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Recent advances in the marketing, impurity characterization and purification of quartz 石英营销、杂质表征和提纯方面的最新进展
Pub Date : 2023-11-29 DOI: 10.20517/mmm.2023.17
Yongping Xie, Suqin Li, Xiaodong Pan, Yongkui Li, Ao Zhang
Due to its stable physical and chemical properties and its abundance in nature, quartz is widely employed in industrial and high-tech applications. However, the presence of diverse types and states of impurities in quartz ores from different geological formations poses a challenge in the process of purifying high-purity quartz, leading to wastage of raw materials and escalated costs. This study presents the socio-economic applications of quartz, scrutinizes the formation and separation mechanisms of impurities in quartz ores from a mineralogical perspective, examines the obstacles faced in quartz purification, explains the current state of development, and provides a technical summary of quartz purification. The analysis reveals that lattice impurity elements and various types of inclusion impurities are the principal factors affecting the purity of quartz. Various green separation techniques are applied based on the composition of the quartz minerals and the state of the impurities. Standard practices may involve physical pre-treatment such as scrubbing, ultrasonic crushing, and electromagnetic pulse cracking, followed by rough cleaning through color separation, superconducting high gradient magnetic separation, and flotation, and chemical pre-treatment (high-temperature or microwave roasting with chloride doping, and ammonium sulfate thermal crushing combined with water quenching to remove gas-liquid inclusions from quartz minerals). Finally, finishing processes such as fluorine-free and catalytic hot-pressure acid leaching or microbiological purification treatment with filamentous or Aspergillus fungi are used to obtain high-purity silica sand with an anticipated purity of about 99.99%.
由于石英具有稳定的物理和化学性质,且在自然界中含量丰富,因此被广泛应用于工业和高科技领域。然而,来自不同地质构造的石英矿石中存在多种类型和状态的杂质,这给提纯高纯度石英的过程带来了挑战,导致原材料浪费和成本上升。本研究介绍了石英的社会经济应用,从矿物学角度研究了石英矿石中杂质的形成和分离机制,探讨了石英提纯过程中面临的障碍,解释了石英提纯的发展现状,并对石英提纯进行了技术总结。分析表明,晶格杂质元素和各类包体杂质是影响石英纯度的主要因素。根据石英矿物的成分和杂质的状态,采用了各种绿色分离技术。标准做法可能包括物理预处理,如擦洗、超声波破碎和电磁脉冲裂解,然后通过色选、超导高梯度磁选和浮选进行粗选,以及化学预处理(掺杂氯化物的高温或微波焙烧,硫酸铵热破碎结合水淬去除石英矿物中的气液夹杂物)。最后,采用无氟和催化热压酸浸出或用丝状真菌或曲霉菌进行微生物净化处理等精加工工艺,以获得高纯度硅砂,预计纯度约为 99.99%。
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引用次数: 0
Overview of interfacial interaction mechanisms of bubble-mineral systems at the nanoscale 纳米尺度气泡-矿物系统界面相互作用机制概览
Pub Date : 2023-11-24 DOI: 10.20517/mmm.2023.31
Zhoujie Wang, Yan Xiang, Jingyi Wang, Zhiyong Gao, Wei Sun, Lei Xie
Understanding the interfacial interaction mechanisms of bubble-mineral systems is of paramount importance in the fields of fundamental science and engineering. Over the past few decades, researchers have employed the techniques such as atomic force microscope colloidal or bubble probe to quantitatively measure the bubble-mineral and bubble-bubble interactions at the nanoscale. However, accurately quantifying the interactions involving deformable bubbles has proven challenging due to the complexity of both theoretical analysis and experimental verification. To improve the understanding of interfacial mechanisms involved in the bubble and mineral systems, an overview of recent nanomechanical advancements in bubble-mineral interaction is required. In this review, we provide a comprehensive review of recent advancements in the nanomechanical understanding of interactions of bubble-mineral particles or surfaces and the interactions of bubble-bubble in mineral systems during various interfacial processes. Furthermore, we highlight the potential challenges for future research in this area. By shedding light on the underlying mechanisms governing interfacial interactions in bubble-mineral systems, this review offers valuable insights and paves the way for the development of effective strategies to manipulate and control these interactions in both environmental and engineering applications.
