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Fluctuations in Human's Walking (IV) 人类行走的波动(四)
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897889
T. Obata, T. Mashiyama, T. Kogure, S. Itakura, T. Sato, K. Takahashi, H. Oshima, Hiroaki Hara
A field experiment of ring‐wandering is executed on a wide playground. Blindfolded and stoppled subjects are observed to do ring‐wandering rather than random‐walking. This experiment simulates the phenomenon of ring‐wandering that climbers encounter in snowy mountains. 15 samples of walking for 13 subjects are reported. Their walking periods are about 40 minutes or 2 hours. The walking data are acquired every second, using a GPS receiver. The discrete velocity v(t) and discrete angular velocity ω(t) of the data are analyzed, using Hurst's R/S analysis and Fourier spectrum analysis. The Hurst exponents of v(t) show long‐range correlations. The Hurst exponents of ω(t) show anti‐correlations in short‐ranges and correlations in long‐ranges. These characteristics of the Hurst exponents in the present data in addition to previous data in this study series describe the ring‐wandering phenomena very well. Significant differences are not seen between 40‐minutes walking and 2‐hours walking.
在一个宽阔的场地上进行了环漂移的现场实验。被蒙住眼睛和被阻止的受试者被观察到做环形漫游而不是随机行走。这个实验模拟了登山者在雪山中遇到的环漂移现象。报告了13个受试者的15个步行样本。他们的步行时间约为40分钟或2小时。通过GPS接收器,每秒钟采集一次行走数据。利用赫斯特R/S分析和傅立叶谱分析,对数据的离散速度v(t)和离散角速度ω(t)进行了分析。v(t)的Hurst指数显示出长期相关性。ω(t)的Hurst指数在短期表现为反相关,在长期表现为相关。这些赫斯特指数在当前数据中的特征以及本研究系列中以前的数据都很好地描述了环漂移现象。步行40分钟和步行2小时之间没有显著差异。
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引用次数: 0
Liquid Polyamorphism: Some Unsolved Puzzles of Water in Bulk, Nanoconfined, and Biological Environments 液体多变性:水在体积、纳米和生物环境中的一些未解之谜
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897798
H. Stanley, Pradeep Kumar, G. Franzese, Limei Xu, Zhen-Wei Yan, M. Mazza, S. H. Chen, F. Mallamace, S. Buldyrev
We investigate the relation between changes in dynamic and thermodynamic anomalies arising from the presence of the liquid‐liquid critical point in (i) Two models of water, TIP5P and ST2, which display a first order liquid‐liquid phase transition at low temperatures; (ii) the Jagla model, a spherically symmetric two‐scale potential known to possess a liquid‐liquid critical point, in which the competition between two liquid structures is generated by repulsive and attractive ramp interactions; and (iii) A Hamiltonian model of water where the idea of two length/energy scales is built in; this model also displays a first order liquid‐liquid phase transition at low temperatures besides the first order liquid‐gas phase transition at high temperatures. We find a correlation between the dynamic fragility crossover and the locus of specific heat maxima CPmax (“Widom line”) emanating from the critical point. Our findings are consistent with a possible relation between the previously hypothesized liquid‐liquid phase transition and the transition in the dynamics recently observed in neutron scattering experiments on confined water. More generally, we argue that this connection between CPmax and the dynamic crossover is not limited to the case of water, a hydrogen bonded network liquid, but is a more general feature of crossing the Widom line, an extension of the first‐order coexistence line in the supercritical region. We present evidence from experiments and computer simulations supporting the hypothesis