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[Characteristics and Source Apportionment of Atmospheric Volatile Organic Compounds in Zhengzhou During O3 Campaign Period]. [O3 活动期间郑州大气挥发性有机化合物的特征和来源分配]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202310136
Si Chen, Jing-Wei Ni, Yi-Jin Qi, Tian-Tian Ji, Ling-Ling Wang, Xiao-Na Shan, Shan-Ling Gong
<p><p>An online gas chromatograph (GC5000) was used to monitor the volatile organic compounds (VOCs) in the atmospheric environment of Zhengzhou City during the ozone campaign period from May to September of 2022. The relationship between O<sub>3</sub> and its precursors as well as meteorology was analyzed and the pollution characteristics of VOCs during the O<sub>3</sub> exceeding and non-exceeding the standard days were compared and explored. Different VOC activity evaluation methods of OFP and <i>L</i><sub>·OH</sub> were utilized to compare and analyze the key active components and species and the ratio analysis (RA) and positive matrix factorization (PMF) analysis models were used to study the apportionment contribution of VOCs. The results showed that the O<sub>3</sub> pollution in June and September in Zhengzhou was mainly due to the adverse meteorological conditions of high temperature and low humidity, strong radiation, and low wind speed, superimposed by the prominent concentrations of local VOCs and NO<sub>2</sub>, resulting in frequently high and excessive O<sub>3</sub> occurrences. The VOCs concentration in Zhengzhou during the campaign period was an average of (68.3 ± 18.4) μg·m<sup>-3</sup>, whereas it was 75.7 μg·m<sup>-3</sup> during O<sub>3</sub> exceeding standard days and 13.4 μg·m<sup>-3</sup> during O<sub>3</sub> non-exceeding days, respectively. Among the VOC species, the OVOCs was 31.6%, accounting for the highest mass fraction, followed by halogenated hydrocarbon, alkane, and aromatic hydrocarbon, and the major species were ethane, <i>n</i>-butane, dichloromethane, propane, isopentane, toluene, chloromethane, 1,2-dichloroethane, and acetylene. VOC diurnal variation indicated that the emission of VOC pollution sources in the morning, evening peak, and at night should be paid more attention. The contribution of VOCs to OFP during the campaign period was (130.5 ± 46.4) μg·m<sup>-3</sup>, and the <i>L</i><sub>·OH</sub> was (6.5 ± 2.9) s<sup>-1</sup>, among which the top 15 species with high activity were primarily acetaldehyde, isoprene, ethylene, <i>m/p</i>-xylene, toluene, hexal, isopentane, propanal, propylene, trans-2-butene, <i>etc</i>. In particular, the contributions of acetaldehyde, isoprene, ethylene, and hexal species were prominent during the O<sub>3</sub> exceeding days. Ratio analysis showed that the B/T ratio in Zhengzhou from May to September ranged from 0.05 to 5.3, with an average value of 1.1 ± 0.6, and the regional VOCs was mainly controlled by the aging air mass with possible long-distance transports. The analysis of the PMF model showed that the major pollution sources to VOC concentration in Zhengzhou were motor vehicle exhaust emission sources and industrial solvent and secondary conversion sources, contributing 25.6% and 25.8%, respectively. The contribution rates of solvent coating sources, oil and gas volatile sources, plant emission sources, industrial solvents, and secondary conversion sources durin
使用在线气相色谱仪(GC5000)监测挥发性有机化合物(VOCs用于监测 2022 年 5 月至 9 月臭氧行动期间郑州市大气环境中的挥发性有机物(VOCs)。在2022年5月至9月臭氧行动期间,对郑州市大气环境中的挥发性有机物(VOCs)进行了监测。分析了 O3 与其前体物以及气象之间的关系,比较并探讨了 O3 超标日和非超标日 VOCs 的污染特征。利用OFP和L-OH不同的挥发性有机物活性评价方法对主要活性组分和物种进行了比较和分析,并利用比值分析法(RA)和正矩阵因式分解(PMF)分析模型来研究挥发性有机化合物的比例贡献。结果表明,郑州 6 月和 9 月的 O3 污染主要是由于高温低湿、强辐射、低风速等不利气象条件,叠加本地 VOCs 和 NO2 浓度突出,导致 O3 频繁偏高和超标。活动期间,郑州的 VOCs 浓度平均为(68.3±18.4)μg-m-3,而 O3 超标日为 75.7 μg-m-3,非超标日为 13.4 μg-m-3。在 VOC 种类中,OVOCs 占 31.6%,质量分数最高,其次是卤代烃、烷烃和芳香烃,主要种类有乙烷、正丁烷、二氯甲烷、丙烷、异戊烷、甲苯、氯甲烷、1,2-二氯乙烷和乙炔。VOC 的昼夜变化表明,应更多地关注早、晚高峰和夜间 VOC 污染源的排放情况。活动期间,VOCs 对 OFP 的贡献率为(130.5 ± 46.4)。μg-m-3,L-OH 为(6.5 ± 2.9)s-1,其中活性最高的 15 个物种主要是乙醛、异戊二烯、乙烯、间/对二甲苯、甲苯、己醛、异戊烷、丙醛、丙烯、反式-2-丁烯等。其中,乙醛、异戊二烯、乙烯和己醛的贡献在 O3 超标日尤为突出。比值分析表明,郑州 5-9 月的 B/T 比值在 0.05 至 5.3 之间,平均值为 1.1 ± 0.6,区域 VOCs 主要受老化气团控制,可能存在长距离输送。PMF 模型分析表明,郑州市 VOC 浓度的主要污染源为机动车尾气排放源和工业溶剂及二次转化源,贡献率分别为 25.6% 和 25.8%。在 O3 超标日,溶剂涂装源、油气挥发源、工厂排放源、工业溶剂和二次转化源的贡献率分别比 O3 非超标日高 5.4%、4.7%、3.3% 和 0.7%。研究表明,应加强对挥发性有机物和氮氧化物污染源的管理,以减少它们在 O3 超标时对 O3 生成的贡献。
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引用次数: 0
[Characteristics of Soil Respiration and Organic Carbon Mineralization in Dryland Potato Fields Under Different Ridge-furrow Mulching Patterns]. [不同垄沟覆盖模式下旱地马铃薯田土壤呼吸和有机碳矿化的特征]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202310083
Dan Li, Xiao-Ming Ma, Jia Lei, Jie Yu, Yong-Jin Zhou, Chun-Hua Wu, Rong Li, Xian-Qing Hou
