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Numerical simulation and operation optimization for billet heating in disc reheating furnace based on grey correlation 基于灰色关联的圆盘式加热炉钢坯加热数值模拟及操作优化
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023060
Ji-min Wang, X. Chen
To further promote the equipment improvement of reheating furnaces in iron and steel production, considering heating movement and oxidation loss for the billet in 40 tons/hour self-designed disc reheating furnace, a comprehensive CFD model is established through the dynamic mesh technology with UDF subroutines. The billet heating process in the disc reheating furnace is numerically simulated to explore the dynamic heating characteristics of the billet in the disc reheating furnace. According to the orthogonal design, the grey correlation method is used to optimize the operation parameters such as the oxygen concentration, the charging temperature, the air preheated temperature, and the rotation speed. The results show the discharging temperature increases as the charging temperature, the oxygen concentration, or the air preheated temperature, and yet reduces with the rotation speed, which is opposite to the temperature difference. The important order is successively the oxygen concentration, the rotation speed, the air preheated temperature, and the charging temperature. The charging temperature has little effect on oxidation weight, while the oxygen concentration is obvious. It is of great significance for the current heat treatment of steel to increase efficiency, save cost, lower energy consumption, reduce pollutant emissions, and improve the automation application.
为进一步促进钢铁生产中加热炉的设备改进,考虑自行设计的40吨/小时盘式加热炉钢坯的加热运动和氧化损失,通过动态网格技术和UDF子程序建立了全面的CFD模型。对钢坯在圆盘式加热炉内的加热过程进行了数值模拟,探讨了钢坯在圆盘式加热炉内的动态加热特性。根据正交设计,采用灰色关联法对氧浓度、进料温度、空气预热温度、转速等操作参数进行优化。结果表明:放电温度随充料温度、氧气浓度和空气预热温度的升高而升高,随转速的增加而降低,与温差相反;重要的顺序依次是氧气浓度、转速、空气预热温度、装料温度。充装温度对氧化量影响不大,而氧浓度对氧化量影响明显。对当前钢材热处理提高效率、节约成本、降低能耗、减少污染物排放、提高自动化应用具有重要意义。
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引用次数: 0
Hot ductility improvement of copper-arsenic steel by rare earth cerium 稀土铈改善铜砷钢的热延展性
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022067
Yuyu Liang, Wen-bin Xin, Jing Zhang, Qingyang Meng, Yin-ju Jiang, Yong-chun Deng
The effect of Ce on hot ductility of Cu-As bearing steel in the temperature ranging from 700 to 1100 °C was investigated using Gleeble-3800 thermal-mechanical simulator. The hot ductility evaluation and fracture morphology observation showed that the hot ductility was obviously improved as Ce content increased from 0 to 0.0290 wt%. Detailed, the upper limit temperature of the ductility trough was decreased from 1057 to 765 °C, and the temperature corresponding to the minimum reduction of area was decreased from 850 to 750 °C. The fracture morphology was overall transformed from the dominantly intergraular brittle failure to the ductile failure characterized by the large and deep dimples. Analysis of metallographic, inclusions and grain boundary elements suggested that increasing Ce content inhibited the proeutectoid ferrite formation, which enhanced hot ductility of the steel bearing Cu and As. Moreover, the competitive grain boundary segregation of the solute Ce and As in steel with 0.0022 wt% Ce without arsenious rare earth inclusions decreased the quantity of As distributed at grain boundaries and thereby improved the hot ductility. When the Ce content reached 0.0290 wt%, a large number of arsenious rare earth inclusions were formed, and the grain boundary segregation of As was further decreased As, which was more beneficial to hot ductility than that with the lower Ce content in austenite single phase region.
