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Consumer Perception of Personal Care Products and Cosmetics on Health and Environmental Effects 消费者对个人护理产品和化妆品对健康和环境影响的看法
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-29 DOI: 10.1002/tqem.22339
Sachith Gihan Gamage, Mahagama Gedara Yohan Lasantha Mahagamage

Personal care products and cosmetics have become an essential part of present society. Since the composition of these products directly correlates with public health and the environment, understanding consumer behaviors and attitudes is a significant aspect in controlling their negative impacts. The present study surveyed 300 consumers in Sri Lanka to attain insights into the selection, usage, disposal, and participants' attitudes and knowledge of these products. The majority of the respondents were female (58%) and 71% were between the ages of 18 and 65. Most of them (48%) selected products by their evaluations and 34% were highly concerned about the ingredients. Removal of applied products was mainly done by washing (97%) and in many households, generated wastewater ended up in wastewater gullies (69%). The remaining plastic packages were discarded into municipal garbage trucks (42%) or burned (31%). Alarmingly, 29% of the participants have experienced some kind of adverse reaction by using these products during their lifetime. Therefore, proper monitoring, waste management, and regulation of these products could be beneficial to control many related health and environmental consequences.

个人护理产品和化妆品已成为当今社会的重要组成部分。由于这些产品的成分与公众健康和环境直接相关,因此了解消费者的行为和态度对于控制其负面影响具有重要意义。本研究对斯里兰卡的 300 名消费者进行了调查,以深入了解这些产品的选择、使用、处置以及参与者的态度和知识。大多数受访者为女性(58%),71%的受访者年龄在 18 岁至 65 岁之间。大多数受访者(48%)通过评价来选择产品,34%的受访者高度关注产品的成分。清除涂抹产品的方法主要是清洗(97%),许多家庭产生的废水最终流入污水沟(69%)。剩余的塑料包装被丢弃到城市垃圾车(42%)或焚烧(31%)。令人震惊的是,29% 的参与者在一生中使用过这些产品,并出现过某种不良反应。因此,对这些产品进行适当的监测、废物管理和监管,可以有效控制许多相关的健康和环境后果。
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引用次数: 0
Impact Assessment of Ports and Effluent Discharge on Macrobenthic Communities in Indian Coastal Ecosystems: A Comprehensive Review 港口和污水排放对印度沿海生态系统大型底栖生物群落的影响评估:全面回顾
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-29 DOI: 10.1002/tqem.22341
Atchuthan Purushothaman, Anju Krishnan

The burgeoning industrialization and urbanization along the Indian coastline have led to an increased prevalence of port infrastructure and effluent discharge, raising concerns about their potential impact on the delicate macrobenthic communities in coastal ecosystems. This comprehensive review aims to evaluate and synthesize existing literature on the ecological repercussions of port activities and effluent discharge on macrobenthic organisms in Indian coastal regions. The study encompasses a thorough analysis of relevant research articles, government reports, and scientific databases, focusing on diverse ecosystems such as estuaries, mangroves, and open coastlines. The review discusses the various stressors associated with port operations, including dredging, habitat alteration, and chemical contamination from effluent discharge. Furthermore, it explores the response mechanisms of macrobenthic communities, encompassing changes in species composition, abundance, and diversity. Special attention is given to the potential long-term impacts on ecosystem functioning and services. The synthesis of available data enables the identification of knowledge gaps and the formulation of recommendations for future research and management strategies. Understanding the cumulative effects of port activities on macrobenthic communities is crucial for developing sustainable practices and policies to mitigate adverse impacts while fostering the resilience of coastal ecosystems in the face of anthropogenic pressures. This review contributes to the growing body of knowledge on the ecological consequences of human activities in Indian coastal areas, providing valuable insights for researchers, policymakers, and environmental managers alike.

