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Synthesis, Characterization, and Electrochemical Performance of Reduced Graphene Oxide-Metal (Cu,Zn)-Oxide Materials 还原氧化石墨烯-金属(Cu,Zn)-氧化物材料的合成、表征及电化学性能
Q1 Earth and Planetary Sciences Pub Date : 2023-03-10 DOI: 10.17509/ijost.v8i2.56065
S. sugianto, N. M. D. Putra, E. Rahayu, W. Widayatno, C. Firdharini, S. Priyono, D. Aryanto
The reduced graphene oxide (rGO) and metal (Cu,Zn)-oxide composites were prepared using a one-step hydrothermal technique. The role of (Cu,Zn)-oxide on the physical and electrochemical properties of the composite was investigated. The composite consists of various shapes of ZnO nanoflowers and micro-spheres, as well as Cu-oxide nanoflakes and octahedron-like shapes. The (Cu,Zn)-oxides were formed in between the rGO layers and observed in the rGO-ZnO, rGO-CuO, and rGO-CuO-ZnO composites. The presence of ZnO, CuO, and rGO within the composite structure is also confirmed by the analyses of crystal structure, microstructure, and surface functional groups. Some excess impurities remaining from the surfactant give considerable differences in the electrochemical performance of the composites. The specific capacitance values of the rGO, rGO-ZnO, rGO-CuO, rGO-(0.5CuO-0.5ZnO), and rGO-(0.25CuO-0.75ZnO) composites are 9.32, 58.53, 54.14, 25.21, and 69.27 F/g, respectively. The formation ofa double metal-oxide structure as well as their insertion into the rGO sheet can significantly improve the electrochemical properties of the supercapacitor.
采用一步水热法制备了还原氧化石墨烯(rGO)和金属(Cu,Zn)氧化物复合材料。研究了(Cu,Zn)-氧化物对复合材料物理和电化学性能的影响。该复合材料由各种形状的氧化锌纳米花和微球,以及氧化铜纳米片和八面体形状组成。在rGO- zno、rGO- cuo和rGO- cuo - zno复合材料中可以观察到(Cu,Zn)氧化物在rGO- zno层之间形成。通过晶体结构、微观结构和表面官能团的分析也证实了复合结构中存在ZnO、CuO和rGO。表面活性剂残留的一些多余杂质使复合材料的电化学性能产生相当大的差异。rGO、rGO- zno、rGO- cuo、rGO-(0.5CuO-0.5ZnO)和rGO-(0.25CuO-0.75ZnO)复合材料的比电容值分别为9.32、58.53、54.14、25.21和69.27 F/g。双金属氧化物结构的形成以及将其插入氧化石墨烯薄膜中可以显著改善超级电容器的电化学性能。
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引用次数: 0
Design of Robust Control for Vehicle Steer-by-Wire System 汽车线控转向系统鲁棒控制设计
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.54794
S. S. Husain, M. Q. Kadhim, A. Al-Obaidi, Alaq F. Hasan, A. Humaidi, Dwi Novia Al Husaeni
This study presented the design of a robust controller based on Integral Sliding Mode Control (ISMC) for controlling the Vehicle Steer-by-Wire (VSbW) system. The dynamic model of the VSbW system is first developed and then the design of ISMC has been conducted via the states of the system. The VSbW system has been described by two terms; one term represents the nominal model, which is free from nonlinearities, and the other term lumps the uncertainties in system parameters. The integral sliding mode controller has been designed for controlling the VSbW system. The control design consists of two parts. The first control part has addressed the nominal term of the system, while the second control part tackles and eliminates the effects of uncertainties and perturbation due to the uncertain term of the system. The numerical simulation has been conducted to show the robustness of ISMC and its capability to reduce the chattering effect in the control signal. In addition, a comparison study in performance has been conducted between the proposed controller and other controllers in the literature. We also carry out bibliometric analysis to see research trends. Based on our analysis, the number of publications regarding the keywords "controller", "steer", and "wire system" changes every year (25 (2018), 56 (2019), 51 (2020), 71 (2021), and 61 (2022)).
