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Impact of Cedzyna Reservoir on Selected Physicochemical Parameters of River Water Quality (Swietokrzyskie Mountains, Poland) 塞兹纳水库对波兰斯韦托克日斯基山脉河流水质理化参数的影响
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2019-12-01 DOI: 10.2478/cdem-2019-0010
J. Przybylska, J. Kaleta, R. Kozłowski
Abstract The monitoring of selected physicochemical parameters and chemical composition of water was conducted in 2017-2018 in the Lubrzanka river and the Cedzyna reservoir (Swietokrzyskie Mountains, Poland). The results indicate that the impact of reservoir on the quality of river water depends on natural characteristics of the catchment as well as on the present anthropogenic pressure. Retention of water in the reservoir caused seasonally diversified changes in analysed parameters, including an increase in water temperature, retention of major ions, nutrients and trace elements. Further research is needed to assess the risk of contamination of lower course of the river with metals deposited in reservoir’s bottom sediments.
摘要/ Abstract摘要:2017-2018年,对波兰斯韦托克日斯基山脉(swietokrzysky Mountains)卢布赞卡河(luzzanka river)和塞济纳水库(Cedzyna reservoir)的部分水体进行了理化参数和化学成分监测。结果表明,水库对河流水质的影响不仅取决于流域的自然特征,还取决于当前的人为压力。水库中水的滞留引起了分析参数的季节性多样化变化,包括水温的升高、主要离子、营养物质和微量元素的滞留。水库底部沉积物中的金属污染下游河道的风险需要进一步研究。
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引用次数: 2
Verifying the Weight of Different Learning Tasks in Student Assessment by Chemistry Teachers 化学教师在学生评价中验证不同学习任务的权重
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2019-12-01 DOI: 10.2478/cdem-2019-0007
Miroslav Prokša, Anna Drozdíková, Zuzana Haláková
Abstract Learning tasks are a great motivation tool in chemistry teaching, necessary in the exposure and fixation part of a teaching process, and also often used when diagnosing the depth and type of student knowledge. Our research analysed the relationship between the student assessment in chemistry and their success in solving memory, algorithmic and conceptual tasks at symbolic, submicroscopic and macroscopic levels. The testing focused on chemical equilibrium, because this topic is appropriate to design and test the tasks. The collected data was evaluated by one-factor ANOVA analysis. We expected that, in comparison to average and weak learners, the excellent ones should be significantly more successful in tackling all the types of tasks and at all levels. However, our findings indicate that this assumption is invalid in the case of conceptual tasks, i.e. the understanding the depth of chemical concepts does not always correlate with the student assessment.
摘要学习任务是化学教学中一个很好的激励工具,是教学过程中暴露和固定部分所必需的,也是诊断学生知识深度和类型时经常使用的工具。我们的研究分析了学生在化学方面的评估与他们在符号、亚微观和宏观层面上解决记忆、算法和概念任务的成功之间的关系。测试的重点是化学平衡,因为这个主题适合设计和测试任务。通过单因素方差分析对收集的数据进行评估。我们预计,与普通和薄弱的学习者相比,优秀的学习者在处理所有类型的任务和各个级别的任务时应该更成功。然而,我们的研究结果表明,在概念任务的情况下,这一假设是无效的,即理解化学概念的深度并不总是与学生的评估相关。
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引用次数: 1
The Level of Mastery of the Concept of Chemical Reaction Rate by 9th Grade Students 九年级学生对化学反应速率概念的掌握程度
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0005
Renáta Michalisková, Miroslav Prokša
Abstract In this paper, we focused on the results of research, which we have conducted to ascertain the knowledge of Slovak students who have just finished their lower secondary education concerning the topic of chemical reaction rate. The study was attended by a total of 320 15-year-old graduates of basic chemistry education belonged to several schools. Students’ knowledge was found through didactic test consisted of 1 item related to clustering and several two-level tasks. The results were analyzed in terms of deeper insight into the students’ understanding of the issue and students’ misconceptions were also identified. The findings related to the problems connected with acquiring the concept of chemical reaction rate, especially in relation to the students’ grasp the mentioned topic at submicroscopic, macroscopic and symbolic levels of representation were analyzed. We managed to investigate the students’ various difficulties associated with mentioned topic. Several problems were found. Students have a problem with understanding the basic term “chemical reaction rate”, relating it to bodies in motion, which they know from physics lessons and everyday life. They also have problems to distinguish and interconnect information at different levels of representation. Students often do not know which factors affect the rate of reaction and how. They do not understand the concepts of concentration and catalyst and do not distinguish the terms temperature and heat. Students’ knowledge is often only formal and lacks a real conceptual understanding of the problem. Their solving of problems does not go beyond the algorithmic level of solution and they are not able to solve tasks that are not typically school-related issues.
