Pub Date : 2024-06-03DOI: 10.3390/resources13060076
Cédric Mpié Simba, Emmanuel Lemelin
The aim of this article was to conduct a spatial and territorial analysis of the urban mining potential of the European Metropolis of Lille (MEL), which had 1,174,273 inhabitants in 2018. This involved quantifying construction and demolition waste (CDW) deposits and analyzing their spatial distribution. The chosen quantification approach utilized building and demolition permits as input data, along with waste diagnostics for Construction and Building Materials Products (CBMPs) obtained from stakeholders in the building sector. Waste quantities were estimated using the production rate calculation method (GRC). Specifically, the calculation based on surface area combined with GIS geographic information systems. CDW quantities were categorized by demolition rehabilitation and construction; by type (hazardous non-hazardous inert); and by urban fabric. For the MEL area, the findings revealed that building sites covered the largest surface area, with over 8 million m² being constructed between 2013 and 2022. The construction activity, including renovation, is expected to constitute approximately 20% of the MEL’s building stock from 2013 to 2022. During the same period, 5.51% of the MEL’s building stock was demolished. This corresponds to nearly 6 million tons of CDW being generated during this period, averaging 661318 tons per year. Demolition sites contributed 73% of the total CDW production, compared to 22% for new construction and 4% for renovation sites. Inert waste continued to dominate the composition of waste, accounting for 90% of the total with 9% for non-hazardous waste and 1% for hazardous waste. Semi-detached and grouped houses business fabrics and townhouses or collective fabrics were identified as the primary type of waste-producing urban fabrics. Furthermore, our GIS-based methodology enabled the analysis of CDW quantity distribution by municipality, providing essential data for understanding the urban mining potential and the disparity between construction material requirements for new buildings and resources derived from building demolition. This approach facilitates the assessment of (1) a geographical area’s reliance on construction materials, and (2) the significance of reusing and recycling products equipment materials and waste (PEMW) in new construction to achieve circular economy objectives and to comply with the Extended Producer Responsibility (EPR) channel initiated in France in 2023. Over the period from 2013 to 2022, annual construction material requirements remained significantly higher than resources from building demolition and rehabilitation, ranging between 29% and 35%. Additionally, the analysis indicated a potential 41% rate of substitution of new construction materials with secondary primary materials in the MEL, varying by municipality and typology, with higher rates in rural communities and lower rates in urban communities.
{"title":"Spatio-Temporal Analysis of Resources and Waste Quantities from Buildings (as Urban Mining Potential) Generated by the European Metropolis of Lille: A Methodology Coupling Data from Construction and Demolition Permits with Geographic Information Systems","authors":"Cédric Mpié Simba, Emmanuel Lemelin","doi":"10.3390/resources13060076","DOIUrl":"https://doi.org/10.3390/resources13060076","url":null,"abstract":"The aim of this article was to conduct a spatial and territorial analysis of the urban mining potential of the European Metropolis of Lille (MEL), which had 1,174,273 inhabitants in 2018. This involved quantifying construction and demolition waste (CDW) deposits and analyzing their spatial distribution. The chosen quantification approach utilized building and demolition permits as input data, along with waste diagnostics for Construction and Building Materials Products (CBMPs) obtained from stakeholders in the building sector. Waste quantities were estimated using the production rate calculation method (GRC). Specifically, the calculation based on surface area combined with GIS geographic information systems. CDW quantities were categorized by demolition rehabilitation and construction; by type (hazardous non-hazardous inert); and by urban fabric. For the MEL area, the findings revealed that building sites covered the largest surface area, with over 8 million m² being constructed between 2013 and 2022. The construction activity, including renovation, is expected to constitute approximately 20% of the MEL’s building stock from 2013 to 2022. During the same period, 5.51% of the MEL’s building stock was demolished. This corresponds to nearly 6 million tons of CDW being generated during this period, averaging 661318 tons per year. Demolition sites contributed 73% of the total CDW production, compared to 22% for new construction and 4% for renovation sites. Inert waste continued to dominate the composition of waste, accounting for 90% of the total with 9% for non-hazardous waste and 1% for hazardous waste. Semi-detached and grouped houses business fabrics and townhouses or collective fabrics were identified as the primary type of waste-producing urban fabrics. Furthermore, our GIS-based methodology enabled the analysis of CDW quantity distribution by municipality, providing essential data for understanding the urban mining potential and the disparity between construction