that water displays polyamorphism, i.e., water separates into two distinct liquid phases. This concept of a new liquid‐liquid phase transition is finding application to other liquids as well as water, such as silicon and silica. We also discuss related puzzles, such as the mysterious behavior of confined water and the “skin” of hydration water near a biomolecule. Specifically, using molecular dynamics simulations, we also investigate the relation between the dynamic transitions of biomolecules (lysozyme and DNA) and the dynamic and thermodynamic properties of hydration water. We find that the dynamic transition of the macromolecules, sometimes called a “protein glass transition”, occurs at the temperature of dynamic crossover in the diffusivity of hydration water, and also coincides with the maxima of the isobaric specific heat CP and the temperature derivative of the orientational order parameter. We relate these findings to the hypothesis of a liquid‐liquid critical point in water. Our simulations are consistent with the possibility that the protein glass transition results from a change in the behavior of hydration water, specifically from crossing the Widom line.We investigate the relation between changes in dynamic and thermodynamic anomalies arising from the presence of the liquid‐liquid critical point in (i) Two models of water, TIP5P and ST2, which display a first order liquid‐liquid phase transition at low temperatures; (ii) the Jagla model, a sph
我们研究了(i)两种水模型TIP5P和ST2中由于液-液临界点的存在而引起的动力学和热力学异常变化之间的关系,这两种模型在低温下表现为一级液-液相变;(ii) Jagla模型,一个已知具有液-液临界点的球对称二尺度势,其中两种液体结构之间的竞争是由排斥和吸引斜坡相互作用产生的;(iii)水的哈密顿模型,其中建立了两个长度/能量尺度的概念;除了高温下的一阶液相-气相转变外,该模型还显示了低温下的一阶液相-液相相变。我们发现动态脆性交叉与从临界点出发的比热最大值CPmax(“智慧线”)轨迹之间存在相关性。我们的发现与之前假设的液-液相变与最近在承压水中中子散射实验中观察到的动力学转变之间的可能关系一致。更一般地说,我们认为CPmax和动态交叉之间的这种联系并不局限于水(氢键网络液体)的情况,而是跨越Widom线(超临界区域一阶共存线的延伸)的更普遍的特征。我们从实验和计算机模拟中提出证据,支持水表现出多相性的假设,即水分成两个不同的液相。这种新的液-液相变的概念正在寻找其他液体以及水的应用,如硅和二氧化硅。我们还讨论了相关的难题,如封闭水的神秘行为和水合水在生物分子附近的“皮肤”。具体来说,通过分子动力学模拟,我们还研究了生物分子(溶菌酶和DNA)的动态转变与水合水的动力学和热力学性质之间的关系。我们发现大分子的动态转变,有时被称为“蛋白质玻璃化转变”,发生在水化水扩散率的动态交叉温度,也与等压比热CP的最大值和取向顺序参数的温度导数一致。我们将这些发现与水存在液-液临界点的假设联系起来。我们的模拟结果与蛋白质玻璃化转变的可能性是一致的,这是由于水合水的行为发生了变化,特别是由于越过了“智慧线”。我们研究了(i)两种水模型TIP5P和ST2中由于液-液临界点的存在而引起的动力学和热力学异常变化之间的关系,这两种模型在低温下表现为一级液-液相变;(ii) Jagla模型,一个已知具有液-液临界点的球对称二尺度势,其中两种液体结构之间的竞争是由排斥和吸引斜坡相互作用产生的;(iii)水的哈密顿模型,其中建立了两个长度/能量尺度的概念;除了高温下的一阶液相-气相转变外,该模型还显示了低温下的一阶液相-液相相变。我们发现动态脆性交叉与从临界点出发的比热最大值CPmax(“智慧线”)轨迹之间存在相关性。我们的发现与之前假设的液-液相之间的可能关系是一致的。
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引用次数: 9
Brillouin and Raman Scattering Study of Ethylene Glycol Aqueous Solutions 乙二醇水溶液的布里渊散射和拉曼散射研究
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897819
Y. Seshimo, Y. Ike, S. Kojima
We studied the cluster structure of ethylene glycol aqueous solutions by Brillouin and Raman scattering. We measured the ultrasonic sound velocity of the sample by Brillouin scattering. From the concentration dependence of the sound velocity, we studied the cluster structure in the solution. We showed that the number of H2O molecule neighboring a EG molecule becomes a little higher with increasing temperature and the intermolecular interaction between EG and H2O molecules weakened with increasing temperature. In Raman scattering study, We studied the hydrogen bond in the solution using the OD stretching band. We revealed that the strength of the hydrogen bond is independent of the EG concentration.
