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Preparation of hydrophilic MgAl type layered double hydroxide films with elevated Mg/Al molar ratio on aluminum substrates via a facile approach 通过简便方法在铝基底上制备具有较高镁/铝摩尔比的亲水性镁铝型层状双氢氧化物薄膜
Pub Date : 2024-02-12 DOI: 10.1007/s43939-024-00072-y
Satoru Fukugaichi, Yuta Tomosugi, Hiromichi Aono
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引用次数: 0
Effect of papain enzyme surface modification on hydrophilic and comfort properties of polyester/cotton blend fabric 木瓜蛋白酶表面改性对涤棉混纺织物亲水性和舒适性的影响
Pub Date : 2024-01-05 DOI: 10.1007/s43939-023-00071-5
W. Tegegne, Adane Haile
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引用次数: 0
Effect of water absorption, hardness, and acoustic properties on sandwich syntactic foam composite for structural and marine applications 吸水性、硬度和声学特性对结构和海洋应用中夹层合成泡沫复合材料的影响
Pub Date : 2024-01-02 DOI: 10.1007/s43939-023-00070-6
O. Afolabi, T. Mohan, K. Kanny
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引用次数: 0
Amorphous multimetal based catalyst for oxygen evolution reaction. 基于非晶多金属的氧进化反应催化剂。
Pub Date : 2024-01-01 Epub Date: 2024-06-25 DOI: 10.1007/s43939-024-00087-5
Zishuai Zhang, Daniela Vieira, Jake E Barralet, Geraldine Merle

The development of efficient, low-cost water splitting electrocatalysts is needed to store energy by generating sustainable hydrogen from low power clean but intermittent energy sources such as solar and wind. Here, we report a highly sustained low overpotential for oxygen evolution reached by the unique combination of three metals (NiCoV) prepared from a simple low temperature auto-combustion process. The amorphous multimetal oxygen evolving catalyst could be stably coated on a stainless-steel support using a tribochemical particle blasting method to create an oxygen evolution reaction (OER) electrode with a low overpotential of 230 mV at 10 mA cm-2 and a low Tafel slope of 40 mV dec-1. In addition to their low overpotential, this oxygen evolving electrocatalyst preserved performance demonstrating a stability after 10 h at the technologically relevant current density and without any surface morphology alteration. Given the importance of sustainable hydrogen production, the development of this new OER catalyst points the way to removing a key technical bottleneck for the water splitting reaction and could offer a route to cost reduction and lowering hurdles to more widespread adaptation of electrolyser technologies for hydrogen production.

Supplementary information: The online version contains supplementary material available at 10.1007/s43939-024-00087-5.

