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Porous Lanthanide Metal–Organic Frameworks for Gas Storage and Separation 用于气体储存和分离的多孔镧系金属-有机框架
4区 化学 Q3 Chemistry Pub Date : 2014-01-01 DOI: 10.1007/430_2014_159
Bin Li, Banglin Chen
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引用次数: 23
Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses 磷化氢配位纯金团簇:不同的几何结构和独特的光学性质/响应
4区 化学 Q3 Chemistry Pub Date : 2014-01-01 DOI: 10.1007/430_2014_143
K. Konishi
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引用次数: 69
Theoretical Understanding of Anisotropy in Molecular Nanomagnets 分子纳米磁体各向异性的理论认识
4区 化学 Q3 Chemistry Pub Date : 2014-01-01 DOI: 10.1007/430_2014_171
L. Chibotaru
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引用次数: 50
Spectroscopy Methods for Molecular Nanomagnets 分子纳米磁体的光谱学方法
4区 化学 Q3 Chemistry Pub Date : 2014-01-01 DOI: 10.1007/430_2014_155
M. Baker, S. Blundell, N. Domingo, S. Hill
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引用次数: 19
Synthetic models of copper-nitrosyl species proposed as intermediates in biological denitrification 提出了作为生物反硝化中间体的亚硝基铜的合成模型
4区 化学 Q3 Chemistry Pub Date : 2013-05-29 DOI: 10.1007/430_2013_93
Debra J. Salmon, W. Tolman
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引用次数: 3
Structure and Bonding in Heme-Nitrosyl Complexes and Implications for Biology 血红素-亚硝基配合物的结构和键合及其生物学意义
4区 化学 Q3 Chemistry Pub Date : 2013-05-04 DOI: 10.1007/430_2013_92
N. Lehnert, W. Scheidt, Matthew W. Wolf
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引用次数: 44
Orientation-Selective DEER Using Rigid Spin Labels, Cofactors, Metals, and Clusters 定向选择性鹿使用刚性自旋标签,辅因子,金属,和集群
4区 化学 Q3 Chemistry Pub Date : 2013-01-01 DOI: 10.1007/430_2013_115
Alice M. Bowen, C. Tait, C. Timmel, J. Harmer
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引用次数: 26
The Preparation, Structural Characteristics, and Physical Chemical Properties of Metal-Nitrosyl Complexes. 金属硝基配合物的制备、结构特征和物理化学性质。
4区 化学 Q3 Chemistry Pub Date : 2013-01-01 Epub Date: 2013-05-29 DOI: 10.1007/430_2013_101
Lauren R Holloway, Lijuan Li

The preparation and characterization of a representative group of novel non-heme metal nitrosyl complexes that have been synthesized over the last decade are discussed here. Their structures are examined and classified based on metal type, the number of metal centers present, and the type of ligand that is coordinated with the metal. The ligands can be phosphorus, nitrogen, or sulfur based (with a few exceptions) and can vary depending on the presence of chelation, intermolecular forces, or the presence of other ligands. Structural and bonding characteristics are summarized and examples of reactivity regarding nitrosyl ligands are given. Some of the relevant physical chemical properties of these complexes, including IR, EPR, NMR, UV-vis, cyclic voltammetry, and X-ray crystallography are examined.

本文讨论了近十年来合成的一组具有代表性的新型非血红素金属亚硝酰配合物的制备和表征。根据金属类型、存在的金属中心的数量以及与金属配位的配体的类型来检查和分类它们的结构。配体可以是基于磷、氮或硫的(除了少数例外),并且可以根据螯合作用、分子间作用力或其他配体的存在而变化。综述了亚硝酰配体的结构和键合特性,并举例说明了亚硝酰基配体的反应性。研究了这些配合物的一些相关物理化学性质,包括IR、EPR、NMR、UV-vis、循环伏安法和X射线晶体学。
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引用次数: 0
Reliable measurements of dipole moments from single-crystal diffraction data and assessment of an in-crystal enhancement 从单晶衍射数据中偶极矩的可靠测量和晶内增强的评估
4区 化学 Q3 Chemistry Pub Date : 2012-01-01 DOI: 10.1007/430_2012_78
B. Dittrich, D. Jayatilaka
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引用次数: 17
Ligand Field and Molecular Orbital Theories of Transition Metal X-ray Absorption Edge Transitions 过渡金属x射线吸收边跃迁的配体场和分子轨道理论
4区 化学 Q3 Chemistry Pub Date : 2011-01-01 DOI: 10.1007/430_2011_60
R. Hocking, E. Solomon
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引用次数: 26
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Structure and Bonding
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