采用Gleeble-3800热机械模拟器,研究了Ce在700 ~ 1100℃范围内对Cu-As轴承钢热塑性的影响。热延性评价和断口形貌观察表明,随着Ce含量从0 wt%增加到0.0290 wt%,热延性得到明显改善。塑性槽的上限温度从1057℃降低到765℃,与最小面积缩减温度对应的温度从850℃降低到750℃。断裂形态由以晶间脆性破坏为主转变为以大而深的韧窝为特征的延性破坏。金相、夹杂物和晶界元素分析表明,增加Ce含量抑制了原共析铁素体的形成,增强了含Cu和As钢的热塑性。此外,当Ce含量为0.0022 wt%时,不含砷稀土夹杂物的钢中溶质Ce和As的晶界竞争性偏析减少了晶界处分布的As数量,从而提高了热塑性。当Ce含量达到0.0290 wt%时,形成大量含砷稀土夹杂体,As的晶界偏析进一步减少,这比低Ce含量时在奥氏体单相区更有利于热塑性。
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引用次数: 0
Dissolution behaviour of lime in converter slag: evolution of morphology and ions migration 石灰在转炉炉渣中的溶解行为:形态演变和离子迁移
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023045
Shuai Tong, Chenxiao Li, Shuhuan Wang, L. Ai
The dissolution behaviour of lime in converter slag at 1300–1500 °C was studied, and the evolution of morphology and component ions migration under different dissolution time were examined. The results showed that with the increase of dissolution time, the lime surface changed from irregular to regular, and micropores and cracks were formed. The lime melting is a diffusion phenomenon, the slag promoted lime dissolution through these cracks and micropores, the mass transfer coefficient of Fe2+ in the boundary layer is the smallest, which is 5.4 × 10−7 cm/s, and the linear equation fitting the reaction rate constant versus temperature is ln vr = –24.43/T - 14.62. Moreover, the lime dissolution was a process of melting from outside to inside, layer by layer, the CaO-SiO2 complex phases were formed on the surface of lime and CaO-FeO complex phases were formed inside.
研究了石灰在转炉渣中1300 ~ 1500℃的溶解行为,考察了不同溶解时间下石灰的形貌演变和组分离子迁移。结果表明:随着溶解时间的延长,石灰表面由不规则变为规则,并形成微孔和裂纹;石灰熔融为扩散现象,炉渣通过这些裂纹和微孔促进石灰溶解,边界层中Fe2+的传质系数最小,为5.4 × 10−7 cm/s,反应速率常数随温度的线性方程为ln vr = - 24.43/T - 14.62。石灰的溶解是一个由外向内熔融的过程,石灰表面形成CaO-SiO2络合相,内部形成CaO-FeO络合相。
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引用次数: 0
Valuable metals recovery and vitrification of chromium-containing electroplating sludge 含铬电镀污泥有价金属回收及玻璃化处理
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022042
Hong-yang Wang, Yong Hou, Guo-hua Zhang, K. Chou
In this work, a two-stage process was developed to recover the valuable elements from chromium-containing electroplating sludge (CES). The low sulfur/carbon Fe-Si-Cr alloy containing 31.61%Fe, 31.78%Cr, 36.59%Si, 0.01%C and 0.01%S was produced, and the recovery extent of Cr reached 98.62%. The CES was pre-desulfurized at 1000–1200 ℃, and reaction between components CaSO4 and Fe2O3 in the CES to produce CaFe4O7 was the main desulfurization mechanism. The desulfurized CES was then reduced by silicon at 1600 ℃ to prepare the Fe-Si-Cr alloy, and the SiO2 generated from the silicothermic reduction helps the vitrification of the slag. The presence of silicon in alloys and the CaO in the slag are the key factors for the low content of sulfur in alloy. Adding CaO also helped to decrease the viscosity of slag, and thus reduced the metal loss by enhancing the slag-metal separation efficiency.
本文研究了一种从含铬电镀污泥(CES)中回收有价元素的两阶段工艺。制备出fe含量为31.61%、Cr含量为31.78%、si含量为36.59%、c含量为0.01%、s含量为0.01%的Fe-Si-Cr低硫碳合金,Cr的回收率达到98.62%。在1000 ~ 1200℃对铈进行预脱硫,铈中组分CaSO4与Fe2O3反应生成CaFe4O7是主要的脱硫机理。将脱硫后的ce在1600℃下用硅还原制得Fe-Si-Cr合金,硅热还原生成的SiO2有利于渣的玻璃化。合金中硅的存在和炉渣中CaO的存在是导致合金中硫含量低的关键因素。CaO的加入还有助于降低炉渣的粘度,从而通过提高渣-金属分离效率来减少金属的损失。
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引用次数: 1
Effects of powder feeding rate on porosity and tensile strength of powder feeding laser welded Al-30wt.% B4C composite with the addition of Al powder 送粉速率对Al-30wt激光送粉焊接气孔率和抗拉强度的影响添加Al粉的% B4C复合材料
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023028
Yunjiang Li, G. Le, Xiaoxuan Pang, Jin-ru Luo, Jiqing Cai, Pengcheng Zhang
Al-B4C metal matrix composite is an advanced neutron absorption material. In order to obtain a wider application in spent nuclear fuel storage and transport, the welding technique is essential for Al-B4C composites. In this paper, powder feeding laser welding (PFLW) method was used to weld Al-30wt.% B4C composite. During the experiments, Al powder was used as the filler metal, the effects of powder feeding rate on porosity, neutron shielding ratio and tensile strength of the joints were investigated by using micro-CT (micro computed tomography), OM, SEM and TEM. It is found that PFLW has a significant weld porosity suppression effect, and a joint efficiency (UTS) of 87% is obtained in PFLW of Al-30wt.% B4C composite with the powder feeding rate of 1.2 g/min. The neutron shielding ratio of the joint reduced by 3% due to the volume ratio of AlB12C2 (a B-rich reaction product) reduced by 7.6% when the powder feeding rate is 1.2 g/min. The results illustrate the great potential of PFLW in welding Al-B4C composites.
