{"title":"Structure and Bonding of Group 14 Clusters: Wade’s Rules and Beyond","authors":"Jing-Xuan Zhang, F. Sheong, Zhenyang Lin","doi":"10.1007/430_2021_84","DOIUrl":"https://doi.org/10.1007/430_2021_84","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84801636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Introduction to Tensor Surface Harmonic Theory","authors":"D. Mingos","doi":"10.1007/430_2021_89","DOIUrl":"https://doi.org/10.1007/430_2021_89","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87356398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electron Counting Rules for Gold Clusters Which Are Stereochemically Non-rigid and Exhibit Skeletal Isomerism","authors":"D. Mingos","doi":"10.1007/430_2021_87","DOIUrl":"https://doi.org/10.1007/430_2021_87","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82387524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Personal Historical Perspective on the Development of Electron Counting Rules for Boranes and Clusters and Ken Wade’s Contribution","authors":"D. Mingos","doi":"10.1007/430_2021_86","DOIUrl":"https://doi.org/10.1007/430_2021_86","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82633714","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Binary Zintl Anions Involving Group 13–15 (Semi-)Metal Atoms, and the Relationship of Their Structures to Electron Count","authors":"Fuxing Pan, B. Weinert, S. Dehnen","doi":"10.1007/430_2021_88","DOIUrl":"https://doi.org/10.1007/430_2021_88","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85912186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C. Candolfi, P. Gougeon, P. Gall, M. Potel, A. Dauscher, B. Lenoir
{"title":"Thermoelectric Properties of Ternary and Quaternary Mo6 and Mo9 Cluster Selenides","authors":"C. Candolfi, P. Gougeon, P. Gall, M. Potel, A. Dauscher, B. Lenoir","doi":"10.1007/430_2019_36","DOIUrl":"https://doi.org/10.1007/430_2019_36","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84336429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Despite the availability of a vast variety of metal ions in the periodic table, biology uses only a selective few metal ions. Most of the redox active metals used belong to the first row of transition metals in the periodic table and include Fe, Co, Ni, Mn and Cu. On the other hand, Ca, Zn and Mg are the most commonly used redox inactive metals in biology. In this chapter, we discuss the periodic table's impact on bio-inorganic chemistry, by exploring reasons behind this selective choice of metals biology. A special focus is placed on the chemical and functional reasons why one metal ion is preferred over another one. We discuss the implications of metal choice in various biological processes including catalysis, electron transfer, redox sensing and signaling. We find that bioavailability of metal ions along with their redox potentials, coordination flexibility, valency and ligand affinity determine the specificity of metals for biological processes. Understanding the implications underlying the selective choice of metals of the periodic table in these biological processes can help design more efficient catalysts, more precise biosensors and more effective drugs.
{"title":"The Periodic Table's Impact on Bioinorganic Chemistry and Biology's Selective Use of Metal Ions.","authors":"Ambika Bhagi-Damodaran, Yi Lu","doi":"10.1007/430_2019_45","DOIUrl":"https://doi.org/10.1007/430_2019_45","url":null,"abstract":"<p><p>Despite the availability of a vast variety of metal ions in the periodic table, biology uses only a selective few metal ions. Most of the redox active metals used belong to the first row of transition metals in the periodic table and include Fe, Co, Ni, Mn and Cu. On the other hand, Ca, Zn and Mg are the most commonly used redox inactive metals in biology. In this chapter, we discuss the periodic table's impact on bio-inorganic chemistry, by exploring reasons behind this selective choice of metals biology. A special focus is placed on the chemical and functional reasons why one metal ion is preferred over another one. We discuss the implications of metal choice in various biological processes including catalysis, electron transfer, redox sensing and signaling. We find that bioavailability of metal ions along with their redox potentials, coordination flexibility, valency and ligand affinity determine the specificity of metals for biological processes. Understanding the implications underlying the selective choice of metals of the periodic table in these biological processes can help design more efficient catalysts, more precise biosensors and more effective drugs.</p>","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/430_2019_45","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9448612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Periodic Table as a Career Guide: A Journey to Rare Earths","authors":"A. J. Ryan, W. Evans","doi":"10.1007/430_2019_43","DOIUrl":"https://doi.org/10.1007/430_2019_43","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90239021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Chemical Valency: Its Impact on the Proposal of the Periodic System and Some Thoughts About Its Current Significance","authors":"L. Gade","doi":"10.1007/430_2019_40","DOIUrl":"https://doi.org/10.1007/430_2019_40","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89631362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes","authors":"V. Fedorov, N. Naumov","doi":"10.1007/430_2019_33","DOIUrl":"https://doi.org/10.1007/430_2019_33","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74583192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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