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Chemical shift tensors as probes of chalcogen bonds: solid-state NMR study of telluradiazole-XCN (X = O, S, Se) salt cocrystals 化学位移张量作为硫键探针:碲二唑- xcn−(X = O, S, Se)盐共晶的固态核磁共振研究
3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2023-0082
Carina Almario, Tamali Nag, David L. Bryce
We report experimental 125 Te magic-angle spinning solid-state nuclear magnetic resonance (MAS NMR) measurements of the tellurium chemical shift (CS) tensors in three [K(18-crown-6)] + 3,4-dicyano-1,2,5-telluradiazole-XCN − (X = O, S, Se) salt cocrystals featuring chalcogen bonds. These data are compared to those for pure 3,4-dicyano-1,2,5-telluradiazole (1). A reduction in the span of the 125 Te CS tensor is consistently noted in the salt cocrystals compared to pure 1. Isotopically 15 N-labelled [K(18-crown-6)] + [1-OC 15 N] − , which features a chalcogen bond between Te and the cyanate nitrogen atom, is synthesized using KOC 15 N, and the nitrogen CS tensors are measured for both samples via 15 N slow MAS NMR spectroscopy. Possible dynamic disorder of the cyanate ions in KOCN is ruled out. Two crystallographically distinct nitrogen sites are resolved for the salt cocrystal. Upon formation of [K(18-crown-6)] + [1-OC 15 N] − , the 15 N isotropic CS and CS tensor span both decrease relative to the values for pure KOC 15 N, and the axial symmetry of this tensor is lost. These findings are supplemented with a series of density functional theory calculations of magnetic shielding tensors using cluster models or periodic boundary conditions. Inclusion of spin–orbit relativistic effects in the calculation of tellurium shielding tensors is particularly important in achieving agreement with experiment.
本文报道了三种[K(18-冠-6)]+ 3,4-二氰-1,2,5-telluradiazol - xcn−(X = O, S, Se)盐共晶中碲化学位移(CS)张量的魔角旋转固体核磁共振(MAS NMR)实验测量。这些数据与纯3,4-二氰-1,2,5-碲二唑(1)的数据进行了比较。与纯1相比,盐共晶中125 Te CS张量的跨度减小一致。用KOC - 15n合成了同位素- N标记的[K(18-crown-6)] + [1-OC - 15n]−,其特征是Te与氰酸氮原子之间存在一个硫键,并通过15n慢MAS NMR测量了两种样品的氮CS张量。排除了KOCN中氰酸盐离子可能的动力学紊乱。两个晶体学上不同的氮位点被分解为盐共晶。当[K(18-crown-6)] + [1-OC 15n]−形成时,15n各向同性CS和CS张量跨度都相对于纯KOC 15n的值减小,并且失去了该张量的轴对称。这些发现补充了一系列使用簇模型或周期边界条件的磁屏蔽张量的密度泛函理论计算。在碲屏蔽张量的计算中包含自旋轨道相对论效应对于与实验结果一致是非常重要的。
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引用次数: 0
Prediction method of soil horizontal displacement caused by non-uniform distribution of disturbance force in shield construction 盾构施工扰动力不均匀分布引起的土体水平位移预测方法
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0197
Baoxin Jia, Zong-xian Gao, Hong-yan Hua
Based on the Mindlin solution, this paper considers the influence of factors such as the non-uniform distribution of additional thrust of the cutter head influenced by lateral earth pressure in shield excavation, the non-uniform distribution of friction of shield shell influenced by soil softening and slurry spreading, and the non-uniform distribution of grouting pressure influenced by slurry spreading on the horizontal displacement of soil. The existing prediction formula is revised and verified by engineering examples. It is found that: affected by the shield construction disturbance force, the horizontal displacement behind the excavation surface is larger than that in front of the excavation surface, and the peak value of the horizontal displacement appears around the tunnel axis; through the verification of engineering case, when calculating the horizontal displacement in front of the excavation surface, the calculation results of both the modified formula and the original formula are in good agreement with the measured values, which can reflect the change trend of the measured horizontal displacement; when calculating the horizontal displacement behind the excavation surface, the calculation result of the existing formula has a great error due to the assumption of uniform distribution of disturbance force, which is different from the law of the measured result; the calculation result of the modified prediction formula is obviously in better agreement with the measured deformation value, and the error is smaller, which is more in line with the engineering reality.