<p><p>Exploring the response mechanism of soil respiration rate to hydrothermal factors and organic carbon mineralization under different ridge-furrow mulching modes is of high importance for the development of the regional carbon cycle and assessment of its ecological benefits. An experimental study was carried out in 2020 in a dry-crop potato field in the mountainous area of southern Ningxia by setting three furrow-ridge ratios [60 cm∶30 cm (R1), 60 cm∶45 cm (R2), and 60 cm∶60 cm (R3)] combined with three mulching modes [ridge covered with ordinary plastic film, furrow covered with straw (DJ), degradable water-permeable plastic film (DS), and no mulching (DB) in furrows, respectively]. The soil hydrothermal factors, respiration rate, organic carbon content, and mineralization characteristics of potatoes during the reproductive period under different mulching modes were investigated with plain mulching without mulching (CK) as the control. The results showed that different furrow-ridge ratios combined with the mulching mode could significantly increase the soil water storage capacity in the 0-60 cm layer, and the R3DJ treatment had a better effect, with a significant increase of 24.99% compared with that in CK. The R2 treatment had the best effect of increasing temperature during the whole life cycle of the potato. The DS treatment had the effect of increasing temperature, and the DJ treatment had the effect of decreasing temperature under different mulching materials. Different furrow and ridge cover patterns could significantly increase the average soil respiration rate during the reproductive period, and the R3DS treatment was the most significant among the different furrow and ridge cover patterns, with a significant increase of 24.71% compared with that in the CK treatment. The soil organic carbon content in the 0-20 cm and 20-40 cm layers at harvest time was higher in the R2 and R1 ridges, respectively, and higher in the DB and DS treatments for different mulching materials. The soil organic carbon mineralization rate declined rapidly in the early stage of cultivation and then slowly declined and leveled off in the middle and late stages, which was highest in the R3 treatment for the three types of ridge ratios and highest in the DS treatment for different mulching materials. The fitting equations of soil respiration rate with soil hydrothermal factors during the reproductive period revealed that the synergistic effect of soil hydrothermal dual factors on soil respiration was higher than that of a soil hydrothermal single factor and that the quadratic hydrothermal dual factors could well explain 86.4% to 99.9% of the soil respiration. Correlation analysis showed that the average soil respiration rate during the whole life span of the potato was highly significantly and positively correlated with the average soil temperature in the 0-25 cm layer and the average soil organic carbon mineralization rate in the 0-40 cm layer, and the soil tempe
探索不同垄沟覆盖模式下土壤呼吸速率对水热因子和有机碳矿化的响应机制对区域碳循环发展及其生态效益评估具有重要意义。2020 年,在宁夏南部山区的一块旱作马铃薯田中进行了一项试验研究,设定了三种沟-垄比例[60 cm∶30 cm (R1)、60 cm∶45 cm (R2)、60 cm∶60 cm (R3)]、和 60 厘米∶60 厘米(R3)]结合三种地膜覆盖模式[脊上覆盖普通塑料薄膜,沟内覆盖稻草(DJ)、可降解透水塑料薄膜(DS)和沟内不覆盖地膜(DB)]。]。研究了不同地膜覆盖模式下马铃薯生育期的土壤水热因子、呼吸速率、有机碳含量和矿化特性。作为对照。结果表明,不同沟脊比结合地膜覆盖模式可显著提高0-60 cm土层的土壤蓄水能力,其中R3DJ处理效果更好,比CK处理显著提高24.99%。在马铃薯的整个生命周期中,R2 处理的增温效果最好。在不同的覆盖材料下,DS 处理具有增温效果,DJ 处理具有降温效果。不同的沟垄覆盖模式可显著提高生育期土壤平均呼吸速率,其中 R3DS 处理在不同沟垄覆盖模式中效果最显著,比 CK 处理显著提高 24.71%。收获期 0-20 厘米和 20-40 厘米土层的土壤有机碳含量在 R2 和 R1 田埂上分别较高,在不同覆土材料的 DB 和 DS 处理中也较高。土壤有机碳矿化率在栽培初期迅速下降,中后期缓慢下降并趋于平稳,三种埂比中 R3 处理最高,不同覆土材料中 DS 处理最高。生育期土壤呼吸速率与土壤水热因子的拟合方程显示,土壤水热双因子对土壤呼吸的协同效应高于土壤水热单因子,二次水热双因子能很好地解释86.4%-99.9%的土壤呼吸。相关分析表明,马铃薯全生育期的平均土壤呼吸速率与 0-25 cm 土层的平均土壤温度和 0-40 cm 土层的平均土壤有机碳矿化速率高度显著正相关,土壤温度与有机碳矿化速率高度显著正相关。结果表明,沟脊比结合地膜覆盖模式可改善土壤水热环境,提高土壤有机碳矿化率,从而影响土壤呼吸速率,其中沟脊比为 60 cm∶45 cm 或 60 cm∶60 cm 的沟脊地膜覆盖沟覆盖可降解渗水地膜覆盖模式效果更好。
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引用次数: 0
[Diversity and Functional Characteristics of Fungal Communities and Influencing Factors in Typical Paddy Fields of China]. [中国典型稻田真菌群落的多样性和功能特征及其影响因素]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202310031
Ting-E Ye, Mei-Fen Lin, Chao-Fan Yu, Yu-Jun Xiao, Li-Wen Cheng, Yi Zheng, Wei-Qi Wang

To investigate the structure, diversity, and function of different paddy soil fungal communities and the factors affecting them in typical paddy cropping areas in China, five typical Chinese paddy soils were selected in this study, and the composition and diversity of soil fungal communities were comparatively analyzed using high-throughput sequencing technology and functionally predicted using the FUNGuild microecological tool. The results showed that: ① The fungal community diversity of soil samples from Heilongjiang (HLJ) was significantly lower than that of the other four regions (P<0.05); the highest fungal community richness was found in paddy soils from Yunnan (YN), which was significantly higher than that of the other regions (P<0.05); and the soil samples from Hainan (HN), Jiangxi (JX), and Shandong (SD) were relatively close to each other. The highest average relative abundance at the level of the five typical paddy phyla was Ascomycota, and the genus with the highest average relative abundance was Tausonia. ② Fungi had the largest proportion of saprophytic trophic types, and their corresponding environmental functions were stronger. ③ The species abundance of soil fungi was highly significantly correlated with soil TP, EC, and BD (P<0.01), and redundancy analyses also showed that soil TP was the main driver of the fungal community as well as the saprophytic functional taxa. The above results showed that the soil fungal community diversity and structure varied greatly among samples, and the relative abundance of fungal genera was affected by soil physical and chemical properties and altered the fungal community structure in paddy fields. The development of this study will provide theoretical references for the sustainable management based on fungal diversity and function of paddy fields.

