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A parametric analysis on PEFCs for high-temperature applications 高温应用pefc的参数分析
Q4 Energy Pub Date : 2020-06-01 DOI: 10.5130/pamr.v7i0.1594
System Administrator, Filip Bojko, Giorge Gemisis, James Mitchell, Christopher Parker
Polymer Electrolyte Fuel Cells (PEFCs) are an increasingly significant facet of modern renewable energy and transportation, providing an electrochemical method of energy generation with high power density, thermal properties, and efficiency. PEFCs tend to increase in efficiency as temperature increases but detrimental effects begin to occur, including membrane degradation and dehydration. These effects are unfavourable in the design of optimised fuel cells as they can result in reduced efficiency and lifetime. Current PEFCs are in a state where they are commercially viable but have a very limited temperature operation region (<80°C). This meta-study analysis presents research around expanding the operational temperatures of PEFCs through a parametric analysis of active cell area, phosphonic acid content, and organic/inorganic fillers. This analysis finds an increase in proton conductivity for PEFCs at higher temperature by using phosphonic acid functionalised membranes with maximised degree of phosphonation (up to 1.5 DP). It was also found that using ionic liquid functionalised carbon materials as fillers was an effective strategy to enhance the proton conductivity of PEFCs in a higher temperature environment while also providing increased thermal stability of the membrane. Additionally, higher thermal efficiency and power density may be achieved by increasing temperature and humidity to maximise proton conductivity towards theoretical maxima dictated by the active cell area, which was found to peak at 36 cm2.
聚合物电解质燃料电池(pefc)是现代可再生能源和交通运输中日益重要的一个方面,它提供了一种具有高功率密度、热性能和效率的电化学发电方法。随着温度的升高,pefc的效率趋于提高,但也开始出现不利影响,包括膜降解和脱水。这些影响对优化燃料电池的设计是不利的,因为它们会导致效率和寿命的降低。目前的pefc处于商业上可行的状态,但其温度工作区域非常有限(<80°C)。本meta研究分析通过对活性电池面积、磷酸含量和有机/无机填料的参数分析,介绍了围绕扩大pefc操作温度的研究。该分析发现,在较高温度下,通过使用磷酸功能化膜,最大程度的磷化(高达1.5 DP), pefc的质子电导率增加。研究还发现,使用离子液体功能化碳材料作为填料是一种有效的策略,可以提高pefc在高温环境下的质子导电性,同时还可以提高膜的热稳定性。此外,更高的热效率和功率密度可以通过提高温度和湿度来实现,以最大限度地提高质子电导率,达到由活性电池面积决定的理论最大值,发现活性电池面积的峰值为36 cm2。
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引用次数: 0
Differential probabilistic space-temporal model for real-time power prognosis in failures in a nuclear reactor 核反应堆故障实时功率预测的微分概率时空模型
Q4 Energy Pub Date : 2019-10-22 DOI: 10.1504/ijnest.2019.10024814
Nazira Guerrero-Jezzini, A. Nuñez-carrera, A. Vázquez-Rodríguez, Zaira I. Jiménez-Balbuena, P. Ibargüengoytia, L. Sucar
The aim of this paper is the neutronic flux prognosis in a nuclear reactor for faults in the measurement of local power range monitors (LPRMs) in real time using differential probabilistic space-temporal model (DPSTM). The LPRMs provide inputs to the average power range monitor (APRM). The LPRM houses a fission chamber and their associated signal cables. The failure of one or more chains of LPRMs is common during the operational cycle. The circuit averages only LPRM signals that are operational and the output from the averaging circuit for each APRM channel is the route to the process computer. The DPSTM allows a reliable reconstruction in real time signal of those LPRMs that are out of order. The DPSTM is evaluated in terms of predictive accuracy for different time horizons and compared to a time series. The DPSTM based prognosis methodology was developed and validated with real signals of Ringhals stability benchmarks.