基于Mindlin解,本文考虑了盾构开挖中侧向土压力对刀盘附加推力分布的不均匀性、土体软化和浆液铺展对盾构壳体摩擦分布的不一致性等因素的影响,浆液铺展对土体水平位移的影响以及注浆压力的不均匀分布。对现有的预测公式进行了修正,并通过工程实例进行了验证。研究发现:受盾构施工扰动力影响,开挖面后水平位移大于开挖面前水平位移,水平位移峰值出现在隧道轴线附近;通过工程实例验证,在计算开挖面前水平位移时,修正公式和原公式的计算结果与实测值吻合较好,能够反映实测水平位移的变化趋势;在计算开挖面后水平位移时,由于假定扰动力均匀分布,现有公式的计算结果存在较大误差,与实测结果的规律不同;修正后的预测公式计算结果与实测变形值吻合较好,误差较小,更符合工程实际。
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引用次数: 0
Can fisheries be “regenerative”? Adapting agroecological concepts for fisheries and the blue economy 渔业可以“再生”吗?适应渔业和蓝色经济的农业生态概念
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2023-0011
P. Loring
Regenerative design, in which agricultural practices are organized to work with nutrient cycles and successional processes, is increasingly being explored in food systems research and practice. In this commentary, I explore whether regenerative design concepts can be adapted to marine contexts, given increased global interest in the potential of marine ecosystems to support sustainable development, i.e., the blue economy. There are numerous fundamental ecological differences between terrestrial and marine ecologies that make it difficult to directly translate regenerative farming's focus on managing the nutrient cycle. However, building on a framework for regenerative food systems that focuses on how production activities are organized rather than the specific practices and technologies in use, I find multiple useful parallels to familiar patterns in the fisheries literature, specifically, fishing down the food web, poverty traps, and portfolio-based fishing. I conclude with a discussion of directions for research on regenerative fisheries and concerns regarding the potential for greenwashing under the banner of a regenerative blue economy.
再生设计,即农业实践与营养循环和演替过程相结合,在食品系统研究和实践中越来越多地被探索。在这篇评论中,我探讨了再生设计概念是否可以适应海洋环境,因为全球对海洋生态系统支持可持续发展(即蓝色经济)的潜力越来越感兴趣。陆地生态和海洋生态之间存在许多根本的生态差异,这使得很难直接转化再生农业对管理营养循环的关注。然而,在再生粮食系统框架的基础上,重点关注生产活动的组织方式,而不是使用的具体做法和技术,我发现与渔业文献中熟悉的模式有很多有用的相似之处,特别是在粮食网中捕鱼、贫困陷阱和基于投资组合的捕鱼。最后,我讨论了再生渔业的研究方向,以及在再生蓝色经济的旗帜下对洗绿潜力的担忧。
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引用次数: 0
Balancing privacy with access to information for commercial fisheries data: A critical review of Fisheries and Oceans Canada’s “rule of five” policy 平衡商业渔业数据的隐私与信息获取:对加拿大渔业和海洋部“五条规则”政策的批判性审查
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0153
Nicole Tomasic
Although Canada’s oceans are a public resource, commercial fisheries data are routinely withheld from researchers and the general public by Fisheries and Oceans Canada (DFO) due to privacy obligations. However, data can be released if considered sufficiently de-personalized through an internal guideline called the “rule of five,” under which data sources are aggregated to a threshold of five to allow for data publication or disclosure. This article provides an overview of the “rule of five,” summarizes key legislative provisions that have bearing on the “rule” and potential for its reform, and discusses the findings from two tools used to collect information on the “rule” and its use in Canada: (1) an Access to Information and Privacy request and (2) an anonymous survey conducted to evaluate the impacts of the “rule” on various stakeholders. The “rule of five” is not mandatory but rather represents a conservative approach to access to information that can be detrimental to independent researchers and the public interest in transparent fisheries data. The article concludes with recommendations to further a rebalancing of privacy and access to information, including emphasizing existing legislative exemptions that could allow for data disclosure when the “rule of five” is not met.
