502%,比2/3 CV Horwitz为9.757,相对标准偏差值的重复性为5.225%,比2/3 CV-Howitz为9.695;%回收率在80-110%之间,平均回收率为98.56%;检测限为0.056mg/kg,定量限为0066mg/kg;用标准溶液的浓度、体积、质量、精度和纯度等不确定度分量进行测量的不确定度估计,得到95%置信水平下的扩展不确定度值为±0.197mg/kg,不确定度百分数为10.43%。
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引用次数: 0
SABUN CAIR EKONOMIS DENGAN PEMANFAATAN LIMBAH MINYAK JELANTAH 石油废弃物使用的经济液体肥皂
Pub Date : 2021-11-30 DOI: 10.30872/jkm.v19i1.927
Indica Septriyanti
Reducing Environmental pollution from household products that are used continuously, Processing waste cooking oil waste can be used to make innovations that benefit the community. Cooking oil that is used in excess of its use is called used cooking oil which is not well consumed by the body and has a negative impact on soil and air pollution. Processing of used cooking oil can be made as soap, one of which is liquid soap. Liquid soap is cleaner and more effective soap in packaging and usage.
减少连续使用的家庭产品对环境的污染,处理废弃的食用油废物可以用来进行创新,造福社会。过量使用的食用油被称为废食用油,不能很好地被人体消耗,对土壤和空气污染有负面影响。用过的食用油加工后可以制成肥皂,其中一种是液体肥皂。液体肥皂在包装和使用上都是更清洁、更有效的肥皂。
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引用次数: 0
STUDI KOMPUTASI INTERAKSI ZEOLIT LTA (LINDE TYPE A) DENGAN KATION ALKALI (LI+, NA+, K+) MENGGUNAKAN METODE MEKANIKA MOLEKULER ZEOLIT-LTA(线型A)与碱作用(LI+,NA+,K+)相互作用的计算研究机械分子的适用方法
Pub Date : 2021-11-30 DOI: 10.30872/jkm.v19i1.1012
Audi Zahid Iswaradi, Rahmat Gunawan, Noor Hindryawati
A study of computation on zeolite LTA (Linde Type A) interaction with alkaline cation (Li+, Na+, K+) using the mechanical molecular method was conducted. Data processing was conducted computationally using Hyperchem 7.0 with the mechanical molecular method. The result of the study showed zeolite LTA with ratio Si/Al 2,4286 has the lowest minimum energy. Furthermore, impregnation by cation Li+ increases structure stability, and impregnation by cation Na+ has the largest diameter window on Zeolite LTA.
用机械分子方法计算了沸石LTA(Linde A型)与碱性阳离子(Li+、Na+、K+)的相互作用。使用Hyperchem 7.0和机械分子方法对数据进行计算处理。研究结果表明,Si/Al比为24286的LTA沸石具有最低的最小能量。此外,阳离子Li+的浸渍提高了结构稳定性,阳离子Na+的浸渍在沸石LTA上具有最大的直径窗口。
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引用次数: 0
PEMBUATAN KOMPOSIT WO3-ZnO MELALUI REAKSI PADAT-PADAT DAN KARAKTERISASINYA WO3-ZnO组分的还原与PADAT反应及表征
Pub Date : 2021-05-31 DOI: 10.30872/jkm.v18i2.955
Wahyuni Ramadhani, Noor Hindryawati
Pembuatan komposit WO3-ZnO melalui reaksi padat-padat telah dilakukan. Tahapan penelitian meliputi pencampuran padatan WO3 dan ZnO dengan penambahan polivinil alkohol, pengeringan, pengayakan dan pemanasan. Padatan WO3 dan  ZnO sebelum dikompositkan serta komposit WO3-ZnO dikarakterisasi menggunakan instrumen X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), dan uji luas permukaan menggunakan larutan methylene blue. Hasil karakterisasi XRD menunjukkan bahwa pada sampel mengandung WO3 dan ZnO juga adanya puncak difraksi ZnWO4. Pada analisa SEM dapat diamati bahwa terdapat ukuran dan bentuk partikel yang tidak homogen. Komposit WO3-ZnO memiliki luas permukaan sebesar 110,7596 m2/g.