印度沿岸蓬勃发展的工业化和城市化导致港口基础设施和污水排放日益普遍,引起了 人们对其对沿海生态系统中脆弱的大型底栖生物群落的潜在影响的关注。本综合综述旨在评估和归纳有关港口活动和污水排放对印度沿海地区大型底栖生物生态影响的现有文献。研究对相关研究文章、政府报告和科学数据库进行了全面分析,重点关注河口、红树林和开阔海岸线等不同生态系统。综述讨论了与港口作业相关的各种压力因素,包括疏浚、生境改变和污水排放造成的化学污染。此外,它还探讨了大型底栖生物群落的反应机制,包括物种组成、丰度和多样性的变化。特别关注对生态系统功能和服务的潜在长期影响。通过对现有数据的综合分析,可以找出知识差距,并为未来的研究和管理策略提出建议。了解港口活动对大型底栖生物群落的累积效应,对于制定可持续的实践和政策,减 轻不利影响,同时提高沿岸生态系统在人为压力下的恢复能力至关重要。这篇综述为印度沿海地区人类活动的生态后果提供了越来越多的知识,为研究人员、政策制定者和环境管理者提供了宝贵的见解。
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引用次数: 0
Environmental Impact of Automobile Wastes on Surface Water Quality in Ebonyi State, Southeast Nigeria 尼日利亚东南部埃邦伊州汽车废物对地表水水质的环境影响
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-28 DOI: 10.1002/tqem.22340
Odera Chukwumaijem Okafor, Anselem Nwabuaku Akwuebu, Chima Njoku, Okechukwu Okorie Ekwe

The negative impact of operations in informal auto mechanic workshops is a major public health concern, and its effect on surface water pollution cannot be overlooked. This current work evaluates the environmental impact of automobile waste on surface water quality in Ebonyi State, Southeast Nigeria. A total of 108 surface water samples were taken in 2022 and 2023 from Abakaliki, Onueke, and Afikpo streams, and WHO as controls using standard analytical methods. Data sets were analyzed using Fisher's Significance Least Difference (F-LSD) at the 0.05 probability level. The study showed that surface water appearance was slightly brown, and the observed upstream is acidic in nature, the midstream is alkaline, and the downstream is natural. Water samples from Abakaliki, Onueke, and Afikpo streams were observed to be hard since their concentration levels were above the WHO standard. Furthermore, the high concentrations of heavy metals (Pb and Mn) as well as the oil and grease content indicate that the surface water in the area of study is polluted and its overall quality is degraded. The study therefore concluded that automobile waste had a negative influence on the surface water quality in the study area. Based on these new findings, it is recommended that automobile waste be properly treated and disposed of to avoid their adverse effects on surface water quality. In addition, given the uncontrolled development of these informal auto workshops across the nation in recent years, there is a need for the execution of environmental standards connected to automobile service activities.

非正规汽车维修车间作业的负面影响是一个重大的公共卫生问题,其对地表水污染的影响也不容忽视。本研究评估了汽车废料对尼日利亚东南部埃邦伊州地表水水质的环境影响。采用标准分析方法,分别于 2022 年和 2023 年从阿巴卡利基、奥努埃克和阿菲克波溪流以及世卫组织提取了 108 份地表水样本作为对照。在 0.05 的概率水平上,使用费雪显著性最小差(F-LSD)对数据集进行分析。研究结果表明,地表水外观略呈褐色,观察到的上游水质呈酸性,中游水质呈碱性,下游水质呈天然水。阿巴卡利基溪、奥努埃克溪和阿菲克波溪的水样被观测到较硬,因为其浓度水平超过了世界卫生组织的标准。此外,高浓度的重金属(铅和锰)以及油脂含量表明,研究地区的地表水受到污染,整体质量下降。因此,研究得出结论,汽车废弃物对研究区域的地表水水质产生了负面影响。基于这些新发现,建议对汽车废弃物进行适当处理和处置,以避免其对地表水水质造成不利影响。此外,鉴于近年来全国各地非正规汽车修理厂的无序发展,有必要执行与汽车服务活动相关的环境标准。
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引用次数: 0
Net-Zero Transition Pathways in Belt and Road Economies: Insights From Threshold Effects and Heterogeneous Analysis 一带一路 "经济体的净零转型途径:阈值效应和异质分析的启示
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-23 DOI: 10.1002/tqem.22335
Rabiatu Kamil, Ummar Faruk Saeed, Francis Kofi Essel, Timothy Masuni Nagriwum

