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About the weathering effect on sedimentary rocks organic matter 关于风化作用对沉积岩有机质的影响
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.7
M. Delengov, N. Fadeeva, M. Bolshakova, E. Kozlova
To get properties and characteristics of oil and gas source rocks and for other geological aims, geologists analyzes core samples from wells and outcrop samples. But we should probably somehow correct geochemical source rock properties data we get on outcrop samples, because organic matter could change significantly due to oxidizing and weathering. This problem is very important but poorly developed in modern publications, so it attracted our interest and led to this investigation. Published information on the organic matter weathering which change it’s content and quality in sedimentary rocks is collected and summarized in this article. The changes of the kerogen (isolated from the mineral matrix) elemental composition during its long-term storage are presented. We compared the results we get in laboratory and results of other authors who dealt with natural changes of organic matter in outcrops. An attempt to interpret the results obtained from the point of view of hypergene changes in OM was made. Uncertainties that require further study and development are indicated. This work is the first step to better understanding of weathering effect on organic matter content and properties – question of great importance for making adequate oil and gas prospects estimations.This study continues the work of our foregoers and Teachers – geochemists of the Petroleum Geology Department of Lomonosov Moscow State University: N.B. Vassoevich, Yu.I. Korchagina, O.A. Radchenko, V.A. Uspensky, I.E. Leifman, A.N. Guseva, O.K. Bazhenova, T.A. Kiryukhina.
为了获得油气源岩的性质和特征以及其他地质目的,地质学家分析了来自井和露头样品的岩芯样品。但我们可能应该以某种方式纠正我们在露头样本上获得的地球化学源岩性质数据,因为有机物可能会因氧化和风化而发生显著变化。这个问题非常重要,但在现代出版物中发展得很差,因此引起了我们的兴趣,并导致了这项研究。本文对沉积岩中有机质风化作用改变其含量和质量的已有资料进行了收集和总结。介绍了干酪根(从矿物基质中分离出来)在长期储存过程中元素组成的变化。我们比较了我们在实验室得到的结果和其他作者处理露头有机物自然变化的结果。试图从OM中超生变化的角度来解释所获得的结果。指出了需要进一步研究和发展的不确定性。这项工作是更好地了解风化作用对有机质含量和性质的影响的第一步,这一问题对充分估计油气前景具有重要意义。这项研究延续了我们的前辈和教师——罗蒙诺索夫莫斯科国立大学石油地质系的地球化学家的工作:N.B.Vassoevich、Yu.I.Korchagina、O.A.Radchenko、V.A.Uspensky、I.E.Leifman、A.N.Guseva、O.K.Bazenova、T.A.Kiryukhina。
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引用次数: 1
Different types of void space and quality of unconventional reservoirs in the Upper Devonian domanic high-carbon deposits of Mukhanovo-Erokhovsky trough (Volga-Ural basin) Mukhanovo-Erokhovsky槽(伏尔加-乌拉尔盆地)上泥盆统domanic高碳矿床中不同类型的孔隙空间和非常规储层质量
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.14
V. Chupakhina, N. I. Korobova, G. Kalmykov, A. Zavyalova, M. Karpushin, K. Radchenko
Domanic deposits have already been studied in sufficient details. Various aspects of their study were described previosly in many works, but so far, these deposits have been considered mainly as source rocks. Domanic deposits are distributed in a wide stratigraphic range from the Middle Frasnian of the Late Devonian to the Tournaisian of the Early Carboniferous. In this paper, domanic formation is considered as an unconventional reservoir. Due to the complex and heterogeneous structure of rocks, their uneven saturation with organic matter and low porosity values, the methodology for assessing reservoir properties is at a low stage of production. An integrated study of the void space in such deposits, including macro- and microdescription of the core, analytical studies, makes it possible to predict zones with best quality of reservoirs and helped successfullу produce such deposits. In the section of domanic formation were identified the main lithotypes and characterized of each of them. Comparison of the types of void space identified in thin sections and reservoir properties made it possible to classify the main types of reservoirs and assess their quality.