material requirements for new buildings and resources derived from building demolition. This approach facilitates the assessment of (1) a geographical area’s reliance on construction materials, and (2) the significance of reusing and recycling products equipment materials and waste (PEMW) in new construction to achieve circular economy objectives and to comply with the Extended Producer Responsibility (EPR) channel initiated in France in 2023. Over the period from 2013 to 2022, annual construction material requirements remained significantly higher than resources from building demolition and rehabilitation, ranging between 29% and 35%. Additionally, the analysis indicated a potential 41% rate of substitution of new construction materials with secondary primary materials in the MEL, varying by municipality and typology, with higher rates in rural communities and lower rates in urban communities.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141268526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-14DOI: 10.3390/resources13050069
Kseniya Levickaya, N. Alfimova, Ivan Nikulin, Natalia Kozhukhova, Aleksander Buryanov
Gypsum binders and the products based on them are widely in demand in the construction materials market, which is due to their easy production technology, lower energy consumption, and low environmental impact in relation to Portland cement. Not only natural gypsum (NG), but also phosphogypsum (PG), which is a by-product of the synthesis of orthophosphoric acid from phosphorite rock, can be used as a source of raw materials for the production of gypsum materials. PG is produced annually in large quantities throughout the world. In chemical composition, PG mainly consists of calcium sulfate dihydrate CaSO4·2H2O, so it is a good potential analogue of natural gypsum, which is used as the main component of gypsum building materials. Thus, the useful recycling of PG as a technogenic resource with valuable properties will expand the raw material base for the production of gypsum materials. This approach to handling technogenic resources fits well with the principles of a circular economy. However, like any technogenic resource, PGs from different enterprises normally differ in their deposits of the original phosphate rock and production technologies. Therefore, PG contains a large number of undesirable impurities, the proportion and composition of which vary over a wide range. This feature does not allow for predicting the properties of PG-based materials without a preliminary detailed study of PG. This research was aimed at carrying out a comprehensive study of the characteristics of PGs from three different industrial plants to evaluate their relationship with the properties of gypsum materials based on them. It was found that PGs have significant differences in their structural and morphological characteristics both in relation to each other and in relation to NG. Also, binders based on PG and NG have significant differences in their physical properties. The average density, compressive strength, and flexural strength for the PG binders with equal workability are lower than those of NG binders. At a water/solid ratio (W/S) < 0.7, all PG binders exhibit comparable compressive strength to NG binders. Thus, PG can act as an alternative to natural gypsum in gypsum binders.
石膏粘合剂和以石膏粘合剂为基础的产品在建筑材料市场上有着广泛的需求，这是因为与波特兰水泥相比，石膏粘合剂和以石膏粘合剂为基础的产品具有生产技术简单、能耗低、对环境影响小等优点。不仅天然石膏（NG），磷石膏（PG）也可以作为生产石膏材料的原料来源，磷石膏是利用磷矿石合成正磷酸的副产品。全世界每年都会大量生产 PG。从化学成分上看，PG 主要由二水硫酸钙 CaSO4-2H2O 组成，因此是天然石膏的潜在替代品，而天然石膏是石膏建材的主要成分。因此，将 PG 作为一种具有宝贵特性的技术资源进行有用的回收利用，将扩大生产石膏材料的原料基础。这种处理技术资源的方法非常符合循环经济的原则。然而，与其他技术资源一样，不同企业生产的 PG 通常在原始磷矿石的矿床和生产技术方面存在差异。因此，PG 中含有大量的不良杂质，其比例和成分差异很大。如果不对 PG 进行初步的详细研究，就无法根据这一特点预测 PG 基材料的特性。这项研究旨在对三个不同工业厂房的 PGs 特性进行全面研究，以评估它们与基于 PGs 的石膏材料特性之间的关系。研究发现，PGs 的结构和形态特征在相互之间以及与 NG 之间都存在显著差异。此外，基于 PG 和 NG 的粘结剂在物理性质上也有显著差异。具有相同施工性的 PG 粘合剂的平均密度、抗压强度和抗折强度均低于 NG 粘合剂。当水/固比（W/S）小于 0.7 时，所有 PG 粘合剂的抗压强度都与 NG 粘合剂相当。因此，在石膏粘结剂中，PG 可作为天然石膏的替代品。
{"title":"The Use of Phosphogypsum as a Source of Raw Materials for Gypsum-Based Materials","authors":"Kseniya Levickaya, N. Alfimova, Ivan Nikulin, Natalia Kozhukhova, Aleksander Buryanov","doi":"10.3390/resources13050069","DOIUrl":"https://doi.org/10.3390/resources13050069","url":null,"abstract":"Gypsum binders and the products based on them are widely in demand in the construction materials market, which is due to their easy production technology, lower energy consumption, and low environmental impact in relation to Portland cement. Not only natural gypsum (NG), but also phosphogypsum (PG), which is a by-product of the synthesis of orthophosphoric acid from phosphorite rock, can be used as a source of raw materials for the production of gypsum materials. PG is produced annually in large quantities throughout the world. In chemical composition, PG mainly consists of calcium sulfate dihydrate CaSO4·2H2O, so it is a good potential analogue of natural gypsum, which is used as the main component of gypsum building materials. Thus, the useful recycling of PG as a technogenic resource with valuable properties will expand the raw material base for the production of gypsum materials. This approach to handling technogenic resources fits well with the principles of a circular economy. However, like any technogenic resource, PGs from different enterprises normally differ in their deposits of the original phosphate rock