利用布里渊散射和拉曼散射研究了乙二醇水溶液的团簇结构。用布里渊散射法测量了样品的超声声速。从声速的浓度依赖性出发,研究了溶液中的团簇结构。结果表明,随着温度的升高,EG分子与H2O分子之间的相互作用逐渐减弱,而与EG分子相邻的H2O分子数量逐渐增加。在拉曼散射研究中,我们用OD拉伸带研究了溶液中的氢键。我们发现氢键的强度与EG的浓度无关。
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引用次数: 2
A Theory of Electrical Conductivity of Pseudo‐Binary Equivalent Molten Salt 伪二元等效熔盐的电导率理论
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897825
S. Matsunaga, T. Koishi, S. Tamaki
Many years ago, Sundheim proposed the “universal golden rule” by experiments, i.e. the ratio of the partial ionic conductivities in molten binary salt is equal to the inverse mass ratio of each ions, σ+/σ− = m−/m−. In the previous works, we have proved this relation by the theory using Langevin equation, and by molecular dynamics simulations (MD). In this study, the pseudo binary molten salt NaCl‐KCl system is investigated in the same theoretical framework as previous works as the serial work in molten salts. The MD results are also reported in connection with the theoretical analysis.
多年前,Sundheim通过实验提出了“通用黄金法则”,即熔融二元盐中部分离子电导率的比值等于各离子质量的反比,σ+/σ−= m−/m−。在以前的工作中,我们已经用朗之万方程和分子动力学模拟证明了这一关系。在本研究中,我们采用与之前研究熔盐系列工作相同的理论框架研究了伪二元熔盐NaCl - KCl体系。结合理论分析,还报道了MD结果。
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引用次数: 2
Dynamic crossover phenomenon in confined supercooled water and its relation to the existence of a liquid-liquid critical point in water 承压过冷水中的动态交叉现象及其与水中液-液临界点存在的关系
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897826
Sow-Hsin Chen, F. Mallamace, Li Liu, Dazhi Liu, Xiang-Qiang Chu, Yang Zhang, Chansoo Kim, A. Faraone, C. Mou, E. Fratini, P. Baglioni, A. Kolesnikov, V. García-Sakai
We have observed a Fragile‐to‐Strong Dynamic Crossover (FSC) phenomenon of the α‐relaxation time and self‐diffusion constant in confined supercooled water. The α‐relaxation time is measured by Quasielastic Neutron Scattering (QENS) experiments and the self‐diffusion constant by Nuclear Magnetic Resonance (NMR) experiments. Water is confined in 1‐d geometry in cylindrical pores of nanoscale silica materials, MCM‐41‐S and in Double‐Wall Carbon Nanotubes (DWNT). The crossover phenomenon can also be observed from appearance of a Boson peak in Incoherent Inelastic Neutron Scattering experiments. We observe a pronounced violation of the Stokes‐Einstein Relation at and below the crossover temperature at ambient pressure. Upon applying pressure to the confined water, the crossover temperature is shown to track closely the Widom line emanating from the existence of a liquid‐liquid critical point in an unattainable deeply supercooled state of bulk water. Relation of the dynamic crossover phenomenon to the existence of a density minimum in supercooled confined water is discussed. Finally, we discuss a role of the FSC of the hydration water in a biopolymer that controls the biofunctionality of the biopolymer.We have observed a Fragile‐to‐Strong Dynamic Crossover (FSC) phenomenon of the α‐relaxation time and self‐diffusion constant in confined supercooled water. The α‐relaxation time is measured by Quasielastic Neutron Scattering (QENS) experiments and the self‐diffusion constant by Nuclear Magnetic Resonance (NMR) experiments. Water is confined in 1‐d geometry in cylindrical pores of nanoscale silica materials, MCM‐41‐S and in Double‐Wall Carbon Nanotubes (DWNT). The crossover phenomenon can also be observed from appearance of a Boson peak in Incoherent Inelastic Neutron Scattering experiments. We observe a pronounced violation of the Stokes‐Einstein Relation at and below the crossover temperature at ambient pressure. Upon applying pressure to the confined water, the crossover temperature is shown to track closely the Widom line emanating from the existence of a liquid‐liquid critical point in an unattainable deeply supercooled state of bulk water. Relation of the dynamic crossover phenomenon to the existence...