为研究中国典型水稻种植区不同水稻土真菌群落的结构、多样性、功能及其影响因素,本研究选取了5个中国典型水稻土,利用高通量测序技术对土壤真菌群落的组成和多样性进行了比较分析,并利用FUNGuild微生态工具对其功能进行了预测。结果表明:① 黑龙江(HLJ)土壤样品的真菌群落多样性明显低于其他地区;② 黑龙江(HLJ)土壤样品的真菌群落多样性明显低于其他地区;③ 黑龙江(HLJ)土壤样品的真菌群落多样性明显低于其他地区。结果表明:①黑龙江(HLJ)土壤样本的真菌群落多样性明显低于其他四个地区(PPTausonia)。从图中可以看出:①黑龙江(HLJ)的真菌群落多样性明显低于其他四个地区(PPTausonia);②真菌的营养盐型比例最大,相应的环境功能也更强。土壤真菌的物种丰度与土壤 TP、EC 和 BD 呈显著正相关(P
{"title":"[Diversity and Functional Characteristics of Fungal Communities and Influencing Factors in Typical Paddy Fields of China].","authors":"Ting-E Ye, Mei-Fen Lin, Chao-Fan Yu, Yu-Jun Xiao, Li-Wen Cheng, Yi Zheng, Wei-Qi Wang","doi":"10.13227/j.hjkx.202310031","DOIUrl":"https://doi.org/10.13227/j.hjkx.202310031","url":null,"abstract":"<p><p>To investigate the structure, diversity, and function of different paddy soil fungal communities and the factors affecting them in typical paddy cropping areas in China, five typical Chinese paddy soils were selected in this study, and the composition and diversity of soil fungal communities were comparatively analyzed using high-throughput sequencing technology and functionally predicted using the FUNGuild microecological tool. The results showed that: ① The fungal community diversity of soil samples from Heilongjiang (HLJ) was significantly lower than that of the other four regions (<i>P</i><0.05); the highest fungal community richness was found in paddy soils from Yunnan (YN), which was significantly higher than that of the other regions (<i>P</i><0.05); and the soil samples from Hainan (HN), Jiangxi (JX), and Shandong (SD) were relatively close to each other. The highest average relative abundance at the level of the five typical paddy phyla was Ascomycota, and the genus with the highest average relative abundance was <i>Tausonia</i>. ② Fungi had the largest proportion of saprophytic trophic types, and their corresponding environmental functions were stronger. ③ The species abundance of soil fungi was highly significantly correlated with soil TP, EC, and BD (<i>P</i><0.01), and redundancy analyses also showed that soil TP was the main driver of the fungal community as well as the saprophytic functional taxa. The above results showed that the soil fungal community diversity and structure varied greatly among samples, and the relative abundance of fungal genera was affected by soil physical and chemical properties and altered the fungal community structure in paddy fields. The development of this study will provide theoretical references for the sustainable management based on fungal diversity and function of paddy fields.</p>","PeriodicalId":35937,"journal":{"name":"Huanjing Kexue/Environmental Science","volume":"45 10","pages":"6068-6076"},"PeriodicalIF":0.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142509627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
[Evolution Characteristics and Typical Pollution Episodes of PM2.5 and O3 Complex Pollution in Bozhou City from 2017 to 2022]. [2017-2022年亳州市PM2.5和O3复合污染演变特征及典型污染事件]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202311032
Ke Wu, Xue-Zhong Wang, Dan-Dan Zhang, Hua-Long Zhu, Yong-Xin Yan, Fan-Xiu Li, Zhen-Hai Wu, Zhen-Wei Zheng, Qi-Kai Gao

In China, atmospheric pollution exhibits a complex pattern, with simultaneous exceedances of fine particulate matter (PM2.5) and ozone (O3) levels becoming evident. To understand the complex pollution characteristics and evolution patterns of PM2.5 and O3 in Bozhou City, various methods such as weather classification, analysis of typical pollution processes, and investigation of precursor sources were employed to explore the pollution and variations of PM2.5 and O3 in Bozhou City from 2017 to 2022 and subsequently analyze their causes and precursor sources. The results indicated that: ① PM2.5-O3 complex pollution in Bozhou City mostly occurred under high-pressure weather conditions, with daytime high temperatures and low humidity promoting the formation of O3 pollution, whereas nighttime high humidity and atmospheric oxidative conditions promoted the generation of secondary components such as nitrates and ammonium salts in PM2.5. ② During the pollution process, PM2.5 in Bozhou City mainly originated from biomass burning, secondary generation, traffic pollution, coal combustion, and dust sources. Volatile organic compounds (VOCs) primarily emerged from plant sources, traffic pollution, oil and gas evaporation, solvent use, fossil fuel combustion, residential emissions, and industrial emissions. Biomass burning and traffic pollution made significant contributions to the pollution process. ③ Analysis of air mass trajectories and regional pollution situations indicated that the overlay of northern and southern air masses, along with local generation, were the main causes of the PM2.5-O3 complex pollution in Bozhou from October 18th to 27th, 2022.

