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Color Modification of Spinel by Nickel Diffusion: A New Treatment 镍扩散法处理尖晶石的新方法
Pub Date : 2023-08-01 DOI: 10.5741/gems.59.2.164
M. Jollands, A. Ludlam, Aaron C. Palke, W. Vertriest, Shiyun Jin, Pamela Cevallos, Sarah Arden, Elina Myagkaya, Ulrika D’Haenens-Johannson, Vararut Weeramongkhonlert, Ziyin Sun
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引用次数: 0
Morphology of Colombian Emerald: Some Less-Common Cases and Their Growth and Dissolution History 哥伦比亚祖母绿的形态:一些不常见的案例及其生长和溶解史
Pub Date : 2023-05-01 DOI: 10.5741/gems.59.1.46
K. Schmetzer, G. Martayan
GEMS & GEMOLOGY SPRING 2023 In general, the morphology of Colombian emerald originating from different mines is rather simple and formed by a small number of external crystal faces. We observe two dominant planes, the basal pinacoid and the first-order hexagonal prism, occasionally in combination with small second-order hexagonal prism faces and firstand/or second-order hexagonal dipyramids (Goldschmidt, 1913; Schwarz and Giuliani, 2002; Moore and Wilson, 2016). The internal growth pattern of such samples, which normally show prismatic habit, consists of growth planes parallel to the external crystal faces (Kiefert and Schmetzer, 1991). Occasionally, natural emerald and beryl crystals show etching and dissolution features (an overview of the pertinent literature is given in box A). Other growth features are due to skeletal and polygonal growth of beryl crystals (see box B). Both growth features are related to the observations made in this article for Colombian emerald crystals. Rarely mentioned are emerald crystals with conical habit (Johnson, 1961a,b)—or vasos in the form of slightly conical empty tubes (Klein, 1941)—or emeralds in the form of prismatic, empty “cups” with planar bottoms (Weldon et al., 2016). In most references,
总的来说,来自不同矿山的哥伦比亚祖母绿的形态相当简单,由少量的外部晶面组成。我们观察到两个优势面,基底松状面和一阶六边形棱柱,偶尔与小的二阶六边形棱柱面和一阶/或二阶六边形双棱柱面结合在一起(Goldschmidt, 1913;施瓦茨和朱利安尼,2002;Moore and Wilson, 2016)。这类样品的内部生长模式通常表现为棱柱形习惯,由与外部晶面平行的生长面组成(Kiefert和Schmetzer, 1991)。偶尔,天然祖母绿和绿柱石晶体表现出蚀刻和溶解特征(相关文献概述见方框A)。其他生长特征是由于绿柱石晶体的骨骼和多边形生长(见方框B)。这两种生长特征都与本文中对哥伦比亚祖母绿晶体的观察有关。很少被提及的是具有圆锥形习惯的祖母绿晶体(Johnson, 1961a,b)——或略呈圆锥形的空管形式的维管(Klein, 1941)——或具有平面底部的棱柱形空“杯”形式的祖母绿(Weldon et al., 2016)。在大多数参考文献中,
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引用次数: 0
Gemological Characterization of Montana Sapphire from the Secondary Deposits at Rock Creek, Missouri River, and Dry Cottonwood Creek 岩石溪、密苏里河和干棉木溪次生矿床蒙大拿蓝宝石的宝石学特征
Pub Date : 2023-05-01 DOI: 10.5741/gems.59.1.2
Aaron C. Palke, Nathan D. Renfro, J. R. Hapeman, R. Berg
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引用次数: 0
Methods and Challenges of Establishing the Geographic Origin of Diamonds 确定钻石地理来源的方法与挑战
Pub Date : 2022-11-01 DOI: 10.5741/gems.58.3.270
Evan M. Smith, K. Smit, S. Shirey
GEMS & GEMOLOGY FALL 2022 Some famous diamonds, such as the Hope, the Cullinan, and the 404.2 ct “4 de Fevereiro” diamond in figure 1, have high-profile histories that include their geographic provenance. Other diamonds with a known origin can occasionally be sourced in the marketplace or directly from miners. But for the majority of diamonds, this information is not preserved, instead becoming obscured as they move through the supply chain. To some extent, diamond provenance has not been seen as a valuable piece of information and is not presented as a relevant pricing factor the way it sometimes is for some other gemstones. Rough diamonds are typically bought and sold in lots or parcels based on physical characteristics, including color, clarity, size, and morphology. In assembling these parcels, it is common practice to mix diamonds of similar character from different mines. Faceted diamonds are sold mainly on the basis of the 4Cs (color, cut, clarity, and carat weight) and may be mixed further. Beyond the historical or scientific interest in provenance, several recent developments have put dia mond origin at the forefront of conversations in the industry and among consumers. Initially, this was driven by a need to track conflict diamonds and prevent their entrance into the trade. Now, with mountMETHODS AND CHALLENGES OF ESTABLISHING THE GEOGRAPHIC ORIGIN OF DIAMONDS