Given the pressing need for economies to mitigate climate change and champion carbon neutrality, this study investigates the threshold effects of financial development and foreign direct investment (FDI) on carbon dioxide (CO₂) emissions in Sub-Saharan Africa (SSA) within the Belt and Road Initiative (BRI) bloc, taking into account the moderating role of the regulatory environment. Drawing on the environmental Kuznets curve and the pollution haven hypothesis, the study utilizes the dynamic generalized method of moments (GMM) modeling, proposed by Arellano and Bover, to analyze panel data from 37 SSA countries spanning 1990–2022. The findings reveal that financial development in the banking, financial, and private sectors, along with FDI outflows, is associated with a reduction in CO₂ emissions. Conversely, FDI inflows are linked to increased CO₂ emissions. A curvilinear relationship is observed, where initial increases in financial development and FDI correlate with higher emissions, which decline beyond a certain threshold. Stronger regulations enhance the positive impact of financial development on reducing CO₂ emissions. Finally, the findings show a significant heterogeneous effect across the SSA regional blocs. These findings underscore the critical need for implementing stringent environmental regulations and promoting sustainable financial practices to mitigate negative environmental impact. This research provides both theoretical and practical insights into fostering a carbon neutrality agenda and advancing Sustainable Development Goal 13.

鉴于各经济体迫切需要减缓气候变化并倡导碳中和,本研究调查了 "一带一路 "倡议集团内撒哈拉以南非洲地区金融发展和外国直接投资(FDI)对二氧化碳(CO₂)排放的门槛效应,同时考虑了监管环境的调节作用。本研究以环境库兹涅茨曲线和污染天堂假说为基础,利用 Arellano 和 Bover 提出的动态广义矩量法(GMM)模型,分析了 37 个撒哈拉以南非洲国家 1990-2022 年的面板数据。研究结果表明,银行、金融和私营部门的金融发展以及外国直接投资的流出与二氧化碳排放量的减少有关。相反,外国直接投资的流入则与二氧化碳排放量的增加有关。可以观察到一种曲线关系,即金融发展和外国直接投资的初始增长与较高的排放量相关,超过一定阈值后,排放量会下降。更严格的监管加强了金融发展对减少 CO₂ 排放量的积极影响。最后,研究结果表明,在撒哈拉以南非洲地区集团之间存在显著的异质性影响。这些发现强调了实施严格的环境法规和促进可持续金融实践以减轻对环境的负面影响的迫切需要。这项研究为促进碳中和议程和推进可持续发展目标 13 提供了理论和实践见解。
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引用次数: 0
Comprehensive Review of Fly Ash: Environmental Impact and Applications 全面回顾粉煤灰:环境影响与应用
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-23 DOI: 10.1002/tqem.22338
Vaibhav Sharma, Subhakanta Dash, Piyush Gupta

Fly ash (FyA), a byproduct from coal combustion in power plants, has become increasingly valuable due to its pozzolanic properties. Primarily, FyA finds applications in the construction industry, including road and brick construction, forest road building, and the cement industry. When added to concrete, it enhances splitting tensile strength, compressive strength, and workability, while also reducing the environmental impact of cement production. Beyond construction, FyA is utilized for air pollutant removal and serves as an adsorbent for various contaminants. It also plays a role in creating geopolymers and nanocomposites, promoting the development of eco-friendly construction materials. This review article presents current data on thermal power plants (ThPPs) in India, the challenges in FyA management, and its environmental impact. It also discusses relevant Indian policies and highlights ongoing research aimed at improving the efficiency and expanding the applications of FyA in various industrial sectors, such as battery manufacturing, zeolite synthesis, and cenosphere extraction. These efforts underscore FyA's potential in supporting sustainable practices. The findings of this review address critical issues related to FyA. By reducing the environmental footprint of cement manufacturing, removing air pollutants, and acting as an adsorbent for various contaminants, FyA demonstrates significant potential in pollution mitigation. It also contributes to the development of eco-friendly construction materials and promotes sustainability in the construction sector. Effective management practices are essential to minimize FyA's negative impact on human health and the environment. The article emphasizes the need for greater awareness and implementation of policies to address these issues comprehensively. By providing a detailed understanding of the benefits and challenges associated with FyA, it aims to pave the way for more effective and sustainable utilization of this industrial byproduct.