Domanic矿床已经进行了足够详细的研究。他们研究的各个方面以前在许多著作中都有描述,但到目前为止,这些矿床主要被认为是烃源岩。Domanic矿床分布在从晚泥盆纪的中Frasnian到早石炭纪的Tournaisian的广泛地层范围内。在本文中,domanic组被认为是一个非常规储层。由于岩石结构复杂且不均匀,其有机质饱和度不均匀,孔隙度值低,因此评估储层性质的方法处于较低的生产阶段。对此类矿床孔隙空间的综合研究,包括岩心的宏观和微观描述、分析研究,使预测具有最佳储层质量的区域成为可能,并有助于成功地控制此类矿床的产生。在domanic组的剖面中,确定了主要的岩石类型和每种岩石的特征。通过比较薄片中确定的孔隙空间类型和储层性质,可以对主要储层类型进行分类并评估其质量。
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引用次数: 1
The significance of the macerals identification for understanding and study the transformation processes of organic matter in source rocks 有机质鉴定对认识和研究烃源岩有机质转化过程具有重要意义
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.6
N. Pronina, Anastasia P. Vaitekhovich, A. Kalmykov, D. A. Marunova
The question of the correct terminology is highly relevant, since researchers should understand one another in communication with specialists in different branches of geology. An overview of the terms already existing in the English-speaking world for describing oil-prone macerals, such as alginite, bituminite, bitumen, solid bitumen, pyrobitumen, oil, was presented, and it is more convenient to combine all zooclasts into bioclasts, since it is not always possible to determine whether the remains belong to the animal or plant world. Particular difficulties emerged with the term “bitumen”, which in Russian has two meanings. Increasingly, the films between mineral grains can be named both bitumen and oil. It was also suggested to divide bituminite in pre-mature bituminite, mature bituminite and post-mature bituminite in order to emphasize the features of those transformations that occurred with the initial organic matter during thermal maturity. Due to the fact that in the process of thermal maturity, the reactive part of kerogen = bituminite will transform into a liquid and gas, its solid part (“residual organic matter”) was suggested to be called solid bitumen or pyrobitumen.
正确的术语问题是高度相关的,因为研究人员应该在与不同地质学分支的专家交流时相互理解。概述了英语世界中已经存在的用于描述易发油的显微组分的术语,如褐藻岩、沥青、沥青、固体沥青、焦沥青、油,并且将所有动物碎屑组合成生物碎屑更方便,因为不总是能够确定遗骸是属于动植物世界。“沥青”一词出现了特殊的困难,在俄语中有两种含义。矿物颗粒之间的薄膜越来越多地被命名为沥青和石油。还建议将沥青岩分为预成熟沥青岩、成熟沥青岩和后成熟沥青岩,以强调热成熟过程中初始有机物发生的转化特征。由于在热成熟过程中,干酪根=沥青质的反应部分将转变为液体和气体,因此建议将其固体部分(“残余有机物”)称为固体沥青或焦沥青。
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引用次数: 1
The theory of sedimentation cyclicity of N.B. Vassoevich in the educational and scientific activities of the Petroleum Geology Department of Lomonosov Moscow State University in the XXI century 21世纪莫斯科国立大学罗蒙诺索夫石油地质系教育和科学活动中N.B. Vassoevich的沉积旋回理论
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.3
E. Karnyushina
The article is devoted to the 120th anniversary of Nikolay Bronislavovich Vassoevich (1902–1981) – a famous petroleum geologist, professor, corresponding member of the USSR Academy of Sciences. The article recalls his significant achievements in the field of fundamental geology. The first and main work in this field was his monograph on the methodology for studying the sedimentation cyclicity of flysch strata (1948), with the continuation of the topic in the next book, published in 1951. The scientific heritage of N.B. Vassoevich, who headed the Petroleum Geology Department of Lomonosov Moscow State University in 1963–1981, is preserved and developed in the modern educational and scientific activities of this Department. Teachers, staff and students with deep gratitude and respect honor the memory of N.B. Vassoevich, using his methodological recommendations on sedimentation cyclicity both in the training course of lithofacial analysis and applied in practical work in the study of oil and gas bearing strata of sedimentary rock basins. A huge role in the development of the terminology of this theory is associated with the development of the conceptual base of this geological direction. Professor N.B. Vassoevich had invested continuous work on the creation of systematic and logical classifications according to the composition, structure, genesis and hierarchy of geological sedimentary bodies that make up oil and gas bearing rock complexes.
