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Energy-Efficient and Resilient Secure Routing in Energy Harvesting Wireless Sensor Networks with Transceiver Noises: EcoSecNet Design and Analysis 具有收发器噪声的能量收集无线传感器网络中的高能效和弹性安全路由:EcoSecNet 设计与分析
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-05-30 DOI: 10.1155/2024/3570302
Mushtaq Muhammad Umer, Jiang Hong, Owais Muhammad, Fuad A. Awwad, Emad A. A. Ismail
Cooperative energy harvesting wireless sensor networks (EH-WSNs) using energy-harvesting-based physical layer security (PLS) appears to be a promising way to meet information security and energy efficiency goals at the same time. PLS uses energy harvesting (EH) features to protect data while transmitting. This eliminates the need for traditional upper-layer data encryption. However, this method introduces new challenges, particularly in scenarios where potential adversaries can intercept sensitive information through network relays. When it comes to multihop, multipath cooperative EH-WSNs, it becomes even more complicated to optimize transmit power for EH while reducing eavesdropping risk. In this study, three routing protocols, direct route designation (DRD), casual route designation (CRD), and superlative route designation (SRD) are presented. The protocols will improve multihop, multipath cooperative EH-WSNs’ security in the presence of eavesdroppers as well as noises at the transceiver. In this framework, both source nodes and relay nodes use power-beaming techniques to make their data transmission operations easier. This study goes beyond the protocol recommendations by presenting comprehensive closed-form formulas and asymptotic outage probability analysis for each protocol under various eavesdropping attack scenarios, i.e., coordination and noncoordination of eavesdroppers. According to simulation data, the suggested SRD protocol outperforms the CRD and DRD protocols by 19% and 25%, respectively, when eavesdroppers are not coordinating. The suggested SRD protocol outperforms the CRD and DRD protocols by 28% and 32%, respectively, in terms of eavesdropper coordination.
使用基于能量收集的物理层安全(PLS)的合作能量收集无线传感器网络(EH-WSN)似乎是同时满足信息安全和能源效率目标的一种有前途的方法。PLS 利用能量收集(EH)功能在传输过程中保护数据。这样就不需要传统的上层数据加密。不过,这种方法也带来了新的挑战,尤其是在潜在对手可以通过网络中继拦截敏感信息的情况下。当涉及到多跳、多径合作 EH-WSN 时,如何在降低窃听风险的同时优化 EH 的发射功率变得更加复杂。本研究提出了三种路由协议,即直接路由指定(DRD)、临时路由指定(CRD)和超级路由指定(SRD)。在存在窃听者和收发器噪音的情况下,这些协议将提高多跳、多路径合作 EH-WSN 的安全性。在这个框架中,源节点和中继节点都使用功率波束技术,使其数据传输操作更容易。本研究在协议建议之外,还提出了每种协议在各种窃听攻击情况(即窃听者协调和不协调)下的全面闭式公式和渐近中断概率分析。根据仿真数据,当窃听者不协调时,建议的 SRD 协议比 CRD 和 DRD 协议分别优胜 19% 和 25%。在窃听者协调的情况下,建议的 SRD 协议分别比 CRD 和 DRD 协议优胜 28% 和 32%。
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引用次数: 0
A Passive Wireless Smart Washer for Locking Force Monitoring on the Orthopedic Pedicle Screw 用于监测骨科椎弓根螺钉锁定力的无源无线智能垫圈
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-05-17 DOI: 10.1155/2024/6690983
Che-Fu Liu, Tze-Hong Wong, Hsin-Chuan Wang, Asher Sun, Wensyang Hsu
A pedicle screw is a component for fixation in spine fusion surgery, often for patients with osteoporosis. Spine fusion condition highly depends on whether the pedicle screw is tightly fixed on spine, if not, spine fusion will not work properly. After the surgery, the first 3 months is the most crucial period, and bone healing situation cannot be shown through X-ray before the first radiologic images taken around the sixth week. Therefore, it is helpful to have a nonradiative method to monitor the locking force of the pedicle screw after surgery, especially during the early stage. Here a passive wireless force sensor is developed for monitoring the locking force of the pedicle screw, as we call it a smart washer. By integrating a capacitive ring-shape force sensor with an inductor, a passive LC sensor can be built by measuring the resonant frequency wirelessly. The smart washer is designed and calibrated to establish the relation between the locking force and resonant frequency, and then it is fixed with a screw in a porcine femur, with and without medium between the reader and inductor. When the locking force decreases from 8.3 to 0.9 N, the error is less than 0.5 N, and the maximum wireless sensing distance is 72 mm. However, the medium between the reader and the sensor inductor will affect the resonant frequency, but not the sensitivity. Therefore, the locking force variation can still be calculated by the resonant frequency shift accurately. Furthermore, by designing another five LC sensors with different operating resonant frequency ranges, it is possible to identify locking forces at different locations for more pedicle screws. To our knowledge, no LC force sensor was proposed to monitor the locking force of pedicle screws after surgery in the past.
