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Prognosis of leaching zones distribution in carbonate reservoirs 碳酸盐岩储层浸出带分布预测
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.10
A. Tchistiakov, Kseniia O. Zudina, Aigul R. Davletshina, E. Shvalyuk, V. Baranov
The proposed method of predicting spatial distribution of leaching zones in carbonate reservoirs includes integrated interpretation of well logging data, including electrical microimages (Formation MicroImager – FMI), together with analysis of lithofacies within depositional cycles. Based on the comparison of FMI data with results of lithological and petrophysical studies of the core, an atlas of diagenetic porosity images for the studied formation was developed. Choquette and Pray international classification was used for pore typing. Applying the developed atlas to FMI logs, karstification zones were identified and classified in reference wells. In wells, where only standard well loggings was performed, karstification zones were identified using a developed decision tree. Sedimentological and sequence stratigraphic analysis made it possible to identify sedimentation cycles and to correlate the main lithofacies within the target reservoir. It was established that microbial and shallow facies form the most productive part of the reservoir. These facies with initially high primary porosity were subjected to the most intensive karstification along sequence stratigraphic boundaries due to subaerial exposure. The established relationships between leaching zones, lithofacies, and sequence-stratigraphic boundaries made it possible to carry out inter-well correlation of karstified intervals. The correlation will allow construction of leaching zones maps, that will be further applied for geological modeling.
提出的预测碳酸盐岩储层浸出带空间分布的方法包括综合解释测井数据,包括电显微图像(地层微成像- FMI),以及沉积旋回内的岩相分析。基于FMI数据与岩心岩性和岩石物理研究结果的比较,建立了研究地层的成岩孔隙度图谱。孔隙分型采用Choquette和Pray国际分类。将开发的图谱应用于FMI测井,在参考井中识别和分类岩溶层。在仅进行标准测井的井中,使用开发的决策树识别岩溶层。沉积学和层序地层学分析使识别沉积旋回和对比目标储层内的主要岩相成为可能。确定了微生物相和浅层相是储层最具生产力的部分。这些初始孔隙度较高的相,由于地面暴露,沿层序地层边界受岩溶作用最为强烈。浸出带、岩相、层序地层边界之间的关系为岩溶层段的井间对比提供了可能。这种相关性将允许构建浸出带图,这将进一步应用于地质建模。
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引用次数: 0
Complex matrix treatment technologies selection and adaptation for the injection wells of the Republic of Tatarstan oilfields 鞑靼斯坦油田注水井复杂基质处理技术选择与适应
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.8
A. Lutfullin, E. M. Abusalimov, A. E. Folomeev, A. R. Khatmullin, A. Sharifullin, M. R. Sitdikov
Nowadays, oil fields on the territory of the Republic of Tatarstan are developed with application of systems for reservoir pressure maintenance, involving injection of large volumes of water into the formation. Efficiency of waterflooding depends on the quality of the injected agent, and, despite the use of various technologies of preparation and treatment of injected water, with the lapse of time critical matrix porosity and permeability inevitably decreases. In this work the main sources of injection wells critical matrix clogging are considered: mechanical impurities, oil products and scales formation, and the results of the component composition analysis of deposits from cluster pumping stations are given. Using the Oddo-Thomson methodology, it is revealed that injected water is prone to calcite and barite deposition at bottomhole conditions. Physicochemical and core-flooding study of several reagents for removing colmatants: acid compositions, hydrocarbon solvents and complexing agents were carried out and their optimal formulations were determined. The matrix treatment technology, including the sequential injection of compositions based on hydrochloric and mud acids, was substantiated. An algorithm for calculating the optimal reagent volume has been developed on the basis of research data on the mineralogical composition of mechanical impurities and ionic composition of injected water. Four types of matrix treatment technologies were determined for the conditions of injection wells at the Romashkinskoye oil field Devonian formation, taking into account the composition of colmatant, and acid treatment designs were developed.
