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Recent developments in reactivity testing of supplementary cementitious materials 辅助胶凝材料反应性测试的最新进展
Q2 Engineering Pub Date : 2021-12-29 DOI: 10.21809/rilemtechlett.2021.150
P. Suraneni
Identification and rapid characterization of novel supplementary cementitious materials (SCMs) is a critical need, driven by shortfalls in conventional SCMs. In this study, we present a discussion of recently developed reactivity tests – the R3 test, the modified R3 test, the lime strength test, and the bulk resistivity index test. These tests measure reactivity parameters such as heat release, bound water, calcium hydroxide consumption, strength, and bulk resistivity. All tests can screen inert from reactive materials. To additionally differentiate pozzolanic and latent hydraulic materials, two parameters, for example, calcium hydroxide consumption and heat release, are needed. The influences of SCM bulk chemistry, amorphous content, and fineness on measured reactivity are outlined. Reactivity test outputs can predict strength and durability of cement paste/mortar/concrete; however, caution must be exercised as these properties are influenced by a variety of other factors independent of reactivity. Thoughts are provided on using reactivity tests to screen materials for concrete durability.
由于传统SCMs的不足,识别和快速表征新型补充胶凝材料是一项关键需求。在本研究中,我们讨论了最近开发的反应性测试——R3测试、改进的R3测试、石灰强度测试和体电阻率指数测试。这些测试测量反应性参数,如热释放、结合水、氢氧化钙消耗、强度和体积电阻率。所有测试都可以从反应性材料中筛选出惰性材料。为了进一步区分火山灰和潜在水力材料,需要两个参数,例如氢氧化钙消耗量和热释放量。概述了SCM本体化学、无定形含量和细度对测量反应性的影响。反应性测试输出可以预测水泥浆/砂浆/混凝土的强度和耐久性;然而,必须谨慎行事,因为这些性质受到与反应性无关的各种其他因素的影响。提出了利用反应性试验筛选混凝土耐久性材料的思路。
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引用次数: 12
Life Cycle Assessment of alkali activated materials: preliminary investigation for pavement applications 碱活性材料的生命周期评估:路面应用的初步调查
Q2 Engineering Pub Date : 2021-12-07 DOI: 10.21809/rilemtechlett.2021.120
F. Lolli, K. Kurtis
The capital investment in the US for construction and maintenance of the infrastructure road network is $150 billion/year. Investments in OECD countries will likely stabilize, while other countries will face an exponential growth of investments for infrastructures driven by the development of metropolitan cities. Continued “business-as-usual” practice for portland and asphalt cement concrete pavement construction ignores the increasing warning calls for the identification of more sustainable and less energy intensive paving materials. Alkali activated materials concrete (AAM) have been studied with growing interest during the last three decades. AAM show promising results in terms of mechanical performance, while also having a global warming potential impact 30-80% less than that of portland cement concrete. The global warming potential of AAM is closely dependent on the: 1) activating solution used to activate the raw material and 2) origin of the raw material. Specifically, the impact of the transport for both of these components is ~ 10% of its global warming potential. Hence, to increase the adoption of AAM for pavements, it is fundamental to analyze the existing literature to clarify the link between environmental impact and mechanical performance, identifying opportunities for applications that are tailored to the local availability of raw material.
