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Effect of Ca/Fe additives on the serial reactions of coke and sinter with CO2 Ca/Fe添加剂对焦炭和烧结矿与CO2串联反应的影响
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023005
Zhang Sun, Jiawei Han, Yang Sun, Minghui Dou, Rui Guo, Ying-hua Liang
To investigate the effect of Ca/Fe additives on the coke-sinter serial reaction with CO2, the serial reactions of the high-reactivity cokes with Ca/Fe additives and sinter were studied. The results showed that the Ca/Fe additives promote the coupling degree of sinter-coke serial reaction. The reduction degree of sinter has a linear correlation with the carbon loss ratio of coke, and the intercept (b) and slope (k) obtained from the fitting linear function are used to characterize the serial reaction. The intercept (b) increases with the carbon loss ratio of coke derived from CRI, which indicated that b value can represent the intrinsic ability of coke to reduce oxygen atom in iron ore. The slope (k) decreases with the increase of carbon loss ratio of coke, and k value can characterize the matching degree of the sinter-coke serial reaction. Also, the Ca/Fe additives lower the OTI index of cokes, and the solution-loss reactions are easy to take place on the surface of the high-reactivity cokes. The Ca additive has more effect on the large pore evolution of coke structures during reaction than the Fe additive. Therefore, the Ca additive has more catalytic activity than the Fe additive, and the high-reactivity coke should be mixed with the high-reducibility ore to get higher efficiency of blast furnace.
为了研究Ca/Fe添加剂对焦炭-烧结体与CO2的串联反应的影响,研究了高活性焦炭与Ca/Fe添加剂和烧结体的串联反应。结果表明,Ca/Fe添加剂提高了烧结-焦炭串联反应的耦合度。烧结矿的还原程度与焦炭的碳损失率呈线性相关,用拟合的线性函数得到的截距(b)和斜率(k)来表征串联反应。截距(b)随炭损比的增大而增大,说明b值可以表征焦炭还原铁矿石中氧原子的内在能力。斜率(k)随炭损比的增大而减小,k值可以表征烧结-焦炭串联反应的匹配程度。此外,Ca/Fe添加剂降低了焦炭的OTI指数,并且易于在高活性焦炭表面发生溶损反应。在反应过程中,Ca对焦炭大孔结构演化的影响大于Fe。因此,Ca添加剂比Fe添加剂具有更高的催化活性,高反应性焦炭应与高还原性矿石混合使用,以获得更高的高炉效率。
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引用次数: 0
Oxidation behavior of vanadium and phosphorus during simultaneous vanadium extraction and dephosphorization of hot metal 铁水同时提钒脱磷过程中钒磷的氧化行为
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023059
J. Diao, Cancan Yu, Liyuan Jiang, Jing Lei, Lian Chen, Hong-Yi Li, B. Xie
In this paper, the indirect equilibrium method was used to study the equilibrium distribution ratios of vanadium and phosphorus in the metal phase and the slag phase, and simultaneous vanadium extraction and dephosphorization experiments were carried out under different slag basicity (the mass ratio of CaO to SiO2) conditions to explore the oxidation behavior of vanadium and phosphorus during simultaneous vanadium extraction and dephosphorization of hot metal. The results show that with the increase of slag basicity, the equilibrium distribution ratio of V (lgLV) increases slightly and the equilibrium distribution ratio of P (lgLP) increases significantly. With slag basicity increasing from 0.5 to 2.5, lgLV and lgLP increase from 1.7 to 2.0 and 0.1 to 1.9, respectively. Both lgLV and lgLP decrease with the increase of temperature, and increase with the increase of FeO content. High MgO content is not conducive to vanadium extraction. MnO has less effect on lgLV and lgLP. lgLV increases with the increase of V2O3 content, and decreases with the increase of P2O5 content. lgLP decreases with the increase of V2O3 content, and increases with the increase of P2O5 content. Both lgLV and lgLP decrease with the increase of TiO2 content. When the slag basicity is 1.5, the oxidation rate of vanadium reaches 95% after 10 min of reaction. The total mass transfer coefficient of P is in the range of 0.0040–0.0084 cm/s, and increases obviously with the increase of slag basicity. However, the influence of slag basicity on the total mass transfer coefficient of V is not obvious. Both the rate-limiting step of vanadium extraction and dephosphorization are the mixed mass transfer in the metal phase and the slag phase.