一些著名的钻石,如图1中的“希望”、“库里南”和404.2克拉的“4 de Fevereiro”钻石,有着引人注目的历史,包括它们的地理来源。其他来源已知的钻石偶尔可以在市场上或直接从矿工那里获得。但对于大多数钻石来说,这些信息并没有被保存下来,而是在它们通过供应链的过程中变得模糊不清。在某种程度上,钻石的来源并没有被视为一种有价值的信息,也没有像其他宝石那样被视为一个相关的定价因素。未经加工的钻石通常是根据其物理特性(包括颜色、净度、大小和形态)成批或包裹买卖的。在组装这些包裹时,通常的做法是将来自不同矿山的相似性质的钻石混合在一起。多面钻石的销售主要基于4c(颜色、切割、净度和克拉重量),也可能进一步混合。除了历史或科学对钻石来源的兴趣之外,最近的一些进展也使钻石的来源成为业内和消费者讨论的焦点。最初,这是由于需要追踪冲突钻石并防止它们进入贸易。现在,通过各种方法和挑战来确定钻石的地理来源
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引用次数: 0
Sapphire Beneath the Rich Black Soil of Muling, Northeastern China 中国东北穆陵富饶黑土下的蓝宝石
Pub Date : 2022-11-01 DOI: 10.5741/gems.58.3.290
Yimiao Liu, Ren Lu
The rich black soil of Muling in northeastern China yields not only abundant crops but also glittering gem corundum. In this study, gemological quality and characteristics and provenance-related features of sapphire from Muling are first reported with comprehensive analytical results. Muling sapphire exhibits a wide spectrum of hue and saturation. Mineral inclusions (e.g., rutile, zircon, anorthite, and pyrope) as well as other distinctive internal features (e.g., polysynthetic twinning accompanied by intersecting tubes, iridescent hexagonal thin films, and angular color zoning) are identified by microscopic observation and Raman spectroscopy. Spectral features and trace element chemistry of the various colors of gem-quality Muling sapphire are analyzed by ultraviolet/visible/near-infrared spectroscopy and laser ablation–inductively coupled plasma–mass spectrometry. To assess the characteristics of Muling sapphire against well-known corundum sources worldwide, inclusion analysis and trace element discrimination diagrams are utilized. Analytical results indicate that Muling sapphire originated from a more diverse geological environment than typical magmatic or metamorphic origin. The Muling deposit shows great potential to produce fine gem-quality sapphire material.
中国东北牧陵肥沃的黑土地不仅出产丰富的农作物,而且出产闪闪发光的宝石刚玉。本文首次报道了木陵蓝宝石的宝石质量特征和物源相关特征,并进行了综合分析。穆陵蓝宝石具有广泛的色相和饱和度。矿物包裹体(如金红石、锆石、钙长石和欧长石)以及其他独特的内部特征(如聚合成孪晶伴随着相交管、彩虹六角形薄膜和角色带)通过显微观察和拉曼光谱识别出来。采用紫外/可见/近红外光谱和激光烧蚀-电感耦合等离子体质谱分析了不同颜色的宝石级穆陵蓝宝石的光谱特征和微量元素化学性质。利用内含物分析和微量元素鉴别图,对比世界上知名的棕刚玉产地,对穆陵蓝宝石的特征进行了评价。分析结果表明,与典型的岩浆或变质成因相比,木岭蓝宝石的成因地质环境更为多样化。木岭矿床具有生产优质宝石级蓝宝石材料的巨大潜力。
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引用次数: 0
Color Mechanism and Spectroscopic Thermal Variation of Pink Spinel Reportedly from Kuh-i-Lal, Tajikistan 塔吉克斯坦Kuh-i-Lal粉红色尖晶石的显色机理和光谱热变化
Pub Date : 2022-11-01 DOI: 10.5741/gems.58.3.338
Yicen Liu, Li-jian Qi, D. Schwarz, Zhengyu Zhou
The color mechanism of pink spinel from Kuh-i-Lal in the Pamir Mountains of Tajikistan was studied using photo luminescence, mid-infrared, and ultraviolet/visible spectroscopy. This included studying the variations in spectra after heating to a series of temperatures ranging from 300° to 1000°C. Laser ablation–inductively coupled plasma–mass spectrometry was used to measure the trace elements present. The results reveal that the color is caused by the combined effect of spin-allowed transitions of Cr 3+ , Fe 3+ , V 3+ , and Fe 2+ -Fe 3+ intervalence charge transfer mechanisms. The photoluminescence spectra show that during heat treatment, the intensity of the N 1 peak (687 nm) and the full width half maximum of the R-line and N-lines increase with temperature. Following heating in the range of 750°–825°C, there is a linear relationship between temperature and the ratio of integral areas of the R-line and N-lines. The mid-infrared spectra indicate that the band at 581 cm –1 ( ν 3 ) gradually disappears during the heating process, which is likely related to the variation of octahedral M-O and tetrahedral T-O bond length in the spinel lattice.