美国用于基础设施公路网建设和维护的资本投资为1500亿美元/年。经合组织国家的投资可能会稳定下来,而其他国家的基础设施投资将因大都市的发展而呈指数级增长。波特兰和沥青水泥混凝土路面施工的持续“一切照旧”做法忽视了越来越多的警告,即需要确定更可持续、能耗更低的路面材料。在过去的三十年里,人们对碱活性材料混凝土(AAM)的研究越来越感兴趣。AAM在力学性能方面显示出有希望的结果,同时其对全球变暖的潜在影响也比硅酸盐水泥混凝土低30-80%。AAM的全球变暖潜力与以下因素密切相关:1)用于活化原材料的活化溶液和2)原材料的来源。具体而言,运输对这两种成分的影响约为其全球变暖潜力的10%。因此,为了增加AAM在路面上的应用,分析现有文献以澄清环境影响和机械性能之间的联系,确定根据当地原材料可用性定制应用的机会是至关重要的。
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引用次数: 2
Concrete damage due to oxidation of pyrrhotite-bearing aggregate: a review 含磁黄铁矿骨料氧化引起混凝土损伤的研究进展
Q2 Engineering Pub Date : 2021-07-26 DOI: 10.21809/rilemtechlett.2021.138
J. Duchesne, A. Rodrigues, B. Fournier
Oxidation of pyrrhotite-bearing aggregates is one of the major causes of concrete damage in numerous buildings in Trois-Rivières in Canada and Connecticut in the USA. In the presence of moisture and oxygen, pyrrhotite oxidizes to generate iron-and sulfate-rich secondary minerals that cause internal sulfate attack. Iron sulfides are accessory minerals of different rock types. The distribution of sulfides is often very heterogeneous in terms of aggregate particles, even at the level of the quarries in which some areas may contain copious amounts than others, which complicates the sampling method. Pyrrhotite is a complex mineral with varying chemical composition, crystallographic structure, and specific surface area. These factors influence the reactivity of pyrrhotite. Therefore, it is challenging to control the quality of the aggregate sources. In this study, recent advances in the identification and quantification of pyrrhotite to diagnose complicated cases are presented, and a performance-based approach for the quality control of new sources of aggregates is introduced. The performance-based approach is preferred because it eliminates the influence of the oxidation of pyrrhotite.
含磁黄铁矿骨料的氧化是加拿大trois - rivi和美国康涅狄格州许多建筑物混凝土损坏的主要原因之一。在水分和氧气的存在下,磁黄铁矿氧化生成富含铁和硫酸盐的二次矿物,引起内部硫酸盐的攻击。硫化铁是不同岩石类型的辅助矿物。硫化物的分布在聚集颗粒方面往往是非常不均匀的,即使在采石场的水平上,有些地区可能比其他地区含有大量的硫化物,这使取样方法复杂化。磁黄铁矿是一种复杂的矿物,具有不同的化学成分、晶体结构和比表面积。这些因素影响磁黄铁矿的反应性。因此,如何控制聚合源的质量是一个挑战。在本研究中,介绍了磁黄铁矿鉴定和定量诊断复杂病例的最新进展,并介绍了一种基于性能的方法来控制新骨料来源的质量。基于性能的方法是首选的,因为它消除了磁黄铁矿氧化的影响。
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引用次数: 8
Sharp Front analysis of moisture buffering 锐锋分析水分缓冲
Q2 Engineering Pub Date : 2021-07-22 DOI: 10.21809/RILEMTECHLETT.2021.136
C. Hall, Gloria J. Lo, A. Hamilton
Moisture buffering describes the use of materials with high water-vapour sorption capacity to provide humidity control in interior spaces. Established models of the moisture dynamics of buffering are derived from conventional Fickian vapour-diffusion equations. We describe an alternative analysis using a Sharp-Front formulation. This yields a similar expression for the  moisture effusivity, several consistent scalings and a new definition of the moisture penetration depth. Features of the model are compared with  some published experimental data. A new sorption buffer index is a measurable experimental property that describes the water-vapour  buffer strength of the material.
湿气缓冲描述了使用具有高水蒸气吸收能力的材料来在内部空间中提供湿度控制。所建立的缓冲水分动力学模型是从传统的菲基蒸汽扩散方程中推导出来的。我们描述了一种使用Sharp-Front公式的替代分析。这就产生了类似的水分渗出率表达式、几个一致的刻度以及水分渗透深度的新定义。将该模型的特点与一些已发表的实验数据进行了比较。一种新的吸附缓冲指数是一种可测量的实验性质,它描述了材料的水蒸气缓冲强度。
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引用次数: 2
Mechanically activated mine tailings for use as supplementary cementitious materials 用作辅助胶结材料的机械活化尾矿
Q2 Engineering Pub Date : 2021-07-16 DOI: 10.21809/RILEMTECHLETT.2021.143
S. Ramanathan, P. Perumal, M. Illikainen, P. Suraneni
Two mine tailings are evaluated for their potential as supplementary cementitious materials. The mine tailings were milled using two different methods – ball milling for 30 minutes and disc milling for durations ranging from 1 to 15 minutes. The modified R3 test was carried out on the mine tailings to quantify their reactivity. The reactivity of the disc milled tailings is greater than those of the ball milled tailings. Strong correlations are obtained between milling duration, median particle size, amorphous content, dissolved aluminum and silicon, and reactivity of the mine tailings. The milling energy results in an increase in the fineness and the amorphous content, which do not appreciably increase beyond a disc milling duration of 8 minutes. The reactivity increases significantly beyond a certain threshold fineness and amorphous content. Cementitious pastes were prepared at 30% supplementary cementitious materials replacement level at a water-to-cementitious materials ratio of 0.40. No negative effects of the mine tailings were observed at early ages in cement pastes based on isothermal calorimetry and thermogravimetric analysis, demonstrating the potential for these materials to be used as supplementary cementitious materials.