研究了基于积分滑模控制(ISMC)的汽车线控系统鲁棒控制器的设计。首先建立了VSbW系统的动力学模型,然后根据系统的状态进行ISMC的设计。VSbW系统用两个术语来描述;其中一项表示没有非线性的标称模型,另一项则集中了系统参数中的不确定性。设计了积分滑模控制器来控制VSbW系统。控制设计包括两个部分。第一个控制部分解决了系统的名义项,而第二个控制部分处理和消除了系统不确定项引起的不确定性和扰动的影响。数值仿真结果表明了ISMC的鲁棒性和抑制控制信号抖振效应的能力。此外,本文还对所提出的控制器与文献中其他控制器的性能进行了比较研究。我们还进行文献计量分析,以了解研究趋势。根据我们的分析,关于“控制器”、“转向”和“电线系统”等关键词的出版物数量每年都在变化(25篇(2018年)、56篇(2019年)、51篇(2020年)、71篇(2021年)和61篇(2022年))。
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引用次数: 6
Bifunctional CaCO3/HY Catalyst in the Simultaneous Cracking-Deoxygenation of Palm Oil to Diesel-Range Hydrocarbons 双功能CaCO3/HY催化剂在棕榈油裂解-脱氧制柴油烃类中的应用
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.55494
Rosyad Adrian Febriansyar, Teguh Riyanto, I. Istadi, D. Anggoro, B. Jongsomjit
Palm oil is a promising raw material for biofuel production using the simultaneous catalytic mechanism of the bifunctional cracking-deoxygenation reactions. Through the cracking-deoxygenation process, the chains of palmitic acid and oleic acid in the palm oil were converted to diesel-range hydrocarbons. The combination effects of CaCO3 and HY zeolite enhanced the bifunctional catalytic cracking-deoxygenation of palm oil into biofuel, because of the increasing acid and basic sites in the catalysts due to the synergistic roles of CaCO3 and HY. The introduction of CaCO3 on HY zeolite generated both a strong acid and strong basic sites simultaneously on the designed catalyst, which supports the bifunctional mechanisms of hybrid cracking-deoxygenation, respectively. The CaCO3 impregnated on the HY catalyst has a synergistic and bifunctional effect on the catalyst supporting cracking-deoxygenation reaction mechanisms as mentioned previously. The deoxygenation reaction required the bifunctional strong acid and strong basic sites on the CaCO3/HY catalyst through decarboxylation, decarbonylation, and hydrodeoxygenation reaction mechanisms. Meanwhile, the cracking reaction pathway was supported by the strong acid sites generated on the CaCO3/HY catalyst. In other words, the high acidity strength promotes diesel selectivity, whereas the high strength of basicity leads to the deoxygenation reaction.
棕榈油是利用双功能裂解-脱氧反应同时催化机制生产生物燃料的重要原料。通过裂解-脱氧过程,棕榈油中的棕榈酸链和油酸链转化为柴油级烃类。CaCO3和HY沸石的联合作用增强了棕榈油裂解-脱氧成生物燃料的双功能催化作用,这是因为CaCO3和HY的协同作用增加了催化剂中的酸和碱位点,在HY沸石上引入CaCO3同时在催化剂上产生了强酸和强碱位点,分别支持了混合裂解-脱氧的双功能机制。浸渍在HY催化剂上的CaCO3对支持裂化-脱氧反应机理的催化剂具有协同和双功能作用。该脱氧反应需要CaCO3/HY催化剂上的双官能团强酸和强碱位点通过脱羧、脱羰和加氢脱氧反应机制进行。同时,CaCO3/HY催化剂上生成的强酸位点支持了裂化反应途径。也就是说,高酸性强度促进柴油的选择性,而高碱性强度导致脱氧反应。
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引用次数: 0
Phytochemical Profile and Biological Activities of Ethylacetate Extract of Peanut (Arachis hypogaea L.) Stems: In-Vitro and In-Silico Studies with Bibliometric Analysis 花生乙酸乙酯提取物的植物化学特征及生物活性研究茎:体外和计算机研究与文献计量分析
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.54822
I. Sahidin, N. Nohong, M. Manggau, A. Arfan, W. Wahyuni, Iren Meylani, M. Malaka, Nurisma Rahmatika, A. W. Yodha, N. U. E. Masrika, A. Kamaluddin, A. Sundowo, S. Fajriah, Rathapon Asasutjarit, A. Fristiohady, Rina Maryanti, Nur Indri Rahayu, M. Muktiarni