and production technologies. Therefore, PG contains a large number of undesirable impurities, the proportion and composition of which vary over a wide range. This feature does not allow for predicting the properties of PG-based materials without a preliminary detailed study of PG. This research was aimed at carrying out a comprehensive study of the characteristics of PGs from three different industrial plants to evaluate their relationship with the properties of gypsum materials based on them. It was found that PGs have significant differences in their structural and morphological characteristics both in relation to each other and in relation to NG. Also, binders based on PG and NG have significant differences in their physical properties. The average density, compressive strength, and flexural strength for the PG binders with equal workability are lower than those of NG binders. At a water/solid ratio (W/S) < 0.7, all PG binders exhibit comparable compressive strength to NG binders. Thus, PG can act as an alternative to natural gypsum in gypsum binders.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140978666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-14DOI: 10.3390/resources13050067
Jirapan Satjarak, S. Klomklao, Yi Zhang, K. Thongprajukaew
Chymotrypsin from the digestive organs of bigfin reef squid, a major commercial squid species in Thailand, was purified to 41-fold with 5.7% yield by a sequential purification process including ammonium sulfate precipitation, size exclusion, and ion exchange chromatography. According to SDS-PAGE, the molecular weight of purified chymotrypsin was 43 kDa. Native-PAGE analysis revealed a single band for this purified enzyme. The optimum pH and temperature for chymotrypsin activity of the purified enzyme were a pH of 7.0 with a temperature of 55 °C. The purified chymotrypsin remained stable throughout a wide range of pH levels (6–11) and at relatively high temperature (55 °C). It was significantly inhibited by PMSF and TPCK. The values of the kinetic constants Km and Kcat were found to be 1.33 mM and 31.46 s−1, respectively. The purified chymotrypsin has the N-terminal amino acid IVGGQEATPGEWPWQAALQV. This study provided new information about the biochemical properties of pure chymotrypsin from bigfin reef squid, which will be useful in the future investigation, aquaculture, and application of bigfin reef squid.
{"title":"Novel Chymotrypsin Purified and Biochemically Characterized from Digestive Organs of Bigfin Reef Squid (Sepioteuthis lessoniana)","authors":"Jirapan Satjarak, S. Klomklao, Yi Zhang, K. Thongprajukaew","doi":"10.3390/resources13050067","DOIUrl":"https://doi.org/10.3390/resources13050067","url":null,"abstract":"Chymotrypsin from the digestive organs of bigfin reef squid, a major commercial squid species in Thailand, was purified to 41-fold with 5.7% yield by a sequential purification process including ammonium sulfate precipitation, size exclusion, and ion exchange chromatography. According to SDS-PAGE, the molecular weight of purified chymotrypsin was 43 kDa. Native-PAGE analysis revealed a single band for this purified enzyme. The optimum pH and temperature for chymotrypsin activity of the purified enzyme were a pH of 7.0 with a temperature of 55 °C. The purified chymotrypsin remained stable throughout a wide range of pH levels (6–11) and at relatively high temperature (55 °C). It was significantly inhibited by PMSF and TPCK. The values of the kinetic constants Km and Kcat were found to be 1.33 mM and 31.46 s−1, respectively. The purified chymotrypsin has the N-terminal amino acid IVGGQEATPGEWPWQAALQV. This study provided new information about the biochemical properties of pure chymotrypsin from bigfin reef squid, which will be useful in the future investigation, aquaculture, and application of bigfin reef squid.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140980711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-14DOI: 10.3390/resources13050068
Jaqueline Souza de Freitas, Alex Aguiar Novo, C. N. Kunigami, D. Moreira, S. Freitas, V. M. da Matta, E. P. Jung, Leilson de Oliveira Ribeiro
The genus Spondias has two species of native trees from Brazil that deserve to be highlighted: Spondias tuberosa (“umbu”) and Spondias mombin (“cajá”). Their fruit contain bioactive compounds which have been associated with several biological activities. However, they remain little exploited in the development of food and pharmaceutical products. In this perspective, the present review summarizes the literature data about the physicochemical and nutritional characteristics, bioactive compounds, potential health benefits, and industrial applications of these fruit, including their pulp, seed, and peel. The current scenery mapping for scientific articles was performed in the Scopus and Web of Science databases. The study also considered patent applications collected in the Derwent database. Results showed an increase in scientific publications in recent years for both species. Many applications are related to food technology; nevertheless, due to the composition of their non-edible fractions, they have the potential for use in biorefinery, being their use an opportunity for bioeconomy. Thus, this review provides a comprehensive overview of these Brazilian native fruit to offer a theoretical foundation and valuable data for future investigations and exploitation.