对两种尾矿作为补充胶凝材料的潜力进行了评价。采用球磨30分钟和圆盘磨1 ~ 15分钟两种不同的方法对尾矿进行磨矿。对尾矿进行了改良R3试验,量化了尾矿的反应性。盘磨尾矿的反应性比球磨尾矿的反应性大。磨矿时间、中位粒度、非晶含量、溶铝和溶硅与尾矿反应性有较强的相关性。铣削能量导致细度和非晶含量的增加,超过8分钟的圆盘铣削持续时间不会明显增加。超过一定的阈值细度和非晶态含量后,反应性显著提高。在水胶比0.40的条件下,以30%的补充胶凝材料替代水平制备胶凝体。等温量热分析和热重分析结果显示,尾矿在早期龄期未对水泥浆体产生负面影响,表明其具有作为补充胶凝材料的潜力。
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引用次数: 14
CO2 mineralization of demolished concrete wastes into a supplementary cementitious material – a new CCU approach for the cement industry 将拆除的混凝土废物CO2矿化为补充胶凝材料——水泥行业的CCU新方法
Q2 Engineering Pub Date : 2021-07-15 DOI: 10.21809/RILEMTECHLETT.2021.141
M. Zając, J. Skocek, J. Skibsted, Mohsen Ben Haha
This contribution discusses the carbon capture and utilization (CCU) approach based on CO2 mineralization of cement paste from recycled concrete as new approach to capture CO2 and significantly contribute to the reduction in CO2 emissions associated with cement production. The current literature suggests that all CO2 released from the decomposition of limestone during clinker production can be sequestered by carbonation of the end-of-life cement paste. This carbonation can be achieved in a few hours at ambient temperature and pressure and with a relatively low CO2 concentration (< 10 %) in the gas. The carbonation of cement paste produces calcite and an amorphous alumina-silica gel, the latter being a pozzolanic material that can be utilized as a supplementary cementitious material. The pozzolanic reaction of the alumina-silica gel is very rapid as a result of its high specific surface and amorphous structure. Thus, composite cements containing carbonated cement paste are characterized by a rapid strength gain. The successful implementation of this CCU approach relies also on improved concrete recycling techniques and methods currently under development to separate out the cement paste fines and such. Full concrete recycling will further improve the circular utilization of cement and concrete by using recycled aggregates instead of natural deposits of aggregates.  Although the feasibility of the process has already been demonstrated at the industrial scale, there are still several open questions related to optimum carbonation conditions and the performance of carbonated material in novel composite cements.
这篇文章讨论了基于回收混凝土水泥浆CO2矿化的碳捕获和利用(CCU)方法,作为捕获CO2的新方法,并对减少与水泥生产相关的CO2排放做出了重大贡献。目前的文献表明,在熟料生产过程中,石灰石分解释放的所有二氧化碳都可以通过使用寿命终止的水泥浆的碳酸化来封存。这种碳酸化可以在环境温度和压力下在几个小时内实现,并且气体中的CO2浓度相对较低(<10%)。水泥浆的碳化作用产生方解石和无定形氧化铝-硅胶,后者是一种火山灰材料,可作为补充胶凝材料。氧化铝-硅胶的火山灰反应由于其高比表面积和无定形结构而非常迅速。因此,含有碳酸化水泥浆的复合水泥的特征在于快速增加强度。这种CCU方法的成功实施还依赖于目前正在开发的改进的混凝土回收技术和方法,以分离出水泥浆细粒等。全面的混凝土回收利用将通过使用再生骨料而不是骨料的自然沉积,进一步提高水泥和混凝土的循环利用率。尽管该工艺的可行性已经在工业规模上得到了证明,但仍有几个悬而未决的问题与最佳碳酸化条件和新型复合水泥中碳酸化材料的性能有关。
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引用次数: 31
CemGEMS – an easy-to-use web application for thermodynamic modeling of cementitious materials CemGEMS–一个易于使用的web应用程序,用于胶结材料的热力学建模
Q2 Engineering Pub Date : 2021-06-08 DOI: 10.21809/RILEMTECHLETT.2021.140
D. Kulik, F. Winnefeld, A. Kulik, G. Miron, B. Lothenbach