椎弓根螺钉是脊柱融合手术中的固定部件,通常用于骨质疏松症患者。脊柱融合的状况在很大程度上取决于椎弓根螺钉是否紧密地固定在脊柱上,否则脊柱融合将无法正常进行。术后前 3 个月是最关键的时期,在第 6 周左右拍摄第一张 X 光片之前,骨愈合情况无法通过 X 光片显示出来。因此,采用非辐射方法监测术后椎弓根螺钉的锁定力很有帮助,尤其是在早期阶段。在此,我们开发了一种用于监测椎弓根螺钉锁定力的无源无线力传感器,我们称之为智能垫圈。通过将电容式环形力传感器与电感器集成在一起,可以通过无线测量谐振频率建立一个无源 LC 传感器。我们设计并校准了智能垫圈,以确定锁定力与共振频率之间的关系,然后用螺钉将其固定在猪股骨上,读取器与电感器之间有无介质。当锁定力从 8.3 N 减小到 0.9 N 时,误差小于 0.5 N,最大无线感应距离为 72 mm。然而,读取器和感应器之间的介质会影响谐振频率,但不会影响灵敏度。因此,仍然可以通过谐振频率偏移准确计算出锁定力的变化。此外,通过设计另外五个具有不同工作谐振频率范围的 LC 传感器,可以识别更多椎弓根螺钉在不同位置的锁定力。据我们所知,过去没有人提出用 LC 力传感器来监测椎弓根螺钉术后的锁定力。
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引用次数: 0
Modeling Forest Above-Ground Biomass of Teak (Tectona grandis L. F.) Using Field Measurement and Sentinel-2 Imagery 利用实地测量和哨兵-2 图像模拟柚木(Tectona grandis L. F.)的森林地上生物量
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-05-11 DOI: 10.1155/2024/9910094
Santosh Ghimire, Rajeev Joshi, Jeetendra Gautam, Binod Bhatta
Over the last few decades, remote sensing has emerged as a dependable and cost-effective method for collecting precise data on forest biophysical parameters, aiding in sustainable forest management and global initiatives to combat climate change. This research aimed to develop a model for estimating the above-ground biomass (AGB) of Teak (Tectona grandis L. F.) by combining field measurements with Sentinel-2 earth observation data. The study took place in 36-year-old teak plantation areas within the Sagarnath Forest Development Project in Nepal’s Sarlahi district. Field measurements were conducted using a destructive systematic sampling method, employing 10 × 10 m2 sample plots, and the volume of logs was determined using Newton’s formula. A total of 30 sample plots were used for calibration, while 10 were utilized for validation purposes. The findings revealed that the average AGB per plot was 814 kg (equivalent to 81.4 t ha−1), with a minimum value of 716 kg (71.6 t ha−1) and a maximum value of 1,060 kg (106 t ha−1). The study utilized five independent variables, namely, the Red band, Green band, Blue band, near-infrared (NIR), and normalized difference vegetation index (NDVI) values from Sentinel-2 imagery data, to develop estimation models. Among the 12 models examined, model M10 proved to be the best fit for accurate AGB estimation (adjusted R2 = 0.9809, RMSE = 0.01269, AIC = −170, and p-value = < 8.39e−21). The equation of the best-fitted model was ln (AGB) = A + B × Red + C × Green + D × Blue2 + E × ln (NIR) + F × ln (NDVI), providing an accurate estimate of AGB. Model validation involved a t-test comparing the observed and calculated AGB values for ten sample plots, demonstrating no significant difference (p-value = 0.3662 > 0.05). This model has the potential to facilitate AGB biomass calculations and carbon stock estimates for teak plantations of similar age groups.