粉煤灰(FyA)是发电厂燃煤产生的副产品,因其具有水青石特性而变得越来越有价值。粉煤灰主要应用于建筑行业,包括道路和砖块建筑、森林道路建设和水泥行业。当添加到混凝土中时,它能增强劈裂拉伸强度、抗压强度和工作性,同时还能减少水泥生产对环境的影响。除建筑业外,FyA 还可用于清除空气污染物,并可作为各种污染物的吸附剂。它还可用于制造土工聚合物和纳米复合材料,促进生态友好型建筑材料的发展。这篇综述文章介绍了印度火力发电厂(ThPPs)的当前数据、FyA 管理面临的挑战及其对环境的影响。文章还讨论了印度的相关政策,并重点介绍了正在进行的旨在提高 FyA 效率和扩大其在电池制造、沸石合成和碳圈提取等各工业领域应用的研究。这些努力凸显了 FyA 在支持可持续实践方面的潜力。本综述的结论涉及与 FyA 有关的关键问题。通过减少水泥生产对环境的影响、去除空气污染物以及作为各种污染物的吸附剂,FyA 在减轻污染方面展现出了巨大的潜力。它还有助于开发生态友好型建筑材料,促进建筑行业的可持续发展。有效的管理方法对于最大限度地减少 FyA 对人类健康和环境的负面影响至关重要。文章强调,有必要提高人们的认识并实施相关政策,以全面解决这些问题。通过详细了解与 FyA 相关的益处和挑战,文章旨在为更有效、更可持续地利用这种工业副产品铺平道路。
{"title":"Comprehensive Review of Fly Ash: Environmental Impact and Applications","authors":"Vaibhav Sharma,&nbsp;Subhakanta Dash,&nbsp;Piyush Gupta","doi":"10.1002/tqem.22338","DOIUrl":"https://doi.org/10.1002/tqem.22338","url":null,"abstract":"<div>\u0000 \u0000 <p>Fly ash (FyA), a byproduct from coal combustion in power plants, has become increasingly valuable due to its pozzolanic properties. Primarily, FyA finds applications in the construction industry, including road and brick construction, forest road building, and the cement industry. When added to concrete, it enhances splitting tensile strength, compressive strength, and workability, while also reducing the environmental impact of cement production. Beyond construction, FyA is utilized for air pollutant removal and serves as an adsorbent for various contaminants. It also plays a role in creating geopolymers and nanocomposites, promoting the development of eco-friendly construction materials. This review article presents current data on thermal power plants (ThPPs) in India, the challenges in FyA management, and its environmental impact. It also discusses relevant Indian policies and highlights ongoing research aimed at improving the efficiency and expanding the applications of FyA in various industrial sectors, such as battery manufacturing, zeolite synthesis, and cenosphere extraction. These efforts underscore FyA's potential in supporting sustainable practices. The findings of this review address critical issues related to FyA. By reducing the environmental footprint of cement manufacturing, removing air pollutants, and acting as an adsorbent for various contaminants, FyA demonstrates significant potential in pollution mitigation. It also contributes to the development of eco-friendly construction materials and promotes sustainability in the construction sector. Effective management practices are essential to minimize FyA's negative impact on human health and the environment. The article emphasizes the need for greater awareness and implementation of policies to address these issues comprehensively. By providing a detailed understanding of the benefits and challenges associated with FyA, it aims to pave the way for more effective and sustainable utilization of this industrial byproduct.</p>\u0000 </div>","PeriodicalId":35327,"journal":{"name":"Environmental Quality Management","volume":"34 2","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zwitterion Modification in Desalination Membrane for Rejecting Salt and Salt Ions in Brackish Water – A Mini Review 海水淡化膜中用于排斥咸水中的盐和盐离子的齐聚物改性--微型综述
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-23 DOI: 10.1002/tqem.22332
Anisa Ratnasari, Bieby Voijant Tangahu, Adhi Yuniarto, Agus Slamet, Eddy Setiadi Soedjono, Samrendra Singh Thakur