在本文中,我们关注的是研究结果,我们进行了研究,以确定刚刚完成初中教育的斯洛伐克学生关于化学反应速率主题的知识。参加这项研究的共有320名15岁的基础化学教育毕业生,他们来自几个学校。教学测试由1个与聚类相关的项目和若干个两级任务组成。对结果进行分析,以更深入地了解学生对问题的理解,并确定学生的误解。分析了学生在化学反应速率概念习得过程中存在的问题,特别是在亚微观、宏观和符号表征层面对化学反应速率概念的把握。我们设法调查了学生们与上述主题相关的各种困难。发现了几个问题。学生在理解“化学反应速率”这一基本术语以及将其与运动中的物体联系起来方面存在问题,这些术语是他们从物理课和日常生活中了解到的。他们在区分和连接不同表征层次的信息方面也存在问题。学生们常常不知道哪些因素影响反应速度,以及如何影响反应速度。他们不理解浓度和催化剂的概念,也不区分温度和热量这两个术语。学生的知识往往只是形式上的,对问题缺乏真正的概念性理解。他们对问题的解决没有超越算法层面的解决方案,他们无法解决与学校无关的任务。
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引用次数: 2
What the Old Microbiologists Knew... 古代微生物学家所知道的……
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/CDEM-2018-0002
A. Nowak
Abstract Amazing is the fact that although the organisms have been known since the end of the seventeenth century, effective study of this group of organisms started after about 160 years, in the last two decades of the nineteenth century. The origins of science about bacteria were very difficult, there were many unknowns and conflict information. The research results provided by various scientists created complete chaos. From today’s perspective, it is difficult to imagine how it was possible, do research in such conditions, and obtain reliable results? Yet despite these difficulties, knowledge of our predecessors was neither so small nor so doubtful as might be supposed. On the contrary, it was surprisingly big and wide. What our predecessors knew about bacteria and especially their importance in nature? They knew that bacteria live everywhere, knew about their unlimited spread in the biosphere. The role of microorganisms in the mineralization of organic matter was known, as well as the circulation of matter in nature and role of bacteria in cycles of nutrient elements, and the solar energy as the driving force behind these changes. Today - although we understand these mechanisms much more accurately, we know a lot details and individual changes - but the basic outline of the functioning of the biosphere, valid until today created our predecessors. A look back at the beginning of the microbiology teaches us, how much can be achieved with seemingly primitive methods, if accompanied by a passion for research and imagination.