过去几十年来,遥感技术已成为收集森林生物物理参数精确数据的可靠且具有成本效益的方法,有助于可持续森林管理和应对气候变化的全球倡议。这项研究旨在通过将实地测量结果与哨兵-2 号地球观测数据相结合,建立一个估算柚木(Tectona grandis L. F.)地上生物量(AGB)的模型。研究在尼泊尔萨尔拉希县萨加纳特森林开发项目的 36 年柚木种植区进行。实地测量采用破坏性系统取样法,使用 10 × 10 平方米的样地,并使用牛顿公式确定原木的体积。共有 30 块样地用于校准,10 块样地用于验证。研究结果显示,每个样地的平均 AGB 为 814 千克(相当于 81.4 吨/公顷),最小值为 716 千克(71.6 吨/公顷),最大值为 1,060 千克(106 吨/公顷)。研究利用五个自变量,即哨兵-2 图像数据中的红波段、绿波段、蓝波段、近红外(NIR)和归一化差异植被指数(NDVI)值,建立了估算模型。在研究的 12 个模型中,模型 M10 被证明是最适合准确估算 AGB 的模型(调整 R2 = 0.9809,RMSE = 0.01269,AIC = -170 和 p 值 = <8.39e-21)。最佳拟合模型方程为 ln (AGB) = A + B × Red + C × Green + D × Blue2 + E × ln (NIR) + F × ln (NDVI),提供了对 AGB 的准确估计。模型验证包括对十块样地的观测值和计算值进行 t 检验,结果显示两者无显著差异(p 值 = 0.3662 >0.05)。该模型可用于类似树龄组柚木种植园的 AGB 生物量计算和碳储量估算。
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引用次数: 0
Effect of Electrode Shape on the Performance of ZnO-Based Ethanol Sensor 电极形状对氧化锌乙醇传感器性能的影响
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-04-23 DOI: 10.1155/2024/6696108
Shokoufeh Sirjani, Ali Fattah, Hamid Haratizadeh
This paper reports the deposition of Zn on glass substrates using the physical vapor deposition (PVD) method, followed by an annealing process to grow ZnO for gas-sensing applications. Surface morphologies were characterized using scanning electron microscopy, which revealed nanowire shape. The diameter of the wire was about 35 nm. In addition, X-ray diffraction analysis demonstrated that the ZnO nanowire possessed a wurtzite structure with an orientation of (002). Three types of resistive gas sensors with a spiral-square and two-comb electrode geometries were designed, fabricated, and tested for their ethanol vapor-sensing properties. The experimental results show that the sensor with square-spiral electrode has the sensitivity of 43% for 2,000 ppm of ethanol vapor at 200°C, while the sensor with a comb electrode shows the sensitivity of 32% at the same conditions. Also, two sensors with different dimensions of comb-shaped electrodes showed the same sensitivity, as both the width and the distance between the fingers change simultaneously in the larger comb-shaped electrode. The response time for the comb electrode is shorter than the square-spiral type, and the recovery time is almost independent of the electrode geometry. Therefore, the optimal structure should be selected based on the application.
本文报告了利用物理气相沉积(PVD)方法在玻璃基底上沉积锌,然后进行退火处理,从而生长出用于气体传感应用的氧化锌。使用扫描电子显微镜对表面形貌进行了表征,结果显示出纳米线的形状。纳米线的直径约为 35 纳米。此外,X 射线衍射分析表明,氧化锌纳米线具有取向为 (002) 的乌兹石结构。设计、制造并测试了三种具有螺旋方形和双梳形电极几何形状的电阻式气体传感器的乙醇蒸汽传感性能。实验结果表明,采用方形螺旋电极的传感器在 200°C 温度条件下对 2,000 ppm 乙醇蒸气的灵敏度为 43%,而采用梳状电极的传感器在相同条件下的灵敏度为 32%。此外,两个梳状电极尺寸不同的传感器也显示出相同的灵敏度,因为在较大的梳状电极中,指间的宽度和距离同时发生变化。梳状电极的响应时间比方形螺旋型短,而且恢复时间几乎与电极的几何形状无关。因此,应根据应用选择最佳结构。
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引用次数: 0
Implementation and Comparison of Wearable Exoskeleton Arm Design with Fuzzy Logic and Machine Learning Control 利用模糊逻辑和机器学习控制实现和比较可穿戴外骨骼手臂设计
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-04-03 DOI: 10.1155/2024/6808322
Çağatay Ersin, Mustafa Yaz
In this study, a wearable exoskeleton arm was designed and controlled with different control methods to help people with muscle disorders in their arms and support treatment. The developed robot arm was transferred to Simulink software with the Simmechanics application. Two electromyography (EMG) muscle sensors and the ADXL335 position and acceleration sensors attach to the human arm’s biceps and triceps muscle areas. As the human moved the arm, data were obtained from the EMG muscle sensors and the ADXL335 position and acceleration sensor. The received data were first trained with the fuzzy logic algorithm. The same data were then trained with machine learning algorithms in Simulink software. It has been determined that the best result is the quadratic support vector machine (SVM) algorithm. The fuzzy logic algorithm trained with the PID controller block and the received sensor data have been added to the degrees of freedom regions that will enable rotation in the block diagram of the previously exported system. Later, the fuzzy logic block was removed and the machine learning algorithm, the quadratic SVM algorithm, was added. The designed system was operated with two different control systems, and the control algorithm closest to the human arm movement was determined. In addition, each part of the system, whose design was prepared, was removed and assembled separately with a 3D printer. ESP32 microcontroller development board was used to control the system, and it was run in real-time with EMG muscle sensors and position sensors.