本文采用间接平衡法研究了钒磷在金属相和渣相中平衡分布比,并进行了不同渣碱度(CaO / SiO2质量比)条件下的同时提钒脱磷实验,探讨了铁水同时提钒脱磷过程中钒磷的氧化行为。结果表明:随着渣碱度的增加,V (lgLV)平衡分配比略有增加,P (lgLP)平衡分配比显著增加;随着矿渣碱度从0.5增加到2.5,lgLV和lgLP分别从1.7和0.1增加到2.0和1.9。lgLV和lgLP均随温度的升高而降低,随FeO含量的增加而升高。MgO含量高不利于钒的提取。MnO对lgLV和lgLP的影响较小。lgLV随V2O3含量的增加而增大,随P2O5含量的增加而减小。lgLP随V2O3含量的增加而减小,随P2O5含量的增加而增大。lgLV和lgLP随TiO2含量的增加而降低。当炉渣碱度为1.5时,反应10min后钒的氧化率达到95%。P的总传质系数在0.0040 ~ 0.0084 cm/s之间,随矿渣碱度的增加而明显增大。而矿渣碱度对V总传质系数的影响不明显。提钒和脱磷的限速步骤都是金属相和渣相的混合传质。
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引用次数: 0
Reducing effect of biomass derived char on iron ore fines; a statistical investigation and regression modelling 生物质衍生炭对铁矿粉的还原作用统计调查和回归模型
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022060
S. Sahoo, Subhabrata Mishra, S. N. Sahu, M. Sahoo, S. Soren
India is an economically developing country. Country’s development and growth is largely interlinked with iron and steel industry as well as availability of energy and its utilization. Energy sector and iron and steel industry mainly consumes convectional and fossil fuel like coal and gas. Present coal reserves of India will last for about 30-40 years at present consumption rate. Consumption of conventional fuels is not economically feasible and environment friendly. Biomass can be an alternative source of fuel for numerous engineering and scientific applications. The char derived from biomass known as biochar can be utilized in the iron and steel-making processes. It can lessen the coke consumption rate and subsequently reduce pollution as well as cost economics. Utilization of low and lean grade iron ore is need of the hour. Removal of gangue impurities from lean and low-grade iron ore is difficult through convectional beneficiation process. The reduction roasting process can be adopted to counter these challenges. The present study focuses on the reduction behavior of iron ore using three various biochar derived from three biomass, viz; wood dust, sugarcane bagasse and coconut shell. A single factorial Design of Experiment with two levels and three variables was adopted and a first-order regression equation was generated to estimate the degree of reduction. The Student’s T-test and Fisher test were performed to validate the regression equation. The obtained results showed that the biochar can be used as a substitute reductant. However, the residence time and temperature play a vital role in the reduction process. The obtained regression equation also validates the effect of residence time and temperature on the reduction process.
印度是一个经济发展中国家。国家的发展和增长在很大程度上与钢铁工业以及能源的供应和利用密切相关。能源行业和钢铁行业主要消耗煤炭、天然气等传统燃料和化石燃料。按照目前的消费速度,印度现有的煤炭储量大约可以维持30-40年。使用传统燃料既不经济也不环保。生物质能是众多工程和科学应用的替代燃料来源。从生物质中提取的炭被称为生物炭,可用于炼铁和炼钢过程。它可以降低焦炭的消耗率,从而减少污染,并具有成本经济性。利用低贫品位铁矿石是当务之急。对贫、低品位铁矿进行常规选矿是去除脉石杂质的难点。可以采用还原焙烧工艺来应对这些挑战。本研究的重点是利用来自三种生物质的三种不同的生物炭对铁矿石的还原行为,即;木屑,甘蔗渣和椰子壳。采用双水平三变量单因子试验设计,生成一阶回归方程估计降低程度。采用Student’s t检验和Fisher检验对回归方程进行验证。实验结果表明,生物炭可以作为一种替代还原剂。然而,停留时间和温度对还原过程起着至关重要的作用。得到的回归方程也验证了停留时间和温度对还原过程的影响。
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引用次数: 0
The quantitative model of hearth activity based on data mining and characteristics of deadman 基于数据挖掘的炉膛活动性定量模型及炉膛活动性特征
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023002
Yong Deng, Ran Liu, Tao Li, Ke-xin Jiao, Sai Meng, Ziyi Guo
In order to obtain the quantitative model of hearth activity, the key control parameters of hearth activity were mined based on big data technology, the distribution characteristics of slag-iron-coke in deadman and the change of voidage in deadman were analyzed, and then the quantitative model of hearth activity was constructed. The results show that a temperature ratio was selected as the characterization parameter of hearth activity combined with some manifestations when the hearth activity became poor, through data sensitivity analysis. Blast speed, average particle size of coke, binary basicity of slag and Ti in iron were preliminarily selected as the key control parameters based on data correlation. The distribution of slag-iron-coke in hearth showed that the average particle size, CSR of coke and the fluidity of slag iron were very important for hearth activity. The coke particle size and the blast momentum should be given priority consideration according to the voidage of deadman in hearth. Finally, the quantitative model of hearth activity was constructed, the accuracy of the model was verified through the data of a commercial BF, so the hearth activity of any BF can be calculated by substituting the known production data of BF.