这篇文章是为了纪念尼古拉·布罗尼斯拉沃维奇·瓦索耶维奇(1902-1981)诞辰120周年,他是一位著名的石油地质学家、教授、苏联科学院通讯委员。文章回顾了他在基础地质学领域的重大成就。这一领域的第一部主要著作是他关于复理石地层沉积旋回性研究方法的专著(1948年),在1951年出版的下一本书中继续了这一主题。N.B. Vassoevich于1963年至1981年担任莫斯科国立罗蒙诺索夫大学石油地质系主任,他的科学遗产在该系的现代教育和科学活动中得到了保存和发展。教师、教职员工和学生怀着深深的感激和敬意纪念N.B. Vassoevich,在岩面分析的培训课程中,以及在沉积岩盆地含油气地层研究的实际工作中,都采用了他关于沉积旋回性的方法论建议。在这一理论的术语发展中,一个巨大的作用是与这一地质方向的概念基础的发展有关。N.B. Vassoevich教授根据构成含油气岩石复合体的地质沉积体的组成、结构、成因和层次,投入了持续不断的工作,以建立系统和逻辑的分类。
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引用次数: 0
To the 110th anniversary of my mentor, professor of the Lomonosov Moscow State University Igor Vladimirovich Vysotsky 献给我的导师,莫斯科国立罗蒙诺索夫大学教授伊戈尔·弗拉基米罗维奇·维索茨基诞辰110周年
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.4
E. Ablya
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引用次数: 0
Conditions of sedimentation and distribution of organic matter in the Lower-Middle Jurassic complex of the South-Western part of the West Siberian oil and gas basin 西西伯利亚油气盆地西南部下-中侏罗统杂岩沉积条件及有机质分布
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.15
I. K. Komkov, A. Mordasova, M. Dakhnova, M. Bolshakova, S. Mozhegova, N. Pronina
The article is devoted to the variation of generation potential of the Lower-Middle Jurassic organic matter in the Karabash area (South-Western part of the West Siberian basin) depending on facies and sedimentary cyclisity. Based on geochemical and lithological core studies, specific geochemical features of organic matter established for main facies groups of Early-Middle Jurassic in the study area. The best generation potential inherent in deposits of swamps, swampy floodplains and tidal plains. These facies groups characterized by predominance of the continental organic matter and considered to gas source rocks. However, macerals composition, kinetic spectra and biomarker analysis show the presence also of marine organic matter. Some facies groups, such as flooded swamps and swampy floodplains has potential to generate hydrocarbons due to preservation of liptinites with high hydrogen index. Cyclic analysis with basics of sequence stratigraphy of the continental deposits allow tracing the correlation between generation potential and relative sea level changes.
本文研究了卡拉巴什地区(西西伯利亚盆地西南部)下-中侏罗统有机质生势随相和沉积旋回性的变化规律。通过地球化学和岩性岩心研究,建立了研究区早中侏罗统主要相群的具体有机质地球化学特征。沼泽、沼泽洪泛平原和潮汐平原沉积物具有最好的发电潜力。这些相组以陆相有机质为主,被认为是气源岩。然而,矿物组成、动力学光谱和生物标志物分析也显示了海相有机质的存在。一些相群,如淹水沼泽和沼泽洪泛平原,由于保存了高氢指数的岩质岩,有可能产生碳氢化合物。结合陆相沉积层序地层学的基本原理进行旋回分析,可以追踪生电位与相对海平面变化之间的关系。
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引用次数: 1
Geological structure and oil and gas potential of Domanik deposits in the central part of the Volga-Ural oil and gas basin 伏尔加-乌拉尔油气盆地中部Domanik矿床的地质结构和油气潜力
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.13
M. Karpushin, A. Stoupakova, A. Zavyalova, Vitalia V. Chupakhina, A. Suslova, K. Radchenko
The paper describes the structure and depositional conditions of a domanicoid high-carbon formation (HCF) in the central part of the Volga-Ural oil and gas basin. The structure of the HCF depends on the structural relatedness and paleogeographic conditions of the Late Devonian period, where the time of maximum sea level standing within the basin led to deposition of high organic carbon content intervals. The structural-facies zonation of the HCF distribution area is associated with the zone of relatively deep-water depressions, the zone of slopes, highs and the shallow water shelf with numerous bioherm buildups. The boundaries of the zones were determined by the position of large structural elements of the Tatar and Bashkir arches and depressions of the Kama-Kinel system of troughs. These zones differ not only in the distribution of the thickness of HCF deposits, but also in the nature of the distribution of intervals of the section enriched in organic matter. The maximum number of interlayers enriched by organic matter of the siliceous-carbonate rocks is observed in the section of the Frasnian and Famennian deposits within the central part of the Kama-Kinel system of troughs. Numerous of oil shows from the HCF intervals indicate the potential for further study and spotting of promising areas for hard-to-recover hydrocarbon reserves exploration.