Desalination membrane using zwitterion modification provides a significant opportunity to enhance excellent properties for rejecting salt and salt ions. The outstanding properties are designed by positive and negative charges attached to the membrane surface, including water permeability, salt permeability, fouling, and hydrophilicity of the membrane surface. The hydrophilic membrane, which is mentioned as one of the types of desalination membrane, presents the ability to repel salt and salt ions and pass the water. The modification of hydrophilic membranes is also affected by several factors, including water permeability, salt permeability, fouling of membrane surfaces, crossflow velocity, transmembrane pressure, and temperature. Regarding membrane modification, zwitterion has been applied for several ranges, such as the hemodialysis process, live cell imaging, antibacterial surfaces, and wound dressing. However, using a zwitterion modification membrane for desalinating water containing salt content, including brackish water, has yet to be developed. In addition, literature reviews related to polymer membranes for brackish water desalination have never been comprehensively documented. Thus, this review article addresses the zwitterion modification for desalination membranes, which can reject salt and salt ions in brackish water. Furthermore, the mechanism of zwitterion modification for desalination membranes has been presented. Finally, the challenge of zwitterion modification for desalination membranes has been evaluated to inspire insight for future studies.

使用齐聚物改性的海水淡化膜为提高排斥盐和盐离子的优异性能提供了重要机会。卓越的性能是由附着在膜表面的正负电荷设计的,包括膜表面的透水性、透盐性、结垢性和亲水性。亲水膜是海水淡化膜的一种,具有排斥盐和盐离子并使水通过的能力。亲水膜的改性也受多种因素的影响,包括透水性、透盐性、膜表面污垢、横流速度、跨膜压力和温度。在膜改性方面,齐聚物已被应用于多个领域,如血液透析过程、活细胞成像、抗菌表面和伤口敷料。然而,使用齐聚物改性膜来淡化含盐水质(包括苦咸水)的技术尚待开发。此外,有关用于苦咸水脱盐的聚合物膜的文献综述也从未有过全面的记录。因此,这篇综述文章探讨了用于海水淡化膜的齐聚物改性,这种膜可以剔除苦咸水中的盐和盐离子。此外,文章还介绍了用于海水淡化膜的齐聚物改性机理。最后,对用于海水淡化膜的齐聚物改性所面临的挑战进行了评估,以期为今后的研究提供启示。
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引用次数: 0
A Review of the Technological Aspects and Process Optimization of Bioethanol Production From Corn Stover Biomass: Pretreatment Process, Hydrolysis, Fermentation, Purification Process, and Future Perspective 利用玉米秸秆生物质生产生物乙醇的技术和工艺优化综述:预处理工艺、水解、发酵、纯化工艺和未来展望
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-23 DOI: 10.1002/tqem.22336
Hamzah Fansuri, Umi Purwandari, Sugili Putra, Arief Adhiksana, Irvan Dwi Junianto, Rama Oktavian, Joan Cordiner