为获得炉膛活度定量模型,基于大数据技术挖掘炉膛活度关键控制参数,分析炉膛内钢渣-铁-焦的分布特征及炉膛内空隙率的变化,构建炉膛活度定量模型。结果表明,通过数据敏感性分析,结合炉膛活度变差时的一些表现,选择一个温度比作为炉膛活度的表征参数。在数据关联的基础上,初步选择了鼓风速度、焦炭平均粒度、炉渣二元碱度和铁中Ti作为关键控制参数。炉膛内铁渣-焦炭的分布表明,平均粒度、焦炭的CSR和铁渣的流动性对炉膛活性有重要影响。根据炉膛空腔的大小,应优先考虑焦炭的粒度和鼓风动量。最后,建立了炉底活度的定量模型,并通过某工业高炉的生产数据验证了模型的准确性,从而可以用已知的高炉生产数据代入计算任意高炉的炉底活度。
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引用次数: 0
Investigation of electrode pressure parameter on mechanical properties and microstructural characteristics of spot welded DP800 steel joints 电极压力参数对DP800钢点焊接头力学性能和显微组织特征的影响
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022014
C. Rajarajan, P. Sivaraj, S. Raja, V. Balasubramanian
This investigation details the effect of electrode pressure on mechanical behavior and microstructural characteristics of Resistance Spot Welded (RSW) DP800 steel joints. The joints were fabricated for the range of 0.35–0.45 MPa electrode pressure. Tensile Shear Fracture Load (TSFL) and Cross Tensile Shear Fracture Load (CTSFL) recorded a maximum of 20.06 kN and 16.53 kN respectively for the joints. The hardness map revealed that the heat affected zone has lower hardness among other zones due to the presence of coarser grains. The Nugget Zone (NZ) microstructure consists of lath/needle-like martensite structures. The confirmed crystallography planes and intermetallics in the weld and nearer regions correspond to [101]α/, [200]γ, and cementite (Fe3C), manganese carbide (Mn3C). The above results concluded that the electrode pressure played a significant role in controlling the quality and integrity of the RSW joints.
研究了电极压力对DP800电阻点焊(RSW)钢接头力学性能和显微组织特性的影响。电极压力为0.35 ~ 0.45 MPa。张剪断裂载荷(TSFL)和交叉张剪断裂载荷(CTSFL)最大分别为20.06 kN和16.53 kN。硬度图显示,由于晶粒粗,热影响区硬度较低。熔核区(NZ)组织由板条状/针状马氏体组织组成。焊缝及邻近区域的晶相和金属间化合物分别为[101]α/、[200]γ和渗碳体(Fe3C)、碳化锰(Mn3C)。以上结果表明,电极压力对RSW接头的质量和完整性起着重要的控制作用。
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引用次数: 0
Study on microstructure, phase transformation behavior of T15 high-speed steel and the effect of adding REEs T15高速钢组织、相变行为及稀土元素添加效果的研究
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022082
B. Zhao, Min Xia, C. Ge
Rare earth elements (REEs) are a vital modifier in tool & die steel. Their effects on the phase transformation behavior, microstructure characteristics and property of as-cast T15 high-speed steel (HSS) were investigated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffractometry (XRD), differential scanning calorimetry (DSC) and dilatometry. The experimental results show that the as-cast microstructure of samples is refined and ameliorated after adding REEs, and the total quantity of eutectic carbides with hard and brittle properties is significantly reduced, which contribute to lower Rockwell hardness levels and higher bending strength. The morphology of grain boundaries carbides turns from lamellar to blocky polygonal. During the reheating process, REEs can reduce the thermal expansion coefficient of studied steel before austenitizing and promote the dissolution of alloying elements into austenite matrix. During cooling, REEs delays the occurrence of phase transformation, but it is favorable to the increase of the expansion amount of martensite transformation. Additionally, the microhardness value also increases with the increase of cooling rate. When the cooling rate is 20 °C/s, the full martensite transformation will occur and the microhardness of HSS1 reaches the maximum value of HV738, greater than that of RE-free HSS0 (HV701).