本研究设计了一种可穿戴外骨骼机械臂,并采用不同的控制方法对其进行控制,以帮助手臂肌肉有障碍的人并支持治疗。开发的机械臂通过 Simmechanics 应用程序转移到 Simulink 软件中。两个肌电图(EMG)肌肉传感器和 ADXL335 位置与加速度传感器分别安装在人体手臂的肱二头肌和肱三头肌部位。当人移动手臂时,EMG 肌肉传感器和 ADXL335 位置与加速度传感器会获取数据。首先用模糊逻辑算法对接收到的数据进行训练。然后用 Simulink 软件中的机器学习算法训练相同的数据。结果表明,二次支持向量机(SVM)算法效果最佳。使用 PID 控制器块训练的模糊逻辑算法和接收到的传感器数据已被添加到自由度区域,从而可以在先前导出的系统框图中进行旋转。之后,模糊逻辑块被移除,并添加了机器学习算法,即二次 SVM 算法。设计的系统通过两种不同的控制系统运行,并确定了最接近人类手臂运动的控制算法。此外,还将设计好的系统各部分拆卸下来,用 3D 打印机分别组装。使用 ESP32 微控制器开发板控制该系统,并通过 EMG 肌肉传感器和位置传感器实时运行。
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引用次数: 0
Platform Design of Passive Target Perception and Localization Based on Sensor Networks 基于传感器网络的被动目标感知和定位平台设计
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-04-02 DOI: 10.1155/2024/1315785
Qin Cheng, Lin Zhang, Yang Yu, Lingjiao Pan
With the rapid development, extensive knowledge, and diverse application scenarios of target perception and positioning technology in sensor networks, a passive target perception and localization platform based on Wireless Sensor Networks (WSN) has been designed. The platform is mainly applied for the teaching of electronic information, communication, and Internet of Things (IoT) engineering. The platform follows the teaching concept of “developing students’ ability to solve complex engineering problems” in the emerging engineering discipline and combines experimental simulation with real-world testing, as well as integrating scientific research and teaching. It encompasses technical elements such as perception and localization theory, sparse representation classification modeling, solving underdetermined equations, data analysis, and sparse coding, as well as nontechnical aspects such as team collaboration and cost budgeting. The platform boasts high fidelity and scalability, providing students with the opportunity to develop comprehensive practical and innovative skills in solving complex engineering problems.
随着传感器网络中目标感知与定位技术的快速发展、知识的广泛普及和应用场景的多样化,设计了一个基于无线传感器网络(WSN)的无源目标感知与定位平台。该平台主要应用于电子信息、通信和物联网工程专业的教学。该平台遵循新兴工程学科 "培养学生解决复杂工程问题的能力 "的教学理念,将实验仿真与实际测试相结合,将科研与教学相结合。它涵盖了感知和定位理论、稀疏表示分类建模、解欠定方程、数据分析和稀疏编码等技术内容,以及团队协作和成本预算等非技术内容。该平台具有高保真和可扩展性的特点,为学生提供了培养解决复杂工程问题的综合实践和创新能力的机会。
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引用次数: 0
Advancements in Mobile-Based Air Pollution Detection: From Literature Review to Practical Implementation 移动式空气污染检测的进展:从文献综述到实际应用
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-03-28 DOI: 10.1155/2024/4895068
Srdjan Sladojevic, Marko Arsenovic, Danilo Nikolic, Andras Anderla, Darko Stefanovic
The aim of this paper is to investigate the effectiveness of combining mobile technologies and sensors to detect harmful particles in the air and address the problem of air pollution caused by traffic and exhaust emissions. The paper contains a systematic literature review of information technology research related to pollution detection in order to point out the main obstacles in the field and propose solutions. Furthermore, the paper presents the development of an Android smartphone-based real-time monitoring system that utilizes an external analog sensor board to acquire and evaluate physical measurements. The proposed system is calibrated for CO gas measurements, and it is compared with a commercial gas analyzer instrument. Results imply that the developed system is capable of detecting concentration levels in the air and that the accuracy is within the range of the industrial device’s accuracy.
