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Structure and Bonding of Group 14 Clusters: Wade’s Rules and Beyond 14组簇的结构和键合:韦德的规则及以后
4区 化学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.1007/430_2021_84
Jing-Xuan Zhang, F. Sheong, Zhenyang Lin
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引用次数: 0
Introduction to Tensor Surface Harmonic Theory 张量曲面调和理论导论
4区 化学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.1007/430_2021_89
D. Mingos
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引用次数: 0
Electron Counting Rules for Gold Clusters Which Are Stereochemically Non-rigid and Exhibit Skeletal Isomerism 具有立体非刚性和骨架异构的金簇的电子计数规则
4区 化学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.1007/430_2021_87
D. Mingos
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引用次数: 1
Personal Historical Perspective on the Development of Electron Counting Rules for Boranes and Clusters and Ken Wade’s Contribution 硼烷和团簇电子计数规则发展的个人历史观点及肯·韦德的贡献
4区 化学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.1007/430_2021_86
D. Mingos
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引用次数: 0
Binary Zintl Anions Involving Group 13–15 (Semi-)Metal Atoms, and the Relationship of Their Structures to Electron Count 含13-15族(半)金属原子的二元锌离子及其结构与电子数的关系
4区 化学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.1007/430_2021_88
Fuxing Pan, B. Weinert, S. Dehnen
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引用次数: 2
Thermoelectric Properties of Ternary and Quaternary Mo6 and Mo9 Cluster Selenides 三元和季系Mo6和Mo9簇硒化物的热电性质
4区 化学 Q3 Chemistry Pub Date : 2019-04-28 DOI: 10.1007/430_2019_36
C. Candolfi, P. Gougeon, P. Gall, M. Potel, A. Dauscher, B. Lenoir
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引用次数: 3
The Periodic Table's Impact on Bioinorganic Chemistry and Biology's Selective Use of Metal Ions. 元素周期表对生物无机化学的影响及生物对金属离子的选择性利用。
4区 化学 Q3 Chemistry Pub Date : 2019-01-01 DOI: 10.1007/430_2019_45
Ambika Bhagi-Damodaran, Yi Lu

Despite the availability of a vast variety of metal ions in the periodic table, biology uses only a selective few metal ions. Most of the redox active metals used belong to the first row of transition metals in the periodic table and include Fe, Co, Ni, Mn and Cu. On the other hand, Ca, Zn and Mg are the most commonly used redox inactive metals in biology. In this chapter, we discuss the periodic table's impact on bio-inorganic chemistry, by exploring reasons behind this selective choice of metals biology. A special focus is placed on the chemical and functional reasons why one metal ion is preferred over another one. We discuss the implications of metal choice in various biological processes including catalysis, electron transfer, redox sensing and signaling. We find that bioavailability of metal ions along with their redox potentials, coordination flexibility, valency and ligand affinity determine the specificity of metals for biological processes. Understanding the implications underlying the selective choice of metals of the periodic table in these biological processes can help design more efficient catalysts, more precise biosensors and more effective drugs.

尽管元素周期表中有各种各样的金属离子,但生物学只使用几种有选择性的金属离子。大多数氧化还原活性金属在元素周期表中属于第一行过渡金属,包括Fe, Co, Ni, Mn和Cu。另一方面,Ca、Zn和Mg是生物学中最常用的氧化还原活性金属。在本章中,我们通过探索金属生物学选择性选择背后的原因,讨论元素周期表对生物无机化学的影响。一个特别的重点放在化学和功能的原因,为什么一种金属离子优于另一种。我们讨论了金属选择在各种生物过程中的意义,包括催化、电子转移、氧化还原传感和信号传导。我们发现金属离子的生物利用度及其氧化还原电位、配位柔韧性、配价和配体亲和力决定了金属在生物过程中的特异性。了解这些生物过程中元素周期表中金属选择性选择的潜在含义可以帮助设计更有效的催化剂,更精确的生物传感器和更有效的药物。
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引用次数: 1
The Periodic Table as a Career Guide: A Journey to Rare Earths 元素周期表作为职业指南:稀土之旅
4区 化学 Q3 Chemistry Pub Date : 2019-01-01 DOI: 10.1007/430_2019_43
A. J. Ryan, W. Evans
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引用次数: 1
Chemical Valency: Its Impact on the Proposal of the Periodic System and Some Thoughts About Its Current Significance 化学价:对周期制提出的影响及对其当前意义的思考
4区 化学 Q3 Chemistry Pub Date : 2019-01-01 DOI: 10.1007/430_2019_40
L. Gade
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引用次数: 1
Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes 八面体硫系铼簇:从固体到分离簇配合物
4区 化学 Q3 Chemistry Pub Date : 2019-01-01 DOI: 10.1007/430_2019_33
V. Fedorov, N. Naumov
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引用次数: 6
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Structure and Bonding
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