Pub Date : 2022-04-30DOI: 10.1007/s00769-022-01503-0
Joanna Gray, Jennifer Ross, Tony Badrick
ISO Standards provide a minimal benchmark for organisations to achieve accreditation or certification and maintain compliance to the core elements of the standard. These standards assist organisations in establishing and maintaining a quality management system. Business Excellence models are integrated collections of proven activities for how an organisation should operate to pursue excellence or world-class performance and sustainability. The focus is on the customers and internal processes to meet customer expectations. The pursuit of ISO compliance and business excellence are interrelated, synergistic and will lead to common approaches for progress and sustainability if well managed. Embracing quality assurance systems, tools of organisational excellence and benchmarking against the best international standards and practices are essential for businesses operating in a global community. The Royal College of Pathologists of Australasia Quality Assurance Programs Pty Ltd has long been a compliance-driven organisation, but more recently embraced the pursuit of business excellence by adopting the Australian Business Excellence Framework. These two approaches to quality management and continual improvement are compared and the value of incorporating both approaches is explored.
{"title":"The path to continual improvement and business excellence: compliance to ISO standards versus a business excellence approach","authors":"Joanna Gray, Jennifer Ross, Tony Badrick","doi":"10.1007/s00769-022-01503-0","DOIUrl":"10.1007/s00769-022-01503-0","url":null,"abstract":"<div><p>ISO Standards provide a minimal benchmark for organisations to achieve accreditation or certification and maintain compliance to the core elements of the standard. These standards assist organisations in establishing and maintaining a quality management system. Business Excellence models are integrated collections of proven activities for how an organisation should operate to pursue excellence or world-class performance and sustainability. The focus is on the customers and internal processes to meet customer expectations. The pursuit of ISO compliance and business excellence are interrelated, synergistic and will lead to common approaches for progress and sustainability if well managed. Embracing quality assurance systems, tools of organisational excellence and benchmarking against the best international standards and practices are essential for businesses operating in a global community. The Royal College of Pathologists of Australasia Quality Assurance Programs Pty Ltd has long been a compliance-driven organisation, but more recently embraced the pursuit of business excellence by adopting the Australian Business Excellence Framework. These two approaches to quality management and continual improvement are compared and the value of incorporating both approaches is explored.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-022-01503-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3999461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-29DOI: 10.1007/s00769-022-01498-8
Jolly C. Cotara, Leah C. Dajay, Melissa O. Guerra, Mylene B. Martin, Jennifer C. Laurea, Prudencio E. Adona Jr., Maricar Giel Y. Parcarey, Chriscel Z. Capili
As the only ISO/IEC 17043:2010-accredited food PT provider in the Philippines since 2013, the Department of Science and Technology-Food and Nutrition Research Institute successfully organized a PT Round on corn-based snack food for nutrition labeling parameters. The PT Round aimed at evaluating the performance of chemical laboratories in the Asia-Pacific area on the analysis of proximates (moisture, fat, protein and ash), total dietary fiber (TDF), saturated fatty acids and minerals (iron, calcium, sodium, potassium and zinc) in corn-based snack food through an interlaboratory comparison. A sufficiently homogeneous corn-based snack food test item was distributed to 67 registered laboratories. Results were evaluated using appropriate statistical procedures based on ISO 13528:2015. The mass fractions such as moisture, fat, protein, saturated fatty acids, calcium, sodium, potassium and zinc in corn-based snack food, which have xpt with negligible uncertainties, i.e., u(xpt) ≤ 0.3σpt, were issued with z scores, while other measurands with wide variability in the results, i.e., u(xpt) > 0.3σpt, were issued with z′ scores. The xpt (in % for proximates, TDF and saturated fatty acids, and 10–5 g/g for minerals) and the percentage of laboratories that obtained “Satisfactory” performance (│z or z′ score│ ≤ 2) were: moisture (2.95, 88 %), fat (15.75, 91 %), protein (9.75, 69 %), ash (1.61, 64 %), TDF (5.04, 54 %), saturated fatty acid (5.90, 78 %), iron (2.93, 69 %), calcium (161, 74 %), sodium (139, 82 %), potassium (170, 77 %) and zinc (2.68, 85 %). This PT Round allowed to assess laboratories’ performances on the analysis of nutrition labeling parameters in corn-based snack food and improvement on performance by conducting investigative and corrective actions for those participants with “Warning” and “Action” signals.