本文的目的是使用差分概率时空模型(DPSTM)实时测量局部功率范围监测器(LPRM)中的故障,对核反应堆中的中子通量进行预测。LPRM为平均功率范围监测器(APRM)提供输入。LPRM包含一个裂变室及其相关信号电缆。一个或多个LPRM链的故障在运行周期中很常见。该电路仅对可操作的LPRM信号进行平均,并且每个APRM通道的平均电路的输出是通往过程计算机的路径。DPSTM允许对那些失序的LPRM的实时信号进行可靠的重建。DPSTM根据不同时间范围的预测精度进行评估,并与时间序列进行比较。开发了基于DPSTM的预后方法,并用Ringhals稳定性基准的真实信号进行了验证。
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引用次数: 0
Small modular reactor core neutronic evaluation via Monte Carlo method 基于蒙特卡罗方法的小型模块化反应堆堆芯中子评价
Q4 Energy Pub Date : 2019-10-22 DOI: 10.1504/ijnest.2019.103238
R. Akbari, D. R. Ochbelagh, A. Gharib
The main purpose of this study is a core neutronic parameter evaluation via the Monte Carlo method, for the SMART reactor which is a certified design Small Modular Reactor (SMR). The SMART neutronic parameters such as axial and radial distributions of neutron fluxes, Power Peaking Factors (PPFs), effective delayed neutron fraction, xenon and samarium effects, burnup calculation and neutron flux energy spectrum have been assessed. Daily load follow operation in soluble-boron-free with control regulating banks is one of the best SMART reactor core advantages. Accordingly, the effects of main regulating bank insertion in SMART core have been evaluated. For developed model verification, some of the neutronic parameters have been compared with the SMART Standard Safety Analysis (SSAR) and show proper match. Then other neutronic parameters of the SMART core as a pioneer SMR have been calculated and evaluated.
本研究的主要目的是通过蒙特卡罗方法对SMART反应堆的核心中子参数进行评估,SMART反应堆是一种经过认证设计的小型模块化反应堆(SMR)。SMART中子参数包括中子通量的轴向和径向分布、功率峰值因子(PPFs)、有效延迟中子分数、氙和钐效应、燃耗计算和中子通量能谱。无可溶性硼控制调节堆的日负荷跟随运行是SMART堆芯的一大优点。据此,对主要监管银行插入SMART核心的效果进行了评估。为了验证所建立的模型,将一些中子参数与SMART标准安全分析(SSAR)进行了比较,显示出适当的匹配。然后对SMART堆芯作为先锋SMR的其他中子参数进行了计算和评价。
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引用次数: 1
Enhanced calculations of fusion barrier distribution for heavy-ion fusion reactions using Wong formula 利用Wong公式改进了重离子聚变反应的聚变势垒分布计算
Q4 Energy Pub Date : 2019-10-22 DOI: 10.1504/ijnest.2019.103237
F. A. Majeed, F. M. Hussain, Yousif A. Abdul-Hussien
The effects of coupled-channels in heavy-ion fusion reaction for the system 40Ca + 192Os, 40Ca + 194Pt, and 48Ca + 197Au are discussed. The fusion cross-section σfus, the fusion barrier distribution Dfus and fusion probability Pfus are also discussed. The fusion barrier distribution is calculated using numerical three point, five point and Wong methods. Full quantum coupled-channels calculations are performed using CCFULL code with all order coupling to compare and with available experimental data. The χ² values for the case of no-coupling and coupling effects included shows clearly that the present calculations are in agreement with the experimental.