了解气泡-矿物系统的界面相互作用机制在基础科学和工程学领域至关重要。在过去几十年中,研究人员采用了原子力显微镜胶体或气泡探针等技术来定量测量纳米尺度的气泡-矿物和气泡-气泡相互作用。然而,由于理论分析和实验验证的复杂性,准确量化涉及可变形气泡的相互作用具有挑战性。为了更好地理解气泡与矿物系统中涉及的界面机制,需要对气泡与矿物相互作用的最新纳米力学进展进行综述。在这篇综述中,我们全面回顾了对气泡-矿物颗粒或表面相互作用以及各种界面过程中矿物系统中气泡-气泡相互作用的纳米力学理解的最新进展。此外,我们还强调了该领域未来研究的潜在挑战。通过阐明气泡-矿物系统界面相互作用的基本机制,本综述提供了宝贵的见解,并为在环境和工程应用中开发操纵和控制这些相互作用的有效策略铺平了道路。
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引用次数: 0
Tungsten tailings issues and reprocessing solutions 钨尾矿问题和后处理解决方案
Pub Date : 2023-11-07 DOI: 10.20517/mmm.2023.21
Deus Albert Msumange, Joshua Albert Msumange, Kathy Bru, Florent Bourgeois
This paper aims to provide an overview of tungsten (W) tailings properties, detrimental impacts of these tailings, approaches to mitigate these impacts, and a presentation of methods to reprocess them to capture their economic value. Since W is widely used in a variety of industries, it has been extensively mined since the 19th century, and the mining continues to generate significant volumes of tailings. Recent data show that global W production stands at 84 kt per year, and more than 100 Mt of W tailings exist containing over 100 kt of WO3. The tailings contain variable amounts of valuable products and deleterious environmental substances. Some of the contained metals are in great demand for the energy transition. However, these tailings usually contain FeS2/Pyrrhotite and FeAsS minerals, which, when exposed to air and water, can produce acid mine drainage. As such, W tailings may pose environmental and human health risks. Globally, the reprocessing of W tailings presents a potential resource that can be regarded as a paradigm of sustainability and circular economy. Flotation, enhanced gravity separation, and wet high-intensity magnetic separation have been reported to be the common approaches to reprocessing W tailings. However, W processing presents particular difficulties owing to complex material properties, such as fine particle size, surface weathering, similarity in surface properties exhibited by gangue materials (fluorite, apatite, calcite), low concentrations of the elements of interest, and poor mineral liberation.
本文旨在概述钨(W)尾矿的特性,这些尾矿的有害影响,减轻这些影响的方法,并介绍了对它们进行再处理以获取其经济价值的方法。由于W广泛应用于各种行业,自19世纪以来,W就被广泛开采,开采过程中不断产生大量的尾矿。最近的数据显示,全球钨产量为每年84万吨,存在超过1亿吨的钨尾矿,其中含有超过10万吨的WO3。尾矿中含有不同数量的有价产品和有害环境物质。其中一些金属在能源转型中需求量很大。然而,这些尾矿通常含有FeS2/磁黄铁矿和FeAsS矿物,当暴露于空气和水中时,会产生酸性矿山废水。因此,钨尾矿可能对环境和人类健康构成风险。在全球范围内,钨尾矿的后处理是一种潜在的资源,可以被视为可持续发展和循环经济的典范。浮选、强化重选和湿法强磁选是钨尾矿再处理的常用方法。然而,由于复杂的材料特性,如细粒度、表面风化、脉石材料(萤石、磷灰石、方解石)表面特性的相似性、低浓度的感兴趣元素和较差的矿物解离,W的加工特别困难。
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引用次数: 0
Towards improvement of hydroprocessing catalysts - understanding the role of advanced mineral materials in hydroprocessing catalysts 迈向加氢催化剂的改进——了解先进矿物材料在加氢催化剂中的作用
Pub Date : 2023-10-30 DOI: 10.20517/mmm.2023.23
Siphumelele Majodina, Olwethu Poswayo, Tendai O. Dembaremba, Zenixole R. Tshentu