在受限过冷水中,我们观察到α -弛豫时间和自扩散常数的脆性-强动态交叉(FSC)现象。用准弹性中子散射(QENS)实验测量了α -弛豫时间,用核磁共振(NMR)实验测量了自扩散常数。水被限制在纳米级二氧化硅材料MCM - 41 - S和双壁碳纳米管(DWNT)的圆柱形孔中,呈一维几何形状。从非相干非弹性中子散射实验中玻色子峰的出现也可以观察到交叉现象。我们观察到在环境压力下的交叉温度及以下明显违反斯托克斯-爱因斯坦关系。当对承压水施加压力时,交叉温度显示出密切跟踪从存在的液-液临界点而产生的智慧线,该临界点处于散装水无法达到的深度过冷状态。讨论了过冷承压水中动态交叉现象与密度极小值存在的关系。最后,我们讨论了水合水的FSC在生物聚合物中控制生物聚合物的生物功能的作用。在受限过冷水中,我们观察到α -弛豫时间和自扩散常数的脆性-强动态交叉(FSC)现象。用准弹性中子散射(QENS)实验测量了α -弛豫时间,用核磁共振(NMR)实验测量了自扩散常数。水被限制在纳米级二氧化硅材料MCM - 41 - S和双壁碳纳米管(DWNT)的圆柱形孔中,呈一维几何形状。从非相干非弹性中子散射实验中玻色子峰的出现也可以观察到交叉现象。我们观察到在环境压力下的交叉温度及以下明显违反斯托克斯-爱因斯坦关系。当对承压水施加压力时,交叉温度显示出密切跟踪从存在的液-液临界点而产生的智慧线,该临界点处于散装水无法达到的深度过冷状态。动态交叉现象与存在的关系
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引用次数: 20
Viscoelasticity and Dynamics of Single Biopolymer Chain Measured with Magnetically Modulated Atomic Force Microscopy 用磁调制原子力显微镜测量生物聚合物单链的粘弹性和动力学
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897846
M. Kageshima, Y. Nishihara, Y. Hirata, T. Inoue, Y. Naitoh, Y. Sugawara
Viscoelactic response of a titin single molecule chain during the course of forced unraveling was studied using atomic force microscopy. Effect of transition to/from an unfolding intermediate onto the measured elasticity data was analyzed. The result hinted that emergence of the transition onto the elasticity depends on the experimental condition such as modulation force amplitude. Anomalous slow unraveling of one domain was observed and its viscoelastic response was discussed from the viewpoint of internal friction of polymer.
用原子力显微镜研究了titin单分子链在强制展开过程中的粘弹性响应。分析了从展开中间体过渡到展开中间体对弹性测量数据的影响。结果表明,弹性过渡的出现取决于调制力振幅等实验条件。从聚合物内摩擦的角度讨论了其中一个区域的反常慢解及其粘弹性响应。
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引用次数: 2
Radio‐Frequency, Atmospheric‐Pressure Glow Discharges: Producing Methods, Characteristics and Applications in Bio‐Medical Fields 射频、大气压辉光放电:产生方法、特性及其在生物医学领域的应用
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897862
He-ping Li, Guo Li, Wenting Sun, Sen Wang, Cheng-Yu Bao, Liyan Wang, Ziliang Huang, Nan Ding, Hongxin Zhao, X. Xing
Radio‐frequency (RF), atmospheric‐pressure glow discharge (APGD) plasmas with bare metallic electrodes have shown their promising prospects in different fields. In this paper, based on the induced gas discharge approach, the discharge characteristics of RF, APGD plasmas using helium/oxygen mixture as the plasma working‐gas are presented. The bio‐medical effects of the helium RF APGD plasma jet acting on the gfp DNA and E. coli are also reported. Studies concerning the lethal and sub‐lethal effects of the RF APGDs on the molecular and cell levels, which are related with the characteristics of the plasmas and their operation conditions are necessary in the future work based on a closer cooperation between the researchers in the field of the plasma science & technology and of the bio‐medical science.