我们需要开发高效、低成本的水分离电催化剂,通过利用太阳能和风能等低能耗、清洁但间歇性的能源产生可持续的氢来储存能源。在此,我们报告了通过简单的低温自燃工艺制备的三种金属(NiCoV)的独特组合所达到的高度持续的低过电位氧进化。这种非晶态多金属氧进化催化剂可通过摩擦化学粒子喷射法稳定地涂覆在不锈钢载体上,从而形成氧进化反应(OER)电极,在 10 mA cm-2 的条件下具有 230 mV 的低过电位和 40 mV dec-1 的低塔菲尔斜率。除了过电势低之外,这种氧进化电催化剂还能保持性能稳定,在技术相关的电流密度下工作 10 小时后,其表面形态没有发生任何改变。考虑到可持续制氢的重要性,这种新型氧进化催化剂的开发为消除水分离反应的一个关键技术瓶颈指明了方向,并为降低成本和减少电解槽制氢技术更广泛应用的障碍提供了途径:在线版本包含补充材料,可查阅 10.1007/s43939-024-00087-5。
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引用次数: 0
Development of aluminum composite reinforced with selected agricultural residues 用选定农作物残留物强化铝复合材料的开发
Pub Date : 2023-12-21 DOI: 10.1007/s43939-023-00069-z
L. Osunmakinde, T. B. Asafa, P. Agboola, M. Durowoju
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引用次数: 0
The current impacts and future prospects of graphene derivatives in polymer-based supercapacitors 石墨烯衍生物在聚合物基超级电容器中的当前影响和未来前景
Pub Date : 2023-12-17 DOI: 10.1007/s43939-023-00068-0
E. T. Mombeshora, E. Muchuweni
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引用次数: 0
A vertically translating collection system to facilitate roll-to-roll centrifugal spinning of highly aligned polyacrylonitrile nanofibers 垂直平移收集系统,促进高排列聚丙烯腈纳米纤维的卷对卷离心纺丝
Pub Date : 2023-12-01 DOI: 10.1007/s43939-023-00067-1
Jason Ippolito, V. Beachley
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引用次数: 0
Effect of Pb doping on the structural, optical and electrical properties of sol–gel ZnO nanoparticles 掺杂铅对溶胶凝胶氧化锌纳米粒子的结构、光学和电学特性的影响
Pub Date : 2023-11-18 DOI: 10.1007/s43939-023-00066-2
Fatemeh Moosavi, G. Neri
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引用次数: 0
A review on electrolytes for supercapacitor device 超级电容器用电解液的研究进展
Pub Date : 2023-10-26 DOI: 10.1007/s43939-023-00065-3
Arpit Mendhe, H. S. Panda
Abstract Electrodes and electrolytes have a significant impact on the performance of supercapacitors. Electrodes are responsible for various energy storage mechanisms in supercapacitors, while electrolytes are crucial for defining energy density, power density, cyclic stability, and efficiency of devices. Various electrolytes, from aqueous to ionic liquid, have been studied and implemented as potential electrolytes for supercapacitors. The ionic size, conductivity, mobility, diffusion coefficient, and viscosity of electrolytes affect the device’s capacitance. Electrode type and its interaction with electrolytes are other factors to consider when choosing an electrolyte for a supercapacitor. In this review, an attempt has been made to provide a comprehensive and straightforward overview of the numerous electrolytes widely used for supercapacitor study and how these electrolytes interact with the electrodes to improve the performance of the supercapacitors.
电极和电解质对超级电容器的性能有重要影响。在超级电容器中,电极负责各种能量存储机制,而电解质对于定义器件的能量密度、功率密度、循环稳定性和效率至关重要。各种电解质,从水到离子液体,已经被研究和实现作为超级电容器的潜在电解质。电解质的离子大小、电导率、迁移率、扩散系数和粘度影响器件的电容。在为超级电容器选择电解液时,电极类型及其与电解质的相互作用是要考虑的其他因素。在这篇综述中,试图提供一个全面的和简单的概述了广泛用于超级电容器研究的电解质,以及这些电解质如何与电极相互作用以提高超级电容器的性能。
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引用次数: 0
Fabrication of flat stainless steel substrates with improved oxidation behavior for metal-supported solid oxide cells using aqueous tape casting 采用水带铸造技术制备具有改善氧化性能的金属支撑固体氧化物电池用平面不锈钢衬底
Pub Date : 2023-10-20 DOI: 10.1007/s43939-023-00063-5
Yifei Yan, Olivera Kesler
Abstract An aqueous tape casting procedure was developed and optimized to fabricate thick, flat tapes for use as porous stainless-steel substrates for metal-supported solid oxide cells (MS-SOCs). Curling tape is one of the main challenges when using aqueous based slurry formation. This work demonstrated that the sedimentation problem can be solved by increasing solid loading rather than adding excessive binder to raise viscosity. The effect of various casting surfaces on tape curling was also investigated. Materials that allow easy tape release resulted in flatter tapes once the water was evaporated. In addition, substrate oxidation resistance at high temperature was evaluated with respect to starting powder size, sintering extent, and pore former types. High sintering extent that removes or encloses the porosity between steel particles while retaining porosity left by pore formers can effectively prevent breakaway oxidation due to local chromium depletion. Carbon residue in the steel substrates from the slurry organic content can be decreased when formulating the slurry to prevent Cr-rich phase formation in the steel, which severely compromises the substrate oxidation resistance and ductility. By dwelling the substrate in high purity hydrogen, the sensitization can be reversed, but more detailed investigation of the reaction dynamics is needed. By combining the strategies described, this work produced crack-free, flat, 400–500 μm thick stainless steel substrates with 28.7 vol% porosity and improved oxidation resistance compared to previous substrates fabricated by dry pressing of fine powders.
开发并优化了一种水带铸造工艺,用于制造厚而平的带,用于金属支撑固体氧化物电池(ms - soc)的多孔不锈钢衬底。卷绕带是使用水基泥浆地层时的主要挑战之一。这项工作表明,沉降问题可以通过增加固体负荷来解决,而不是添加过多的粘合剂来提高粘度。研究了不同铸造表面对卷材卷边的影响。一旦水分蒸发,容易释放胶带的材料会使胶带变平。此外,基材在高温下的抗氧化性根据起始粉末尺寸、烧结程度和孔隙形成类型进行了评估。烧结程度高,既能消除或封闭钢颗粒之间的孔隙,又能保留成孔者留下的孔隙,可有效防止因局部铬耗尽而导致的分离氧化。当配制浆料时,可以降低钢基体中碳渣的有机含量,以防止钢中富cr相的形成,这严重损害了基体的抗氧化性和延展性。通过将底物置于高纯氢中,敏化作用可以逆转,但需要对反应动力学进行更详细的研究。通过结合上述策略,该工作生产了无裂纹、平坦、400-500 μm厚的不锈钢衬底,其孔隙率为28.7 vol%,与以前通过细粉末干压制备的衬底相比,其抗氧化性得到了提高。
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引用次数: 0
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