讨论了耦合通道对40Ca + 192Os、40Ca + 194Pt和48Ca + 197Au体系重离子聚变反应的影响。讨论了熔合截面σfus、熔合势垒分布Dfus和熔合概率Pfus。采用数值三点法、五点法和王氏法计算聚变势垒分布。使用CCFULL代码进行全量子耦合信道计算,并与现有实验数据进行比较。不耦合和耦合效应情况下的χ 2值清楚地表明,本文的计算与实验结果一致。
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引用次数: 2
Study of nuclear structure of 58,62Ni isotopes using the F5PVH effective interaction 利用F5PVH有效相互作用研究58,62Ni同位素的核结构
Q4 Energy Pub Date : 2019-10-22 DOI: 10.1504/ijnest.2019.10024819
K. S. Jassim, Aqeel I. Faris
The nuclear structure of 58,62Ni nuclei has been calculated using F5PVH as effective interaction for 1f5/2 2p3/2 2p1/2 shell model wave functions. Skyrme-Hartree Fock (SKX), Harmonic Oscillator (HO) and Woods-Saxon (WS) potentials were used to calculate the single particle wave function. The core-polarisation effects have been adopted using the shape of Tassie model. The level schemes are compared with the experimental data up to 3.42 MeV and 4.018 MeV for 58Ni and 62Ni, respectively. In this study, very good agreements are obtained for all nuclei. Results from C2 form factor and Charge Density Distribution (CDD) calculations give good agreement with the experimental data with no adjustable parameters.
用F5PVH作为1f5/22p3/22p1/2壳层模型波函数的有效相互作用,计算了58,62Ni核的核结构。用Skyrme-Hartree-Fock(SKX)、谐振子(HO)和Woods-Saxon(WS)势计算了单粒子波函数。使用Tassie模型的形状采用了核心极化效应。将58Ni和62Ni的能级方案分别与3.42MeV和4.018MeV的实验数据进行了比较。在这项研究中,所有核都得到了非常好的一致性。C2形状因子和电荷密度分布(CDD)的计算结果与无可调参数的实验数据吻合良好。
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引用次数: 2
Reactivity worth calculation for control rods groups of the VVER-1000 nuclear reactor core considering shadowing effect using Monte Carlo method 考虑遮蔽效应的VVER-1000核反应堆堆芯控制棒组反应性的蒙特卡罗计算
Q4 Energy Pub Date : 2019-10-22 DOI: 10.1504/ijnest.2019.103240
Z. Tabadar, G. Ansarifar, K. Hadad, M. Jabbari
Global core calculations use the diffusion equation to predict theoretically the nuclear reactor behaviour. However, this equation is not valid in strong absorbing media where the neutron spectrum is a rapidly varying function of the position, such as control rods or burnable poisons. In this paper, to overcome this misleading, the Monte Carlo simulation has been performed and the VVER-1000 reactor core in the MCL (Reactor Minimally Controlled Power Level) condition is modelled using the MCNPX code to calculate the reactivity worth of the control rod groups. The calculations in this model are divided into four steps. At first, the integral and differential worth are calculated for control groups 8, 9 and 10 with 50% overlapping and shadowing effect is considered. And in three other steps the integral and differential reactivity worths of control groups 8, 9 and 10 are calculated separately (without overlapping). In each step, the core is maintained critical by variation of the boron concentration. In these processes, the boric acid coefficient is achieved while the core is critical. The results are compared with experimental values and are in good agreement with them.