本文旨在研究结合移动技术和传感器检测空气中有害颗粒的有效性,解决交通和废气排放造成的空气污染问题。本文对与污染检测相关的信息技术研究进行了系统的文献综述,以指出该领域的主要障碍并提出解决方案。此外,论文还介绍了基于安卓智能手机的实时监测系统的开发情况,该系统利用外部模拟传感器板来获取和评估物理测量值。该系统针对一氧化碳气体测量进行了校准,并与商用气体分析仪进行了比较。结果表明,所开发的系统能够检测空气中的浓度水平,而且精度在工业设备的精度范围之内。
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引用次数: 0
The Ammunition Projectile Test and Evaluation Used Polymer Flexible Film Sensors System Design and Application 使用聚合物柔性薄膜传感器的弹药射弹测试和评估系统设计与应用
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-03-22 DOI: 10.1155/2024/3068590
Xiangdong Cui, Youliang Xu, Yanli Zhang, Xinglin Qi, Aiqiang Guo
Background. The mainly lethal ability of ammunition fragments on creatures is achieved by hitting the effective organs or key parts of the biological body with high-speed projectiles. How to efficiently and accurately obtain the projectile speed and hitting position coordinates when the fragment hits the creature after the ammunition blast is the key to the scientific evaluation of ammunition power. Materials and Methods. For the measurement of fragment velocity and hitting coordinates, a series of flexible film circuit sensors can be generated by printing comb-like circuits on polyethylene terephthalate substrates using silver paste printing technology. These sensors are cheap, flexible, and easy to fold and can be printed into different shapes according to the characteristics of the test target to simulate the biological key organs or lethal parts. At the same time, the software and hardware design of the high-speed data signal reading and processing module can realize the data rapidly recording and processing and quickly give the ammunition fragment parameter test results. Results. The test accuracy of the fragment velocity of the laser light screen target and the flexible circuit sensor is compared through the live-fire test. It is proved that the test accuracy of the flexible sensor based on the polymer substrate can meet the accuracy requirements. The flexible sensor based on the organ simulation can quickly give the accurate hit position of the fragment. Conclusion. The newly polymer substrate printed circuit sensor system is a new type of sensor used to replace the laser screen target, and the copper comb printed circuit in the ammunition power test, which can improve the parameter test accuracy, reduce the test consumption, and improve the test quality.
背景。弹药碎片对生物的杀伤力主要是通过高速弹丸击中生物体的有效器官或关键部位来实现的。如何高效准确地获取弹药爆炸后碎片击中生物体时的射速和命中位置坐标,是科学评价弹药威力的关键。材料与方法。为测量弹片速度和命中坐标,可利用银浆印刷技术在聚对苯二甲酸乙二醇酯基板上印刷梳状电路,从而生成一系列柔性薄膜电路传感器。这些传感器价格低廉、柔性好、易于折叠,可根据测试目标的特点印制成不同形状,模拟生物的关键器官或致命部位。同时,高速数据信号读取和处理模块的软硬件设计,可实现数据的快速记录和处理,快速给出弹药破片参数测试结果。测试结果通过实弹射击试验,比较了激光光屏靶和柔性电路传感器的破片速度测试精度。结果证明,基于聚合物基板的柔性传感器的测试精度可以满足精度要求。基于器官模拟的柔性传感器能快速给出碎片的准确命中位置。结论新型聚合物基板印制电路传感器系统是弹药威力试验中替代激光屏靶、铜梳印制电路的新型传感器,可提高参数试验精度,降低试验消耗,提高试验质量。
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引用次数: 0
Evasion Attacks on Deep Learning-Based Helicopter Recognition Systems 对基于深度学习的直升机识别系统的规避攻击
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-03-22 DOI: 10.1155/2024/1124598
Jun Lee, Taewan Kim, Seungho Bang, Sehong Oh, Hyun Kwon
Identifying objects in surveillance and reconnaissance systems with the human eye can be challenging, underscoring the growing importance of employing deep learning models for the recognition of enemy weapon systems. These systems, leveraging deep neural networks known for their strong performance in image recognition and classification, are currently under extensive research. However, it is crucial to acknowledge that surveillance and reconnaissance systems utilizing deep neural networks are susceptible to vulnerabilities posed by adversarial examples. While prior adversarial example research has mainly utilized publicly available internet data, there has been a significant absence of studies concerning adversarial attacks on data and models specific to real military scenarios. In this paper, we introduce an adversarial example designed for a binary classifier tasked with recognizing helicopters. Our approach generates an adversarial example that is misclassified by the model, despite appearing unproblematic to the human eye. To conduct our experiments, we gathered real attack and transport helicopters and employed TensorFlow as the machine learning library of choice. Our experimental findings demonstrate that the average attack success rate of the proposed method is 81.9%. Additionally, when epsilon is 0.4, the attack success rate is 90.1%. Before epsilon reaches 0.4, the attack success rate increases rapidly, and then we can see that epsilon increases little by little thereafter.