Al-B4C金属基复合材料是一种先进的中子吸收材料。为了在乏燃料储存和运输中获得更广泛的应用,焊接技术是Al-B4C复合材料必不可少的技术。本文采用给粉激光焊接(PFLW)方法焊接Al-30wt。% B4C复合材料。实验过程中,采用Al粉末作为填充金属,采用显微ct、OM、SEM和TEM等分析手段研究了粉末加料速率对接头孔隙率、中子屏蔽率和抗拉强度的影响。结果表明,Al-30wt的PFLW具有明显的焊缝气孔抑制效果,接头效率(UTS)达到87%。% B4C复合材料,粉料加量为1.2 g/min。当粉末加料速度为1.2 g/min时,由于富b反应产物AlB12C2的体积比降低了7.6%,接头的中子屏蔽率降低了3%。结果表明PFLW在焊接Al-B4C复合材料方面具有巨大的潜力。
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引用次数: 0
Effect of B2O3 on the structure and properties of aluminate slag B2O3对铝酸盐渣组织和性能的影响
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022051
Chen Zhang, Yuran Kong, Ting Wu, Guang-da Bao, J. Lei, Hai-chuan Wang
The spectral experiment, hemispherical melting point apparatus, rotating cylinder method, and four-probe method are conducted to measure the structure, melting temperature, apparent viscosity and electrical conductivity of aluminate slag. The results show that in order to reduce the comprehensive effect of capacitance and inductance, the frequency of value 6000 Hz corresponding to the minimum impedance is most suitable for the electrical conductivity measurement. Higher B2O3 content leads to a lower degree of polymerization, symmetry, and uniformity in the complex three-dimensional structure of the slag, meanwhile the slag hemispheric temperature declines gradually, which enhances the slag superheat, hence decreases the apparent viscosity and increases the electrical conductivity comprehensively, as well as the relation between viscosity logarithm and the conductivity logarithm at 1300 °C was linear. The breaking temperature of apparent viscosity-temperature curve reduces gradually with B2O3 addition, while the conductivity-temperature curve indicate that the slag crystallized at about 1210 to 1224 °C, and with the lower B2O3 content, the crystallization trend is more obvious.
采用光谱实验、半球形熔点仪、旋转圆筒法和四探针法对铝酸盐渣的结构、熔化温度、表观粘度和电导率进行了测量。结果表明,为了减小电容和电感的综合影响,最小阻抗对应的频率为6000hz最适合进行电导率测量。B2O3含量越高,熔渣复杂的三维结构中聚合度、对称性和均匀性越低,同时熔渣半球温度逐渐下降,熔渣过热度增大,因此表观粘度降低,电导率全面提高,1300℃时粘度对数与电导率对数呈线性关系。随着B2O3的加入,表观粘温曲线的破碎温度逐渐降低,而电导率-温度曲线表明,渣在1210 ~ 1224℃左右结晶,且B2O3含量越低,结晶趋势越明显。
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引用次数: 5
Mechanical behaviour and microstructure evolution of wrought magnesium alloys under dynamic compression loading: a review 动态压缩载荷下变形镁合金的力学行为和微观组织演变研究进展
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023053
Yong-Hua Li, Bo Yin, Junhe Li
As one of the lightest structural metals, magnesium alloys have attracted enormous attention owing to its attributes of high specific strength and specific stiffness, superior damping capacity and shock absorbency and so on. The wide application fields of wrought magnesium alloys include aerospace, transportation, and so on. It is critical to understand the correlation between dynamic mechanical response and microstructure evolution of wrought magnesium alloys in stringent impact service environment. Split Hopkinson pressure bar has become the universal and common apparatus to investigate the dynamic compression mechanical behaviour of materials under impact loading state. The recent development of dynamic (high strain rate) compression mechanical behaviour and microstructure evolution of common wrought magnesium alloys are summarized in this paper. The research directions in the future are also suggested.