The utilization of the stems, leaves, and hulls of peanuts (Arachis hypogea) is not as popular as the seeds. This study aimed to investigate the chemical contents and pharmacological activities of A. hypogaea stems in-vitro and in-silico. This study was also completed with bibliometric analysis. The methanol extract (ME) was reextracted by ethylacetate to get ethyl acetate extract (EAE). The chemical contents of EAE were analyzed by phytochemical screening, Liquid Chromatography-Mass Spectroscopy (LC-MS/MS), TPC (Total Phenolic Content), and TFC (Total Flavonoid Content). In-vitro and in-silico studies evaluated antioxidant potency, toxicity, and cytotoxicity toward MCF-7 cell lines. The results showed that EAE contained terpenoids, flavonoids, alkaloids, and phenolics which were supported by LC-MS/MS data. The EAE was categorized as a very strong antioxidant and moderately active in both cytotoxicity and toxicity.
花生(arachhis hypogea)的茎、叶和壳的利用不如种子受欢迎。本研究旨在研究金合欢茎的化学成分及体外和体外的药理活性。本研究亦以文献计量学分析完成。甲醇提取物(ME)经乙酸乙酯再萃取得到乙酸乙酯提取物(EAE)。采用植物化学筛选、液相色谱-质谱联用(LC-MS/MS)、总酚含量(TPC)、总黄酮含量(TFC)等方法对EAE的化学成分进行分析。体外和计算机研究评估了MCF-7细胞系的抗氧化能力、毒性和细胞毒性。结果表明,EAE中含有萜类、黄酮类、生物碱和酚类物质,与LC-MS/MS数据一致。EAE被归类为很强的抗氧化剂,在细胞毒性和毒性方面都具有中等活性。
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引用次数: 2
Technological Aptitude and Sensitivity of Lactic Acid Bacteria Leuconostoc Isolated from Raw Milk of Cows: From Step-by-Step Experimental Procedure to the Results 从奶牛原料乳中分离乳酸菌的技术倾向和敏感性:从一步一步的实验过程到结果
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.53730
Nora Hamdaoui, Y. Rokni, A. Asehraou, M. Mouncif, Z. Mennane, Abdelouadoud Omari, Asmae Sellam, B. Hammouti, M. Meziane
We demonstrated several technological aptitudes and sensitivity of lactic acid bacteria (Leuconostoc) isolated from the raw milk of cows. We explained the experiments in detail to get the reader to understand what kinds of technology can be used for testing bacteria. Lactic acid bacteria are used in the production of dairy products to increase their shelf life and improve their organoleptic and nutritional properties. Leuconostocs is a heterofermentative bacterium that produces lactic acid, acetic acid or ethanol, and carbon dioxide. A collection of 138 strains of lactic acid bacteria were isolated from the raw milk of cows in the region of eastern Morocco. 38 strains were identified as Leuconostocs. Their subspecies are 16 Mesenteroides, 11 Dextranicum, and 11 Cremoris. Our study was interested in the technological aptitude of this genus looking for the production of dextran and growth in milk with additional sunflower dye, as well as the acidifying, flavoring, thickening, coagulating, proteolytic activity in solid medium and Lipolytic activity. This work also consisted of studying the profile of the resistance and the sensitivity of these strains to antibiotics.