尽管加拿大的海洋是一种公共资源,但出于隐私义务,加拿大渔业和海洋局(DFO)通常不对研究人员和公众提供商业渔业数据。然而,如果通过一项被称为“五规则”的内部指导方针考虑到充分去个性化,则可以发布数据,根据该指导方针,数据源被汇总到五个阈值,以允许数据发布或披露。本文概述了“五人规则”,总结了与“规则”及其改革潜力有关的关键立法条款,并讨论了用于收集“规则”及其在加拿大使用的信息的两种工具的调查结果:(1)获取信息和隐私请求;(2)进行匿名调查,以评估“规则”对各种利益相关者的影响。“五原则”不是强制性的,而是代表了一种保守的获取信息的方法,这种方法可能不利于独立的研究人员和公众对透明渔业数据的兴趣。文章最后提出了进一步平衡隐私和信息获取的建议,包括强调现有的立法豁免,允许在不符合“五原则”的情况下披露数据。
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引用次数: 0
British Columbia freshwater salmon hatcheries demonstrate minimal contribution to piscine orthoreovirus (PRV) regional occurrence with no evidence for nonendemic strain introductions 不列颠哥伦比亚省淡水鲑鱼孵化场对鱼类正呼肠孤病毒(PRV)区域发生的贡献最小,没有证据表明非地方性菌株的引入
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0218
M. Polinski, Colleen A. Haddad, A. Siah, Chad Fuller, M. Higgins, Jay Parsons
Piscine orthoreovirus genotype 1 (PRV-1) is a common virus in farmed and wild salmon in the northeastern Pacific Ocean. Its regional occurrence in freshwater is far less clear. From 2019 to 2021, tissues of 5619 juvenile anadromous salmon (primarily Atlantic, Chinook, and coho) sampled from 12 commercial and 27 enhancement British Columbia hatcheries during 83 sampling events were screened for PRV-1 prior to seawater entry. More than 2200 (∼40%) were also screened using a Pan-PRV assay targeting all known PRV genotypes. PRV-1 was detected in four coho salmon at two freshwater enhancement facilities and in one Chinook salmon at a commercial facility. Partial (S1 segment) genome sequencing identified detections to be of the PRV-1 subgenotype endemic to the northeastern Pacific. PRV-1 was not detected (5611 individuals; 99.9%) or test results were inconclusive (3 individuals; 0.05%) for all remaining samples screened for PRV-1. PRV-2 and PRV-3 were not detected using the Pan-PRV assay. It is concluded that commercial and enhancement freshwater hatcheries of British Columbia contribute minimally to the prevalence and persistence of PRV-1 in anadromous salmon of the northeastern Pacific, and these hatcheries appear not to have contracted or participated in the distribution of nonendemic forms of PRV in recent years.
Piscine原呼肠孤病毒基因型1(PRV-1)是东北太平洋养殖和野生鲑鱼中常见的病毒。它在淡水中的区域分布远不清楚。从2019年到2021年,在83次采样活动中,从不列颠哥伦比亚省12个商业孵化场和27个强化孵化场采样的5619条幼年溯河产卵三文鱼(主要是大西洋、奇努克和升麻)的组织在海水进入前进行了PRV-1筛查。还使用针对所有已知PRV基因型的泛PRV测定法筛选了2200多个(~40%)。在两个淡水强化设施的四条升麻三文鱼和一个商业设施的一条支奴干三文鱼中检测到PRV-1。部分(S1片段)基因组测序确定检测结果为东北太平洋特有的PRV-1亚基因型。未检测到PRV-1(5611人;99.9%),或所有剩余PRV-1筛查样本的检测结果不确定(3人;0.05%)。使用Pan-PRV测定法未检测到PRV-2和PRV-3。得出的结论是,不列颠哥伦比亚省的商业和强化淡水孵化场对东北太平洋溯河产卵三文鱼中PRV-1的流行和持久性的贡献最小,而且这些孵化场近年来似乎没有感染或参与非流行型PRV的分布。
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引用次数: 0
Considering the implications of climate-induced species range shifts in marine protected areas planning 考虑气候引起的物种范围变化对海洋保护区规划的影响
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0041
C. Whitney, W. Cheung, Natalie Ban
Climate change is affecting the ocean, altering the biogeography of marine species. Yet marine protected area (MPA) planning still rarely incorporates projected species range shifts. We used the outputs of species distribution models fitted with biological and climate data as inputs to identify trends in occurrence for marine species in British Columbia (BC), Canada. We assessed and compared two ways of incorporating climate change projections into MPA planning. First, we overlaid 98 species with modelled distributions now and by the mid-21st century under two contrasting (“no mitigation” and “strong mitigation”) climate change scenarios with existing Provincial marine parks in BC, to ask which species could overlap with protected areas in the future. Second, we completed a spatial prioritization analysis using Marxan with the projected future species ranges as inputs, to ask where priority regions exist for the 98 marine species. We found that many BC marine parks will lose species in both climate scenarios that we analyzed, and that protecting 30% of important marine species will be challenging under the “no mitigation” climate change scenario. Challenges included the coarse resolution of the data and uncertainty in projecting species range shifts.