全局堆芯计算使用扩散方程从理论上预测核反应堆的行为。然而,在中子光谱是位置的快速变化函数的强吸收介质中,例如控制棒或可燃毒物,该方程是无效的。在本文中,为了克服这种误导,进行了蒙特卡罗模拟,并使用MCNPX代码对MCL(反应堆最小控制功率水平)条件下的VVER-1000堆芯进行建模,以计算控制棒组的反应性价值。该模型中的计算分为四个步骤。首先,计算了具有50%重叠的对照组8、9和10的积分和微分值,并考虑了阴影效应。在其他三个步骤中,分别计算对照组8、9和10的积分和微分反应性值(没有重叠)。在每个步骤中,通过硼浓度的变化来保持堆芯的临界状态。在这些过程中,硼酸系数是在堆芯处于临界状态时实现的。结果与实验值进行了比较,与实验值吻合较好。
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引用次数: 0
锦屏深地核天体物理实验(JUNA)进展 锦屏深地核天体物理实验(JUNA)进展
Q4 Energy Pub Date : 2019-10-20 DOI: 10.7538/YZK.2019.53.10.1729
Weiping Liu, Zhihong Li, Jianjun He, Xiaodong Tang, G. Lian, B. Guo, Jun Su, Yunju Li, B. Cui, Liangting Sun, Qi Wu, Z. An, Qinghao Chen, Xiongjun Chen, Yangping Chen, Zhijun Chen, X. Du, C. Fu, Lin Gan, Guozhu He, A. Heger, S. Hou, Hanxiong Huang, N. Huang, B. Jia, Liyang Jiang, S. Kubono, Jianmin Li, Kuo-Ang Li, Tao Li, M. Lugaro, X. Luo, Shaobo Ma, D. Mei, Y. Qian, J. Qin, Jie Ren, Wanpeng Tan, I. Tanihata, Peng Wang, Shuo Wang, Y. Wang, Shi-wei Xu, Shengquan Yan, Litao Yang, Xiangqing Yu, Qianyu Yue, S. Zeng, Huanyu Zhang, Hui Zhang, Li-yong Zhang, N. Zhang, Qi Zhang, Tao Zhang, Xiaodong Fang, Xiao Zhang, X. Zhang, Zhimin Zhang, Wei Zhao, Zhuo Zhao, Chao Zhou, Yunhua Chen, Ningchun Qi, Shi-ying Wu, Xuyuan Guo, Jifang Zhou, Sheng-Dong He, J. Ning, Jianfeng Yue
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引用次数: 0
Study of Grodzins product in collective nuclear structure 集体核结构中Grodzins产物的研究
Q4 Energy Pub Date : 2019-07-08 DOI: 10.1504/IJNEST.2019.10022532
Amit Bindra, H. M. Mittal
The systematic dependence of Grodzins product E(2+1)*B(E2)↑ on the nucleonic promiscuity factor, i.e. P-factor = (Np Nn)/(Np + Nn), is studied in the Z = 50−82, N = 82−126 major shell space. The anomalous behaviour is noticed at N = 88−90, where the Grodzins product fails to maintain the constancy corresponding to P ≥ 4. The nuclei for P ≥ 4 region are recognised for enhanced collectivity, where p−n interaction is of the order of ~250 keV and it begins to dominate the pairing interaction of ~1 MeV. The P-factor also resolves the anomaly of not obtaining smooth universal Casten curve in Np Nn scheme. The approximate constancy in Grodzins product is noticed for well deformed nuclear region. The relation between Grodzins product and P-factor has been studied for the first time.
在Z = 50−82,N = 82−126的主壳层空间中,研究了Grodzins积E(2+1)*B(E2)↑对核子混杂因子的系统依赖,即p因子= (Np Nn)/(Np + Nn)。在N = 88−90时,注意到异常行为,此时Grodzins积不能保持对应于P≥4的常数。P≥4区的原子核集体性增强,其中P - n相互作用约为~250 keV,并开始主导~1 MeV的配对相互作用。p因子还解决了Np - Nn格式不能得到光滑的通用Casten曲线的异常。对于形变较好的核区,注意到格罗津积的近似常数。本文首次研究了Grodzins产品与p因子之间的关系。
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引用次数: 0
Searching for the optimum number of integral burnable absorber rods used in PWR assembly 压水堆组件用整体式可燃吸收棒最佳数量的探索
Q4 Energy Pub Date : 2019-07-08 DOI: 10.1504/IJNEST.2019.10022540
A. Galahom
This article discusses the effect of different Integral Burnable Absorber numbers (IBAs) on the neutronic characteristics of a Pressurised Water Reactor (PWR) to provide a suitable safety level. MCNPX code version 2.6 was used to design a three dimensional model for PWR assembly. The designed model has been validated by comparing the output values of the infinity multiplication factor (Kinf) with a previously published value. The designed MCNPX model was used to analyse the radial distribution of thermal neutrons and the power through PWR assembly with and without IBA. Due to the high absorption cross-section of gadolinium, it has been used as a burnable absorber material in the IBA rods. The gadolinium isotopes suppressed the power in the regions where they were distributed. The existence of IBA rods has a large effect on the Kinf. This effect decreases gradually with burnup due to the degradation of gadolinium. The gadolinium isotopes degradation was analysed with burnup. Different numbers of IBA rods were investigated to optimise the suitable number that can be used in the PWR assembly. The reactivity has been investigated at different numbers of IBAs. The gadolinium effect on the concentration of 135Xe and 149Sm resulting from the fission process was analysed.