{"title":"Provision of chemical proficiency testing round on corn-based snack food for laboratories in the Asia-Pacific","authors":"Jolly C. Cotara, Leah C. Dajay, Melissa O. Guerra, Mylene B. Martin, Jennifer C. Laurea, Prudencio E. Adona Jr., Maricar Giel Y. Parcarey, Chriscel Z. Capili","doi":"10.1007/s00769-022-01498-8","DOIUrl":"10.1007/s00769-022-01498-8","url":null,"abstract":"<div><p>As the only ISO/IEC 17043:2010-accredited food PT provider in the Philippines since 2013, the Department of Science and Technology-Food and Nutrition Research Institute successfully organized a PT Round on corn-based snack food for nutrition labeling parameters. The PT Round aimed at evaluating the performance of chemical laboratories in the Asia-Pacific area on the analysis of proximates (moisture, fat, protein and ash), total dietary fiber (TDF), saturated fatty acids and minerals (iron, calcium, sodium, potassium and zinc) in corn-based snack food through an interlaboratory comparison. A sufficiently homogeneous corn-based snack food test item was distributed to 67 registered laboratories. Results were evaluated using appropriate statistical procedures based on ISO 13528:2015. The mass fractions such as moisture, fat, protein, saturated fatty acids, calcium, sodium, potassium and zinc in corn-based snack food, which have <i>x</i><sub>pt</sub> with negligible uncertainties, i.e., <i>u</i>(<i>x</i><sub>pt</sub>) ≤ 0.3<i>σ</i><sub>pt</sub>, were issued with <i>z</i> scores, while other measurands with wide variability in the results, i.e., <i>u</i>(<i>x</i><sub>pt</sub>) > 0.3<i>σ</i><sub>pt</sub>, were issued with <i>z</i>′ scores. The <i>x</i><sub>pt</sub> (in % for proximates, TDF and saturated fatty acids, and 10<sup>–5</sup> g/g for minerals) and the percentage of laboratories that obtained “Satisfactory” performance (│<i>z</i> or <i>z</i>′ score│ ≤ 2) were: moisture (2.95, 88 %), fat (15.75, 91 %), protein (9.75, 69 %), ash (1.61, 64 %), TDF (5.04, 54 %), saturated fatty acid (5.90, 78 %), iron (2.93, 69 %), calcium (161, 74 %), sodium (139, 82 %), potassium (170, 77 %) and zinc (2.68, 85 %). This PT Round allowed to assess laboratories’ performances on the analysis of nutrition labeling parameters in corn-based snack food and improvement on performance by conducting investigative and corrective actions for those participants with “Warning” and “Action” signals.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-022-01498-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5104991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-27DOI: 10.1007/s00769-022-01499-7
Richard J. C. Brown
Dominik Pražák recently published in this journal a thoughtful discussion of the implications of a shortage of Latin letters for use in the SI. This is a short reply, intended to develop the opinions in that article.