中国的大气污染呈现出复杂的模式,细颗粒物(PM2.5)和臭氧(O3)同时超标。和臭氧(O3)水平越来越明显。为了解亳州市PM2.5和O3的复杂污染特征及演变规律,采用气象分类、典型污染过程分析、前体源调查等多种方法,探讨了2017-2022年亳州市PM2.5和O3的污染及变化情况,进而分析其成因及前体来源。结果表明:①亳州市PM2.5-O3复合污染多发生在高压天气条件下,白天高温低湿促进了O3污染的形成,而夜间高湿和大气氧化条件促进了PM2.5中硝酸盐、铵盐等二次成分的生成。在污染过程中,亳州市的 PM2.5 主要来源于生物质燃烧、二次生成、交通污染、燃煤和扬尘源。挥发性有机物(VOCs)主要来自植物源、交通污染、油气蒸发、溶剂使用、化石燃料燃烧、居民排放和工业排放。生物质燃烧和交通污染在污染过程中贡献巨大。气团轨迹和区域污染形势分析表明,南北气团叠加和本地生成是 2022 年 10 月 18 日至 27 日亳州 PM2.5-O3 复合污染的主要原因。
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引用次数: 0
[Characteristics of Spatiotemporal Changes in China's Carbon Budget at Different Administrative Scales]. [不同行政尺度下中国碳预算的时空变化特征]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202311005
Hai-Yue Lu, Jiao-Jiao Qi, Yan-Lei Ye, Bei-Er Zhang, Jing-Lu Sun, Can-Can Yang, Ming-Wei Zhao
<p><p>Currently, scientifically and reasonably specifying carbon emission reduction measures in the context of "double carbon" has become a common concern worldwide. China's administrative divisions have a notable impact on the formulation and implementation of relevant policies. Therefore the carbon emissions must be calculated accurately under China's administrative divisions at different scales. The spatiotemporal change characteristics of absorption and carbon emissions can provide scientific basis for the formulation of reasonable and differentiated carbon emission reduction policies in different administrative regions in China. To this end, this study used multi-source data such as remote sensing and statistics and integrated ecological models, statistics, and GIS space analysis and other methods to analyze the spatiotemporal dynamic change characteristics of carbon emissions and carbon absorption at different administrative scales (provinces, cities, and counties) in China. The results showed that: ① The total carbon absorption of vegetation in China continued to increase from 2000 to 2021 and the average value gradually increased. Differences were observed in spatiotemporal changes in carbon emissions at different administrative scales. The spatiotemporal changes at smaller scales were more evident. Carbon emissions showed obvious spatial differences of "high in the north and low in the south, high in the east and low in the west." ② The spatiotemporal distribution of CPI at the administrative scale was similar to that of carbon emissions and the overall trend was increasing annually. The pressure of carbon emissions on carbon absorption gradually weakened from the east to the central and western regions. ③ Spatiotemporal hotspot analysis showed that the overall spatial distribution of cold and hot spots in China's carbon absorption was as follows: In the spatial pattern of "hot in the east and cold in the west," the spatial distribution of cold and hot spots of carbon emissions showed agglomeration characteristics. The provincial scale was primarily oscillating hotspot whereas municipal and county scales were majorly continuous hot spots. Further results revealed that: ① Carbon absorption in different regions and periods in China showed significant variability, especially in the central and eastern regions. The possibility of offsetting carbon emissions by increasing carbon absorption remains. ② At the same scale, administrative regions (such as different provinces) and lower-level administrative regions at another scale (such as different cities in the same province) showed varying degrees of variability in carbon absorption and carbon emissions. Therefore, taking provincial administrative regions as an example for subsequent formulation considering carbon trading, emission reduction, and other policies, we should first consider the coordination of emissions between different cities in the province and then consider the coordination bet
当前,科学合理地明确 "双碳 "背景下的碳减排措施已成为全球共同关注的问题。中国的行政区划对相关政策的制定和实施有着显著的影响。因此,必须准确计算中国不同尺度行政区划下的碳排放量。碳吸收和碳排放的时空变化特征可以为我国不同行政区域制定合理的、差异化的碳减排政策提供科学依据。为此,本研究利用遥感、统计等多源数据,综合生态模型、统计、GIS空间分析等方法,分析了我国不同行政区划(省、市、县)碳排放和碳吸收的时空动态变化特征。时空动态变化特征。结果表明:①2000-2021 年,中国植被碳吸收总量持续增长,平均值逐渐增大。不同行政区域碳排放量的时空变化存在差异。小尺度的时空变化更为明显。碳排放量呈现出明显的 "北高南低、东高西低 "的空间差异。CPI在行政区尺度上的时空分布与碳排放相似,总体呈逐年上升趋势。碳排放对碳吸收的压力从东部地区向中西部地区逐渐减弱。时空热点分析表明,我国碳吸收冷热点空间分布总体情况如下: 在 "东热西冷 "的空间格局中,碳排放冷热点空间分布呈现集聚特征。省级尺度主要是振荡型热点,而市级和县级尺度主要是连续型热点。进一步的研究结果表明:①中国不同地区、不同时期的碳吸收量呈现出显著的差异性,尤其是中部和东部地区。通过增加碳吸收来抵消碳排放的可能性依然存在。在同一尺度上,行政区域(如不同省份)在同一尺度上,行政区域(如不同省份)和下级行政区域(如同一省份的不同城市)的碳吸收量存在不同程度的差异。在碳吸收和碳排放方面表现出不同程度的差异。因此,以省级行政区为例,在后续制定碳交易、碳减排等政策时,应首先考虑省内不同城市之间的排放协调,然后再考虑省际之间的协调,这样有望更好地推动相关政策的实施。
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引用次数: 0
[Pollution Characteristics and Source Apportionment of Volatile Organic Compounds in Typical Solvent-using Industrial Parks in Beijing]. [北京典型溶剂使用工业园区挥发性有机化合物的污染特征和来源分配]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202310142
Rui Liu, Zhen Yao, Xiao-Hui Hua, Xiu-Rui Guo, Hai-Lin Wang, Feng Qi