气候变化正在影响海洋,改变海洋物种的生物地理学。然而,海洋保护区(MPA)规划仍然很少纳入预计的物种范围变化。我们使用符合生物和气候数据的物种分布模型的输出作为输入,以确定加拿大不列颠哥伦比亚省海洋物种的出现趋势。我们评估并比较了将气候变化预测纳入MPA规划的两种方法。首先,我们在与不列颠哥伦比亚省现有省级海洋公园形成对比的两种气候变化情景(“无缓解”和“强烈缓解”)下,覆盖了目前和21世纪中期的98个具有模拟分布的物种,以询问哪些物种未来可能与保护区重叠。其次,我们使用Marxan完成了空间优先级分析,并将预测的未来物种范围作为输入,以询问98种海洋物种的优先区域在哪里。我们发现,在我们分析的两种气候情景下,不列颠哥伦比亚省的许多海洋公园都将失去物种,而在“不缓解”气候变化的情景下,保护30%的重要海洋物种将是一项挑战。挑战包括数据的粗略分辨率和预测物种范围变化的不确定性。
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引用次数: 0
The influence of sociodemographic and environmental factors on wildlife carcass submissions in urban areas: Opportunities for increasing equitable and representative wildlife health surveillance 社会人口和环境因素对城市地区野生动物尸体提交的影响:加强公平和有代表性的野生动物健康监测的机会
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0137
J. Giacinti, S. J. Robinson, Shannon K. French, D. Pearl, C. Jardine
Wildlife health surveillance is important in rapidly expanding urban areas, where wildlife live in close association with humans and face unique health risks. Urban areas are not homogeneous, and social and environmental factors may affect the distribution of surveillance data we receive from these environments. The Canadian Wildlife Health Cooperative (CWHC) operates a national wildlife surveillance programme that receives carcass submissions for diagnostic evaluation. Our objective was to evaluate sociodemographic and environmental factors associated with CWHC submissions within two cities in Ontario, Canada. Submissions were mapped at two geographic scales and linked with census and environmental data. The results of mixed multivariable Poisson and negative binomial regression analyses suggest that natural (e.g., percent parkland) and anthropogenic environmental (e.g., presence of a zoo) and social variables (e.g., low income) are associated with submissions at both administratively relevant scales. Associations that are common across scales may represent robust intervention points and inform surveillance methodology/messaging. Surveillance data may influence public health policy, wildlife management, and other decision-making regarding the benefits/risks associated with coexistence with wildlife. This study highlights gaps in surveillance methodology that may prevent equal opportunity for participation in wildlife health surveillance and enable equal opportunity to benefit from the associated outputs.
野生动物健康监测在迅速扩大的城市地区非常重要,在这些地区,野生动物与人类生活密切相关,面临独特的健康风险。城市地区并不均匀,社会和环境因素可能会影响我们从这些环境中收到的监测数据的分布。加拿大野生动物健康合作社(CWHC)开展了一项国家野生动物监测方案,该方案接受提交的尸体用于诊断评估。我们的目的是在加拿大安大略省的两个城市评估与CWHC提交相关的社会人口和环境因素。提交的材料按两个地理比例尺绘制,并与人口普查和环境数据相联系。混合多变量泊松和负二项回归分析的结果表明,自然(例如,公园面积百分比)、人为环境(例如,动物园的存在)和社会变量(例如,低收入)与行政相关尺度的提交有关。跨尺度的共同关联可能代表强大的干预点,并为监测方法/消息传递提供信息。监测数据可能影响公共卫生政策、野生动物管理以及与野生动物共存的利益/风险相关的其他决策。这项研究突出了监测方法方面的差距,这些差距可能妨碍人们有平等机会参与野生动物健康监测,并使人们有平等机会从相关产出中受益。
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引用次数: 0
Toward a wild pollinator strategy for Canada: expert-recommended solutions and policy levers 加拿大野生传粉昆虫战略:专家建议的解决方案和政策杠杆
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0204
Rachel A. Nalepa, S. Colla
Invertebrate pollinators are in trouble: particularly documented are declines among bees and butterflies. Interacting stressors include pesticides, pathogens, habitat loss, nonnative species, and climate change. Many governments have strategies to reduce negative pressures on pollinators, but Canada does not despite widespread public interest in pollinator health. This study serves as a needs assessment for science-based policy solutions for wild pollinator conservation in Canada. We designed a Policy Delphi survey technique to identify solutions that experts deem both desirable and feasible. Our secondary aim was to identify research priorities that would inform the implementation of these solutions. Sixty % of the 83 unique solutions were supported and feasible at a high consensus level (10% were “strongly” supported and “definitely” feasible). General themes included improving the Canadian government's approach in assessing pesticide risk to pollinators, curbing pathogen spillover/spillback between managed and wild pollinators, and reducing the reliance of Canadian agricultural systems on pesticides, among others. We discuss solutions in reference to pollinator conservation policies recommended by the broader scientific community and identify policy levers within the context of Canada's highly decentralized approach to biodiversity conservation/management and a political economy that uses high numbers of managed, mostly nonnative bees for pollination services.