Bioethanol, a sustainable energy solution derived from renewable biomass, has gained prominence, with corn stover emerging as a substantial biomass resource in Indonesia. Corn stover, a corn residue, is one of the top three agricultural wastes worldwide and is abundantly available. However, a significant portion of corn stover is burned in fields rather than utilized for bioethanol production, whereas it has potential as a bioethanol feedstock. As the world strives to realize sustainable and environmentally friendly energy security, bioethanol production from corn stover can be one of the solutions to be developed. Nonetheless, the current immaturity of bioethanol production technology is one of the causes of large-scale production failure. The present paper comprehensively reviews the technological aspects and process optimization of bioethanol production using corn stover as a feedstock comprising pretreatment, hydrolysis, fermentation, and bioethanol purification processes. According to our critical review, ammonia fiber expansion (AFEX) pretreatment is the most effective conventional pretreatment, with glucose yield up to 90%. Moreover, ultrasound appears to be the most viable option for nonconventional pretreatment of corn stover for producing bioethanol. However, combining ultrasound pretreatment and dilute aqueous ammonia produced 80.6% sugar output. Furthermore, enzymatic hydrolysis emerges as the most effective saccharification, yielding up to 81.39%. Moreover, the fermentation process of corn stover with the saccharification and co-fermentation (SScF) method and the process optimization with response surface methodology (RSM) could produce bioethanol with a concentration of up to 59.8 g/L and 92.07% ethanol yield, respectively. This review also reveals that pervaporation for the purification process is the best choice for producing bioethanol with high purity up to > 99%. In addition, this method could reduce the energy used by 6.6% lower, 24.2% lower carbon footprint, and have the lowest total capital and production costs compared to conventional molecular sieves and extractive distillation. We believe this review article can provide a reference for selecting the best bioethanol production process from corn stover for further research.

生物乙醇是一种从可再生生物质中提取的可持续能源解决方案,在印尼,玉米秸秆已成为一种重要的生物质资源。玉米秸秆是一种玉米残渣,是全球三大农业废弃物之一,资源丰富。然而,很大一部分玉米秸秆被烧毁,而不是用于生物乙醇生产,而玉米秸秆作为生物乙醇原料却具有潜力。在全球努力实现可持续和环保型能源安全的过程中,利用玉米秸秆生产生物乙醇可能是有待开发的解决方案之一。然而,目前生物乙醇生产技术的不成熟是导致大规模生产失败的原因之一。本文全面综述了以玉米秸秆为原料生产生物乙醇的技术问题和工艺优化,包括预处理、水解、发酵和生物乙醇纯化过程。根据我们的严格审查,氨化纤维膨胀(AFEX)预处理是最有效的常规预处理,葡萄糖产量可达 90%。此外,超声波似乎是对玉米秸秆进行非常规预处理以生产生物乙醇的最可行方案。然而,将超声波预处理和稀氨水结合使用,糖产量可达 80.6%。此外,酶水解是最有效的糖化方法,产糖率高达 81.39%。此外,玉米秸秆的发酵工艺采用糖化和共发酵(SScF)方法,并利用响应面方法(RSM)进行工艺优化,可生产出浓度高达 59.8 克/升的生物乙醇和 92.07% 的乙醇产量。本综述还揭示,要生产纯度高达 99% 的生物乙醇,蒸发提纯工艺是最佳选择。此外,与传统的分子筛和萃取蒸馏法相比,该方法的能耗降低了 6.6%,碳足迹降低了 24.2%,总投资和生产成本最低。我们相信这篇综述文章能为进一步研究选择最佳的玉米秸秆生物乙醇生产工艺提供参考。
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引用次数: 0
Kinetics and Mechanism Study of Different Types of Surface-Imprinted Polymers for CO2 Adsorption 不同类型表面印迹聚合物吸附二氧化碳的动力学和机理研究
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-23 DOI: 10.1002/tqem.22334
Noorhidayah Ishak, Azalina Mohamed Nasir, Muthmirah Ibrahim, Mohd Azmier Ahmad, Bassim H. Hameed, Azam Taufik Mohd Din

The increased level of CO2 in the atmosphere has led to global warming and climate change. To mitigate these problems, solid adsorbents have become attractive materials for capturing excess CO2 in the post-combustion method. Molecularly imprinted polymer (MIP) can be applied to prepare highly selective adsorbents that could capture CO2 molecules. The MIP was prepared using the surface imprinted polymer technique in this preliminary work. Only two types of support materials were used (graphite and silica gel) to screen the best support material that could enhance the CO2 adsorption capacity of the resulting adsorbent, which was analyzed using a fixed-bed column reactor. Graphite-imprinted polymer (GMIP) was found to be a good potential for CO2 adsorption. The Avrami model best described the adsorption system, while the fixed-bed curve data fit the Yoon–Nelson model well. The semi-empirical method was used to assess the interaction mechanism of the molecularly imprinted polymer with CO2 during adsorption. This investigation involved testing four different ratios of the template complex to functional monomers. The ratio of 1:4 (CO2:Allylthiourea) demonstrated the highest binding energy, with a higher formation of hydrogen bonds. Film diffusion and intraparticle diffusion were the main rate-limiting steps that played vital roles at different stages of CO2 adsorption. This preliminary work has enhanced the development of MIP for CO2 adsorption and showcased the integration of computational approaches in tailoring specific MIPs.