The BCT-7800A PLUS VOC online monitor system was employed to measure ambient volatile organic compounds (VOCs) in a typical solvent-using industrial park in Beijing. From January to June 2023, the pollution characteristics, source apportionment, and ozone formation potential(OFP)of VOCs were studied, and the results of a comparative analysis were also discussed between heating and non-heating periods. The results indicated that VOC concentrations from January to June 2023 were (104.21 ± 91.31) μg·m-3 on average. The concentrations of TVOCs under the influence of southerly and northerly winds were (214.18 ± 202.37) μg·m-3 and (197.56 ± 188.3) μg·m-3, respectively. Alkanes were the species with the highest average concentration and proportion, respectively (45.53 ± 41.43) μg·m-3. The VOC concentration during the heating period was higher than those during the non-heating period, with values of (111.57 ± 83.96) μg·m-3 and (87.92 ± 75.03) μg·m-3, respectively. Propane and ethane were the species with the highest average concentration during the heating period. Compared with those in the non-heating period, the average concentrations of three species (propane, ethane, and n-butane) in the top ten species increased during the heating period, with average concentrations increasing by 51.94%, 54.64%, and 26.32%, respectively. The source apportionment results based on the positive matrix factorization (PMF) model indicated that the major sources of VOCs in the park during the monitoring period were printing emission sources (4.95%), oil and gas evaporation sources (9.52%), fuel combustion sources (15.44%), traffic emissions sources (18.97%), electronic equipment manufacturing (24.59%), and industrial painting sources (26.52%). Therefore, industrial painting sources, electronic equipment manufacturing sources, and traffic emissions sources were the emission sources that the park should focus on controlling. Compared with those during non-heating periods; industrial painting, traffic emission, and fuel combustion sources contributed more during the heating period, with VOC concentrations increasing by 15.02%, 16.53%, and 24.98%, respectively. The average OFP of VOCs from May to June during the monitoring period was 198.51 μg·m-3 and OVOCs, olefins, and aromatic hydrocarbons contributed the most to OFP, which were 47.41%, 22.15%, and 18.41%, respectively. The electronic equipment manufacturing source was the largest contributor to the summer OFP of the park and its contribution rate was 30.11%, which should be strengthened in the future.

BCT-7800A PLUS 挥发性有机化合物在线监测系统用于测量北京典型溶剂使用工业园区的环境挥发性有机化合物(VOCs)。的测量。研究了 2023 年 1 月至 6 月期间挥发性有机化合物的污染特征、来源分配和臭氧形成潜力(OFP),并讨论了采暖期和非采暖期的对比分析结果。结果表明,2023 年 1 月至 6 月的挥发性有机化合物浓度为(104.21 ± 91.31)μg-m-3。μg-m-3。在偏南风和偏北风的影响下,TVOCs 的浓度分别为(214.18 ± 202.37)μg-m-3 和(1970 ± 202.37)μg-m-3。μg-m-3和(197.56 ± 188.3)μg-m-3。μg-m-3。烷烃是平均浓度和比例最高的种类,分别为(45.53 ± 41.43)μg-m-3和(197.56 ± 188.3)μg-m-3。μg-m-3。加热期的挥发性有机化合物浓度高于非加热期,其值分别为(111.57 ± 83.96)μg-m-3和(87.92 ± 75.03)μg-m-3。μg-m-3。丙烷和乙烷是加热期平均浓度最高的物质。与非采暖期相比,采暖期前十位的三个物种(丙烷、乙烷和正丁烷)的平均浓度均有所上升。的平均浓度分别增加了 51.94%、54.64% 和 26.32%。基于正矩阵因式分解(PMF)模型的源分配结果表明,VOCs 的主要来源是甲烷和丁烷。根据正矩阵因式分解(PMF)模型,监测期间公园内 VOCs 的主要来源为印刷排放源(4.95%)、油气蒸发源(9.52%)、燃料燃烧源(15.44%)、交通排放源(18.97%)、电子设备制造源(24.59%)、工业涂装源(26.52%)。因此,工业涂装源、电子设备制造源和交通排放源是园区应重点控制的排放源。与非采暖期相比,采暖期工业涂装源、交通排放源和燃料燃烧源对 VOC 的贡献较大,VOC 浓度分别增加了 15.02%、16.53% 和 24.98%。监测期间,5-6 月 VOCs 的平均 OFP 为 198.51 μg-m-3 ,OVOCs、烯烃和芳香烃对 OFP 的贡献最大,分别为 47.41%、22.15% 和 18.41%。电子设备制造源是园区夏季 OFP 的最大贡献源,其贡献率为 30.11%,今后应进一步加强。
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引用次数: 0
[Spatiotemporal Evolution Characteristics and Influencing Factors of Industrial Carbon Emissions in the Yellow River Basin]. [黄河流域工业碳排放时空演变特征及影响因素]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202308258
Xi-Lian Wang, Li-Hang Qu

Scientific assessment of industrial carbon emissions in the Yellow River Basin and identification of its influencing factors are of great importance for promoting green transformation, ecological protection, and high-quality development of the Yellow River Basin. Considering nine provinces in the Yellow River Basin as the research objects; using relevant data on industrial development and energy consumption in the Yellow River Basin from 2000 to 2019; and with the help of IPCC carbon emission measurement, spatial autocorrelation, and LMDI decomposition, the spatial and temporal evolution characteristics and influencing factors of carbon emissions from industries and industrial sectors in the Yellow River Basin were analyzed. Reasonable suggestions were put forward for reducing the carbon emissions from industries in the Yellow River Basin. The results showed that: ① From 2000 to 2019, industrial carbon emissions in the Yellow River Basin showed a fluctuating growth trend, with a decreasing growth rate. The spatial pattern changed from "low in the upstream and high in the middle and downstream" to "high and low value distribution," and the spatial difference gradually expanded. ② The high carbon industry was the most important source of industrial carbon emissions in the Yellow River Basin, accounting for 96.35% of the carbon emissions between the industries with a continuous growth trend, which was a significant difference. The middle and low carbon industry carbon emissions and the total proportion was low, showing different fluctuations; nine provinces and nine industrial industries had significant spatial variability. ③ Energy structure intensity, economic scale, and population scale promoted the increase in industrial carbon emissions in the Yellow River Basin and energy consumption intensity had an inhibitory effect on the increase in carbon emissions. The economic scale effect was positive and significant, which offset the negative effect of energy consumption intensity. Spatial variability was observed in the contribution value of the influence effect of the factors affecting the carbon emissions of the industry in nine provinces.