令人惊奇的是,尽管人们早在17世纪末就已经知道了这些生物,但对这些生物的有效研究却是在大约160年后,也就是19世纪的最后20年才开始的。关于细菌的科学起源是非常困难的,有许多未知和冲突的信息。各种科学家提供的研究结果造成了彻底的混乱。从今天的角度来看,很难想象这是怎么可能的,在这样的条件下进行研究,并获得可靠的结果?然而,尽管有这些困难,我们对前人的了解并不像想象的那么少,也不像想象的那么可疑。相反,它出奇地大,出奇地宽。我们的前辈对细菌,尤其是它们在自然界中的重要性了解多少?他们知道细菌无处不在,知道它们在生物圈中无限传播。微生物在有机物矿化中的作用,以及自然界中物质的循环和细菌在营养元素循环中的作用,以及太阳能作为这些变化背后的驱动力。今天,尽管我们对这些机制的理解要准确得多,我们也知道了很多细节和个体变化,但生物圈功能的基本轮廓,直到今天才被我们的前辈们所认可。回顾微生物学的开始,我们知道,如果有对研究和想象的热情,用看似原始的方法可以取得多大的成就。
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引用次数: 0
Learners’ Understanding of Chemical Equilibrium at Submicroscopic, Macroscopic and Symbolic Levels 学习者在亚微观、宏观和象征层面上对化学平衡的理解
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0006
Miroslav Prokša, Anna Drozdíková, Zuzana Haláková
Abstract It is not easy for secondary school learners to comprehend the concept of chemical equilibrium at the level of understanding. In this context, a feedback is important for the teachers to optimize their help to students in constructing this concept. We designed and tested sets of particularly prepared tasks, the solution of which reflects the depth of understanding of the basic concept in macroscopic, submicroscopic and symbolic representation. Difficulties in understanding the chemical phenomena and concepts do not result only from the existence of these three levels or from their explanation using abstract concepts, but also from the lack of interconnection between these representations. Consistent interconnection of these levels can lead to an internal conflict in students, and consequently to a more profound understanding of the concept or relationships between concepts at multiple levels of representation to understand them or to change the meaning of one to another. There is also a close connection with the aspect of memory, algorithmic and conceptual approaches to solving educational situations, which extends dimensionally and reinforces the need for a more comprehensive grasp of learners’ mastery of the given concept. The teacher cannot expect that the learners without intensive training, e.g., only by observing the macroscopic representation, can interpret the essence of the submicroscopic representation. Therefore, these aspects need to be consistently involved in the model of learners’ cognitive process early enough to apply them in the educational practice without any problems.
中学学生在理解层面上理解化学平衡的概念并不容易。在这种情况下,反馈对于教师优化他们对学生构建这一概念的帮助是很重要的。我们设计并测试了一组特别准备的任务,其解决方案反映了对宏观,亚微观和符号表示的基本概念的理解深度。理解化学现象和概念的困难,不仅在于这三个层次的存在,也在于用抽象概念来解释它们,而且还在于这些表象之间缺乏相互联系。这些层次之间的一致联系会导致学生的内部冲突,从而对概念或概念之间的关系有更深刻的理解,从而理解它们或将一个概念的含义转换为另一个概念。在解决教育问题的记忆、算法和概念方法方面也有密切的联系,这在维度上延伸,并加强了学习者对给定概念的掌握的更全面把握的需要。教师不能期望未经强化训练的学习者,例如,仅仅通过观察宏观表征,就能解释亚微观表征的本质。因此,这些方面需要尽早持续地参与到学习者的认知过程模型中,以便在教育实践中毫无问题地加以应用。
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引用次数: 7
Determination of Toxicological Parameters of Selected Bioactive Organic Chemicals Using the Ostracodtoxkit FTM 用介形虫毒素试剂盒测定部分生物活性有机化学品的毒理学参数
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0007
B. Kudłak, M. Wieczerzak, J. Namieśnik
Abstract Assessment of the impact of pharmaceutical residues on living organisms is very complex subject. Apart from taking into account the toxicity of individual compounds also their presence in mixtures should be taken into account. In this work, attempts were made to assess the ecotoxicity of biologically active substances (with 50 % effective concentration (EC50) values growing from fluoxetine (EC50 = 4.431 nM) >> gemfibrozil ≈ 17α-ethinylestradiol ≈ ketorolac > indomethacin > theophylline ≈ progesterone > naproxen ≈ trypsin > 2-(2,4,5-trichlorophenoxy)propionic acid > chloramphenicol > acetylsalicylic acid > ibuprofen > ketoprofen > 19-norethindrone to bezafibrate as the least toxic drug among studied ones) to the ISO standardized Ostracodtoxkit FTM bioassay. The Ostracodtoxkit FTM was proven to be very sensitive tool with respect to responding to presence of pharmaceuticals. Results of studies justify the statement that more research is needed in field of assessment of chronic exposure to pharmaceuticals and other newly emerging pollutants especially when they are present in complex mixture.