大气中二氧化碳含量的增加导致了全球变暖和气候变化。为了缓解这些问题,固体吸附剂已成为在燃烧后方法中捕获过量二氧化碳的极具吸引力的材料。分子印迹聚合物(MIP)可用于制备能捕获二氧化碳分子的高选择性吸附剂。在这项初步工作中,MIP 是利用表面印迹聚合物技术制备的。只使用了两种类型的支撑材料(石墨和硅胶),以筛选出能提高所得吸附剂二氧化碳吸附能力的最佳支撑材料,并使用固定床柱式反应器对其进行了分析。结果发现,石墨压印聚合物(GMIP)具有良好的二氧化碳吸附潜力。Avrami 模型对吸附系统进行了最佳描述,而固定床曲线数据则与 Yoon-Nelson 模型十分吻合。半经验法用于评估分子印迹聚合物在吸附过程中与 CO2 的相互作用机理。这项研究包括测试模板复合物与功能单体的四种不同比例。1:4 的比例(二氧化碳:烯丙基硫脲)显示出最高的结合能,形成的氢键也更多。薄膜扩散和颗粒内扩散是主要的限速步骤,在二氧化碳吸附的不同阶段发挥了重要作用。这项初步工作促进了用于二氧化碳吸附的 MIP 的开发,并展示了在定制特定 MIP 时计算方法的整合。
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引用次数: 0
Fly Ash Amendments Reduced Heavy Metal Availability and Uptake in Leafy Vegetables Grown in Agricultural Soils From Selibe Phikwe, Botswana 粉煤灰添加剂降低了博茨瓦纳塞利贝-菲克韦农业土壤中种植的叶菜对重金属的利用率和吸收率
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-17 DOI: 10.1002/tqem.22331
Venecio U. Ultra Jr., Sekgele Bobby Taupedi, Koziba Gaothobogwe, Trust Manyiwa, Katumelo Gajaje

Poor waste management of mining operations in Selibe Phikwe, Botswana, has resulted in elevated levels of heavy metals (HM) in farmlands and crops near the mining regions, contaminating the food chain and posing a health risk. To mitigate HM contamination in food crops grown in this area, different soil amendments were evaluated for their potential to reduce heavy metal uptake and accumulation in harvested crops. A two-factor complete randomized design was used to conduct a pot experiment in which varied rates of fly ash (FA) were applied to HM-contaminated soil in combination with compost and/or NPK inorganic fertilizers. On this setup, two successive cropping of rape and spinach crops were established. Changes in soil chemical characteristics and heavy metal availability, as well as yield and heavy metal content of harvested plants, were monitored. Our findings showed that the addition of FA from 5% to 15% (w/w) had significantly improved the yield, and reduced the concentration of arsenic (As), chromium (Cr), copper (Cu), nickel (Ni), manganese (Mn), and lead (Pb) in shoots for both spinach and rape. Additional application of compost and/or inorganic fertilizer further improved the yield but the optimum yield was obtained through the combination of 10% FA + compost for both spinach and rape. The highest reduction of As, Cr, Cu, Ni, Pb, and Mn in the shoots of spinach and rape was obtained in soils amended with 10% FA + compost + NPK fertilizer. Improvement of growth due to different amendments could be attributed to their ability to modify soil chemical properties, reduce available heavy metals in soils, and provide essential nutrients for plants. Optimum results based on growth and heavy metal mitigation can be attained by the application of 10% FA and the addition of compost + NPK fertilizer for both spinach and rape. Further verification and efficacy tests under field conditions are recommended.