通过固体反应合成WO3-ZnO已经完成。研究阶段包括WO3和ZnO与多聚乙烯酒精、干燥、筛选和加热混合。WO3和ZnO在合成和合成WO3-ZnO之前,使用x射线衍射仪器、扫描电子微镜(SEM)和测试表面积。XRD的分析表明,样本中含有WO3和ZnO以及ZnWO4衍射峰值。在对闪的分析中,可以观察到粒子的大小和形状是不均匀的。WO3-ZnO复合材料的表面积为110.7596平方/g。
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引用次数: 0
DECREASING OF COD AND TSS FROM LAUNDRY WASTE USES ALUMINUM (Al) AND COPPER (Cu) ELECTRODES IN THE ELECTROCOAGULATION METHOD 摘要电絮凝法采用铝(Al)和铜(Cu)电极降低洗衣垃圾中的COD和TSS
Pub Date : 2021-05-31 DOI: 10.30872/jkm.v18i2.737
Mirna Desyderia Sumawan
A research about reduction of COD and TSS from laundry waste with Electrocoagulation method using Al and Cu electrodes in COD and TSS reduction  parameters has been done. In this research, the voltage and optimum time determited based on occurred in electrocoagulation process. The determination of COD and TSS in the contact time was 60 minutes with the value of COD was 90.5645% and TSS 63.7279%. The value of voltage optimum was 12 Volt, obtain COD was 90.2392% and TSS 60.7052%.
研究了铝、铜电极电凝聚法降低洗衣废水中COD和TSS的工艺参数。在本研究中,根据电凝过程中发生的情况确定了电压和最佳时间。接触时间为60min时COD和TSS的测定,COD值为90.5645%,TSS值为63.7279%。最佳电压值为12V,得到COD为90.2392%,TSS为60.7052%。
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引用次数: 0
Validasi Metode Penentuang Minyak dan Lemak dalam air Laut dengan Spektrofotometri Inframerah 验证用红外光谱仪在海水中过滤石油和脂肪的方法
Pub Date : 2021-05-31 DOI: 10.30872/jkm.v18i2.742
Gaisandry Devira Samban
Validation research method of determining oil and grease in sea water with Infrared Spectrophotometry has been conducted. To obtain valid measurement results, the research stages included measurements in the form of validation parameters such as linearity test, limit detection (LOD), quantization limit (LOQ), recovery, precision, reproducibility, detection limit of method (MDL), instrument validation and measurement uncertainty. The results showed that linearity met the good results with a correlation coefficient (R2) ≥ 0.995; LOD is 0.1 mg/L, LOQ is 0.5 mg/L, % recovery with a range of(104,59 ± 1,73)%; repetition and reproducibility was expressed as % SBR <% KV Horwitz, MDL is 0.2745 mg/L. Based on the results of this study, infrared spectrophotometry methods can be used in determining oil and fat in seawater samples with valid results.   Keywords: method validation, oil and greace, infrared spectrophotometry.