{"title":"Reply to “Facing a shortage of the Latin letters for the prospective new SI symbols: alternative proposal for the new SI prefixes”","authors":"Richard J. C. Brown","doi":"10.1007/s00769-022-01499-7","DOIUrl":"10.1007/s00769-022-01499-7","url":null,"abstract":"<div><p>Dominik Pražák recently published in this journal a thoughtful discussion of the implications of a shortage of Latin letters for use in the SI. This is a short reply, intended to develop the opinions in that article.\u0000</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-022-01499-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5027303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-18DOI: 10.1007/s00769-022-01496-w
Fernando Cordeiro, Hendrik Emons, Piotr Robouch
Proficiency testing providers, accreditation bodies and testing laboratories should be aware that a laboratory participating in a proficiency testing round might have reported a biased result despite a satisfactory performance indicated by an assessment using uniquely the z score. A complementary performance evaluation, based on the ζ score and the assessment of the measurement uncertainty, is therefore highly recommended. This work presents an intuitive graphical tool (the Naji2 plot) that combines z and ζ scores together with the reported measurement uncertainties. This tool allows a comprehensive assessment of the laboratory performance and enables to identify the need for corrective actions. The concerned laboratory should then perform a root cause analysis and investigate their bias and/or their measurement uncertainty evaluation.
{"title":"Is the z score sufficient to assess participants’ performance in proficiency testing? The hidden corrective action","authors":"Fernando Cordeiro, Hendrik Emons, Piotr Robouch","doi":"10.1007/s00769-022-01496-w","DOIUrl":"10.1007/s00769-022-01496-w","url":null,"abstract":"<div><p>Proficiency testing providers, accreditation bodies and testing laboratories should be aware that a laboratory participating in a proficiency testing round might have reported a biased result despite a satisfactory performance indicated by an assessment using uniquely the <i>z</i> score. A complementary performance evaluation, based on the <i>ζ</i> score and the assessment of the measurement uncertainty, is therefore highly recommended. This work presents an intuitive graphical tool (the Naji2 plot) that combines <i>z</i> and <i>ζ</i> scores together with the reported measurement uncertainties. This tool allows a comprehensive assessment of the laboratory performance and enables to identify the need for corrective actions. The concerned laboratory should then perform a root cause analysis and investigate their bias and/or their measurement uncertainty evaluation.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-022-01496-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4728758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-01DOI: 10.1007/s00769-022-01495-x
Noureen Saeed, Muhammad Zeeshan, Dania Khalid Saeed, Joveria Farooqi, Sadia Shakoor, Imran Ahmed, Kausar Jabeen, Jason Rao, Rumina Hasan
Objectives
Implementation of standard laboratory practices towards accurate antimicrobial susceptibility testing (AST) is challenging in resource-constrained settings. Efforts to improve AST are required to address knowledge and practice gaps in such settings. In this study, we aimed to address these gaps through external quality assurance surveys and mentoring of laboratories in Pakistan.
Methods
This prospective study (May 2017–September 2019) included 10 consenting laboratories. External quality assessment (EQA) was conducted quarterly and performance scored. Each EQA cycle was followed by an on-site technical visit during which AST methodology, quality procedures and laboratory safety were evaluated using a questionnaire developed for this study. Cumulative scores of performance in the EQA and in the technical evaluation were designated “Composite Laboratory Performance Score; CLPS”. During on-site visits, feedback provided was to each participating laboratory towards addressing gaps identified.
Results
Over the course of the study, our data show significant improvement in CLPS amongst the laboratories included. While improvement in the CLPS scores varied between laboratories, a linear regression model showed improvement within the cohort from 21.37 (May 2017) to 91.5 (September 2019); a significant overall increase of 70.13 points (p = 0.001).
Conclusion
Interventions to improve AMR surveillance include quality assured reporting of antimicrobial resistance. Our data show that in resource-limited settings EQA surveys and on-site evaluations followed by guidance contribute towards such improvement. We propose that this model would be a useful tool for laboratory strengthening in such settings.