Spondias 属有两个值得重点介绍的巴西本地树种：Spondias tuberosa（"umbu"）和 Spondias mombin（"cajá"）。它们的果实含有生物活性化合物，具有多种生物活性。然而，它们在食品和药品开发中的利用率仍然很低。有鉴于此，本综述总结了有关这些水果（包括果肉、种子和果皮）的理化和营养特性、生物活性化合物、潜在健康益处和工业应用的文献数据。目前的科学文章图谱是在 Scopus 和 Web of Science 数据库中进行的。研究还考虑了 Derwent 数据库中收集的专利申请。结果显示，近年来这两种水果的科学出版物都有所增加。许多应用与食品技术有关；然而，由于其非食用馏分的成分，它们有可能用于生物精炼，成为生物经济的一个机遇。因此，本综述全面概述了这些巴西本地水果，为今后的研究和开发提供理论基础和宝贵数据。
{"title":"Spondias tuberosa and Spondias mombin: Nutritional Composition, Bioactive Compounds, Biological Activity and Technological Applications","authors":"Jaqueline Souza de Freitas, Alex Aguiar Novo, C. N. Kunigami, D. Moreira, S. Freitas, V. M. da Matta, E. P. Jung, Leilson de Oliveira Ribeiro","doi":"10.3390/resources13050068","DOIUrl":"https://doi.org/10.3390/resources13050068","url":null,"abstract":"The genus Spondias has two species of native trees from Brazil that deserve to be highlighted: Spondias tuberosa (“umbu”) and Spondias mombin (“cajá”). Their fruit contain bioactive compounds which have been associated with several biological activities. However, they remain little exploited in the development of food and pharmaceutical products. In this perspective, the present review summarizes the literature data about the physicochemical and nutritional characteristics, bioactive compounds, potential health benefits, and industrial applications of these fruit, including their pulp, seed, and peel. The current scenery mapping for scientific articles was performed in the Scopus and Web of Science databases. The study also considered patent applications collected in the Derwent database. Results showed an increase in scientific publications in recent years for both species. Many applications are related to food technology; nevertheless, due to the composition of their non-edible fractions, they have the potential for use in biorefinery, being their use an opportunity for bioeconomy. Thus, this review provides a comprehensive overview of these Brazilian native fruit to offer a theoretical foundation and valuable data for future investigations and exploitation.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140980288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-09DOI: 10.3390/resources13050066
A. Pusz, M. Wiśniewska, Arkadiusz Kamiński, Peter Knosala, D. Rogalski
Despite notable achievements in the development and application of the remediation of metal-contaminated soils, the search for and study of promising immobilizing agents continues. This article presents a new approach to using brown coal and activated carbon and their application for metal stabilization. An experiment was conducted to test Medicago falcata L. on soils from industrial areas contaminated with varying levels of lead (Pb), cadmium (Cd), chromium (Cr), zinc (Zn), copper (Cu), and nickel (Ni) with the addition of carbons. This plant is a stress-tolerant leguminous species. In this study, the total content of metals in soil and the available forms to plants (single extractions with 0.02 M ethylenediaminetetraacetic acid, EDTA) were determined, along with metal contents in the plant. The use of carbons lowered the phytoavailable forms of metals for plants and thus, resulted in a reduction in the phytotoxicity of the soils. The contents of the tested metals in the roots and shoots were lower than in the combinations of soils with no carbon added. The activated carbon had a stronger effect on limiting the availability of metals than brown coal in relation to plants growing on soils without added carbon; the percentage of reduction for the shoots was Cr (18.2%) > Zn (11.5%) > Ni (10.7%) > Cu (10.3%) > Cd (8.9%) > Pb (2.4%) and Cu (13.3%) > Cr (12.5%) > Zn (10.5%) > Pb (9.0%) > Ni (5.7%) > Cd (4.6%) for roots. Metals reduced the growth of Medicago falcata L. roots from 44 to 21%, while the growth of shoots was reduced from 25 to 2%. Adding carbons to soils in all combinations resulted in a decrease in the following pollution indices: pollution index (PI), pollution load index (PLI), and non-carcinogenic (HQ) and carcinogenic risk factors (ILCR).