如今,鞑靼斯坦共和国境内的油田都采用了储层压力维持系统,包括向地层注入大量水。注水效率取决于注入剂的质量,尽管使用了各种注入水的制备和处理技术,但随着时间的推移,基质的孔隙度和渗透率不可避免地会降低。本文考虑了注水井临界基质堵塞的主要来源:机械杂质、油品和结垢,并给出了丛式泵站沉积物成分分析的结果。利用Oddo-Thomson方法,揭示了注入水在井底条件下容易沉积方解石和重晶石。对酸性组分、烃类溶剂和络合剂等几种除垢剂进行了物理化学和岩心驱油研究,确定了它们的最佳配方。基质处理技术,包括基于盐酸和泥浆酸的组合物的顺序注入,得到了证实。根据机械杂质矿物组成和注入水离子组成的研究数据,开发了一种计算最佳试剂体积的算法。针对Romashkinskoye油田泥盆纪组注水井的条件,考虑到冷却剂的组成,确定了四种类型的基质处理技术,并制定了酸处理设计。
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引用次数: 0
Development of a numerical algorithm for solving the problem of processing and determining the basic velocity model 为解决基本速度模型的处理和确定问题,开发了一种数值算法
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.12
A. E. Shumeyko, Vadim A. Tsygankov
This work is devoted to development of an automatic algorithm for determining the velocity model from the data of the field seismic profile. First of all total energy of received signal and the positions of the first arrivals of reflected waves has to be determined. The traces sort by common depth point and the spectra of possible velocities determine at each point of the trace and each assembly of the common deep point. The procedure is fully automated and as a result, instead of about 150 points of manual processing, 4 million points are obtained on the test profile. The values ​​of chosen effective speeds correspond not only to existing criteria for their determination, but also to requirement of smoothness in first derivative. This makes it possible to determine reliable interval velocity profile at each track point and each collection of the common depth point. Speed ​​determination accuracy in the range of 10-50 m/s. After recalculating the time profile into a depth profile, it becomes possible to obtain high-resolution and detailed model of the velocity structure of the geological profile during migration transformations. An iteration process refines the calculations obtained by geologists and geophysicists in order to obtain consistent and consistent results.
本文致力于开发一种从现场地震剖面数据中确定速度模型的自动算法。首先,必须确定接收信号的总能量和反射波首次到达的位置。通过共同深度点对轨迹进行排序,并在轨迹的每个点和共同深度点的每个集合处确定可能的速度谱。该过程是完全自动化的,因此,在测试剖面上获得了400万个点,而不是大约150个点的人工处理。所选的有效速度值不仅符合现有的确定标准,而且符合一阶导数的平滑性要求。这使得在每个轨迹点和每个公共深度点的集合上确定可靠的层间速度剖面成为可能。测速精度在10- 50m /s范围内。将时间剖面重新计算为深度剖面后,可以获得地质剖面在运移转换过程中速度结构的高分辨率详细模型。为了得到一致和一致的结果,迭代过程对地质学家和地球物理学家得到的计算进行了改进。
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引用次数: 0
Geomechanical and lithological characteristics of the Vereysky horizon in the Middle Carboniferous for prediction of hydraulic fracturing technology, on the example of the Ivinskoye field in the South-East of Tatarstan 石炭纪中期Vereysky地层的地质力学和岩性特征用于水力压裂技术预测,以鞑靼斯坦东南部Ivinskoye油田为例
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.5
A. Kolchugin, E. Ziganshin, V. Morozov, E. S. Bystrov, E. Korolev, Salavat I. Gilfanov
The method of acid hydraulic fracturing has been actively used in recent years, for the deposits of the Vereysky horizon of the Moscowian strata in the south-east of Tatarstan. Design development and the use of hydraulic fracturing requires full-fledged studies of the geomechanical characteristics of rocks, including the prediction of the propagation of emerging fractures. It is considered the main geomechanical characteristics for reservoir rocks and dense rocks involved in the structure of the sections, on the example of the study of polyfacial reservoirs of the Vereysky horizon of the Ivinskoye oil field. It was revealed that the carbonate reservoir rocks of the middle and upper parts of the Vereysky horizon (C2vr3 and C2vr5) have the least strength properties and a greater susceptibility to fracturing. More durable were sandstones of the upper part of the horizon, marls and mudstones of the middle and upper parts of the horizon, as well as mudstone and dense packstone, typical for the lower part of the Vereysky horizon. The presented data can be valid for most of the sections of the Vereysky horizon of the southeast of Tatarstan and are used for the choice of optimal solutions when applying the hydraulic fracturing technology.