Thermodynamic equilibrium calculations for cementitious materials enable predictions of stable phases and solution composition. In the last two decades, thermodynamic modelling has been increasingly used to understand the impact of factors such as cement composition, hydration, leaching, or temperature on the phases and properties of a hydrated cementitious system. General thermodynamic modelling codes such as GEM-Selektor have versatile but complex user interfaces requiring a considerable learning and training time. Hence there is a need for a dedicated tool, easy to learn and to use, with little to no maintenance efforts. CemGEMS (https://cemgems.app) is a free-to-use web app developed to meet this need, i.e. to assist cement chemists, students and industrial engineers in easily performing and visualizing thermodynamic simulations of hydration of cementitious materials at temperatures 0-99 °C and pressures 1-100 bar. At the server side, CemGEMS runs the GEMS code (https://gems.web.psi.ch) using the PSI/Nagra and Cemdata18 chemical thermodynamic data-bases (https://www.empa.ch/cemdata). The present paper summarizes the concepts of CemGEMS and its template data, highlights unique features of value for cement chemists that are not available in other tools, presents several calculated examples related to hydration and durability of cementitious materials, and compares the results with thermodynamic modelling using the desktop GEM-Selektor code.
胶凝材料的热力学平衡计算能够预测稳定相和溶液成分。在过去的二十年里,热力学建模越来越多地用于了解水泥成分、水化、浸出或温度等因素对水化胶凝系统相和性能的影响。GEM Selektor等通用热力学建模代码具有通用但复杂的用户界面,需要大量的学习和培训时间。因此,需要一种易于学习和使用、几乎不需要维护的专用工具。CemGEMS(https://cemgems.app)是一款免费使用的web应用程序,旨在满足这一需求,即帮助水泥化学家、学生和工业工程师在0-99°C温度和1-100巴压力下轻松执行和可视化胶结材料水化的热力学模拟。在服务器端,CemGEMS运行GEMS代码(https://gems.web.psi.ch)使用PSI/Nara和Cemdata18化学热力学数据库(https://www.empa.ch/cemdata)。本文总结了CemGEMS的概念及其模板数据,强调了水泥化学家在其他工具中无法获得的独特价值特征,给出了几个与胶凝材料水化和耐久性相关的计算实例,并将结果与使用桌面GEM Selektor代码的热力学建模进行了比较。
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引用次数: 14
Opportunities and challenges for engineering construction materials as carbon sinks 工程建筑材料作为碳汇的机遇与挑战
Q2 Engineering Pub Date : 2021-01-01 DOI: 10.21809/rilemtechlett.2021.146
Sabbie A. Miller, Elisabeth Van Roijen, P. Cunningham, Alyson Kim
Population growth and urbanization over the coming decades are anticipated to drive unprecedented demand for infrastructure materials and energy resources. Unfortunately, factors such as the degree of resource consumption, the energy-intensive nature of production, and the chemical-reaction driven emissions make infrastructure materials production industries among the greatest contributors to anthropogenic CO2 emissions. Yet there is an often-overlooked potential environmental benefit to infrastructure materials: most remain in use for decades and their long service lives can facilitate extended storage of carbon. In this perspective, we present an overview of recent technological advancements that can support infrastructure materials acting as a global, distributed carbon sink and discuss areas for further research and development. We present mechanisms to quantify the extent to which the embodied carbon will be removed from the carbon cycle for a long enough period of time to provide carbon sequestration and climate benefit. We conclude that it is possible to unlock the vast potential to engineer a carbon sequestration system that simultaneously meets societal need for expanding infrastructure systems; however, complexities in how these systems are engineered must be systematically and quantitatively incorporated into materials design.