稀土元素是工具模具钢中重要的改性剂。采用光学显微镜(OM)、扫描电镜(SEM)、x射线衍射仪(XRD)、差示扫描量热仪(DSC)和膨胀法研究了它们对铸态T15高速钢(HSS)相变行为、显微组织特征和性能的影响。结果表明:稀土元素的加入改善了铸态组织,显著减少了具有硬脆性能的共晶碳化物总量,降低了合金的洛氏硬度,提高了合金的抗弯强度;晶界碳化物的形貌由片层状变为块状多边形。在再加热过程中,稀土元素可以降低研究钢在奥氏体化前的热膨胀系数,促进合金元素在奥氏体基体中的溶解。在冷却过程中,稀土元素延缓了相变的发生,但有利于马氏体相变膨胀量的增加。显微硬度值也随冷却速率的增大而增大。当冷却速度为20℃/s时,HSS1发生完全马氏体转变,显微硬度达到最大值HV738,大于无re的HSS0 (HV701)。
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引用次数: 0
Evolution of inclusions in the whole process of GCr15 bearing steel GCr15轴承钢加工全过程夹杂物演化
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023029
Lidong Xing, Y. Bao, Min Wang
Inclusions have an important effect on the fatigue performance of bearing steels. Therefore, the study of the evolution of inclusions in the whole process and the reasonable control of inclusions (quantity, type, size, etc.) in steel can improve the production stability and fatigue performance of bearing steel. In this study, with the help of thermodynamic calculations and experimental studies, the evolution of the whole-process refining slag, oxygen and nitrogen content, and inclusions in bearing steel produced in a plant is systematically investigated. Overall, the refining slag composition of the refining process fluctuates less, and the oxygen content during LF refining and RH refining has been trending down, with an oxygen content of 5.7 × 10‒6 in the bearing steel billets. Although the cleanliness level is good for bearing steels, there is still room for improvement in refining slag composition, refining time, protected casting, and cut waste length.
夹杂物对轴承钢的疲劳性能有重要影响。因此,研究钢中夹杂物在整个过程中的演化规律,合理控制钢中夹杂物(数量、类型、尺寸等),可以提高轴承钢的生产稳定性和疲劳性能。本文采用热力学计算和实验研究相结合的方法,系统研究了某轴承钢生产过程中精炼渣、氧、氮含量及夹杂物的演变规律。总体而言,精炼过程中精炼渣成分波动较小,LF精炼和RH精炼过程中氧含量呈下降趋势,轴承钢坯中氧含量为5.7 × 10-6。虽然轴承钢的洁净度水平较好,但在精炼渣成分、精炼时间、保护铸造、切割废料长度等方面仍有改进的余地。
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引用次数: 1
Hot deformation behavior and comparison of different constitutive models of as-cast ER8 steel 铸态ER8钢热变形行为及不同本构模型的比较
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023046
Fei Chen, Zhen Jia, Xiaofeng Zhang, Y. Jiao, Fei Li, Xuezhong Zhang
To facilitate the numerical simulation of plastic deformation and the determination of thermal deformation process parameters of as-cast ER8 steel, isothermal thermal compression test of ER8 steel was carried out, and the flow stress curves of ER8 steel at high temperature was obtained. The selected deformation temperature was 1173–1523 K and strain rate was 0.001–0.1 s−1. On this basis, three different constitutive models were established and compared. The results show that the flow stress curves of ER8 steel can be divided into two stages, namely work hardening-dynamic recovery stage and dynamic recrystallization stage. The traditional Fields-Backofen model was modified to predict the flow stress at different deformation temperatures. According to the error analysis, the AARE levels of the modified Fields-Backofen model and the strain-coupled constitutive model are the same, while the AARE of the physically‑based constitutive model are smaller. The modified Fields-Backofen model cannot reflect the softening of dynamic recrystallization on the flow stress curves during high temperature deformation, while the strain-coupled constitutive model and the physically‑based constitutive model can. In terms of modeling difficulty, the modified Fields-Backofen model is the easiest to model, followed by the strain-coupled constitutive model, while the physically‑based constitutive model is relatively complex to model.