近年来,在鞑靼斯坦东南部莫斯科地层的Vereysky层的矿床中,酸性水力压裂方法得到了积极的应用。水力压裂的设计开发和使用需要对岩石的地质力学特征进行全面的研究,包括对新裂缝扩展的预测。以伊文斯科耶油田Vereysky层位多面储层研究为例,认为这是剖面结构中涉及的储集岩和致密岩的主要地质力学特征。结果表明,verysky层位中上段(C2vr3和C2vr5)碳酸盐岩储层强度最小,易致压裂;较持久的是层位上部的砂岩,层位中部和上部的泥灰岩和泥岩,以及典型的verysky层位下部的泥岩和致密包岩。所提供的数据适用于鞑靼斯坦东南部verysky地平线的大部分剖面,并可用于在应用水力压裂技术时选择最佳解决方案。
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引用次数: 0
Regulation of hydrocarbon production process based on dynamic tracer monitoring of horizontal well inflow profile 基于水平井流入剖面动态示踪剂监测的油气生产过程调控
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.11
K. Ovchinnikov, Y. Kotenev, Shamil Kh. Sultanov, A. V. Chibisov, D. Chudinova
This paper presents the results of geological and production analysis of development and reserves of the pilot area using the results of dynamic marker monitoring of horizontal wellbores of production wells using high-precision indicators. As part of the research, the geological structure of the reservoir section was updated, which includes a lithological and facial analysis and geological and hydrodynamic simulation of the reservoir. The energy state of the reservoir was analyzed and the efficiency of the waterflood system was evaluated using dynamic data analysis and correlation analysis. The reasons for changes in the dynamics of inflow profiles over time have been analyzed. By the example of the pilot area the decision-making algorithm for adjusting the process of hydrocarbon reserves extraction, based on the analysis of the relevant geological and technical information, obtained during the long-term dynamic marker monitoring of the horizontal wells operation, has been implemented. A set of recommendations has been developed, which makes it possible to achieve stable dynamics of development indicators, to increase the coefficients of coverage by displacement in the area and the reservoir section, to involve previously undrained areas of oil reserves in the development. The results of the analysis of the efficiency of the implemented geological and technological measures are presented.
本文介绍了利用高精度指标对生产井水平井进行动态标记监测的结果,对试验区开发储量进行地质和生产分析的结果。作为研究的一部分,更新了储层剖面的地质构造,其中包括岩性和面相分析以及储层的地质和水动力模拟。利用动态数据分析和相关分析,分析了储层的能量状态,评价了注水系统的效率。分析了流入剖面随时间动态变化的原因。以试验区为例,在对水平井作业长期动态标志监测中获得的相关地质技术信息进行分析的基础上,实现了油气储量开采过程调整的决策算法。已经制订了一套建议,使开发指标能够达到稳定的动态,增加该地区和储层段的驱替覆盖系数,使以前未排水的石油储备地区参与开发。对所实施的地质和技术措施的效果进行了分析。
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引用次数: 0
Potential for improving the efficiency of terrigenous oil deposits waterflooding with the use of low salinity technology at fields of the Tatarstan Republic 鞑靼斯坦共和国油田采用低矿化度技术提高陆源油藏注水效率的潜力
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.7
Zalina R. Saptarova, Alexander A. Mamonov, S. Usmanov, A. Lutfullin, V. Sudakov, M. Shipaeva, A. Shakirov
This article is devoted to the review of one of the currently relevant methods of enhanced oil recovery – low-salinity waterflooding (LSW) – on the example of terrigenous Tulian, Bobrikovian and Devonian reservoirs of the Tatarstan Republic fields.The first part of review contains information about the key processes underlying this method, such as swelling and migration of clay particles and wettability alteration, as well as the mechanisms that explain these processes, which include cation exchange, multicomponent ion exchange, electric double layer expansion, etc. Their understanding, in turn, contributes to the identification of the main factors, the presence or absence of which at the field allows us to give a preliminary assessment of LSW application. There are main factors: the presence of clay particles, a significant content of Ca2+ and Mg2+ ions, as well as multivalent ions in formation water, low formation permeability, reduced oil viscosity, an increased content of acidic and especially basic components in oil and, as a result, a hydrophobic type of initial rock wettability.Then, examples of using the method in other fields are given and the results of laboratory studies, including the measurement of the contact angle, core flooding experiments, are briefly highlighted.A preliminary screening is carried out on the basis of geological and field data from several fields of Tatarstan Republic, candidate fields are identified and a preliminary conclusion about LSW application in this region is made. The positive factors for the reservoirs under consideration, identified at the preliminary screening stage, include low formation temperature, high salinity of formation water with a significant content of divalent cations and the potential to shift the pH level from the current slightly acidic level towards increased alkalinity, and an increased content of polar oil components. In addition, the reservoirs of the Tulian and Bobrikovian horizons are characterized by the presence of clay particles, and the Devonian reservoir are characterized by a reduced oil viscosity coupled with an increased oil base number.