{"title":"Influence of Carbons on Metal Stabilization and the Reduction in Soil Phytotoxicity with the Assessment of Health Risks","authors":"A. Pusz, M. Wiśniewska, Arkadiusz Kamiński, Peter Knosala, D. Rogalski","doi":"10.3390/resources13050066","DOIUrl":"https://doi.org/10.3390/resources13050066","url":null,"abstract":"Despite notable achievements in the development and application of the remediation of metal-contaminated soils, the search for and study of promising immobilizing agents continues. This article presents a new approach to using brown coal and activated carbon and their application for metal stabilization. An experiment was conducted to test Medicago falcata L. on soils from industrial areas contaminated with varying levels of lead (Pb), cadmium (Cd), chromium (Cr), zinc (Zn), copper (Cu), and nickel (Ni) with the addition of carbons. This plant is a stress-tolerant leguminous species. In this study, the total content of metals in soil and the available forms to plants (single extractions with 0.02 M ethylenediaminetetraacetic acid, EDTA) were determined, along with metal contents in the plant. The use of carbons lowered the phytoavailable forms of metals for plants and thus, resulted in a reduction in the phytotoxicity of the soils. The contents of the tested metals in the roots and shoots were lower than in the combinations of soils with no carbon added. The activated carbon had a stronger effect on limiting the availability of metals than brown coal in relation to plants growing on soils without added carbon; the percentage of reduction for the shoots was Cr (18.2%) > Zn (11.5%) > Ni (10.7%) > Cu (10.3%) > Cd (8.9%) > Pb (2.4%) and Cu (13.3%) > Cr (12.5%) > Zn (10.5%) > Pb (9.0%) > Ni (5.7%) > Cd (4.6%) for roots. Metals reduced the growth of Medicago falcata L. roots from 44 to 21%, while the growth of shoots was reduced from 25 to 2%. Adding carbons to soils in all combinations resulted in a decrease in the following pollution indices: pollution index (PI), pollution load index (PLI), and non-carcinogenic (HQ) and carcinogenic risk factors (ILCR).","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140995928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-08DOI: 10.3390/resources13050065
G. Karakatsanis, Christos Makropoulos
Although the Circular Economy (CE) has made remarkable technological progress by offering a wide range of alternative engineering solutions, an obstacle for its large-scale commercialization is nested in the adoption of those business and financial models that accurately depict the value generated from resource recovery. Recovering a resource from a waste matrix conserves natural reserves in situ by reducing demand for virgin resources, as well as conserving environmental carrying capacities by reducing waste discharges. The standard business model for resource recovery is Industrial Symbiosis (IS), where industries organize in clusters and allocate the process of waste matrices to achieve the recovery of a valuable resource at an optimal cost. Our work develops a coherent microeconomic architecture of Chemical Leasing (Ch.L.) contracts within the analytical framework of the Sherwood Plot (SP) for recovering a Value-Added Compound (VAC) from a wastewater matrix. The SP depicts the relationship between the VAC’s dilution in the wastewater matrix and its cost of recovery. ChL is engineered on the SP as a financial contract, motivating industrial synergies for delivering the VAC at the target dilution level at the market’s minimum cost and with mutual profits. In this context, we develop a ChL market typology where information completeness on which industry is most cost-efficient in recovering a VAC at every dilution level determines market dominance via a Kullback–Leibler Divergence (DKL) metric. In turn, we model how payoffs are allocated between industries via three ChL contract pricing systems, their profitability limits, and their fitting potential by market type. Finally, we discuss the emerging applications of ChL financial engineering in relation to three vital pillars of resource recovery and natural capital conservation.