我们展示了从奶牛原料奶中分离的乳酸菌(Leuconostoc)的几种技术适应性和敏感性。我们对实验进行了详细的解释,以使读者了解哪些技术可用于测试细菌。乳酸菌用于乳制品的生产,以延长其保质期,改善其感官和营养特性。白菌是一种异发酵菌,能产生乳酸、乙酸或乙醇和二氧化碳。从摩洛哥东部地区的奶牛原料乳中分离到138株乳酸菌,其中38株为白乳酸菌(leuconostos)。它们的亚种有肠系膜虫16种,右旋虫11种,克雷莫虫11种。我们的研究对该属的技术能力感兴趣,寻找葡聚糖的生产和添加向日葵染料的牛奶中的生长,以及酸化,调味,增稠,凝固,固体培养基中的蛋白水解活性和脂肪水解活性。本工作还包括研究这些菌株对抗生素的耐药性和敏感性。
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引用次数: 0
e-book Multimedia Animation Implementation on Concept Mastery and Problem-Solving Skills of Crystal Structure Subjects in Engineering Materials Course 工程材料课晶体结构学科概念掌握与问题解决能力的多媒体动画实现
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.55320
Amay Suherman, M. Komaro, A. Ana
This research is motivated by students’ difficulties in understanding abstract, complex, and dynamic concepts in the learning process of the Engineering Materials course. The course is very important because it is indispensable for advanced study program expertise courses. The purpose of the research is to analyze the impact of using the e-book Multimedia Animation (e-MMA) in the learning process of engineering materials courses on improving students’ learning outcomes in the crystal structure subject. The research used an experimental method with a randomized control group pretest-posttest design. Two groups were assessed from two classes in Engineering Department randomly selected as the research sample. The subject that becomes the focus of this study is Crystal Structure to understand Concept Mastery and Problem-solving aspects. Thus, there will be two competency data from the research results. The application of e-MMA in the learning process of engineering materials can improve student learning outcomes with an increase in the high category N-gain. The E-MMA is very effective in solving the problems of students in understanding crystal structure subject in engineering materials courses because of their ability to provide images and animations of abstract objects. Students can easily understand the concepts and formulas that exist in the crystal structure subject of engineering materials course
本研究的动机是学生在工程材料课程的学习过程中难以理解抽象、复杂和动态的概念。该课程非常重要,因为它是高级学习计划专业课程不可缺少的。本研究的目的是分析在工程材料课程学习过程中使用电子多媒体动画(e-MMA)对提高学生晶体结构学科学习成果的影响。本研究采用随机对照组前测后测设计的实验方法。从工程学系两个班随机抽取作为研究样本进行两组评估。本研究的重点是晶体结构,以了解概念掌握和问题解决两个方面。因此,研究结果将产生两个胜任力数据。在工程材料学习过程中应用e-MMA可以提高学生的学习效果,并增加高类别n增益。E-MMA能够提供抽象物体的图像和动画,有效地解决了学生在工程材料课程中理解晶体结构的问题。学生可以很容易地理解工程材料晶体结构课程中存在的概念和公式
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引用次数: 1
Green Route Synthesis of Amorphous Silica from Oil Palm Decanter Cake: From Literature Review to Experiments 油棕醒酒器蛋糕绿色合成无定形二氧化硅:从文献综述到实验
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.53724
Nursyahirah Abdul Rahim, N. Y. Harun, A. Saeed, M. Bilad
Numerous agricultural wastes are well-defined as low-cost sources and rich in silica content. The residue of oil palm wastes combustion seems a promising silica source and can be recovered through a straightforward method. In this study, the combustion followed by an alkaline extraction method was employed to extract high purity of silica. The oven-dried oil palm decanter cake (DOPDC) was heated at combustion temperatures of 600, 700, 800, and 900°C to produce OPDC ashes (OPDCA), followed by an alkaline extraction using 5M of NaOH solution. Thermogravimetric analysis (TGA) was used to observe the thermal behavior of DOPDC where the suitable combustion temperatures to produce silica ranged between 600 and 1000 ℃. X-Ray Fluorescence (XRF) analysis showed that silica contents were 31-36% after combustion, increasing to 76.95% after the chemical treatment. Moreover, the spherical shape of the silica was observed through electron microscope analysis. It was represented by the aggregation of silica after going through chemical treatment. The X-Ray Diffraction analysis also proved that the amorphous silica was produced, characterized by the hump-shaped spectrum. The infrared analysis confirmed that the silica had been successfully extracted from OPDCA by the presence of silica functional groups shown in the spectrum.