本文以鞑靼斯坦共和国油田土连系、波布里科夫系和泥盆系陆源油藏为例,综述了目前相关的提高采收率方法之一——低矿化度水驱(LSW)。综述的第一部分介绍了该方法的关键过程,如粘土颗粒的膨胀迁移和润湿性改变,以及解释这些过程的机制,包括阳离子交换、多组分离子交换、双电层膨胀等。反过来,他们的理解有助于识别主要因素,这些因素在现场的存在或不存在使我们能够对LSW应用进行初步评估。主要因素有:粘土颗粒的存在,地层水中Ca2+和Mg2+离子含量高,以及多价离子的存在,地层渗透率低,油粘度降低,油中酸性组分,特别是碱性组分含量增加,从而形成疏水型的初始岩石润湿性。然后,给出了该方法在其他领域的应用实例,并简要介绍了实验室研究的结果,包括接触角的测量和岩心驱油实验。根据鞑靼斯坦共和国几个油田的地质和现场资料进行了初步筛选,确定了候选油田,并对该地区的LSW应用做出了初步结论。在初步筛选阶段确定的储层有利因素包括地层温度低、地层水矿化度高、二价阳离子含量高、pH值有可能从目前的微酸性转向碱性,以及极性油组分含量增加。此外,土连和Bobrikovian层的储层以粘土颗粒的存在为特征,泥盆纪储层的特点是油粘度降低,同时油基数增加。
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引用次数: 0
What classification should be used in order to form the domestic system of independent expertise of hydrocarbon resources? 要形成国内油气资源自主专业知识体系,应采用何种分类?
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.1
D.P. Zabrodin, E.A. Titkov
The authors emphasize the need to take into account the uncertainty, conventionality and chances objectively inherent in the oil and gas industry when estimating oil and gas reserves and resources. It is noted that the current system in Russia for calculating and state accounting for reserves at least does not fully take them into account, nor does it meet the needs of business and financial structures, since the principles laid down in it do not correspond to generally accepted world standards.The authors come to the conclusion that the only reasonable choice for the institution of independent estimation (audit) of hydrocarbon reserves, which is beginning to form in Russia, is the use of the SPE-PRMS classification widely used in the world.