对红外分光光度法测定海水中油脂的方法进行了验证研究。为了获得有效的测量结果,研究阶段包括以验证参数形式进行的测量,如线性试验、极限检测(LOD)、定量限(LOQ)、回收率、精密度、再现性、方法检测限(MDL)、仪器验证和测量不确定度。结果表明,线性关系良好,相关系数(R2)≥0.995;LOD为0.1mg/L,LOQ为0.5mg/L,回收率%,范围为(104,59±1.73)%;重复性和再现性用%SBR<%KV Horwitz表示,MDL为0.2745mg/L。基于本研究结果,红外分光光度法可用于海水样品中油脂的测定,结果有效。关键词:方法验证;油脂;红外分光光度法。
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引用次数: 0
PREPARATION OF MAGNETITE-FULVIC ACID (Fe3O4-FA) FROM PEAT SOIL AND APPLICATION TO ADSORB RHODAMINE-B 从泥炭土中制备富里酸(Fe3O4-FA)及其在吸附罗丹明- b中的应用
Pub Date : 2021-05-31 DOI: 10.30872/jkm.v18i2.964
Deby Ayu Oktaviana
Pada penelitian ini dilakukan preparasi adsorben Fe3O4 terlapis asam fulvat (Fe3O4-AF) dari tanah gambut dan diaplikasikan untuk mengadsorpsi zat warna rhodamin B. Sintesis Fe3O4-AF dilakukan dengan metode ko-presipitasi, karakterisasi meliputi analisis FTIR, XRD, SEM dan VSM serta mengetahui kondisi pH optimum adsorpsi rhodamin-B pada Fe3O4-AF. Adsorben Fe3O4-AF berhasil disintesis dengan menunjukkan munculnya spektra FTIR yang khas yakni gugus Fe-O, O-H, C-H, C=C dan C=O. Struktur kristal Fe3O4-AF tidak mengalami perubahan, morfologi permukaan berupa koloid rigid AF tertempel bulatan sferis Fe3O4 dan nilai kemagnetan Fe3O4 menurun dengan adanya AF. Kondisi optimum adsorpsi rhodamin B pada Fe3O4-AF terjadi pada pada pH 3 dengan saya serap 1,96 mg/g.
本研究制备了Fe3O4 AF吸附剂,从土壤中吸附黄腐酸(Fe3O4-AF),并将其用于吸附罗丹明B色素。采用共沉淀法合成了Fe3O4-AF,包括FTIR、XRD、SEM和VSM分析,并确定了Fe3O_4-AF中pH值最佳的罗丹明-B吸附条件。通过显示特定的FTIR光谱,即Fe-O、O-H、C-H、C=C和C=O的出现,合成了吸附剂Fe3O4 AF。Fe3O4 AF的晶体结构没有发生任何变化,球形Fe3O4和磁性值Fe3O4的刚性AF胶体附着的表面形态随着AF的增加而降低。罗丹明B吸附到Fe3O4上的最佳条件出现在pH 3,me等于1.96mg/g。
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引用次数: 0
Studi Penambatan Molekul Flavonoid Pada Reseptor α-Glukosidase menggunakan PLANTS 确保研究类黄酮分子的α受体-Glukosidase使用植物
Pub Date : 2021-05-30 DOI: 10.30872/JKM.V18I2.1004
Budi Mulyati, Riong seulina Panjaitan
ABSTRACT   Plants that contain flavonoids are widely used in traditional medicine. Flavonoids can reduce blood glucose levels with their ability as anti-oxidants. The purpose of this study was to determine natural compounds from flavonoid derivatives that have good affinity and conformation and their interactions in inhibiting α-glucosidase (an enzyme that breaks down carbohydrates into glucose) and determine the sequence of ligands that interact more strongly with α protein / enzyme α-glucosidase. Molecular docking is a computational method that aims to imitate the interaction of a ligand molecule with the protein it targets in in-vitro tests. Molecular docking between flavonoids and α-glucosidase receptors was carried out using the PLANTS method to see its affinity. The flavonoids used as ligands were flavones, flavanols and chalcone with the results of the docking scores respectively, -65.41, -64.39 and -63.07 where the standard ligand used in this study was deoxynojirimycin (-77.12). In the active side of the α-Glucosidase enzyme that binds to flavonoid ligands is Gly 555, Glu 526 and Pro 556.  