镁合金作为最轻的结构金属之一,因其具有高比强度和比刚度、优越的阻尼和减震能力等特性而受到广泛关注。变形镁合金的广泛应用领域包括航空航天、交通运输等。研究镁合金在严酷冲击工况下的动态力学响应与微观组织演变之间的关系至关重要。劈裂霍普金森压力杆已成为研究材料在冲击载荷状态下动态压缩力学行为的通用设备。本文综述了镁合金动态(高应变率)压缩力学性能和显微组织演变的研究进展。并提出了今后的研究方向。
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引用次数: 0
Formation mechanism of surface upwarping and black line defects on low carbon hot rolled plate 低碳热轧板表面翘起及黑线缺陷的形成机理
Pub Date : 1900-01-01 DOI: 10.1051/metal/2023051
Shuo Zhao, Jingcai Lyu, Gaoyang Song, Jianfeng Wang, Dong Xu, Zushu Li
To improve the surface quality of low-carbon hot-rolled steel plates, the upwarping and black line defects were investigated by means of XRF (X-ray diffractometer), OM (optical microscopy), SEM (scanning electron microscopy) and EBSD (electron back scatter diffraction). The results showed that the micro area compositions under surface upwarping and black line defects were mainly made of secondary oxide particles, steelmaking slag and mould flux respectively. According to the metallographic structure, inclusion compositions and grains texture analysis, it could be concluded that surface defects on hot rolled plates were attributed to the entrapment of ladle slag or mould flux, gas bubbles, micro-cracks of casting slab in the steelmaking process, rolled-in scale and unreasonable sizing press rolling parameters during the rolling process, and the position and formation process of typical surface defects on hot rolled plates were discussed in detail. Finally, it concluded that the slag entrapment and solidification hook should be controlled during continuous casting.
为提高低碳热轧钢板的表面质量,采用x射线衍射仪(XRF)、光学显微镜(OM)、扫描电镜(SEM)和电子背散射衍射仪(EBSD)等分析手段,研究了低碳热轧钢板的上翘和黑线缺陷。结果表明:表面凸起和黑线缺陷下的微区成分主要由二次氧化颗粒、炼钢渣和结晶器助焊剂组成;根据金相组织、夹杂物成分和晶粒织构分析,得出了热轧板表面缺陷是由钢包渣或铸模助焊剂的夹带、炼钢过程中铸坯的气泡、微裂纹、轧制过程中轧入水皮和不合理的压轧参数造成的,并详细讨论了典型热轧板表面缺陷的位置和形成过程。最后得出连铸过程中应控制夹渣和凝固钩的结论。
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引用次数: 0
Preparation and oxidation behavior of novel CeO2/Y2O3-modified aluminide coatings on Ni using sol–gel derived/pack cementation process 溶胶-凝胶/充填胶结法制备新型CeO2/ y2o3改性铝化物涂层及其氧化性能
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022073
Baisen Chen, J. Meng, Zhihui Chen, Chenfan Hao, Chengshuo Li, Xiaoping Shi, Yuebo Zhou
CeO2/Y2O3-modified aluminide coatings were prepared on Ni substrate using a sol–gel derived/pack cementation process. For comparison, simple aluminide coatings were also produced on Ni substrate using the same pack cementation process. The microstructure and high temperature oxidation behavior of three aluminide coatings at 900 °C for 50 h in air were comparably analyzed using SEM/EDS and XRD. The results indicated that both CeO2/Y2O3-modified aluminide coatings exhibited better oxidation resistance than the CeO2/Y2O3-free one, because of various effects of CeO2/Y2O3 on the oxidation including the grain refinement effect of the aluminide, the “reactive element effect”(REE) and the epitaxial template effect of Y2O3 to promote the growth of α-Al2O3.