预计未来几十年的人口增长和城市化将推动对基础设施材料和能源资源的空前需求。不幸的是,诸如资源消耗程度、生产的能源密集型性质以及化学反应驱动的排放等因素使基础设施材料生产行业成为人为二氧化碳排放的最大贡献者之一。然而,基础设施材料有一个经常被忽视的潜在环境效益:大多数材料可以使用数十年,它们的长使用寿命可以促进碳的长期储存。从这个角度来看,我们概述了最近的技术进步,这些技术进步可以支持基础设施材料作为全球分布式碳汇,并讨论了进一步研究和开发的领域。我们提出了一种机制来量化碳在足够长的时间内从碳循环中去除的隐含碳的程度,以提供碳固存和气候效益。我们的结论是,有可能释放巨大的潜力来设计一个碳封存系统,同时满足扩大基础设施系统的社会需求;然而,这些系统工程的复杂性必须系统地和定量地纳入材料设计。
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引用次数: 5
Numerical simulation of multi-layer 3D concrete printing 多层3D混凝土打印的数值模拟
Q2 Engineering Pub Date : 2021-01-01 DOI: 10.21809/rilemtechlett.2021.142
J. Spangenberg, Wilson Ricardo Leal da Silva, R. Comminal, M. Mollah, Thomas Juul Andersen, H. Stang
This paper presents a computational fluid dynamics model fit for multi-layer 3D Concrete Printing. The numerical model utilizes an elasto-visco-plastic constitutive model to mimic the flow behaviour of the cementitious material. To validate the model, simulation data is compared to experimental data from 3D printed walls. The obtained results show that the numerical model can reproduce the experimental results with high accuracy and quantify the extrusion load imposed upon the layers. Such load is found to exceed the material’s yields stress in certain regions of previously printed layers, leading to layer deformation/flow. The developed and validated numerical model can assist in identifying optimal printing strategies, reducing the number of costly experimental print failures and human-process interaction. By doing so, the findings of this paper helps 3D Concrete Printing move a step closer to a truly digital fabrication process.
提出了一种适用于多层混凝土3D打印的计算流体力学模型。数值模型采用弹粘塑性本构模型模拟胶凝材料的流动行为。为了验证模型,将仿真数据与3D打印墙体的实验数据进行了比较。结果表明,该数值模型能较好地再现实验结果,并能量化施加在各层上的挤压载荷。在先前打印层的某些区域,发现这种载荷超过了材料的屈服应力,导致层变形/流动。开发和验证的数值模型可以帮助确定最佳的打印策略,减少昂贵的实验打印失败和人机交互的数量。通过这样做,本文的发现有助于3D混凝土打印向真正的数字制造过程迈进一步。
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引用次数: 15
Pavement energy harvesting technologies: a critical review 路面能量收集技术综述
Q2 Engineering Pub Date : 2021-01-01 DOI: 10.21809/rilemtechlett.2021.131
D. Vizzari, E. Gennesseaux, Stéphane Lavaud, Stéphane Bouron, E. Chailleux
The world energy consumption is constantly increasing and the research point towards novel energy harvesting technologies. In the field of pavement engineering, the exploitable sources are the solar radiation and the vehicle load. At present, these systems are able to convert the sunlight into electricity thanks to some solar cells placed under a semi-transparent layer (photovoltaic roads), or they can harvest thermal heat by means of solar thermal systems. The thermal gradient of the pavement can be exploited by thermoelectric generators, by heat pipes or by heat-transfer fluids (i.e. water) pumped into a medium (asphalt solar collectors, porous layer or air conduits). The traffic load can be exploited by piezoelectric materials, able to convert the vehicle load into an electrical charge. The aim of this paper is to describe the main pavement energy harvesting technologies, pointing out positives and negatives and providing indications for further optimizations. Finally, the systems are compared in terms of initial cost, electrical output, efficiency and technology readiness level.
世界能源消耗不断增加,新的能源收集技术成为研究的热点。在路面工程领域,可利用的辐射源是太阳辐射和车辆荷载。目前,这些系统能够将阳光转化为电能,这要归功于放置在半透明层(光伏道路)下的一些太阳能电池,或者它们可以通过太阳能热系统收集热能。路面的热梯度可以通过热电发电机、热管或将传热流体(即水)泵入介质(沥青太阳能收集器、多孔层或空气导管)来利用。压电材料可以利用交通载荷,将车辆载荷转化为电荷。本文的目的是描述主要的路面能量收集技术,指出其优点和缺点,并为进一步优化提供指示。最后,从初始成本、电力输出、效率和技术就绪水平等方面对系统进行了比较。
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引用次数: 15
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RILEM Technical Letters
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