本文描述了伏尔加-乌拉尔油气盆地中部一个圆顶状高碳地层的结构和沉积条件。HCF的结构取决于晚泥盆纪的结构相关性和古地理条件,在那里,盆地内最高海平面的时间导致高有机碳含量层段的沉积。HCF分布区的结构相分带与相对深水凹陷区、斜坡区、高地区和浅水架区有关,浅水架区有大量生物礁堆积。这些区域的边界由鞑靼和巴什基尔拱门的大型结构元素以及Kama-Kinel槽系的凹陷的位置决定。这些区域不仅在HCF沉积物厚度的分布上不同,而且在富含有机物的剖面的间隔分布性质上也不同。在Kama-Kinel槽系中部的Frasnian和Famennian矿床剖面中,观察到富含硅质碳酸盐岩有机质的夹层数量最大。HCF层段的大量石油显示表明,有可能进一步研究和发现难以回收的碳氢化合物储量勘探的有前景的区域。
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引用次数: 1
Comprehensive evaluation of Neoproterozoic source rocks formation 新元古代烃源岩形成的综合评价
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.8
Ksenia A. Sitar, B. Georgievskiy, M. Bolshakova, R. Sautkin
Based on comprehensive analysis of geological, geochemical, and paleotectonic settings, the conditions for the formation of Neoproterozoic oil and gas source rocks of the Earth are analyzed. A brief review of oil and gas fields in Eastern Siberia, China, the Middle East, Africa, and Australia is given, with Riphean and Vendian terrigenous and carbonate source rock. An overview of the oil and gas bearing basins of the world and a stratigraphic reference of the Neoproterozoic strata discovered within them, containing proven and suspected oil and gas source rocks, are given.The formation of Neoproterozoic oil and gas source rocks is analyzed in a complex way: simultaneously from the point of view of paleotectonics, paleogeographic and paleoclimatic conditions, paleobiological diversity and geochemical conditions. As part of paleotectonic analysis, the results of plate tectonic reconstructions for the Neoproterozoic stage are presented in accordance with one of the most currently relevant geodynamic models. Paleogeographic events and paleoclimatic conditions are described in the context of the specifics of the formation settings of carbonate-terrigenous oil and gas source rocks. In particular, the reasons for the accumulation of sediments enriched with organic carbon in the interglacial epochs of the Neoproterozoic and possible mechanisms for maintaining conditions favorable for their accumulation are considered. The conditions for the accumulation of oil and gas source rocks are also linked to global paleobiological pre-Phanerozoic events, and the analysis of the geochemical data of rocks makes it possible to characterize and correlate Neoproterozoic oil and gas source rocks on a global scale. On the basis of such a comprehensive assessment, a conclusion was made about fundamentally similar geological conditions for the formation of Neoproterozoic oil and gas source rocks in oil and gas bearing basins.
在综合分析地质、地球化学和古构造环境的基础上,分析了地球新元古代油气源岩的形成条件。简要介绍了东西伯利亚、中国、中东、非洲和澳大利亚的油气田,以及Riphean和Vendian陆相和碳酸盐岩源岩。概述了世界上的含油气盆地,并对其中发现的新元古代地层进行了地层参考,其中包含已探明和疑似的油气源岩。从古构造、古地理、古气候条件、古生物多样性和地球化学条件等方面对新元古代油气烃源岩的形成进行了复杂的分析。作为古构造分析的一部分,根据目前最相关的地球动力学模型之一,给出了新元古代阶段板块构造重建的结果。古地理事件和古气候条件是在碳酸盐岩陆生油气源岩形成环境的具体背景下描述的。特别是,考虑了新元古代间冰期富含有机碳的沉积物堆积的原因,以及维持有利于其堆积条件的可能机制。油气源岩的聚集条件也与全球古生物前显生宙事件有关,对岩石地球化学数据的分析使在全球范围内表征和关联新元古代油气源岩成为可能。在此基础上,得出油气盆地新元古代油气源岩形成地质条件基本相似的结论。
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引用次数: 0
Machine learning applications for well-logging interpretation of the Vikulov Formation 机器学习在维库洛夫地层测井解释中的应用
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.21
Vladlen I. Sakhnyuk, E. V. Novikov, Alexander M. Sharifullin, Vasiliy S. Belokhin, A. Antonov, Mikhail U. Karpushin, M. Bolshakova, S. Afonin, R. Sautkin, A. Suslova
Nowadays well logging curves are interpreted by geologists who preprocess the data and normalize the curves for this purpose. The preparation process can take a long time, especially when hundreds and thousands of wells are involved. This paper explores the applicability of Machine Learning methods to geology tasks, in particular the problem of lithology interpretation using well-logs, and also reveals the issue of the quality of such predictions in comparison with the interpretation of specialists. The authors of the article deployed three groups of Machine Learning algorithms: Random Forests, Gradient Boosting and Neural Networks, and also developed its own metric that takes into account the geological features of the study area and statistical proximity of lithotypes based on log curves values.