摘要药物残留对生物体影响的评估是一个非常复杂的课题。除了考虑单个化合物的毒性外,还应考虑它们在混合物中的存在。在该工作中,试图评估生物活性物质的生态毒性(50%有效浓度(EC50)值从氟西汀(EC50=4.431 nM)>>吉非罗齐≈17α-乙炔雌二醇≈酮咯酸>吲哚美辛>茶碱≈黄体酮>萘普生≈胰蛋白酶>2-(2,4,5-三氯氧基)丙酸>氯霉素>乙酰水杨酸>布洛芬>酮洛芬>19去甲肾上腺素对苯扎贝特是所研究药物中毒性最小的药物)。Ostracodtoxkit FTM已被证明是对药物存在做出反应的非常敏感的工具。研究结果证明,在评估药物和其他新出现的污染物的长期暴露领域需要更多的研究,尤其是当它们存在于复杂混合物中时。
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引用次数: 6
Two English Chemists/Authors/Teachers: John Read and James Riddick Partington 两位英国化学家/作家/教师:约翰·里德和詹姆斯·里迪克·帕廷顿
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0003
Z. Szydło
Abstract John Read and James Partington were both prominent and highly respected academics, chemists, authors and teachers during the middle decades of the 20th century. Their books were widely read throughout this period and played a major role in educating and raising the awareness of chemistry among young people and adults. Today their names are forgotten. The aim of the present article is to re-establish these two remarkable men and to bring them to the forefront of educational programs. An outline is given of their careers as chemists, set against the background of the times they lived in, giving an emphasis to their formidable literary output. Although they had widely contrasting personalities, and were specialists in three different fields of chemistry, Read: organic, Partington: physical and inorganic, they both recognized the great importance of setting chemistry in an historical context. Accordingly, they both wrote many works on the origins and development of chemistry and included much historical material in their textbooks. This added not only a great interest to the subject, but also set it in a broader cultural context, which is so clearly lacking in today’s chemistry teaching programs. A chronological list of their books is given and short contrasting fragments from four of them are analysed. Not only are these books of great interest, but they serve as an outstanding foundation for teaching the principles of chemistry today. A recommendation is made to incorporate one work of each author as compulsory reading material for students today, and in future years.
摘要John Read和James Partington都是20世纪中期杰出且备受尊敬的学者、化学家、作家和教师。他们的书在这一时期被广泛阅读,在教育和提高年轻人和成年人对化学的认识方面发挥了重要作用。今天,他们的名字被遗忘了。本文的目的是重建这两位杰出的人,并将他们带到教育项目的前沿。以他们所处的时代背景为背景,概述了他们的化学家生涯,强调了他们强大的文学成果。尽管他们性格迥异,是三个不同化学领域的专家,Read:有机,Partington:物理和无机,但他们都认识到将化学置于历史背景下的重要性。因此,他们都写了许多关于化学起源和发展的著作,并在教科书中收录了许多历史材料。这不仅增加了这门学科的极大兴趣,而且将其置于更广泛的文化背景下,而这在当今的化学教学计划中显然是缺乏的。他们的书按时间顺序排列,并对其中四本书的简短对比片段进行了分析。这些书不仅很有趣,而且是当今化学原理教学的杰出基础。建议将每位作者的一篇作品作为当今和未来几年学生的必修读物。
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引用次数: 1
Mosses as Biomonitor of Air Pollution with Analytes Originating from Tobacco Smoke 苔藓作为烟草烟雾中空气污染分析物的生物监测仪
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0008
M. Rajfur, P. Świsłowski, Filip Nowainski, Bogusław Śmiechowicz
Abstract The aim of the carried out research was the assessment of the possibility to use a popular bioindicator - Pleurozium schreberi mosses as a biosensor of the air pollution in living quarters with the analytes originating from tobacco smoke. The moss bag method of active biomonitoring, popular in environmental studies, was applied; the method is based on exposing mosses collected in clean areas in the locations polluted with, for example, heavy metals. However, this experiment involved exposing mosses in living quarters, in which approximately 10 cigarettes were smoked daily (first room - kitchen). For the purpose of comparison, moss samples were also placed in another room (bedroom), which was potentially not polluted. After three months of exposure, the following heavy metals were determined in mosses: Mn, Fe, Ni, Cu, Zn, Cd, Pb and Hg, using the atomic absorption spectrometry method. Additionally, these analytes were also determined in hair samples from the persons smoking in the room and from other smokers; the determined metal concentrations were compared with the results of the studies carried out using hair samples collected from non-smokers. On the basis of carried out research it was confirmed that, among others, the mosses exposed in living quarters accumulate heavy metals, such as Ni, Zn, Pb and Hg, which originate from tobacco smoke. Higher heavy metal concentrations were determined in hair samples from smokers, compared to hair samples from non-smokers.