许多农业废弃物被定义为低成本来源和富含二氧化硅含量。油棕废弃物燃烧后的残渣是一种很有前途的硅源,可以通过一种简单的方法进行回收。本研究采用燃烧后碱性萃取法提取高纯度二氧化硅。在600、700、800和900℃的燃烧温度下加热烘干油棕滗析饼(DOPDC),生成OPDC灰(OPDCA),然后用5M的NaOH溶液进行碱性萃取。采用热重分析(TGA)对DOPDC的热行为进行了研究,DOPDC的适宜燃烧温度为600 ~ 1000℃。x射线荧光(XRF)分析表明,燃烧后的二氧化硅含量为31-36%,化学处理后的二氧化硅含量为76.95%。此外,通过电子显微镜观察到二氧化硅呈球形。其表现为化学处理后二氧化硅的聚集。x射线衍射分析也证明产生了无定形二氧化硅,具有峰状光谱特征。红外光谱分析显示,二氧化硅官能团的存在证实了从OPDCA中成功提取了二氧化硅。
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引用次数: 4
Biochar from Agricultural Waste for Soil Amendment Candidate under Different Pyrolysis Temperatures 不同热解温度下农业废弃物生物炭的土壤改良剂研究
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.55193
A. Mutolib, A. Rahmat, E. Triwisesa, H. Hidayat, H. Hariadi, K. Kurniawan, S. Sutiharni, S. Sukamto
Indonesia as an agricultural country produces and consumes a huge amount of fruits. One of the popular fruits is durian (Durio zibethinus), which can create issues with the high amount of durian seeds. Durian seeds can be fermented quickly. Thus, if they are not processed immediately, it causes pollution to the environment, particularly an odor issue. One of the waste management is to convert durian seed waste into biochar, an ameliorant agent to improve soil quality. This study aims to analyze the physicochemical properties of durian seed-derived biochar under different pyrolysis temperatures. The results showed that the increases in the temperature allowed the creation of more porosity in the biochars, which is due to chemical structure and crystallinity arrangement. This is confirmed by the increases in surface area and total pore volume also decreases in particle size. The change in the chemical structure can be verified by the decreases in the biochar yield. The produced biochar from fruit seeds has excellent carbon content and elemental components such as potassium, magnesium, phosphor, and sulfur, informing prospective fruit seeds as a soil amendment fertilizer
印度尼西亚作为一个农业国家,生产和消费大量的水果。榴莲(Durio zibethinus)是一种受欢迎的水果,但榴莲种子过多会造成问题。榴莲的种子可以快速发酵。因此,如果不立即处理,就会对环境造成污染,尤其是气味问题。其中一种废弃物管理方法是将榴莲种子废弃物转化为生物炭,作为改善土壤质量的改良剂。本研究旨在分析不同热解温度下榴莲籽生物炭的理化性质。结果表明,温度的升高允许在生物炭中产生更多的孔隙,这是由于化学结构和结晶度排列。这可以通过表面积的增加和总孔隙体积的减小来证实。化学结构的变化可以通过生物炭产量的下降来证实。由水果种子生产的生物炭具有优异的碳含量和元素成分,如钾、镁、磷和硫,为水果种子作为土壤改良剂提供了前景
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引用次数: 1
Sustainable Production-Inventory Model with Multi-Material, Quality Degradation, and Probabilistic Demand: From Bibliometric Analysis to A Robust Model 具有多材料、质量退化和概率需求的可持续生产库存模型:从文献计量分析到稳健模型
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.54056
D. M. Utama, I. Santoso, Y. Hendrawan, W. A. P. Dania
An adequate sustainable production inventory model is expected to represent complex real-life cases involving fuel, emissions, and electricity costs as well as multi-materials, quality degradation, and probabilistic demand. Therefore, this study was conducted to develop this kind of model to determine the number of raw material shipments (), production cycle time (), and the number of finished goods delivered (n) to maximize the Expected Total Profit (ETP). The proposed model is based on a bibliometric literature analysis of the sustainable production-inventory problem which is visualized using the VOSviewer. Moreover, a sophisticated Harris-Hawks Optimization (HHO) algorithm was proposed to solve the problems identified in the sustainable production inventory model optimization. It is also important to note that three numerical cases were provided to evaluate the performance of the algorithm. The findings showed that the suggested HHO method outperforms the Genetic Algorithm (GA) and Particle Swarm Optimization (PSO) in maximizing ETP and this means it is better for ETP optimization. It was also discovered from the sensitivity analysis that an increase in the rate of quality degradation (k) led to a reduction in both the ETP and T.