目前,测井曲线是由地质学家解释的,他们为此目的对数据进行预处理并对曲线进行归一化。准备过程可能需要很长时间,特别是当涉及成百上千口井时。本文探讨了机器学习方法在地质任务中的适用性,特别是利用测井资料进行岩性解释的问题,并揭示了与专家解释相比,这种预测的质量问题。该文章的作者部署了三组机器学习算法:随机森林、梯度增强和神经网络,并开发了自己的度量标准,该度量标准考虑了研究区域的地质特征和基于对数曲线值的岩石类型的统计接近性。
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引用次数: 1
Variations in molecular and isotopes composition of seepage gases in the north-western and south-eastern parts of Lake Baikal 贝加尔湖西北部和东南部渗漏气体分子和同位素组成的变化
IF 0.8 Q3 Earth and Planetary Sciences Pub Date : 2022-05-16 DOI: 10.18599/grs.2022.2.19
O. Vidishcheva, G. Akhmanov, E. V. Kislitsyna, A. Mazzini, Anna Yu. Mal’tseva, E. Poludetkina, E. Bakay, I. E. Man’ko, D. Korost, O. Khlystov
The paper presents results of gas-geochemical studies of bottom sediments and petroleum potential assessment of Baikal Rift Basin. During the expeditions of the Class@Baikal project in 2014–2019, gases from the Lake Baikal bottom sediments were analyzed. The results showed a clear difference in chemical and isotopic composition of the seeping gases collected in the northwestern and southeastern parts of the lake. The seepage released from northwest part were relatively enriched by methane and had a low concentration of C2+ compounds. The seepage gases had relatively lighter carbon isotopes composition of CH4 (from -72,7 to -50,1 ‰ VPDB) and the high variability of δ13C in C2H6 (from -65 to -22 ‰ VPDB). The gases released from southeastern part of the lake had an increase in C2+ compounds and had relatively lighter carbon isotopes composition of methane (from –57,2 to –41,0 ‰ VPDB). The carbon isotopes composition of ethane varies from -32 to -25 ‰ VPDB. Asymmetric structure of the Baikal rift basin and various processes of gas migration within it might cause the variations. Diffusive process led to the lighter carbon isotopes composition of the seepage gases from the northwestern part of lake and the gas molecular composition enrichment by methane. Such molecular and isotopic fractionations caused by geochemical processes helps to understand the migration of gas from source rocks to the earth’s surface. Similar geochemical indicators of fractionation should be taken into consideration when assessing oil and gas source rocks and basin potential from gas geochemical studies data.
本文介绍了贝加尔湖裂谷盆地底部沉积物的气体地球化学研究和油气潜力评价结果。在Class@Baikal在2014-2019年的项目中,对贝加尔湖底部沉积物中的气体进行了分析。结果表明,在湖泊西北部和东南部收集的渗出气体的化学成分和同位素组成存在明显差异。从西北部释放的渗流中甲烷相对富集,C2+化合物浓度较低。渗流气体中CH4的碳同位素组成相对较轻(从-72,7到-50,1‰VPDB),C2H6中δ13C的变化率较高(从-65到-22‰VPDB。从湖泊东南部释放的气体中C2+化合物增加,甲烷的碳同位素组成相对较轻(从-57,2‰VPDB到-41,0‰VPDB)。乙烷的碳同位素组成在-32至-25‰VPDB之间。贝加尔湖裂谷盆地的不对称结构及其内部气体运移的各种过程可能导致了这种变化。扩散过程导致湖泊西北部渗漏气体的碳同位素组成较轻,甲烷富集了气体分子组成。这种由地球化学过程引起的分子和同位素分馏有助于了解天然气从烃源岩向地球表面的迁移。在根据天然气地球化学研究数据评估油气源岩和盆地潜力时,应考虑类似的分馏地球化学指标。
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引用次数: 0
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