科学评估黄河流域工业碳排放及其影响因素,对于推动黄河流域绿色转型、生态保护和高质量发展具有重要意义。以黄河流域九省为研究对象,利用2000-2019年黄河流域工业发展和能源消费的相关数据,借助IPCC碳排放计量、空间自相关、LMDI分解等方法,分析了黄河流域工业及工业部门碳排放的时空演变特征和影响因素。提出了减少黄河流域工业碳排放的合理建议。结果表明:①2000-2019年,黄河流域工业碳排放量呈波动增长趋势,增速呈下降趋势。空间格局由 "上游低、中下游高 "转变为 "高低值分布",空间差异逐渐扩大。高碳行业是黄河流域工业碳排放的最主要来源,占行业间碳排放量的 96.35%,且呈持续增长趋势,差异显著。中低碳工业碳排放量和总量占比较低,呈现不同的波动性;九个省份和九个工业行业的碳排放量具有显著的空间差异性。能源结构强度、经济规模和人口规模促进了黄河流域工业碳排放的增加,能源消费强度对碳排放的增加有抑制作用。经济规模效应为正且显著,抵消了能源消耗强度的负效应。九省工业碳排放影响因素的贡献值存在空间差异。
{"title":"[Spatiotemporal Evolution Characteristics and Influencing Factors of Industrial Carbon Emissions in the Yellow River Basin].","authors":"Xi-Lian Wang, Li-Hang Qu","doi":"10.13227/j.hjkx.202308258","DOIUrl":"https://doi.org/10.13227/j.hjkx.202308258","url":null,"abstract":"<p><p>Scientific assessment of industrial carbon emissions in the Yellow River Basin and identification of its influencing factors are of great importance for promoting green transformation, ecological protection, and high-quality development of the Yellow River Basin. Considering nine provinces in the Yellow River Basin as the research objects; using relevant data on industrial development and energy consumption in the Yellow River Basin from 2000 to 2019; and with the help of IPCC carbon emission measurement, spatial autocorrelation, and LMDI decomposition, the spatial and temporal evolution characteristics and influencing factors of carbon emissions from industries and industrial sectors in the Yellow River Basin were analyzed. Reasonable suggestions were put forward for reducing the carbon emissions from industries in the Yellow River Basin. The results showed that: ① From 2000 to 2019, industrial carbon emissions in the Yellow River Basin showed a fluctuating growth trend, with a decreasing growth rate. The spatial pattern changed from \"low in the upstream and high in the middle and downstream\" to \"high and low value distribution,\" and the spatial difference gradually expanded. ② The high carbon industry was the most important source of industrial carbon emissions in the Yellow River Basin, accounting for 96.35% of the carbon emissions between the industries with a continuous growth trend, which was a significant difference. The middle and low carbon industry carbon emissions and the total proportion was low, showing different fluctuations; nine provinces and nine industrial industries had significant spatial variability. ③ Energy structure intensity, economic scale, and population scale promoted the increase in industrial carbon emissions in the Yellow River Basin and energy consumption intensity had an inhibitory effect on the increase in carbon emissions. The economic scale effect was positive and significant, which offset the negative effect of energy consumption intensity. Spatial variability was observed in the contribution value of the influence effect of the factors affecting the carbon emissions of the industry in nine provinces.</p>","PeriodicalId":35937,"journal":{"name":"Huanjing Kexue/Environmental Science","volume":"45 10","pages":"5613-5623"},"PeriodicalIF":0.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142509657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
[Influence of Typical Regional Land Use/Landscape Pattern on Water TN of the Upper Yellow River]. [典型区域土地利用/景观模式对黄河上游水 TN 的影响]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202310025
Tian-Hong Zhou, Si-Lin Su, Kai Ma, Sen Du, Hui-Juan Xin

This study aimed to explore the relationship between land use landscape pattern and water quality in the upstream of the Gansu water conservation, water and soil erosion, and ecological fragile areas. Based on the land use data and water quality monitoring section in 2020 in the 200 m, 500 m, 1 km, 2 km, 50 km, and 10 km riparian buffer area, the single-factor index evaluation method, random forest regression model, and BP neural network were used to quantify the response relationship between land use and landscape pattern of the upper Yellow River in Gansu province and water quality index and to carry out the basin water quality prediction based on land use landscape index data. The results showed that: ① through the single-factor index method, the major indicators of the total nitrogen (TN) in July and September, dissolved oxygen (DO), permanganate index, ammonia nitrogen (NH4+ -N), total phosphorus (TP), and other surface indexes met the surface water environment class Ⅲ water quality standard. ② The random forest regression model was used to analyze the influence of land use and landscape index on TN, and the difference in TN in different typical areas was obtained. The land use types with the highest influence on the TN index in water conservation areas, soil and soil erosion areas, and ecological fragile areas were cultivated land, grassland, and construction land, respectively. ③ The BP neural network was used to predict the water quality index based on different typical areas of land use landscape index. The result of water conservation areas was good, the error rate between the predicted value and the actual value was below 10%, and the prediction accuracy was high. The study showed that water quality prediction based on land use and landscape index/water quality quantitative relationship model had a good water quality prediction effect.