Mineral materials play a pivotal in heterogeneous catalysts as active, support, or promoter components, with the oil refinery industry being one of the biggest beneficiaries. While conventional hydroprocessing catalysts have historically met the industry’s needs, the growing need to accommodate unique feedstocks, meet the increasing demand for environmentally acceptable products, obtain better product specifications, enhance selectivity for reactions to increase ratios for certain product cuts, and use more cost-effective and abundant mineral materials, has recently motivated for fresh considerations in the development of hydroprocessing catalysts. Based on periodic trends, noble metals possess the most desirable qualities, but their relative abundance in the Earth’s crust is too low to meet industry needs. They are costly and highly sensitive to sulfur poisoning. Mo and W lie in the sweet spot, but it is anticipated that they cannot meet the increasing demand. Investigations of electronic interactions of more economical and abundant metals, such as Nb, V, and Fe, with other elements and support materials have yielded a better understanding of synergistic effects that help to access noble metal-like qualities. This work contrasts conventional hydroprocessing catalysts and recently improved catalysts, detailing the chemistry considerations behind the selection of mineral materials used in the catalysts. It also explores how further manipulation of these mineral materials and synthesis approaches is driving toward more desirable properties. The work brings to the attention of the readers the challenges and opportunities for the further improvement of hydroprocessing catalysts to ensure environmental sustainability while meeting the industry’s growing needs.
矿物材料在多相催化剂中起着关键作用,作为活性、支持或促进组分,炼油工业是最大的受益者之一。虽然传统的加氢处理催化剂在历史上已经满足了工业的需求,但对独特原料的需求日益增长,对环境可接受产品的需求不断增加,获得更好的产品规格,提高反应的选择性以增加某些产品切割的比例,以及使用更经济有效和丰富的矿物材料,最近促使人们在加氢处理催化剂的开发中考虑新的问题。根据周期趋势,贵金属具有最理想的品质,但它们在地壳中的相对丰度太低,无法满足工业需求。它们价格昂贵,对硫中毒非常敏感。Mo和W处于最佳位置,但预计它们无法满足日益增长的需求。对更经济、更丰富的金属(如Nb、V和Fe)与其他元素和支撑材料的电子相互作用的研究,使人们更好地理解了有助于获得贵金属样质量的协同效应。这项工作对比了传统的加氢处理催化剂和最近改进的催化剂,详细介绍了催化剂中使用的矿物材料选择背后的化学考虑。它还探讨了如何进一步操纵这些矿物材料和合成方法是推动更理想的性质。这项工作使读者注意到进一步改进加氢处理催化剂的挑战和机遇,以确保环境的可持续性,同时满足工业日益增长的需求。
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引用次数: 0
Feasibility of CO2 desorption and electrolytic regeneration of potassium carbonate solution in an anion exchange membrane cell 阴离子交换膜电池中碳酸钾溶液CO2解吸和电解再生的可行性
Pub Date : 2023-10-23 DOI: 10.20517/mmm.2023.19
Daxue Fu, Yukun Wang, Shikai Yu
In this work, an electrolytic process was introduced for coupled regeneration of potassium carbonate (K2CO3) solution and water electrolysis by using an anion exchange membrane cell. The process made the CO2 separation from O2 much easier with respect to the existing cationic exchange membrane process. The solution of K2CO3 was used in the cathode chamber to simulate the solution after absorbing CO2. The solution of sulfuric acid (0.1 mol/L H2SO4) was charged in the anode chamber. The feasibility of the process was discussed. The effects of various operation parameters, including temperature, current density, and electrolysis time, were studied. The results indicate that both the yield rate of CO2 and the current efficiency increase initially and decrease afterward with temperature. The yield rate of CO2 increases while the current efficiency decreases with the current density. A low current density can reduce the energy consumption for producing the same amount of CO2. The processes using anion exchange membrane electrolysis can regenerate the absorbent solution to achieve 89% current efficiency, and the simultaneous production of three pure gases, CO2, H2, and O2, makes this method promising.