博茨瓦纳 Selibe Phikwe 采矿作业的废物管理不善,导致采矿区附近农田和农作物中的重金属 (HM) 含量升高,污染了食物链并对健康构成威胁。为了减轻该地区种植的粮食作物中的重金属污染,对不同土壤改良剂减少收获作物中重金属吸收和积累的潜力进行了评估。我们采用双因素完全随机设计法进行了一项盆栽实验,将不同比例的粉煤灰(FA)与堆肥和/或氮磷钾无机肥一起施用到受 HM 污染的土壤中。在此试验中,连续种植了油菜和菠菜。对土壤化学特征和重金属可用性的变化,以及收获植物的产量和重金属含量进行了监测。研究结果表明,添加 5%至 15%(重量比)的 FA 能显著提高产量,并降低菠菜和油菜嫩芽中砷(As)、铬(Cr)、铜(Cu)、镍(Ni)、锰(Mn)和铅(Pb)的浓度。额外施用堆肥和/或无机肥料进一步提高了产量,但菠菜和油菜的最佳产量是通过 10% FA + 堆肥的组合获得的。在施用 10% FA + 堆肥 + 氮磷钾肥的土壤中,菠菜和油菜嫩芽中的砷、铬、铜、镍、铅和锰的降幅最大。不同的改良剂能改善土壤的化学性质,减少土壤中的重金属含量,并为植物提供必需的养分,因此能改善植物的生长。对菠菜和油菜施用 10%的 FA 并添加堆肥和氮磷钾化肥,可获得最佳的生长和重金属缓解效果。建议在田间条件下进行进一步的验证和功效测试。
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引用次数: 0
Opportunities of the Bioeconomy in Mexico: Valorization of Agro-Industrial Waste 墨西哥生物经济的机遇:农工废弃物的价值评估
IF 1.5 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-17 DOI: 10.1002/tqem.22326
Christian Iván Cano-Gómez, Jessica Ivonne Hinojosa-López, Diana B. Muñiz-Marquez, Jorge E. Wong-Paz

The transition toward a sustainable bioeconomy offers a pivotal opportunity for Mexico to mitigate environmental impacts and drive economic growth through the valorization of agro-industrial waste. This review highlights the challenges and opportunities of establishing a waste-based bioeconomy in Mexico, emphasizing the role of advanced technologies and infrastructure in transforming agricultural waste into valuable bioproducts like biofuels, bioplastics, and biochemicals. The paper underscores the necessity for robust policy frameworks and collaborative efforts to address technological, infrastructural, and regulatory barriers. It provides a comparative analysis of circular business models and waste valorization strategies successfully implemented in countries such as Brazil, Chile, and the Mediterranean region, drawing practical insights applicable to Mexico. This review uniquely combines technological, policy, and business model innovations to offer a comprehensive approach to the sustainable development of Mexico's bioeconomy. By navigating these complexities, Mexico can unlock significant economic, environmental, and social benefits, contributing to a more sustainable and prosperous future.

向可持续生物经济的转型为墨西哥提供了一个关键机会,通过农用工业废物的价值化来减轻对环境的影响并推动经济增长。本综述强调了在墨西哥建立以废物为基础的生物经济所面临的挑战和机遇,强调了先进技术和基础设施在将农业废物转化为生物燃料、生物塑料和生物化学品等有价值的生物产品方面所发挥的作用。该文件强调,必须制定强有力的政策框架并开展合作,以解决技术、基础设施和监管方面的障碍。本文对巴西、智利和地中海地区等国家成功实施的循环商业模式和废物价值化战略进行了比较分析,得出了适用于墨西哥的实用见解。本综述将技术、政策和商业模式创新独特地结合在一起,为墨西哥生物经济的可持续发展提供了一种全面的方法。通过驾驭这些复杂问题,墨西哥可以释放出巨大的经济、环境和社会效益,为更加可持续和繁荣的未来做出贡献。
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引用次数: 0
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Environmental Quality Management
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