用人眼识别监视和侦察系统中的物体是一项挑战,这说明采用深度学习模型识别敌方武器系统越来越重要。这些系统利用在图像识别和分类方面表现出色的深度神经网络,目前正在进行广泛的研究。然而,必须承认的是,利用深度神经网络的监视和侦察系统容易受到对抗性示例的影响。此前的对抗性示例研究主要利用公开的互联网数据,而针对真实军事场景中特定数据和模型的对抗性攻击研究却严重缺乏。在本文中,我们介绍了一个为二元分类器设计的对抗示例,该分类器的任务是识别直升机。我们的方法生成了一个被模型错误分类的对抗示例,尽管它在人眼看来毫无问题。为了进行实验,我们收集了真实的攻击直升机和运输直升机,并将 TensorFlow 作为首选的机器学习库。实验结果表明,建议方法的平均攻击成功率为 81.9%。此外,当 epsilon 为 0.4 时,攻击成功率为 90.1%。在ε达到 0.4 之前,攻击成功率迅速上升,之后我们可以看到ε在逐渐增加。
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引用次数: 0
Disposable Screen-Printed Microchip Based on Nanoparticles Sensitive Membrane for Potentiometric Determination of Lead 基于纳米颗粒敏感膜的一次性丝网印刷微芯片用于铅的电位测定
IF 1.9 4区 工程技术 Q3 Engineering Pub Date : 2024-03-13 DOI: 10.1155/2024/7610614
Majed Alrobaian, Munerah Alfadhel, Sayed Zayed, Mohammad AlDosari, Hassan Arida
Realization of screen-printed disposable microchip based on organic membrane sensitive layer highly responsive to lead has been demonstrated for the first time. Fabrication, potentiometric characterization and analytical application of the novel microchip have been reported. A sensitive layer comprises TiO2 nanoparticles and multiwalled carbon nanotubes “MWCNTs” composite incorporated in PVC membrane has uploaded on the plastic screen-printed microelectrode substrate surface using novel protocol. The new chip provided a linear behavior for Pb2+ ions over the lead concentration range of 1 × 10−6–1 × 10−1 mole L−1 with super Nernstian sensitivity (49 mV), relatively long life span (>4 months), and a fast response time (10 s). The advantages showed by the microchip include simple fabrication, small size, mass production, cost effectiveness, and automation and integration feasibility. The realized new microchip has been successfully utilized in the quantification of some lead (II) samples with average recovery of 101.9% and the RDS was <3.
首次实现了基于有机膜敏感层的丝网印刷一次性微芯片对铅的高灵敏度反应。该新型微芯片的制作、电位表征和分析应用已被报道。采用新颖的方案,在塑料丝网印刷微电极基底表面上传了由聚氯乙烯膜中的二氧化钛纳米粒子和多壁碳纳米管(MWCNTs)复合材料组成的敏感层。新芯片在 1 × 10-6-1 × 10-1 摩尔 L-1 的铅浓度范围内对 Pb2+ 离子呈线性关系,具有超强的 Nernstian 灵敏度(49 mV)、相对较长的使用寿命(4 个月)和快速响应时间(10 秒)。该芯片具有制作简单、体积小、可批量生产、成本效益高、可实现自动化和集成等优点。新型芯片已成功用于一些铅(II)样品的定量分析,平均回收率为 101.9%,RDS 为 3。
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引用次数: 0
期刊
Journal of Sensors
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