本研究旨在探讨甘肃水源涵养区、水土流失区、生态脆弱区上游土地利用景观格局与水质的关系。以2020年200 m、500 m、1 km、2 km、50 km、10 km河岸缓冲区的土地利用数据和水质监测断面为基础,采用单因子指数评价法、随机森林回归模型、BP神经网络等方法,量化了甘肃省黄河上游土地利用景观格局与水质指数的响应关系,并基于土地利用景观指数数据进行了流域水质预测。结果表明:①通过单因子指数法,黄河流域主要指标总氮(TN)7、9 月溶解氧(DO)、高锰酸盐指数、氨氮(NH4+-N)、总磷(TP)等地表指标均达到地表水环境Ⅲ类水质标准。采用随机森林回归模型分析土地利用和景观指数对 TN 的影响,得出不同典型区域 TN 的差异。在水源涵养区、水土流失区和生态脆弱区,对 TN 指数影响最大的土地利用类型分别为耕地、草地和建设用地。根据不同典型区域的土地利用景观指数,采用 BP 神经网络预测水质指数。水源保护区的预测结果良好,预测值与实际值的误差率低于 10%,预测精度较高。研究表明,基于土地利用景观指数/水质定量关系模型的水质预测具有较好的水质预测效果。
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引用次数: 0
[Spatial and Temporal Characteristics and Driving Force Analysis of Ecological Environmental Quality in Fengfeng Mining Area with Remote Sensing Ecological Index of PM2.5 Concentration]. [利用 PM2.5 浓度遥感生态指数分析峰峰矿区生态环境质量的时空特征及驱动力]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202311223
Jing-Han Zhang, Wei Zhang, An-Zhou Zhao, Li-Hui Sun

The Fengfeng mining area is an important coal-producing area in China and crucial environmental problems have been caused by large-scale exploitation of coal mines. The spatio-temporal evolution and driving factors of the ecological environment quality in this area must be explored for promoting the transformation of coal-based cities. Based on Landsat data of the Google earth engine (GEE) platform, this study constructed a new remote sensing-based ecological index (RSEInew) for the Fengfeng mining area from 2000 to 2020. The spatial and temporal evolution of RSEInew and its driving factors were evaluated by using trend analysis and geographic detector methods. The results showed that: ① From 2000 to 2020, the RSEInew of the Fengfeng mining area presented a fluctuating increasing trend (trend = 0.002 2), and the proportion of good and excellent ecological environmental quality showed an increasing trend, rising from 24.80% in 2000 to 65.54% in 2020. ② The change in the RSEInew grade indicated that the proportion of significant improvement (3 and 4) of ecological environment quality grade in the Fengfeng Mining area from 2000 to 2020 was 10.21%, which was mainly distributed in Hexun town and Yijing town in the northwest of the Fengfeng mining area. The proportion of significant degradation (-3 and -4) was only 1.58%, mainly scattered in Linshui town and Dashe town. ③ RSEInew values increased significantly during 2000-2020 in the area accounting for 18.29%, mainly distributed in the central and northern areas and the western fringe of the Fengfeng mining area. The significantly reduced area accounted for 9.25%, mainly concentrated in the eastern area of the Fengfeng mining area. The coefficient of variation results showed that the areas with high fluctuation of RSEInew were mainly concentrated in Pengcheng town and Linshui town in the middle and eastern Fengfeng mining area. ④ From the perspective of influencing factors, the average q value of land use type (X6) during 2000-2020 was 0.290, which was much higher than other factors. The q value of social and economic factors showed an increasing trend, indicating that the spatial distribution of ecological environment quality in this region was increasingly strongly influenced by human activities. The interaction results showed that land use change was the key factor influencing ecological environment quality in the Fengfeng mining area.