{"title":"Chemical Leasing (Ch.L.) and the Sherwood Plot","authors":"G. Karakatsanis, Christos Makropoulos","doi":"10.3390/resources13050065","DOIUrl":"https://doi.org/10.3390/resources13050065","url":null,"abstract":"Although the Circular Economy (CE) has made remarkable technological progress by offering a wide range of alternative engineering solutions, an obstacle for its large-scale commercialization is nested in the adoption of those business and financial models that accurately depict the value generated from resource recovery. Recovering a resource from a waste matrix conserves natural reserves in situ by reducing demand for virgin resources, as well as conserving environmental carrying capacities by reducing waste discharges. The standard business model for resource recovery is Industrial Symbiosis (IS), where industries organize in clusters and allocate the process of waste matrices to achieve the recovery of a valuable resource at an optimal cost. Our work develops a coherent microeconomic architecture of Chemical Leasing (Ch.L.) contracts within the analytical framework of the Sherwood Plot (SP) for recovering a Value-Added Compound (VAC) from a wastewater matrix. The SP depicts the relationship between the VAC’s dilution in the wastewater matrix and its cost of recovery. ChL is engineered on the SP as a financial contract, motivating industrial synergies for delivering the VAC at the target dilution level at the market’s minimum cost and with mutual profits. In this context, we develop a ChL market typology where information completeness on which industry is most cost-efficient in recovering a VAC at every dilution level determines market dominance via a Kullback–Leibler Divergence (DKL) metric. In turn, we model how payoffs are allocated between industries via three ChL contract pricing systems, their profitability limits, and their fitting potential by market type. Finally, we discuss the emerging applications of ChL financial engineering in relation to three vital pillars of resource recovery and natural capital conservation.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140999331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-24DOI: 10.3390/resources13050062
G. M. Martínez Pastur, Dante Loto, Julián Rodríguez-Souilla, Eduarda M. O. Silveira, J. M. Cellini, P. L. Peri
Modern forestry systems rely on typologies of forest types (FTs). In Argentina, several proposals have been developed, but they lack unified criteria. The objective was to compare different approaches, specifically focusing on (i) phenoclusters (functional forests based on vegetation phenology variations and climate variables) and (ii) forest canopy cover composition by tree species. We conducted comparative uni-variate analyses using data from national forest inventories, forest models (biodiversity, carbon, structure), and regional climate. We assessed the performance of phenoclusters in differentiating the variability of native forests (proxy: forest structure), biodiversity (proxy: indicator species), and environmental factors (proxies: soil carbon stock, elevation, climate). Additionally, we proposed a simple FT classification methodology based on species composition, considering the basal area of tree species. Finally, we compared the performance of both proposals. Our findings showed that classifications based on forest canopy cover composition are feasible to implement in regions dominated by mono-specific forests. However, phenoclusters allowed for the increased complexity of categories at the landscape level. Conversely, in regions where multi-specific stands prevailed, classifications based on forest canopy cover composition proved ineffective; however, phenoclusters facilitated a reduction in complexity at the landscape level. These results offer a pathway to harmonize national FT classifications by employing criteria and indicators to achieve sustainable forest management and conservation initiatives.
现代林业系统依赖于森林类型（FT）的划分。在阿根廷，已经提出了一些建议，但缺乏统一的标准。我们的目标是比较不同的方法，特别是侧重于 (i) 表层集群（基于植被物候变化和气候变量的功能林）和 (ii) 按树种划分的林冠覆盖成分。我们利用国家森林资源清查数据、森林模型（生物多样性、碳、结构）和区域气候数据进行了单变量比较分析。我们评估了表簇在区分本地森林（替代物：森林结构）、生物多样性（替代物：指示物种）和环境因素（替代物：土壤碳储量、海拔、气候）的变异性方面的性能。此外，我们还提出了一种基于树种组成的简单森林分类方法，考虑了树种的基部面积。最后，我们比较了两种方案的性能。我们的研究结果表明，在以单一树种森林为主的地区，基于林冠覆盖成分的分类方法是可行的。然而，表层集群允许在景观层面增加分类的复杂性。相反，在以多特异性林分为主的地区，基于森林冠层覆盖成分的分类证明是无效的；然而，表型集群有助于降低景观层面的复杂性。这些结果为采用标准和指标协调国家森林分类提供了一条途径，以实现可持续森林管理和保护倡议。
{"title":"Different Approaches of Forest Type Classifications for Argentina Based on Functional Forests and Canopy Cover Composition by Tree Species","authors":"G. M. Martínez Pastur, Dante Loto, Julián Rodríguez-Souilla, Eduarda M. O. Silveira, J. M. Cellini, P. L. Peri","doi":"10.3390/resources13050062","DOIUrl":"https://doi.org/10.3390/resources13050062","url":null,"abstract":"Modern forestry systems rely on typologies of forest types (FTs). In Argentina, several proposals have been developed, but they lack unified criteria. The objective was to compare different approaches, specifically focusing on (i) phenoclusters (functional forests based on vegetation phenology variations and climate variables) and (ii) forest canopy cover composition by tree species. We conducted comparative uni-variate analyses using data from national forest inventories, forest models (biodiversity, carbon, structure), and regional climate. We assessed the performance of phenoclusters in differentiating the variability of native forests (proxy: forest structure), biodiversity (proxy: indicator species), and environmental factors (proxies: soil carbon stock, elevation, climate). Additionally, we proposed a simple FT classification methodology based on species composition, considering the basal area of tree species. Finally, we compared the performance of both proposals. Our findings showed that classifications based on forest canopy cover composition are feasible to implement in regions dominated by mono-specific forests. However, phenoclusters allowed for the increased complexity of categories at the landscape level. Conversely, in regions where multi-specific stands prevailed, classifications based on forest canopy cover composition proved ineffective; however, phenoclusters facilitated a reduction in complexity at the landscape level. These results offer a pathway to harmonize national FT classifications by employing criteria and indicators to achieve sustainable forest management and conservation initiatives.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140659619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-24DOI: 10.3390/resources13050060