本文介绍了一种利用阴离子交换膜电池对碳酸钾(K2CO3)溶液和电解水进行耦合再生的电解工艺。与现有的阳离子交换膜工艺相比,该工艺使CO2与O2的分离更加容易。阴极室采用K2CO3溶液模拟吸收CO2后的溶液。在阳极腔内充入0.1 mol/L H2SO4硫酸溶液。讨论了该工艺的可行性。研究了温度、电流密度、电解时间等操作参数对电解效果的影响。结果表明,随着温度的升高,CO2产率和电流效率均呈先升高后降低的趋势。随着电流密度的增大,CO2的产率增加,而电流效率降低。低电流密度可以降低产生相同数量二氧化碳的能耗。阴离子交换膜电解法可再生吸收液,电流效率达89%,同时可产生3种纯气体:CO2、H2和O2,具有广阔的应用前景。
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引用次数: 0
High-gradient magnetic separation mechanism for separation of chalcopyrite from molybdenite 黄铜矿与辉钼矿高梯度磁选分离机理研究
Pub Date : 2023-10-23 DOI: 10.20517/mmm.2023.12
Pulin Dai, Zixing Xue, Xiaowei Li, Yaxiong Jiang, Nourhan Ahmed, Jianwu Zeng, Luzheng Chen
Removing molybdenite from chalcopyrite by flotation has long been a challenge due to their similar floatability as sulfide minerals. However, the difference in the magnetic susceptibility of the two minerals may be employed to address this challenge. Recently, pulsating high-gradient magnetic separation (PHGMS) has been reported effective as an environmentally friendly and economical strategy for separating chalcopyrite from molybdenite, but the mechanism of their magnetic differences is unclear. The current investigation employed crystal field theory and density functional theory calculations to theoretically elucidate the magnetic properties of these two minerals, and their difference was further demonstrated by experimental investigations. Under optimized conditions in a SLon-100 cyclic PHGMS separator, a chalcopyrite concentrate assaying 31.47% Cu and 0.44% Mo at 81.93% Cu and 5.56% Mo recoveries was produced from a pure chalcopyrite-molybdenite mixture that initially contained 26.29% Cu and 5.42% Mo. After the separation process, the Cu grade decreased to 15.06%, whereas the Mo grade increased to 16.22% in the nonmagnetic product. These findings have potential implications for the separation of chalcopyrite from molybdenite using PHGMS.
由于辉钼矿与硫化物矿物具有相似的可浮性,用浮选法从黄铜矿中去除辉钼矿一直是一个难题。然而,两种矿物磁化率的差异可以用来解决这一挑战。脉动高梯度磁选是一种经济环保的黄铜矿与辉钼矿分离方法,但二者磁性差异的机理尚不清楚。本研究采用晶体场理论和密度泛函理论计算,从理论上阐明了两种矿物的磁性能,并通过实验研究进一步证明了它们之间的差异。在SLon-100循环PHGMS分选机优化条件下,从初始Cu含量为26.29%、Mo含量为5.42%的纯黄铜矿—辉钼矿混合物中分离出Cu含量为31.47%、Mo含量为0.44%、Cu回收率为81.93%、Mo回收率为5.56%的黄铜矿精矿。分离后,非磁性产品中Cu品位降至15.06%,Mo品位上升至16.22%。这些发现对PHGMS从辉钼矿中分离黄铜矿具有潜在的指导意义。
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引用次数: 1
Contribution of mineral processing and metallurgical technology to sustainable development of world mining industry 矿物加工和冶金技术对世界矿业可持续发展的贡献
Pub Date : 2023-09-30 DOI: 10.20517/mmm.2023.18
Johannes H. Potgieter
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引用次数: 0
3D montmorillonite aerogel/SA composite phase change materials with mechanically strong strength and superior thermal energy storage performances 三维蒙脱土气凝胶/SA复合相变材料具有机械强度强、储热性能优异的特点
Pub Date : 2023-09-28 DOI: 10.20517/mmm.2023.20
Lei Qin, Cong Guo, Qijing Guo, Hao Yi, Feifei Jia
Phase change materials (PCMs), which have the ability of absorbing and releasing thermal energy in phase change process, are one of the most reliable materials for thermal energy storage. In this work, stearic acid (SA) used as PCMs were filled into the three-dimensional interconnected montmorillonite (Mt) aerogel to construct composite PCMs (3D-Mt/SA CPCMs) with good shape stability and high mechanical strength. Owing to the super porosity, the CPCMs can encapsulate a large amount of SA and result in the phase change enthalpy as high as 183 J/g. In addition, due to the surface tension and capillary forces of 3D-Mt aerogels, the SA were confined in the pore structure tightly, leading to excellent structural stability and good cycling performances during continuous solid-to-liquid phase change. Results also showed that the prepared 3D-Mt/SA CPCMs can withstand a weight of 500 g without any deformation, and the loads are as high as 1.01 and 13.81 MPa under 55% and 80% deformation, respectively. With high heat storage capacity, good thermal stability, and excellent mechanical strength, the prepared 3D-Mt/SA CPCMs have great application potential in the field of thermal energy storage.