峰峰矿区是中国重要的产煤区,大规模的煤矿开采造成了严重的环境问题。为促进煤基城市转型,必须探究该地区生态环境质量的时空演变及其驱动因素。本研究基于谷歌地球引擎(GEE)平台的陆地卫星数据,构建了一个新的遥感模型。平台的陆地卫星数据,构建了基于遥感的峰峰矿区生态指数(RSEInew)的生态指数(RSEInew)。利用趋势分析法和地理探测法评估了 RSEInew 的时空演变及其驱动因素。结果表明:①2000-2020 年,峰峰矿区 RSEInew 呈波动上升趋势(趋势 = 0.002 2),生态环境质量良好和优良比例呈上升趋势,由 2000 年的 24.80%上升到 2020 年的 65.54%。RSEInew 等级的变化表明,湿地生态环境质量等级明显改善(3 级和 4 级)的比例由 2000 年的 24.80%上升到 2020 年的 65.54%。2000-2020年,峰峰矿区生态环境质量等级明显改善(3级和4级)的比例为10.21%,主要分布在峰峰矿区西北部的和顺镇和义井镇。显著退化(-3 和-4)的比例仅为 1.58%,主要分布在峰峰矿区西北部的和顺镇和义井镇。仅占 1.58%,主要分布在临水镇和大社镇。2000-2020年,③RSEInew值明显增加的面积占18.29%,主要分布在中北部和峰峰矿区西部边缘。明显减少的区域占 9.25%,主要集中在峰峰矿区东部地区。变异系数结果表明,RSEInew 波动较大的区域主要集中在峰峰矿区中、东部的彭城镇和临水镇。从影响因子来看,2000-2020 年土地利用类型(X6)的平均 q 值为 0.2。从影响因子来看,2000-2020 年土地利用类型(X6)的平均 q 值为 0.290,远高于其他因子。社会经济因子的 q 值呈上升趋势,表明该区域生态环境质量的空间分布受人类活动的影响越来越大。交互作用结果表明,土地利用变化是影响峰峰矿区生态环境质量的关键因素。
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引用次数: 0
[Spatiotemporal Characterization and Driving Factors of Fine Particulate Matter and Its Chemical Components in the Huaihe River Basin]. [淮河流域细颗粒物及其化学成分的时空特征和驱动因素]。
Q2 Environmental Science Pub Date : 2024-10-08 DOI: 10.13227/j.hjkx.202312141
Xiao-Yong Liu, Ji-Qiang Niu, Hang Liu, Yi-Dan Zhang, Jun Yan, Jun-Hui Yan, Fang-Cheng Su

According to the data sets of fine particulate matter (PM2.5) and its components in 35 cities in the Huaihe River Basin from 2015 to 2021, the temporal and spatial distribution patterns of pollutants were analyzed. The influence of meteorological factors on PM2.5 concentrations was examined using a random forest model. The original series of PM2.5, sulfate (SO42-), nitrate (NO3-), ammonium salt (NH4+), organic matter (OM), and black carbon (BC) were rebuilt using KZ (Kolmogorov-Zurbenko) filtering and multiple linear regression (MLR) to quantify the effects of meteorological conditions. The results demonstrated that from 2015 to 2021, the declining rates of PM2.5, SO42-, NO3-, NH4+, OM, and BC in the Huaihe River Basin were 4.71, 0.99, 1.05, 0.77, 1.01, and 0.19 μg·(m3·a)-1, respectively. The high mass concentrations of PM2.5 and its components were concentrated in the central and western regions of the HRB, whereas those in coastal and southern cities were lower. The variance contributions of the short-term, seasonal, and long-term components of PM2.5 to the original PM2.5 sequences in 35 cities were 51.6%, 35.9%, and 7.0%, respectively. The PM2.5 in coastal cities were more affected by the short-term components. The meteorological conditions were unfavorable for PM2.5 reduction in the HRB from 2015 to 2018, whereas the meteorological conditions supported the PM2.5 decrease from 2019 to 2021. From 2015 to 2021, the contribution rates of meteorological conditions to the long-term component reductions of PM2.5, SO42-, NO3-, NH4+, OM, and BC were 28.3%, 29.1%, 31.0%, 29.3%, 27.8%, and 28.6%, respectively. The contribution rates of meteorological conditions to the long-term PM2.5 reduction were 43.4%, 25.6%, 25.5%, and 20.6% in the HRB cities in Anhui, Shandong, Jiangsu, and Henan Provinces, respectively. With the decrease in PM2.5 concentration in the HRB, the sulfur oxidation rate (SOR) increased significantly, while the nitrogen oxide oxidation rate (NOR) changed little.

根据淮河流域 35 个城市 2015-2021 年细颗粒物(PM2.5)及其组分数据集,分析了污染物的时空分布规律。及其组分,分析了污染物的时空分布规律。利用随机森林模型研究了气象因子对 PM2.5 浓度的影响。利用 KZ (KZ)模型重建了 PM2.5、硫酸盐(SO42-)、硝酸盐(NO3-)、铵盐(NH4+)、有机物(OM)和黑碳(BC)的原始序列。采用 KZ (Kolmogorov-Zurbenko)滤波和多元线性回归(Multiple滤波和多元线性回归(MLR)来量化气象条件的影响。结果表明,从2015年到2021年,淮河流域PM2.5、SO42-、NO3-、NH4+、OM和BC的下降率分别为4.71、0.99、1.05、0.77、1.01和0.19 μg-(m3-a)-1。PM2.5及其组分的高质量浓度主要集中在人力资源基地的中部和西部地区,而沿海和南部城市的PM2.5及其组分的高质量浓度则较低。35个城市PM2.5的短期、季节和长期成分对原始PM2.5序列的方差贡献率分别为51.6%、35.9%和7.0%。沿海城市的 PM2.5 受短期成分的影响更大。2015年至2018年的气象条件不利于人力资源局PM2.5的下降,而2019年至2021年的气象条件支持PM2.5的下降。2015年至2021年,气象条件对PM2.5、SO42-、NO3-、NH4+、OM和BC长期组分减排的贡献率分别为28.3%、29.1%、31.0%、29.3%、27.8%和28.6%。在安徽、山东、江苏和河南四省的人力资源基地城市,气象条件对 PM2.5 长期下降的贡献率分别为 43.4%、25.6%、25.5% 和 20.6%。随着HRB城市PM2.5浓度的降低,硫氧化率(SOR)显著增加,而氮氧化物氧化率(SOR)则显著降低。明显增加,而氮氧化物氧化率(NOR)变化不大。
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