裸露金属电极的射频(RF)、常压辉光放电(APGD)等离子体在不同领域显示出了广阔的应用前景。本文基于诱导气体放电方法,研究了以氦/氧混合气体作为等离子体工作气体的RF、APGD等离子体的放电特性。本文还报道了氦射频APGD等离子体射流作用于gfp DNA和大肠杆菌的生物医学效应。射频apgd在分子和细胞水平上的致死性和亚致死性效应研究与等离子体特性及其操作条件有关,是今后等离子体科学与技术领域和生物医学领域研究人员密切合作的必要基础。
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引用次数: 7
Chain Structures of Microparticles Induced by Focusing a Laser Beam near the Liquid‐Air Interface of a Droplet 在液滴液-气界面附近聚焦激光束诱导的微粒链结构
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897886
H. Adachi, K. Miyakawa
We investigate optically induced dynamics of micron‐sized particles by focusing a laser beam near the liquid‐air interface of a suspension droplet. We find three distinct regimes in behaviors of particles depending on the contact angle of the droplet: convection, linear flow and formation of a closed‐packed array. These behaviors are governed by the most dominant of effects arising from a focused laser beam, such as local heating and radiation pressure. We find that micron‐sized polystyrene beads can be assembled into a chain structure by taking advantage of linear flows. This novel method is applicable to the formation of a chain of carbon nanotubes, non‐transparent objects which are difficult to trap.
我们通过将激光束聚焦在悬浮液滴的液-气界面附近来研究微米级粒子的光诱导动力学。根据液滴的接触角,我们发现粒子的行为有三种不同的形式:对流、线性流动和封闭排列的形成。这些行为是由聚焦激光束产生的最主要的效应所控制的,例如局部加热和辐射压力。我们发现微米级的聚苯乙烯珠可以利用线性流动的优势组装成链状结构。这种新方法适用于碳纳米管链的形成,碳纳米管是一种难以捕获的非透明物体。
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引用次数: 0
Explanation of Correlation between Adjacent Vertices in Network Formed by Traces of Random Walkers 随机步行者轨迹形成的网络中相邻顶点间相关性的解释
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897891
N. Ikeda
We investigated certain kinds of vertex correlation in networks formed by traces of random walkers. In this paper, the sign of correlation between degree and local clustering on adjacent vertices is interpreted based on the capacity for new creation of links for highly connected vertices. These interpretations are consistent with numerical simulation of network evolution. Other types of correlation can be related with each other. It is interesting that the local rules of network evolution determined by the movement of random walkers naturally provide large clustering coefficients and various finite vertex correlations.
我们研究了由随机步行者轨迹组成的网络中某些类型的顶点关联。在本文中,基于高度连接顶点的新创建链接的能力,解释了相邻顶点的度与局部聚类之间的相关符号。这些解释与网络演化的数值模拟结果一致。其他类型的相关性可以相互关联。有趣的是,由随机行走者的运动所决定的局部网络进化规则自然地提供了大的聚类系数和各种有限的顶点关联。
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引用次数: 0
Effectiveness of Slow Relaxation Dynamics in Finite-Time Optimization by Simulated Annealing 慢弛豫动力学在模拟退火有限时间优化中的有效性
IF 1.2 Q3 Computer Science Pub Date : 2008-02-27 DOI: 10.1063/1.2897906
M. Hasegawa
The origin of the specific temperature beneficial to finite‐time optimization by simulated annealing is discussed on the analogy of the dynamics of complex physical systems. Rate‐cycling experiments are introduced and performed on practical time scales on the random Euclidean traveling salesman problems. In the present systems, the effective relaxation dynamics and the resulting good optimization performance are not only dependent on but also sensitive to the search around an intermediate temperature. This influential temperature is understood to be determined from the temperature dependence of the Deborah number used to identify glass transition.
通过对复杂物理系统动力学的类比,讨论了有利于模拟退火有限时间优化的比温度的来源。介绍了速率循环实验,并在实际时间尺度上对随机欧几里得旅行商问题进行了实验。在现有的系统中,有效的松弛动力学和由此产生的良好的优化性能不仅依赖于中间温度附近的搜索,而且对中间温度附近的搜索敏感。据了解,这一影响温度是由用于识别玻璃化转变的底波拉数的温度依赖性决定的。
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引用次数: 1
期刊
Complex Systems
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