本文讨论了不同可燃吸收体数量()对压水堆(PWR)中子特性的影响,以提供合适的安全水平。采用MCNPX 2.6版代码对压水堆组件进行三维模型设计。通过将无限乘法因子(Kinf)的输出值与先前公布的值进行比较,验证了所设计的模型。利用所设计的MCNPX模型分析了装有和不装有IBA的压水堆组件的热中子径向分布和功率。由于钆的高吸收截面,它已被用作IBA棒的可燃吸收材料。钆同位素在它们分布的区域抑制了能量。IBA棒的存在对Kinf有很大的影响。由于钆的降解,这种效应随着燃耗逐渐减弱。用燃耗法分析了钆同位素的降解情况。研究了不同数量的IBA棒,以优化可用于压水堆组件的合适数量。研究了不同数量的反应性。分析了裂变过程中钆对135Xe和149Sm浓度的影响。
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引用次数: 4
Improving of phenomenological formula for nuclear energy decay (Qα-value) of heavy and super heavy nuclei 改进了重核和超重核能量衰变(q α-值)的现象学公式
Q4 Energy Pub Date : 2019-07-08 DOI: 10.1504/IJNEST.2019.10022536
Firas M. Ali, H. Hadi
The phenomenological formula of Qα-value (α-decay energies) for heavy and super heavy nuclei was presented using modification of a Liquid Drop Model (LDM) which is composed of effects of volume energy, Coulomb energy, symmetry energy and binding energy of α-particle. It can be employed to validate the experimental observation and calculation to a large extent of heaviest nuclei with high accuracy for root mean square deviation (0.54) and standard deviation (0.38) are which useful for future experiments. In comparison of computed Qα-value with experimental data an excellent agreement has been obtained. These results indicate the acceptability of the approach. Furthermore the theoretical quantity (S) has been proposed in order to predict the Qα-value of α-particles. This is done by partial differentiation of both sides of Qα-value with respect to the mass number (A), this quantity describes the Qα-value dependence of (A), and these results show agreement between S and Qα-values behaviours. The separation energy difference (Sp-Sn) increases with increasing mass number (A), on the whole.
通过对由体积能、库仑能、对称能和α-粒子结合能影响的液滴模型(LDM)的修正,给出了重核和超重核的q α-值(α-衰变能)的现象学公式。它可以在很大程度上验证实验观察和计算,最重核的均方根偏差(0.54)和标准差(0.38)具有较高的精度,对今后的实验有帮助。将计算的q α值与实验数据进行了比较,得到了很好的一致性。这些结果表明了该方法的可接受性。此外,还提出了预测α-粒子q α-值的理论量S。这是通过q α-值对质量数(A)的两边偏微分来实现的,这个量描述了(A)的q α-值依赖关系,这些结果表明S和q α-值行为之间是一致的。分离能差(Sp-Sn)总体上随质量数(A)的增加而增大。
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引用次数: 4
期刊
International Journal of Nuclear Energy Science and Technology
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