作者强调,在估计石油和天然气储量和资源时,需要考虑石油和天然气管业客观上固有的不确定性、惯例性和机会。值得注意的是,俄罗斯目前的准备金计算和国家会计制度至少没有充分考虑到这些因素,也不符合商业和金融结构的需要,因为其中规定的原则与公认的世界标准不符。作者得出的结论是,俄罗斯开始形成的油气储量独立估算(审计)机构的唯一合理选择是使用世界上广泛使用的SPE-PRMS分类。
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引用次数: 0
The rock typing of complex clastic formation by means of computed tomography and nuclear magnetic resonance 利用计算机断层扫描和核磁共振技术对复杂碎屑地层进行岩石分型
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-12-20 DOI: 10.18599/grs.2022.4.9
A. Tchistiakov, E. Shvalyuk, Alexandr A. Kalugin
This study provides a new rock-typing approach for low-resistive and low-permeable clastic rocks. The approach includes integrated interpretation of routine core analysis data with microstructural characteristics, acquired from computed tomography (CT) and nuclear-magnetic resonance (NMR) data.The studied formation comprises siltstones in its bottom, which are replaced by sandstones in its top. Sandstones form the main part of the oil reservoir, whereas siltstones were originally considered as water-saturated. The reserves calculation was performed based on a single Archie equation for the whole formation.Despite on apparent water saturation and low permeability of the siltstones, incidental perforation showed considerable oil inflow from them as well. In order to delineate missed productive intervals within the low-resistive siltstones, we had to develop a new rock-typing approach, acknowledging rock multimineral composition, diversity of microstructures, a wide range of porosity, permeability, and residual water saturation values.Designed laboratory program included porosity, permeability, electrical resistivity measurements, capillary, NMR and CT tests. The experiments were performed on the same core samples that enabled reliable correlation between measured parameters.The joint interpretation of flow zone indicator, calculated as a function of porosity and residual water saturation, together with the results of petrophysical and microstructural measurements allowed reliable rock-typing of the clastic formation. It will serve as a petrophysical basis for identification of the missed productive intervals.The developed laboratory program and rock-typing algorithm can be implemented in other oilfields.
本研究为低阻低渗透碎屑岩的岩石分型提供了一种新的方法。该方法包括对从计算机断层扫描(CT)和核磁共振(NMR)数据中获得的具有微观结构特征的常规岩心分析数据进行综合解释。所研究的地层底部由粉砂岩组成,顶部由砂岩取代。砂岩是油藏的主要组成部分,而粉砂岩最初被认为是水饱和的。储量计算是基于整个地层的单一Archie方程进行的。尽管粉砂岩具有明显的水饱和度和低渗透性,但偶然的射孔也显示出大量的油从中流入。为了描绘低阻粉砂岩中遗漏的生产层段,我们必须开发一种新的岩石分型方法,承认岩石的多矿物组成、微观结构的多样性、广泛的孔隙度、渗透率和残余水饱和度。设计的实验室程序包括孔隙度、渗透率、电阻率测量、毛细管、核磁共振和CT测试。实验是在相同的岩心样本上进行的,这使得测量参数之间能够进行可靠的相关性。根据孔隙度和残余水饱和度计算的流动带指标的联合解释,以及岩石物理和微观结构测量的结果,允许对碎屑岩地层进行可靠的岩石分型。它将作为识别遗漏生产层段的岩石物理基础。所开发的实验室程序和岩石分型算法可以在其他油田实施。
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引用次数: 3
Features of geological structure heavy oil field complicated palaeovalley (P-N) 地质构造特征稠油油田复杂古河谷(P-N)
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-09-30 DOI: 10.18599/grs.2022.3.6
A. Bachkov, V. Bazarevskaya, D. Anoshin
The geological study of reservoirs of heavy oil confined to the deposits of the Sheshma horizon, for further involvement of deposits in pilot production, is an expensive project in itself due to the high viscosity of oil from 200 to 200,000 MPa∙s and changes in the depth of the productive formation from 100 up to 500 m. It’s advisable to exclude all kinds of factors, including geological ones, leading to additional costs in the development of heavy oil deposits in an unstable economic situation.The purpose is determining of impact palaeovalley on the efficiency of wells using the example of heavy oil deposits. For the analysis authors have applied, materials the estimation of reserves, laboratory researches and macro descriptions of the core, the results of structural and geomorphological studies, and development parameters.It is viewed heavy oil deposits of the Sheshma horizon, complicated by palevalley, and geological structure. The porosity-permeability properties and characteristics of the bedding are given. The authors’re determined areas of palaeovalley the drilled wells, a macro description of the core and cuttings in the palaeovalley part are given. Zones of deconsolidation of the Upper Permian terrigenous deposits are identified by results of structural and geomorphological studies. A comparison of the map of predictive fracturing with the map of Pliocene formations characterizing the genesis of the palevalley is made. The authors’re comparisoned the operational capabilities of wells with the location of the wellhead in the palaeovalley zone and outside the palaeovalley. Recommendations for the design of horizontal wells complicated by palaeovalleys are determined.