摘要含有黄酮类化合物的植物在传统医药中有着广泛的应用。黄酮类化合物可以作为抗氧化剂降低血糖水平。本研究的目的是从类黄酮衍生物中确定具有良好亲和力和构象的天然化合物,以及它们在抑制α-葡萄糖苷酶(一种将碳水化合物分解为葡萄糖的酶)方面的相互作用,并确定与α蛋白/酶α-葡糖苷酶相互作用更强的配体序列。分子对接是一种计算方法,旨在模拟配体分子与其在体外测试中靶向的蛋白质的相互作用。黄酮类化合物和α-葡萄糖苷酶受体之间的分子对接使用PLANTS方法来观察其亲和力。作为配体的黄酮类化合物为黄酮、黄烷醇和查尔酮,对接得分分别为-65.41、-64.39和-63.07,其中本研究中使用的标准配体为脱氧野霉素(-77.12)。与黄酮类配体结合的α-葡萄糖苷酶的活性侧为Gly 555、Glu 526和Pro 556。
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引用次数: 0
POLIURETAN MINYAK AMPAS KOPI ARABIKA ( Coffea arabica L.) 咖啡
Pub Date : 2021-05-30 DOI: 10.30872/jkm.v18i2.1074
Indra Masmur, Jumadi Septian Sihombing, M. Ginting
Polymerization of coffee grounds oil with Diphenyl Methane 4,4 Diisocyanate (MDI), epoxidation with performic acid and H2SO4(p) catalyst at 40-45°C, followed by hydrolysis to obtain polyols. The synthesis was carried out by reacting the polyol with Diphenyl Methane 4,4 Diisocyanate (MDI) with a ratio (polyol: MDI) 9:1; 8:2 ; 7:3 ; 6:4 ; 5:5 (v/v) in dichloromethane solvent. Each was characterized and the density values were 0.9086 gr/cm to 0.4979 gr/cm-1, the tensile strength and elongation values were 0.113 Mpa to 0.299 Mpa and 3.23% to 6.85%, respectively.
咖啡渣油与二苯基甲烷4,4二异氰酸酯(MDI)聚合,在40-45°C下用过孔酸和H2SO4(p)催化剂进行环氧化,然后水解以获得多元醇。合成是通过使多元醇与二苯基甲烷4,4-二异氰酸酯(MDI)以9:1的比例反应来进行的;8:2;7:3;6:4;5:5(v/v)的二氯甲烷溶剂中。每种材料的密度值为0.9086gr/cm至0.4979gr/cm-1,抗拉强度和伸长率分别为0.113Mpa至0.299Mpa和3.23%至6.85%。
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引用次数: 0
Ekstrak Etanol Kulit Buah Manggis Sebagai Masker Gel Peel-Off Berantioksidan 水果皮乙醇提取物,为游离凝胶面膜
Pub Date : 2021-05-30 DOI: 10.30872/JKM.V18I2.922
Priyanti Priyanti, Tri Partuti, Nusaibah Nur Amalina, Desy Rahmiaty, Wulandari Fera Yanti, Hutssy Elya Nadyana, Alika Arum Daniya, Nurul Annisa, Azza Hanif Harisna
Peel off gel masks have become a trend in the field of beauty as a facial skin care. Utilization of mangosteen rind extract is thought to be able to provide more function on the mask as its high levels of antioxidant. This study discusses the optimum formulation of antioxidant peel off gel mask with mangosteen rind ethanol extract. Mangosteen rind was obtained from the market in the South Tangerang area and then extracted using 96% ethanol as the solvent by maceration. Peel off gel mask preparation is formulated with extract concentrations of 1%, 2% and 4%. Stability test in the form of analysis of pH, viscosity, dry time, and homogenation was carried out for four weeks. Antioxidant analysis was carried out to detect flavonoid, saponins and tannins. The results showed that the extract contained flavonoids, saponins and tannins with free radical scavenging values ​​of 16.10%. The optimum formulation of peel off gel mask is with 2% extract because it has an acidic pH, a viscosity value of 8025 cps, a thick texture, and has a drying time of about 14 minutes.
面膜作为一种面部护肤,已经成为美容领域的一种趋势。山竹果皮提取物被认为能够在面膜上提供更多的功能,因为它具有高水平的抗氧化剂。探讨了山竹皮乙醇提取物抗氧化脱皮凝胶面膜的最佳配方。山竹皮取材于南橘子地区,以96%乙醇为溶剂浸渍提取山竹皮。剥离凝胶面膜制剂的萃取物浓度分别为1%、2%和4%。稳定性测试以pH、粘度、干燥时间和均质分析的形式进行,为期四周。进行抗氧化分析,检测黄酮、皂苷和单宁。结果表明,提取液中含有黄酮类化合物、皂苷类化合物和单宁类化合物,自由基清除率为16.10%。剥离凝胶面膜的最佳配方是添加2%的提取物,因为它具有酸性pH值,粘度值为8025 cps,质地较厚,干燥时间约为14分钟。
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