Pub Date : 2019-05-10DOI: 10.1039/9781788016292-00236
B. Cojocaru, C. K. Waters, F. Lin, L. Woodard, R. Richards, V. Pârvulescu
This chapter focuses on photocatalytic water splitting. First the state-of-the-art techniques in photocatalyst development are presented and challenges in the field are highlighted. Photocatalytic water splitting is covered by a systematic assessment of periodic trends with a focus on d0 and d10 elements. Finally, metal–organic, polymer and carbon structures are evaluated as alternatives and/or additions which may help to limit the use of expensive metals.
{"title":"Chapter 9. Nanoparticles and Nanocomposites Design in Photocatalysis","authors":"B. Cojocaru, C. K. Waters, F. Lin, L. Woodard, R. Richards, V. Pârvulescu","doi":"10.1039/9781788016292-00236","DOIUrl":"https://doi.org/10.1039/9781788016292-00236","url":null,"abstract":"This chapter focuses on photocatalytic water splitting. First the state-of-the-art techniques in photocatalyst development are presented and challenges in the field are highlighted. Photocatalytic water splitting is covered by a systematic assessment of periodic trends with a focus on d0 and d10 elements. Finally, metal–organic, polymer and carbon structures are evaluated as alternatives and/or additions which may help to limit the use of expensive metals.","PeriodicalId":337920,"journal":{"name":"Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116390560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-05-10DOI: 10.1039/9781788016292-00132
H. Jena, Karen Leus, P. Voort
In this chapter, the synthesis, characterization and catalytic applications of metal organic framework nanoparticles (MOF-NPs) are discussed. This chapter begins with a general introduction, then the synthesis and characterization methods of MOFs and MOF-NPs are discussed, as well as the catalytic applications of MOF-NPs. The focus is set on design strategies for the synthesis of MOF-NPs, in conjunction with characterization techniques and recent progress in the synthesis of advanced MOF-NPs, such as base metal NPs, multi-metallic nanoparticles and NPs with a core–shell structure. Regarding the catalytic applications of MOF-NPs, oxidation, hydrogenation, coupling reactions (C–C, A3-type and cascade) and asymmetric synthesis are discussed. Finally, the importance of how to control the shape, size and location of NPs is stressed in order to better understand their reactivity.
{"title":"Chapter 5. Metal–Organic-framework Nanoparticles: Synthesis, Characterization and Catalytic Applications","authors":"H. Jena, Karen Leus, P. Voort","doi":"10.1039/9781788016292-00132","DOIUrl":"https://doi.org/10.1039/9781788016292-00132","url":null,"abstract":"In this chapter, the synthesis, characterization and catalytic applications of metal organic framework nanoparticles (MOF-NPs) are discussed. This chapter begins with a general introduction, then the synthesis and characterization methods of MOFs and MOF-NPs are discussed, as well as the catalytic applications of MOF-NPs. The focus is set on design strategies for the synthesis of MOF-NPs, in conjunction with characterization techniques and recent progress in the synthesis of advanced MOF-NPs, such as base metal NPs, multi-metallic nanoparticles and NPs with a core–shell structure. Regarding the catalytic applications of MOF-NPs, oxidation, hydrogenation, coupling reactions (C–C, A3-type and cascade) and asymmetric synthesis are discussed. Finally, the importance of how to control the shape, size and location of NPs is stressed in order to better understand their reactivity.","PeriodicalId":337920,"journal":{"name":"Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry","volume":"98 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132290940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：