U. Somorowska
This study focuses on temperature and snowfall conditions in Poland, both of which were analyzed from 1981 to 2020. A 40-year record of daily snow fraction time series values was reconstructed using a unique and global multi-source weighted-ensemble precipitation (MSWEP) product, which provided a spatially and temporally consistent reference for the assessment of meteorological conditions. The average states and trends in snow fraction and temperature were analyzed across several years, focusing on the 6-month cold season (November–April). The impact of temperature on the snow fraction pattern was assessed by introducing a snow fraction sensitivity index. To predict short-term changes in snow conditions, a proxy model was established; it incorporated historical trends in the snow fraction as well as its mean state. This study provides clear evidence that the snow fraction is principally controlled by increases in temperature. A warming climate will thus cause a decline in the snow fraction, as we observed in vast lowland areas. Given the ongoing global warming, by the 2050s, snow-dominated areas may go from covering 86% to only 30% of the country’s surface; they will be converted into transient rain–snow areas. Our results demonstrate that a decline in snow water resources has already occurred, and these resources are expected to diminish further in the near future. New insights into the sensitivity of the snow fraction to climate warming will expand our collective knowledge of the magnitude and spatial extent of snow degradation. Such widespread changes have implications for the timing and availability of soil and groundwater resources as well as the timing and likelihood of floods and droughts. Thus, these findings will provide valuable information that can inform environmental managers of the importance of changing snowfall conditions, guiding them to include this aspect in future climate adaptation strategies.
{"title":"Assessing the Impact of Climate Change on Snowfall Conditions in Poland Based on the Snow Fraction Sensitivity Index","authors":"U. Somorowska","doi":"10.3390/resources13050060","DOIUrl":"https://doi.org/10.3390/resources13050060","url":null,"abstract":"This study focuses on temperature and snowfall conditions in Poland, both of which were analyzed from 1981 to 2020. A 40-year record of daily snow fraction time series values was reconstructed using a unique and global multi-source weighted-ensemble precipitation (MSWEP) product, which provided a spatially and temporally consistent reference for the assessment of meteorological conditions. The average states and trends in snow fraction and temperature were analyzed across several years, focusing on the 6-month cold season (November–April). The impact of temperature on the snow fraction pattern was assessed by introducing a snow fraction sensitivity index. To predict short-term changes in snow conditions, a proxy model was established; it incorporated historical trends in the snow fraction as well as its mean state. This study provides clear evidence that the snow fraction is principally controlled by increases in temperature. A warming climate will thus cause a decline in the snow fraction, as we observed in vast lowland areas. Given the ongoing global warming, by the 2050s, snow-dominated areas may go from covering 86% to only 30% of the country’s surface; they will be converted into transient rain–snow areas. Our results demonstrate that a decline in snow water resources has already occurred, and these resources are expected to diminish further in the near future. New insights into the sensitivity of the snow fraction to climate warming will expand our collective knowledge of the magnitude and spatial extent of snow degradation. Such widespread changes have implications for the timing and availability of soil and groundwater resources as well as the timing and likelihood of floods and droughts. Thus, these findings will provide valuable information that can inform environmental managers of the importance of changing snowfall conditions, guiding them to include this aspect in future climate adaptation strategies.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140659813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-24DOI: 10.3390/resources13050061
Bashir Bashiri, Janna Cropotova, Kristine Kvangarsnes, Olga Gavrilova, Raivo Vilu
As global fish consumption rises, a large amount of waste is generated that is generally neglected. Considering the value embedded in these resources, sustainable methods become more important in extracting valuable ingredients from fish processing residues. Enzymatic hydrolysis is a fast and easily reproducible method for recovering protein ingredients and obtaining valuable by-products. To confirm its advantages, an environmental and economic impact assessment is essential. This study overviewed the sustainability and economic viability of extracting protein compounds and oil from Atlantic mackerel processing residues using enzymatic hydrolysis. Life cycle assessment (LCA) and life cycle cost analysis (LCCA) methods were employed. It was found that the climate change impact of the whole process was 0.073 kg CO2-eq per 1 g of fish protein hydrolysate (FPH). As the process produces FPH as the main product and fish oil as the by-product, economic allocation was used to distribute the impacts of FPH and fish oil. The findings of the LCCA showed that producing 1 g of FPH costs EUR 3.68. The contribution analysis indicated the crucial role of electricity and fish in environmental impacts. To ensure the accuracy of the calculation, the results of an LCA study published previously were recalculated. The sensitivity analysis showed that the results were susceptible to the region and source of electricity production. This research provides valuable insights into the sustainability and economic aspects of using enzymatic hydrolysis for extracting protein ingredients and oils from Atlantic mackerel. This can inform future investigations of environmentally friendly and economically viable solutions for extracting fish ingredients.