{"title":"External quality assessment (EQA) combined with on-site technical evaluation for capacity building in clinical microbiology laboratories in Pakistan","authors":"Noureen Saeed, Muhammad Zeeshan, Dania Khalid Saeed, Joveria Farooqi, Sadia Shakoor, Imran Ahmed, Kausar Jabeen, Jason Rao, Rumina Hasan","doi":"10.1007/s00769-022-01495-x","DOIUrl":"10.1007/s00769-022-01495-x","url":null,"abstract":"<div><h3>Objectives</h3><p>Implementation of standard laboratory practices towards accurate antimicrobial susceptibility testing (AST) is challenging in resource-constrained settings. Efforts to improve AST are required to address knowledge and practice gaps in such settings. In this study, we aimed to address these gaps through external quality assurance surveys and mentoring of laboratories in Pakistan.</p><h3>Methods</h3><p>This prospective study (May 2017–September 2019) included 10 consenting laboratories. External quality assessment (EQA) was conducted quarterly and performance scored. Each EQA cycle was followed by an on-site technical visit during which AST methodology, quality procedures and laboratory safety were evaluated using a questionnaire developed for this study. Cumulative scores of performance in the EQA and in the technical evaluation were designated “Composite Laboratory Performance Score; CLPS”. During on-site visits, feedback provided was to each participating laboratory towards addressing gaps identified.</p><h3>Results</h3><p>Over the course of the study, our data show significant improvement in CLPS amongst the laboratories included. While improvement in the CLPS scores varied between laboratories, a linear regression model showed improvement within the cohort from 21.37 (May 2017) to 91.5 (September 2019); a significant overall increase of 70.13 points (<i>p</i> = 0.001).</p><h3>Conclusion</h3><p>Interventions to improve AMR surveillance include quality assured reporting of antimicrobial resistance. Our data show that in resource-limited settings EQA surveys and on-site evaluations followed by guidance contribute towards such improvement. We propose that this model would be a useful tool for laboratory strengthening in such settings.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-022-01495-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4043036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-03DOI: 10.1007/s00769-022-01494-y
Yuhang Chen, Xinlei Qiu, Chao Feng, Qian Xu, Yuanjie Lin, Sunyang Le, Yu’e Jin, Guoquan Wang, Dasheng Lu
Monitoring pesticide residues is a key item in the field of food safety. Tea matrices represent a challenge in pesticide analysis due to the high content of coextracts. An interlaboratory comparison was organized to assess the performance of 73 laboratories, from 28 regions in China, on the quantification of five pesticide residues in tea matrix reference material in order to ensure the accuracy, reliability and comparability of monitored pesticide residues in foods. The tea matrix reference material spiked with pesticides was prepared according to ISO 17034. Briefly, blank green tea was spiked with bifenthrin, permethrin, fenpropathrin, buprofezin and imidacloprid, smashed, sieved, homogenized and bottled. It was assessed to be sufficiently homogeneous and stable. Participant laboratories were requested to submit quantification results with detailed analytical protocols. Assigned values were obtained from consensus values by robust analysis, and the results were assessed using z scores. The robust standard deviations for five pesticides were lower than the expected standard deviations in our interlaboratory comparison. In total, 93.8 % (255/272) of the results were acceptable (|z|≤ 2.0) and 82.2 % (60/73) of participant laboratories had satisfactory performance in pesticide residues quantification. Analytical protocols of extraction, cleanup and quantification methods were reviewed to assess their impacts on the results. Overall, a tea matrix reference material was successfully prepared for an interlaboratory comparison, and the results indicate that most of domestic laboratories have acceptable capability in pesticides quantification, while a few of them need to further optimize their protocols to improve performance.