相变材料在相变过程中具有吸收和释放热能的能力,是最可靠的储热材料之一。本研究将硬脂酸(SA)作为PCMs填充到三维互连蒙脱土(Mt)气凝胶中,构建具有良好形状稳定性和高机械强度的复合PCMs (3D-Mt/SA CPCMs)。由于超孔隙率,cpcm可以包封大量SA,相变焓高达183 J/g。此外,由于3D-Mt气凝胶的表面张力和毛细力,SA被紧密地限制在孔隙结构中,从而在连续的固液相变过程中具有优异的结构稳定性和良好的循环性能。结果还表明,制备的3D-Mt/SA cpcm可以承受500 g的重量而不发生任何变形,在55%和80%变形下的载荷分别高达1.01和13.81 MPa。制备的3D-Mt/SA cpcm具有较高的储热能力、良好的热稳定性和优异的机械强度,在储热领域具有很大的应用潜力。
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引用次数: 0
Chemical synthesis of reduced graphene oxide: a review 还原氧化石墨烯的化学合成研究进展
Pub Date : 2023-07-21 DOI: 10.20517/mmm.2023.07
Yang Hu, Hanyu Gao
Due to its exceptional and distinct features, graphene has become a prominent two-dimensional material. According to the raw materials and synthetic procedures, there are two categories of graphene synthesis techniques: “bottom-up” and “top-down” methods. Reduction of graphene oxide (GO) is one of the “top-down” techniques that use graphite as the starting material. This approach is now regarded as the most potential way to produce graphene on a large scale and is particularly well-suited for chemical modification and subsequent processing. This review summarizes the synthesis procedure of reduced GO (RGO) and presents the preparation methods of it and its precursors, such as graphite oxide and GO. In addition, the possible approaches for reducing the defects in RGO have been discussed.
由于其独特的特性,石墨烯已成为一种突出的二维材料。根据原料和合成程序,石墨烯合成技术分为“自下而上”和“自上而下”两大类。氧化石墨烯还原(GO)是一种以石墨为起始材料的“自上而下”技术。这种方法现在被认为是最有潜力的大规模生产石墨烯的方法,特别适合化学改性和后续处理。本文综述了还原氧化石墨烯(RGO)的合成方法,介绍了还原氧化石墨烯及其前驱体如氧化石墨烯和氧化石墨烯的制备方法。此外,还讨论了减少RGO中缺陷的可能途径。
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引用次数: 0
Welcome to Minerals and Mineral Materials, a new scientific and technological journal 欢迎光临《矿物与矿物材料》这一新的科技期刊
Pub Date : 2021-10-15 DOI: 10.20517/MMM.2021.01
Shaoxian Song
{"title":"Welcome to Minerals and Mineral Materials, a new scientific and technological journal","authors":"Shaoxian Song","doi":"10.20517/MMM.2021.01","DOIUrl":"https://doi.org/10.20517/MMM.2021.01","url":null,"abstract":"","PeriodicalId":319570,"journal":{"name":"Minerals and Mineral Materials","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122848961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Minerals and Mineral Materials
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