一个适当的可持续生产库存模型有望代表复杂的现实情况,包括燃料、排放和电力成本,以及多种材料、质量退化和概率需求。因此,本研究开发这类模型,以确定原材料出货量(),生产周期时间(),产成品交付数量(n),以最大化预期总利润(ETP)。所提出的模型是基于对可持续生产库存问题的文献计量学分析,并使用VOSviewer进行可视化。此外,针对可持续生产库存模型优化中存在的问题,提出了一种复杂的Harris-Hawks优化算法。同样重要的是要注意,提供了三个数值案例来评估算法的性能。结果表明,该方法在最大ETP方面优于遗传算法(GA)和粒子群算法(PSO),更适合ETP优化。从敏感性分析中还发现,质量降解率(k)的增加导致ETP和T的降低。
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引用次数: 2
Predicting Consumption Intention of Consumer Relationship Management Users Using Deep Learning Techniques: A Review 利用深度学习技术预测消费者关系管理用户的消费意愿
Q1 Earth and Planetary Sciences Pub Date : 2022-12-28 DOI: 10.17509/ijost.v8i2.55814
Eshrak Alaros, Mohsen Marjani, Dalia Abdulkareem Shafiq, D. Asirvatham
Consumer/customer relationship management (CRM) can potentially influence business as it predicts changes in people’s perspectives, which could impact future sales. Accordingly, advancements in Information Technology are under investigation to see their capabilities to improve the work of CRM. Many prediction techniques, such as Data Mining, Machine Learning (ML), and Deep Learning (DL), were found to be utilized with CRM. ML methods were found to dominate other approaches in terms of the prediction of consumers’ intention to purchase. This review provides DL algorithms that are mostly used in the last five years, to support CRM to predict purchase intention for better product sales decisions. Prediction criteria related to online activities and behavior were found to be the most inputs of prediction models. DL approaches are slowly applied within purchase intention prediction due to their advanced capabilities in handling large and complicated datasets with minimum human supervision. DL models such as CNN and LSTM result in high accuracy in prediction intention with 98%. Future research uses the two algorithms (CNN, LSTM) compiled to make the best prediction consumption in CRM. Additionally, an effort is being made to create a framework for predicting purchases based on many DL algorithms and the most pertinent characteristics.
消费者/客户关系管理(CRM)可以潜在地影响业务,因为它预测人们观点的变化,这可能会影响未来的销售。因此,信息技术的进步正在被调查,以了解它们改善CRM工作的能力。许多预测技术,如数据挖掘、机器学习(ML)和深度学习(DL),都被发现用于客户关系管理。我们发现机器学习方法在预测消费者购买意愿方面占主导地位。本综述提供了过去五年中主要使用的深度学习算法,以支持CRM预测购买意愿,从而做出更好的产品销售决策。与在线活动和行为相关的预测标准是预测模型的最大输入。深度学习方法在购买意愿预测方面的应用缓慢,因为它们在处理大型复杂数据集方面具有先进的能力,而且人工监督最少。CNN和LSTM等深度学习模型在预测意图上的准确率很高,达到98%。未来的研究将使用这两种算法(CNN, LSTM)来编制CRM中的最佳预测消耗。此外,正在努力创建一个基于许多深度学习算法和最相关特征的预测购买的框架。
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引用次数: 1
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Indonesian Journal of Science and Technology
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