采用光致发光、中红外、紫外/可见光谱等方法研究了塔吉克斯坦帕米尔高原Kuh-i-Lal地区粉色尖晶石的显色机理。这包括研究加热到从300°C到1000°C一系列温度后光谱的变化。采用激光烧蚀-电感耦合等离子体质谱法测定了样品中的微量元素。结果表明,这种颜色是由cr3 +、fe3 +、v3 +和fe2 + - fe3 +间价电荷转移机制的自旋允许跃迁共同作用的结果。光致发光光谱表明,在热处理过程中,N 1峰(687 nm)的强度以及r线和N线的全宽半最大值随温度的升高而增大。在750°-825°C范围内加热后,温度与r线和n线的积分面积之比之间存在线性关系。中红外光谱显示,在加热过程中,581 cm -1 (ν 3)处的波段逐渐消失,这可能与尖晶石晶格中八面体M-O和四面体T-O键长变化有关。
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引用次数: 0
Gems on Canvas: Pigments Historically Sourced from Gem Materials 画布上的宝石:历史上来自宝石材料的颜料
Pub Date : 2022-11-01 DOI: 10.5741/gems.58.3.318
Britni LeCroy
GEMS & GEMOLOGY FALL 2022 The wearing and collecting of gems mark their bearers with powerful symbols of status and allure. Because of their high value, gems are researched with nondestructive methods to feed growing public interest in areas such as geographic origin, synthesis, and treatment. For a gemologist, causing damage to a stone is a cardinal sin. For a painter in the past, gem materials were coveted for their pigment potential. For centuries, perfectly viable gemstones met their fate between a mortar and pestle before becoming immortalized as paint on a canvas, mural, or cave wall. These pigments commemorated color as a means of communication beyond the limits of written or spoken language. Gem materials such as hematite, azurite, malachite, lapis lazuli, bone, ivory, and cinnabar have all played roles as pigments throughout history—for some, a role assumed long before their use as gem materials (figure 1). Pigment research is an important field encompassing geologists, artists, anthropologists, historians, and even gemologists who contribute their knowledge and expertise to a subject where these disciplines converge. Pigment can be defined as the component of paint that contributes color (Siddall, 2018). Natural inorganic pigments are derived from rocks or minerals that have been processed to extract and concentrate the material’s coloring agent (figure 2). Synthetic pigments are often chemically identical to their natural coun-
佩戴和收藏宝石是佩戴者地位和魅力的强大象征。由于宝石的高价值,人们采用非破坏性的方法对其进行研究,以满足公众对地理来源、合成和处理等领域日益增长的兴趣。对宝石学家来说,损坏宝石是大罪。对于过去的画家来说,宝石材料因其颜料潜力而令人垂涎。几个世纪以来,完美的宝石在成为画布、壁画或洞穴墙壁上的颜料之前,在臼和杵之间遭遇了它们的命运。这些颜料将颜色作为一种超越书面或口头语言限制的交流手段来纪念。诸如赤铁矿、蓝铜矿、孔雀石、青金石、骨头、象牙和朱砂等宝石材料在历史上都扮演过颜料的角色——对一些人来说,在它们被用作宝石材料之前很久就扮演了这个角色(图1)。颜料研究是一个重要的领域,涵盖了地质学家、艺术家、人类学家、历史学家,甚至宝石学家,他们将自己的知识和专业知识贡献给了这些学科的融合。颜料可以被定义为颜料中贡献颜色的成分(Siddall, 2018)。天然无机颜料来源于岩石或矿物,经过加工提取和浓缩材料的着色剂(图2)。合成颜料在化学上通常与其天然原色相同
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引用次数: 0
A Gemological and Spectroscopic Study with Mobile Instruments of “Emeralds” from the Coronation Crown of Napoleon III 用移动仪器对拿破仑三世加冕王冠上的“祖母绿”进行宝石学和光谱研究
Pub Date : 2022-08-15 DOI: 10.5741/gems.58.2.168