{"title":"Environmental and Economic Life Cycle Assessment of Enzymatic Hydrolysis-Based Fish Protein and Oil Extraction","authors":"Bashir Bashiri, Janna Cropotova, Kristine Kvangarsnes, Olga Gavrilova, Raivo Vilu","doi":"10.3390/resources13050061","DOIUrl":"https://doi.org/10.3390/resources13050061","url":null,"abstract":"As global fish consumption rises, a large amount of waste is generated that is generally neglected. Considering the value embedded in these resources, sustainable methods become more important in extracting valuable ingredients from fish processing residues. Enzymatic hydrolysis is a fast and easily reproducible method for recovering protein ingredients and obtaining valuable by-products. To confirm its advantages, an environmental and economic impact assessment is essential. This study overviewed the sustainability and economic viability of extracting protein compounds and oil from Atlantic mackerel processing residues using enzymatic hydrolysis. Life cycle assessment (LCA) and life cycle cost analysis (LCCA) methods were employed. It was found that the climate change impact of the whole process was 0.073 kg CO2-eq per 1 g of fish protein hydrolysate (FPH). As the process produces FPH as the main product and fish oil as the by-product, economic allocation was used to distribute the impacts of FPH and fish oil. The findings of the LCCA showed that producing 1 g of FPH costs EUR 3.68. The contribution analysis indicated the crucial role of electricity and fish in environmental impacts. To ensure the accuracy of the calculation, the results of an LCA study published previously were recalculated. The sensitivity analysis showed that the results were susceptible to the region and source of electricity production. This research provides valuable insights into the sustainability and economic aspects of using enzymatic hydrolysis for extracting protein ingredients and oils from Atlantic mackerel. This can inform future investigations of environmentally friendly and economically viable solutions for extracting fish ingredients.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140663813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-19DOI: 10.3390/resources13040059
O. Rahmonov, Bartłomiej Szypuła, M. Sobala, Zebiniso B. Islamova
Mountain societies are strongly linked to natural resources and their rational management. The growing population has led to the management of mountain areas according to emerging human needs. The study was conducted in the Urej River catchment (The Fann Mountains, Tajikistan). This paper aims to present changes in land use in 1988–2023 resulting from environmental conditions and land reform. Pasturelands predominate in the study area (93.8%), while built-up with kitchen garden and irrigated areas cover 1.8% and 4.0% of the area, respectively. Kitchen gardens and irrigated areas provide food for the residents. Significant land-use changes were observed along the Uroz River, where the irrigation system was developed in areas that have not yet been used for plant cultivation. This is typical of many areas in Tajikistan, where it is impossible to obtain crops without irrigation due to climatic conditions. Until 1988, the study area was not as intensively cultivated as it is today. Under the ongoing lease system based on the Dehkan Farm Act, grazing land is still owned by the state, but inhabitants have access to it. The leased land does little to improve the economic situation of households but contributes to preventing ecosystem degradation on the slopes caused by humans.
{"title":"Environmental and Land-Use Changes as a Consequence of Land Reform in the Urej River Catchment (Western Tajikistan)","authors":"O. Rahmonov, Bartłomiej Szypuła, M. Sobala, Zebiniso B. Islamova","doi":"10.3390/resources13040059","DOIUrl":"https://doi.org/10.3390/resources13040059","url":null,"abstract":"Mountain societies are strongly linked to natural resources and their rational management. The growing population has led to the management of mountain areas according to emerging human needs. The study was conducted in the Urej River catchment (The Fann Mountains, Tajikistan). This paper aims to present changes in land use in 1988–2023 resulting from environmental conditions and land reform. Pasturelands predominate in the study area (93.8%), while built-up with kitchen garden and irrigated areas cover 1.8% and 4.0% of the area, respectively. Kitchen gardens and irrigated areas provide food for the residents. Significant land-use changes were observed along the Uroz River, where the irrigation system was developed in areas that have not yet been used for plant cultivation. This is typical of many areas in Tajikistan, where it is impossible to obtain crops without irrigation due to climatic conditions. Until 1988, the study area was not as intensively cultivated as it is today. Under the ongoing lease system based on the Dehkan Farm Act, grazing land is still owned by the state, but inhabitants have access to it. The leased land does little to improve the economic situation of households but contributes to preventing ecosystem degradation on the slopes caused by humans.","PeriodicalId":37723,"journal":{"name":"Resources","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140682486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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