无脊椎动物的传粉昆虫遇到了麻烦:尤其是蜜蜂和蝴蝶的数量减少。相互作用的压力源包括杀虫剂、病原体、栖息地丧失、外来物种和气候变化。许多政府都制定了减少传粉昆虫负面压力的策略,但尽管公众对传粉昆虫健康普遍感兴趣,加拿大却没有。这项研究是对加拿大野生传粉昆虫保护基于科学的政策解决方案的需求评估。我们设计了一种政策德尔菲调查技术,以确定专家认为既可取又可行的解决方案。我们的次要目标是确定研究重点,为这些解决方案的实施提供信息。83个独特的解决方案中,60%得到了高度一致的支持和可行(10%得到了“强烈”支持和“绝对”可行)。一般主题包括改进加拿大政府评估杀虫剂对传粉昆虫风险的方法,遏制病原体在管理传粉昆虫和野生传粉昆虫之间的溢出/回流,以及减少加拿大农业系统对杀虫剂的依赖等。我们讨论了参考更广泛的科学界建议的传粉昆虫保护政策的解决方案,并在加拿大高度分散的生物多样性保护/管理方法和使用大量管理蜜蜂(主要是非本地蜜蜂)提供授粉服务的政治经济背景下确定了政策杠杆。
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引用次数: 0
Comments regarding “A Canadian model for providing high-quality, timely and relevant evidence to meet health system decision-maker needs: the SPOR Evidence Alliance.” 关于“提供高质量、及时和相关证据以满足卫生系统决策者需求的加拿大模式:SPOR证据联盟”的评论。
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0088
C. D. Morales-Plaza, Ivan E. Balanta-Gonzalíaz
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引用次数: 0
Funding change: An environmental scan of research funders’ knowledge translation strategic plans and initiatives across 10 high-income countries/regions 资助变化:10个高收入国家/地区研究资助者知识转化战略计划和举措的环境扫描
IF 3.1 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-01-01 DOI: 10.1139/facets-2022-0124
C. Fahim, Danielle Kasperavicius, Robyn Beckett, Keelia Quinn de Launay, Arthana Chandraraj, Amanda Crupi, Suvabna Theivendrampillai, Sharon E. Straus
Knowledge translation (KT) is the science and practice of dissemination and implementation of evidence. We describe how research funders operationalize and evaluate KT initiatives, identify challenges and opportunities, and suggest strategic considerations for KT support. We conducted an environmental scan, which included a systematic search of published and grey literature and a focus group with Canadian funders. A total of 130 published articles and 2415 grey literature sources were screened; 212 unique data sources were included. Published literature commonly described KT initiatives related to “KT practice and science funding.” These initiatives commonly provided funds for infrastructure development (e.g., clinical technologies, database subscriptions) to facilitate translational or applied research to address regional health priorities. Of the articles, 44% outlined an evaluation plan; few provided validated KT metrics. In the grey literature, 364 initiatives were described; the most commonly described initiatives related to “exchange and integrated KT.” Focus group participants hoped to see increased resources to support KT, exchange opportunities with policy/decision-makers, and evaluate KT initiatives. Funders completed various KT initiatives, which tended to engage stakeholders to set research priorities, collaborate with a range of stakeholders, build KT capacity, and mandate KT requirements. We provide six considerations for funders to support KT.
知识翻译是传播和实施证据的科学和实践。我们描述了研究资助者如何实施和评估KT计划,识别挑战和机遇,并为KT支持提出战略考虑。我们进行了一次环境扫描,其中包括对已发表文献和灰色文献的系统搜索,以及与加拿大资助者的焦点小组。共筛选已发表文章130篇,灰色文献来源2415篇;包括212个独特的数据源。已发表的文献通常将KT计划描述为“KT实践和科学资助”。这些举措通常为基础设施发展(例如临床技术、数据库订阅)提供资金,以促进转化研究或应用研究,以解决区域卫生优先事项。在这些文章中,44%概述了评估计划;很少有人提供经过验证的KT指标。在灰色文献中,描述了364项倡议;最常见的描述是与“交换和集成KT”相关的计划。焦点小组的参与者希望看到更多的资源来支持KT,与政策/决策者交流机会,并评估KT的举措。资助者完成了各种KT计划,这些计划倾向于让利益相关者参与来设定研究优先级,与一系列利益相关者合作,建立KT能力,并授权KT需求。我们为资助KT的人提供了6个考虑因素。
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引用次数: 2
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