S. Karampelas, E. Gaillou, Annabelle Herreweghe, Farida Maouche, Ugo Hennebois, Sophie Leblan, Bérengère Meslin Sainte Beuve, M. Lechartier, D. Nectoux, A. Delaunay
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引用次数: 0
Characteristics of Newly Discovered Amber from Phu Quoc, Vietnam 越南富国新发现琥珀的特征
Pub Date : 2022-08-15 DOI: 10.5741/gems.58.2.184
Le Ngoc Nang, P. T. Hieu, Lam Vinh Phat, P. M. Tien, Ho Nguyen Tri Man, Ha Thuy Hang
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引用次数: 0
Natural Radioactivity in Select Serpentinite-Related Nephrite Samples: A Comparison with Dolomite-Related Nephrite 蛇纹石相关软玉样品中的天然放射性:与白云石相关软玉的比较
Pub Date : 2022-08-15 DOI: 10.5741/gems.58.2.196
D. Malczewski, M. Sachanbiński, M. Dziurowicz
1. these deposits The published literature offers only a few records of direct measurement of the natural radioactivity in nephrite. The present study used high-purity germanium (HPGe) low-background gamma-ray spectrometry to measure activity concentrations of primordial radionuclides in 11 serpentinite-related nephrite (ortho-nephrite) samples from deposits in Poland, Russia, Canada, and New Zealand, along with three samples of rodingite and serpentinite from a nephrite deposit in Nasławice, Poland. All nephrite samples exhibited very low 40 K, 232 Th, and 238 U activity concentrations that fell within the range of published values for ultrabasic and basic rocks. The nephrite samples from Jordanów (Poland) gave the highest uranium and thorium activity concentration values. Two samples of plagiogranitic rodingite showed significantly higher 238 U and 232 Th activity concentrations than the values measured for nephrite. Nephrite thorium and uranium concentrations correlated strongly (r = 0.98), and the corresponding Th/U ratios appear unique according to geographical location. The mean estimated potassium, thorium, and uranium concentrations from ortho-nephrite analyzed here were compared with corresponding mean values previously reported for dolomite-related nephrite (para-nephrite). The comparison indicates that the ortho-nephrites studied have similar uranium concentrations but lower mean potassium concentrations and higher mean thorium concentrations than those reported for para-nephrite in the literature.
1. 已发表的文献只提供了少量直接测量软玉天然放射性的记录。本研究使用高纯度锗(HPGe)低背景伽马射线能谱法测量了来自波兰、俄罗斯、加拿大和新西兰的11个与蛇纹岩相关的软玉(正软玉)样品中的原始放射性核素的活性浓度,以及来自波兰Nasławice软玉矿床的3个菱辉石和蛇纹岩样品。所有软玉样品均表现出极低的40 K、232 Th和238 U活性浓度,这些活性浓度落在超基性和基性岩石的公布值范围内。来自Jordanów(波兰)的软玉样品给出了最高的铀和钍活性浓度值。两种斜花岗质岩样品的238 U和232 Th活性浓度明显高于软玉样品。软玉钍和铀浓度相关性强(r = 0.98),相应的Th/U比值因地理位置不同而不同。本文分析的正软玉中钾、钍和铀的平均估计浓度与先前报道的白云石相关软玉(副软玉)的相应平均值进行了比较。比较表明,与文献报道的副软玉相比,所研究的正软玉具有相似的铀浓度,但平均钾浓度较低,平均钍浓度较高。
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引用次数: 0
期刊
Gems & Gemology
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