{"title":"Preparation of a reference material for tea containing five pesticide residues and its evaluation in an interlaboratory comparison study in China","authors":"Yuhang Chen, Xinlei Qiu, Chao Feng, Qian Xu, Yuanjie Lin, Sunyang Le, Yu’e Jin, Guoquan Wang, Dasheng Lu","doi":"10.1007/s00769-022-01494-y","DOIUrl":"10.1007/s00769-022-01494-y","url":null,"abstract":"<div><p>Monitoring pesticide residues is a key item in the field of food safety. Tea matrices represent a challenge in pesticide analysis due to the high content of coextracts. An interlaboratory comparison was organized to assess the performance of 73 laboratories, from 28 regions in China, on the quantification of five pesticide residues in tea matrix reference material in order to ensure the accuracy, reliability and comparability of monitored pesticide residues in foods. The tea matrix reference material spiked with pesticides was prepared according to ISO 17034. Briefly, blank green tea was spiked with bifenthrin, permethrin, fenpropathrin, buprofezin and imidacloprid, smashed, sieved, homogenized and bottled. It was assessed to be sufficiently homogeneous and stable. Participant laboratories were requested to submit quantification results with detailed analytical protocols. Assigned values were obtained from consensus values by robust analysis, and the results were assessed using <i>z</i> scores. The robust standard deviations for five pesticides were lower than the expected standard deviations in our interlaboratory comparison. In total, 93.8 % (255/272) of the results were acceptable (|<i>z</i>|≤ 2.0) and 82.2 % (60/73) of participant laboratories had satisfactory performance in pesticide residues quantification. Analytical protocols of extraction, cleanup and quantification methods were reviewed to assess their impacts on the results. Overall, a tea matrix reference material was successfully prepared for an interlaboratory comparison, and the results indicate that most of domestic laboratories have acceptable capability in pesticides quantification, while a few of them need to further optimize their protocols to improve performance.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4119140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-03DOI: 10.1007/s00769-021-01486-4
Kemal Ozcan, Timur Canel, Erdogan Tarcan
Natural gas is the most widely used energy source among other gases. For this reason, measuring the gross calorific value with very high precision is of great importance for users and sellers. With the reference calorimeter designed in this study, it was aimed to obtain the calorific value “Hm” of the methane gas which is the principal component of the natural gas and has the EN ISO 6976:2016 standard. The measurements made with the designed and manufactured reference calorimeter were evaluated. The reference calorimeter can measure temperature, mass, power, amount of wastewater absorbed, type and amount of waste gas with the highest precision that TUBITAK-NMI (The Scientific and Technological Research Council of Turkey)-(National Metrology Institute) can measure. Measurements made with the designed calorimeter were insulated so that there is no heat exchange from the external environment, while the gas flow rate and temperature provided by using stable temperature sources are controlled. Certified calibration instruments were used in all measurements. The experiments were carried out at a temperature of 298.16 K. The methane gas with 99.995 % purity was used as the reference gas and as a result of the measurements; experimental data were obtained with errors ranging from 0.5 % / 0.1 %. Analyses from experimental data have shown that the greatest error in gross calorific value “(Hm)G” is due to temperature and mass measurements. The mean gross calorific value obtained using eight measurements is 55460.60 kJ kg−1 or 889.03343 kJ mol−1 within a relative expanded uncertainty of 0.2 % (k = 2).