对Sheshma层的稠油储层进行地质研究,以便进一步使这些储层参与试产,这本身就是一个昂贵的项目,因为石油的粘度很高,从200到200,000 MPa∙s不等,而且生产地层的深度从100到500米不等。在经济形势不稳定的情况下,最好排除各种因素,包括地质因素,这些因素会导致稠油开发成本增加。以稠油油藏为例,确定古河谷对油井效率的影响。为了进行分析,作者应用了储量估算、实验室研究和岩心宏观描述、构造和地貌研究结果以及开发参数。由于古裂谷和地质构造的复杂,发现了Sheshma层的稠油沉积。给出了层理的孔渗特性和特征。作者通过钻井确定了古河谷区域,并对古河谷部分岩心和岩屑进行了宏观描述。根据构造和地貌研究结果,确定了上二叠统陆源沉积的反固结带。将预测压裂图与表征古裂谷成因的上新世地层图进行了比较。对比了古河谷带内和古河谷外井口的作业能力和井口位置。确定了受古河谷影响的复杂水平井的设计建议。
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引用次数: 0
Carbonate reservoir rocks characterization of the Kazanian Stage of the Gorsky ultraviscous oil field by electron paramagnetic resonance method 用电子顺磁共振法表征戈尔斯基超高压油田喀山期碳酸盐岩储层
IF 0.8 Q3 ENGINEERING, PETROLEUM Pub Date : 2022-09-30 DOI: 10.18599/grs.2022.3.8
R. Mudarisova, Y. Volkov, N. M. Khasanova, B. Uspensky
The use of the electron paramagnetic resonance (EPR) method for studying carbonate rocks is widespread. EPR makes it possible to reconstruct lithological and geochemical environments of ancient sedimentation, including redox conditions and paleo-radioactivity of sedimentation basins. The paper considers the heterogeneous structure of carbonate reservoir rocks of the Kazanian Stage of the Gorsky ultraviscous oil field by paramagnetic marks: manganese ions Mn2+, radical ions SO3–, SO2–, РO22-(РO20) in carbonate minerals and radical С600 in the remains of organic matter in the rock. The carbonate reservoirs of the Gorsky structure, tectonically confined to the eastern side of the Melekess Depression, are represented by two main lithotypes: dolomitic boundstones and dolomitic oolitic packstones, which have various post-sedimentary alterations. EPR data were obtained for 28 samples with a step of 0.5-1.5 m along the section. The EPR spectra are characterized by narrow lines that indicate the marine origin of carbonates. Based on the EPR spectra of the ions Mn2+ and its content in carbonate minerals, the lagoonal-marine genesis of the Gorsky structure rocks was revealed. The dominant dolomite mineralization of the section was established. The absence of dolomite radicals and low values of the degree of population of the magnesium and calcium positions of dolomites are due to the secondary nature of carbonates. The distribution of manganese ions, organic and inorganic radicals in the rock along the section is shown simultaneously with its reservoir properties and the conditions for the formation of two dolomite lithotypes.
电子顺磁共振(EPR)方法在碳酸盐岩研究中得到了广泛的应用。EPR可以重建古沉积的岩性和地球化学环境,包括沉积盆地的氧化还原条件和古放射性。利用顺磁标记:碳酸盐岩矿物中的锰离子Mn2+、自由基离子SO3 -、SO2 -、РO22-(РO20)和岩石中有机质残留物中的自由基С600,研究了戈尔斯基超紫外油田喀山期碳酸盐岩储层的非均质结构。高尔斯基构造碳酸盐岩储层在构造上局限于梅勒克斯坳陷东侧,主要有两种岩型:白云质边界岩和白云质鲕粒包岩,它们在沉积后发生了不同的蚀变。获得了28个样品的EPR数据,沿截面步长为0.5-1.5 m。EPR光谱具有窄线特征,表明碳酸盐来源于海相。根据碳酸盐矿物中Mn2+离子的EPR谱及其含量,揭示了Gorsky构造岩的泻湖-海相成因。确定了该段白云岩成矿的主导作用。白云岩自由基的缺失和白云岩镁钙位置的低居群度是由于碳酸盐的次生性质。锰离子、有机自由基和无机自由基沿剖面在岩石中的分布与储层性质及两种白云岩型的形成条件同步显示。
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引用次数: 0
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Georesursy
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