摘要:本研究的目的是评估一种流行的生物指示剂-白蜡苔藓作为生活小区空气污染的生物传感器的可能性,该生物传感器的分析物来自烟草烟雾。采用环境研究中常用的主动生物监测方法——苔藓袋法;该方法的基础是将在清洁地区收集的苔藓暴露在受重金属等污染的地点。然而,这个实验涉及在生活区暴露苔藓,每天大约抽10支烟(第一间房间-厨房)。为了比较,苔藓样本也被放置在另一个可能没有被污染的房间(卧室)。暴露3个月后,采用原子吸收光谱法测定苔藓中的重金属:Mn、Fe、Ni、Cu、Zn、Cd、Pb和Hg。此外,这些分析也在室内吸烟者和其他吸烟者的头发样本中进行了测定;测定的金属浓度与使用非吸烟者头发样本进行的研究结果进行了比较。根据已开展的研究证实,除其他外,暴露在生活区的苔藓会积聚来自烟草烟雾的重金属,如Ni、Zn、Pb和Hg。与不吸烟者的头发样本相比,吸烟者头发样本中的重金属浓度更高。
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引用次数: 15
Ecology and Society. Impacted Ecosystems. Part I 生态与社会。受影响的生态系统。第一部分
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/CDEM-2018-0001
M. Frontasyeva, A. Kamnev
Abstract The Earth has existed for more than four billion years and has sustained life for three billion. Human beings have existed for just 200,000 years, yet our impact on the planet is so great that scientists around the world are calling for our period in the Earth’s history to be named ‘the Anthropocene’ - the age of humans. The changes we are now making have exacted a heavy toll on the natural world around us, and now threaten the planet’s ability to provide for us all. Problems of Ecology and Society in the new geological era as the Anthropocene - ‘the age of humans’ - are overviewed. The name is widely recognized as a useful classification of the period in which human activity has created and continues to generate deep and lasting effects on the Earth and its living systems. Examples of the interrelated effects of exponential population growth and massively expanding consumption of natural resources called Great Acceleration are given. Updated ‘planetary dashboard’ of environmental, economic and social indicators charts the trajectory of the Anthropocene are briefly summarized.
地球已经存在了40多亿年,并维持了30亿年的生命。人类只存在了20万年,但我们对地球的影响如此之大,以至于世界各地的科学家都呼吁将地球历史上的这段时期命名为“人类世”——人类的时代。我们现在所做的变化已经对我们周围的自然世界造成了沉重的代价,现在威胁到地球为我们所有人提供的能力。在新地质时代的生态和社会问题作为人类世-“人类的时代”-被概述。这个名字被广泛认为是对人类活动已经并将继续对地球及其生命系统产生深远而持久影响的时期的有用分类。给出了指数型人口增长和大规模扩大自然资源消耗(称为“大加速”)相互关联的影响的例子。简要总结了环境、经济和社会指标的最新“行星仪表板”,绘制了人类世的轨迹图。
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引用次数: 1
Propylene Oxide Polymerization in the Presence of Layered Double Hydroxides 层状双氢氧化物存在下的环氧丙烷聚合
IF 0.4 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2018-12-01 DOI: 10.1515/cdem-2018-0009
Olena Dan, E. Butenko, A. Kapustin
Abstract Propylene oxide polymerization in the presence of layered double hydroxides with different concentration of basic sites on their surface has been studied. It is shown that the polymerization can be catalyzed by both basic and acidic sites. On the basis of kinetic experiments the mechanisms of reaction undergoing were proposed.
摘要研究了在不同碱性位浓度的层状双氢氧化物存在下环氧丙烷的聚合反应。结果表明,聚合反应可由碱性和酸性位点催化。在动力学实验的基础上,提出了反应机理。
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引用次数: 4
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Chemistry-Didactics-Ecology-Metrology
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