在其他气体中,天然气是使用最广泛的能源。因此,高精度地测量总发热量对用户和销售商都具有重要意义。本研究设计的参考量热计旨在获得天然气的主要成分甲烷气体的热值“Hm”,甲烷气体具有EN ISO 6976:2016标准。对设计和制造的参比量热计的测量结果进行了评价。参考量热计可以测量温度,质量,功率,废水吸收量,废气类型和数量,具有TUBITAK-NMI(土耳其科学技术研究委员会)-(国家计量研究所)可以测量的最高精度。用所设计的量热计进行的测量是绝缘的,因此没有来自外部环境的热交换,同时控制使用稳定温度源提供的气体流速和温度。所有测量均使用经认证的校准仪器。实验在298.16 K的温度下进行。以纯度为99.995%的甲烷气体为参比气体,作为测定结果;得到的实验数据误差在0.5% / 0.1%之间。对实验数据的分析表明,总热值“(Hm)G”的最大误差是由温度和质量测量引起的。在相对扩展不确定度为0.2% (k = 2)的范围内,八次测量得到的平均总热值为55460.60 kJ kg - 1或889.03343 kJ mol - 1。
{"title":"Improvement of reference gas calorimeter to measure the gross calorific value of the reference methane gas having high purity (99.995 %) and calculation of uncertainty","authors":"Kemal Ozcan, Timur Canel, Erdogan Tarcan","doi":"10.1007/s00769-021-01486-4","DOIUrl":"10.1007/s00769-021-01486-4","url":null,"abstract":"<div><p>Natural gas is the most widely used energy source among other gases. For this reason, measuring the gross calorific value with very high precision is of great importance for users and sellers. With the reference calorimeter designed in this study, it was aimed to obtain the calorific value “<i>H</i><sub><i>m</i></sub>” of the methane gas which is the principal component of the natural gas and has the EN ISO 6976:2016 standard. The measurements made with the designed and manufactured reference calorimeter were evaluated. The reference calorimeter can measure temperature, mass, power, amount of wastewater absorbed, type and amount of waste gas with the highest precision that TUBITAK-NMI (The Scientific and Technological Research Council of Turkey)-(National Metrology Institute) can measure. Measurements made with the designed calorimeter were insulated so that there is no heat exchange from the external environment, while the gas flow rate and temperature provided by using stable temperature sources are controlled. Certified calibration instruments were used in all measurements. The experiments were carried out at a temperature of 298.16 K. The methane gas with 99.995 % purity was used as the reference gas and as a result of the measurements; experimental data were obtained with errors ranging from 0.5 % / 0.1 %. Analyses from experimental data have shown that the greatest error in gross calorific value “(<i>H</i><sub><i>m</i></sub>)<sub>G</sub>” is due to temperature and mass measurements. The mean gross calorific value obtained using eight measurements is 55460.60 kJ kg<sup>−1</sup> or 889.03343 kJ mol<sup>−1</sup> within a relative expanded uncertainty of 0.2 % (<i>k</i> = 2).</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4118928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-03DOI: 10.1007/s00769-022-01493-z
Huu Tam Tran, Ngoc Nguyen Vo, Quan Thuy Truong
The production of a simulated urine sample is necessary for external quality assessment schemes in clinical testing. This study aimed to optimize the formulation of a simulated urine sample containing patient urine bacterial Enterococcus faecalis via response surface methodology based on central composite design. The results of a Plackett–Burman design experiment showed that three factors including sodium thioglycolate and peptone concentration and pH value significantly effected to concentration of E. faecalis. Notably, an initial concentration of 1.51 mg/mL of sodium thioglycolate and 3.63 mg/mL of peptone at a pH value of 8.06 of culture medium has been found to maximize the E. faecalis concentration (7.05 log (CFU/mL)). This optimal condition could be applied for production of a simulated urine sample containing E. faecalis.
{"title":"Optimization of medium composition for production of a simulated urine sample containing Enterococcus faecalis","authors":"Huu Tam Tran, Ngoc Nguyen Vo, Quan Thuy Truong","doi":"10.1007/s00769-022-01493-z","DOIUrl":"10.1007/s00769-022-01493-z","url":null,"abstract":"<div><p>The production of a simulated urine sample is necessary for external quality assessment schemes in clinical testing. This study aimed to optimize the formulation of a simulated urine sample containing patient urine bacterial <i>Enterococcus faecalis</i> via response surface methodology based on central composite design. The results of a Plackett–Burman design experiment showed that three factors including sodium thioglycolate and peptone concentration and pH value significantly effected to concentration of <i>E. faecalis</i>. Notably, an initial concentration of 1.51 mg/mL of sodium thioglycolate and 3.63 mg/mL of peptone at a pH value of 8.06 of culture medium has been found to maximize the <i>E. faecalis</i> concentration (7.05 log (CFU/mL)). This optimal condition could be applied for production of a simulated urine sample containing <i>E. faecalis</i>. \u0000</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4462362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-01DOI: 10.1007/s00769-021-01490-8
Xiaoru Xing, Tao Feng, Dajun Xu, Lamei Wang, Zijie Sun, Ping He
This paper introduces the implementation of ISO Guide 34 and ISO 17034 in the Mainland of P R China, especially from the accreditation viewpoint. The comparisons are made regarding different aspects in accreditation, including the accreditation number, the growth (rate) as well as the findings identified during onsite assessments between reference material producers and testing laboratories. The distribution of the non-conformities is also discussed to show the impact of the changed structure from ISO Guide 34 to ISO 17034, with the presentation of highlighted typical non-conformities against ISO 17034.