为了便于对铸态ER8钢塑性变形进行数值模拟和热变形工艺参数的确定,对ER8钢进行了等温热压缩试验,得到了ER8钢在高温下的流变应力曲线。变形温度为1173 ~ 1523 K,应变速率为0.001 ~ 0.1 s−1。在此基础上,建立并比较了三种不同的本构模型。结果表明,ER8钢的流变应力曲线可分为两个阶段,即加工硬化-动态恢复阶段和动态再结晶阶段。对传统的field - backofen模型进行了修正,以预测不同变形温度下的流变应力。误差分析表明,修正field - backofen模型与应变耦合本构模型的AARE水平相同,而基于物理的本构模型的AARE更小。修正的Fields-Backofen模型不能反映高温变形过程中动态再结晶软化对流变应力曲线的影响,而应变耦合本构模型和基于物理的本构模型能反映动态再结晶软化对流变应力曲线的影响。在建模难度方面,修正的field - backofen模型最容易建模,其次是应变耦合本构模型,而基于物理的本构模型相对复杂。
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引用次数: 0
Effect of rotational speed and copper interlayer on the mechanical and fracture behaviour of friction stir spot welds of 5754 aluminium alloy 转速和铜夹层对5754铝合金搅拌摩擦点焊力学性能和断裂行为的影响
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023014
R. Gassaa, L. Hemmouche, R. Badji, L. Gilson, L. Rabet, O. Mimouni
The application of joining processes requires advanced mechanical tests to control the joints’ quality. Generally, welded sheets are verified using tensile shear tests. However, few studies also recommend conducting tension peel and cross-tension tests. The present work evaluates the mechanical behaviour of 5754 aluminium sheets jointed by friction stir spot welding (FSSW). The influence of the rotational speed on joint strength was first compared to riveted assemblies. Then, sheets welded with pure copper interlayers were compared to the precedents. The results indicated that, without an interlayer, lower and intermediate rotational speeds lead to higher mechanical strength under tensile shear tests compared to riveted assembly. However, it performed worse under tension peel and cross-tension tests at all studied rotational speeds. By adding copper, the strength of welded sheets is globally improved under tensile shear tests. Nevertheless, under tension peel and cross-tension tests, it performed worse, although a slight improvement was observed for increasing rotational speeds. Two different failure morphologies and four fracture modes were observed regarding the different tested samples. Microhardness tests were also conducted, to relate the influence of the studied parameters on the joint’s strength.
连接工艺的应用需要先进的机械测试来控制连接的质量。一般来说,焊接板是用拉伸剪切试验来验证的。然而,很少有研究也建议进行张力剥离和交叉张力试验。本文研究了5754铝板搅拌摩擦点焊的力学性能。首先将转速对接头强度的影响与铆接组件进行了比较。然后,将纯铜夹层焊接板与以往的焊接板进行了比较。结果表明,与铆接组件相比,在没有中间层的情况下,较低和中等转速的组件在拉伸剪切试验中的机械强度更高。然而,在所有研究的转速下,它在张力剥离和交叉张力试验中表现较差。在拉伸剪切试验中,铜的加入使焊接板的强度得到全面提高。然而,在张力剥离和交叉张力测试中,它的表现更差,尽管在增加转速时观察到轻微的改善。在不同的试样中观察到两种不同的破坏形态和四种断裂模式。并进行了显微硬度测试,以了解所研究参数对接头强度的影响。
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引用次数: 0
Research progress and prospect of friction stir welding of copper and copper alloys 铜及铜合金搅拌摩擦焊的研究进展与展望
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023011
Yu-meng Sun, W. Gong, Rui-xiang Zhu, Yupeng Li, Shicheng Sun
Copper and copper alloys are widely used in various industries due to the excellent properties, and they are indispensable materials in modern industrial fields. At present, friction stir welding technology is the most promising welding method for copper and copper alloys, and there have been a series of studies on copper and copper alloys FSW field. This paper summarizes the research achievements in this field in the past 30 years, and aims to provide a comprehensive and systematic summary for researchers in this field. In addition, combined with the authors team’s research and experience in this field and existing relevant references, we point out the development direction of this field in the next stage.
铜及铜合金因其优异的性能被广泛应用于各个工业领域,是现代工业领域中不可缺少的材料。目前,搅拌摩擦焊技术是铜及铜合金最有前途的焊接方法,在铜及铜合金搅拌摩擦焊领域已经开展了一系列的研究。本文总结了近30年来该领域的研究成果,旨在为该领域的研究人员提供一个全面、系统的总结。此外,结合作者团队在该领域的研究和经验以及现有的相关文献,指出了该领域下一阶段的发展方向。
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引用次数: 1
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Metallurgical Research & Technology
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