采用溶胶-凝胶衍生/充填胶结工艺在Ni基体上制备了CeO2/ y2o3改性铝化物涂层。为了进行比较,采用相同的包覆胶结工艺在Ni基板上制备了简单的铝化物涂层。采用SEM/EDS和XRD对三种铝化物涂层900℃高温氧化50 h的微观结构和高温氧化行为进行了对比分析。结果表明,由于CeO2/Y2O3对氧化的多种影响,包括氧化铝的晶粒细化效应、活性元素效应(REE)和Y2O3的外延模板效应促进α-Al2O3的生长,CeO2/Y2O3修饰的氧化铝涂层都比无CeO2/Y2O3修饰的氧化铝涂层具有更好的抗氧化性能。
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引用次数: 0
Cause analysis of V-shaped crack pairs on drawn welding wire surface of ER70S-6 steel ER70S-6钢拉丝表面v形裂纹对原因分析
Pub Date : 1900-01-01 DOI: 10.1051/metal/2022070
Haitao Zhao, Shui-yong Wang, Junheng Gao, J. Qi, Ru Su, Hongqi Zhang, Hongwei Chen, Zhiqiang Tian, Lijuan Bai
Welding wires are widely used as electrodes in various welding processes. To produce welding wires, wire rods are drawn gradually to final diameters at welding wire manufacturers. During the wire drawing process, premature failure happens frequently due to various reasons, and a type of wire drawing failure originated from wire surface V-shaped cracks or so-called chevron-like cracks is often found. In this research, V-shaped cracks on drawn welding wire surfaces of ER70S-6 steel were characterised carefully and its underlying mechanism was discussed thoroughly. It was found that the V-shaped cracks on wire surfaces are often present in pairs with opposite directions. Martensite microstructure was found nearby the V-shaped cracks, and its formation can be attributed to deteriorated local lubrication during wire drawing, which causes the austenitization of the wire surface and the subsequent formation of martensite. The large friction on wire surface induces the development of V-shaped cracks along the drawing direction. Meanwhile, as martensite is difficult to deform, strain localization happens in the ferrite/pearlite matrix, and V-shaped strain localization areas were found around the martensite, leading to the development of V-shaped cracks in the opposite direction of the drawing direction.
焊丝作为电极广泛应用于各种焊接工艺中。为了生产焊丝,焊丝制造商将线材逐渐拉至最终直径。在拉丝过程中,由于各种原因,经常发生过早失效,经常发现一种由线材表面v形裂纹或所谓的线形裂纹引起的拉丝失效。本文对ER70S-6钢拉丝表面的v形裂纹进行了详细的表征,并对其产生的机理进行了深入的探讨。研究发现,金属丝表面的v型裂纹常成对相反方向出现。在v型裂纹附近发现了马氏体组织,其形成可归因于拉丝过程中局部润滑恶化,导致线材表面奥氏体化,随后形成马氏体。钢丝表面摩擦力大,沿拉伸方向产生v形裂纹。同时,由于马氏体不易变形,在铁素体/珠光体基体中发生应变局部化,在马氏体周围出现v形应变局部化区,导致与拉伸方向相反方向的v形裂纹发展。
{"title":"Cause analysis of V-shaped crack pairs on drawn welding wire surface of ER70S-6 steel","authors":"Haitao Zhao, Shui-yong Wang, Junheng Gao, J. Qi, Ru Su, Hongqi Zhang, Hongwei Chen, Zhiqiang Tian, Lijuan Bai","doi":"10.1051/metal/2022070","DOIUrl":"https://doi.org/10.1051/metal/2022070","url":null,"abstract":"Welding wires are widely used as electrodes in various welding processes. To produce welding wires, wire rods are drawn gradually to final diameters at welding wire manufacturers. During the wire drawing process, premature failure happens frequently due to various reasons, and a type of wire drawing failure originated from wire surface V-shaped cracks or so-called chevron-like cracks is often found. In this research, V-shaped cracks on drawn welding wire surfaces of ER70S-6 steel were characterised carefully and its underlying mechanism was discussed thoroughly. It was found that the V-shaped cracks on wire surfaces are often present in pairs with opposite directions. Martensite microstructure was found nearby the V-shaped cracks, and its formation can be attributed to deteriorated local lubrication during wire drawing, which causes the austenitization of the wire surface and the subsequent formation of martensite. The large friction on wire surface induces the development of V-shaped cracks along the drawing direction. Meanwhile, as martensite is difficult to deform, strain localization happens in the ferrite/pearlite matrix, and V-shaped strain localization areas were found around the martensite, leading to the development of V-shaped cracks in the opposite direction of the drawing direction.","PeriodicalId":370509,"journal":{"name":"Metallurgical Research & Technology","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129139474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Metallurgical Research & Technology
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