{"title":"Implementation of ISO 17034 & Guide 34 in China","authors":"Xiaoru Xing, Tao Feng, Dajun Xu, Lamei Wang, Zijie Sun, Ping He","doi":"10.1007/s00769-021-01490-8","DOIUrl":"10.1007/s00769-021-01490-8","url":null,"abstract":"<div><p>This paper introduces the implementation of ISO Guide 34 and ISO 17034 in the Mainland of P R China, especially from the accreditation viewpoint. The comparisons are made regarding different aspects in accreditation, including the accreditation number, the growth (rate) as well as the findings identified during onsite assessments between reference material producers and testing laboratories. The distribution of the non-conformities is also discussed to show the impact of the changed structure from ISO Guide 34 to ISO 17034, with the presentation of highlighted typical non-conformities against ISO 17034.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-021-01490-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4021547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-29DOI: 10.1007/s00769-021-01487-3
Igor Renato Bertoni Olivares, Gilberto Batista de Souza, Ana Rita de Araujo Nogueira, Vitor Hugo Polisél Pacces, Pamela Aparecida Grizotto, Paula Souza da Silva Gomes Lima, Rhaissa Mecca Bontempi
The importance of quality in analytical chemistry stimulates the development of different tools to assure the reliability of analytical results. Among different tools, proficiency testing (PT) stands out because it can be used to evaluate bias, check uncertainty, train analysts, or certify if a laboratory can execute a method adequately and provide correct results. There is a growing demand for traceable and reliable results in analytical chemistry, which can be illustrated with the growth of ISO/IEC 17025 accreditation and the importance of PT in this context. This has led to an increase in developments and publications about PT programs. This paper reports a detailed review considering the best practices to develop PT for chemical analysis, focusing on food and environmental matrices. An evaluation of the trends and the statistical strategies in its development in the last two years was performed to guide new developments of this tool that is increasingly necessary for laboratories.
{"title":"Trends in the development of proficiency testing for chemical analysis: focus on food and environmental matrices","authors":"Igor Renato Bertoni Olivares, Gilberto Batista de Souza, Ana Rita de Araujo Nogueira, Vitor Hugo Polisél Pacces, Pamela Aparecida Grizotto, Paula Souza da Silva Gomes Lima, Rhaissa Mecca Bontempi","doi":"10.1007/s00769-021-01487-3","DOIUrl":"10.1007/s00769-021-01487-3","url":null,"abstract":"<div><p>The importance of quality in analytical chemistry stimulates the development of different tools to assure the reliability of analytical results. Among different tools, proficiency testing (PT) stands out because it can be used to evaluate bias, check uncertainty, train analysts, or certify if a laboratory can execute a method adequately and provide correct results. There is a growing demand for traceable and reliable results in analytical chemistry, which can be illustrated with the growth of ISO/IEC 17025 accreditation and the importance of PT in this context. This has led to an increase in developments and publications about PT programs. This paper reports a detailed review considering the best practices to develop PT for chemical analysis, focusing on food and environmental matrices. An evaluation of the trends and the statistical strategies in its development in the last two years was performed to guide new developments of this tool that is increasingly necessary for laboratories.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2022-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5118358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}