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Soil ingestion rates in children identified by parental observation as likely high soil ingesters 经家长观察,儿童土壤摄食率可能较高
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-05-01 DOI: 10.1080/15320389709383565
E. Calabrese, E. Stanek, R. Barnes
Soil ingestion was estimated over seven consecutive days in a soil tracer‐based mass‐balance methodology in 12 children, aged 1 to 3 years. The children had been identified by parents as likely high soil ingesters based on retrospective observation of daily soil ingestion behavior over the past 30 d. While one of the 12 children displayed high soil ingestion (0.5 to 3.05 g/d) on 4 of 7 d, median soil ingestion rates for the 12 children were comparable to those published in other soil ingestion studies of young children selected for studies based on age and not assumed or observed soil ingestion behavior. The lack of ability of parental judgments to predict high soil ingestion rates represents both an important observation and a significant limitation in current methods to efficiently and accurately identify children who ingest high amounts of soil.
采用基于土壤示踪剂的质量平衡方法,对12名1至3岁儿童连续7天的土壤摄食情况进行了评估。根据对过去30天每日土壤摄食行为的回顾性观察,这些儿童被父母确定为可能的高土壤摄食者。虽然12名儿童中的一名在7天中的4天表现出高土壤摄食(0.5至3.05克/天),但这12名儿童的土壤摄食率中位数与其他根据年龄选择的幼儿土壤摄食研究中公布的数据相当,而这些研究没有假设或观察到土壤摄食行为。缺乏父母判断来预测高土壤摄取率的能力,这既是一个重要的观察结果,也是目前有效和准确识别摄入大量土壤的儿童的方法的一个重大限制。
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引用次数: 22
Nitrification and utilization of ammonium and nitrate during oil bioremediation at different soil water potentials 不同土壤水势下石油生物修复过程中铵态氮的硝化作用及利用
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-03-01 DOI: 10.1080/15320389709383553
Z. Chang, R. W. Weaver
Bioremediation of petroleum spills requires aerobic soil conditions and readily available N, which may be susceptible to leaching. Our objectives were to determine the influence of soil water potential on nitrification in the presence of crude oil, the toxicity of oil to NHj‐oxidizing bacteria, and the preferences of microorganisms for NH+ 4 or NO− 3. A Weswood clay loam was amended with crude oil to contain 0, 5, and 10% by soil dry weight, and N was added to achieve C:N ratios of 90:1 and 120:1. Soil water potentials were maintained at ‐0.02, ‐0.1, and ‐1.0 kJ/kg or allowed to fluctuate between ‐0.02 and ‐3 kJ/kg. Concentrations of NH+ 4 and NO3 −were measured during an incubation period of 40 d. Nitrification in soil not amended with oil was rapid at water potentials of ‐0.02 and ‐0.1 kJ/kg but inactive at a water potential of ‐1.0 kJ/kg. Oil reduced nitrification rates and populations of NH+ 4‐oxidizing bacteria. Little NO− 3 accumulated when the C:N ratio was 120:1, but when the C:N ratio was 90:1, u...
石油泄漏的生物修复需要好氧土壤条件和容易获得的N,这可能容易淋出。我们的目的是确定原油存在时土壤水势对硝化的影响,油对NHj氧化细菌的毒性,以及微生物对nh4或NO−3的偏好。以土壤干重为0、5%和10%的原油对Weswood粘壤土进行改性,并添加N,使C:N比分别为90:1和120:1。土壤水势保持在‐0.02、‐0.1和‐1.0 kJ/kg,或允许在‐0.02和‐3 kJ/kg之间波动。在40 d的培养期间,测量了NH+ 4和NO3 -的浓度。在未加油的土壤中,硝化作用在- 0.02和- 0.1 kJ/kg的水势下迅速进行,但在- 1.0 kJ/kg的水势下不活跃。油降低了硝化速率和NH+ 4氧化细菌的数量。当C:N比为120:1时,NO−3积累较少,而当C:N比为90:1时,NO−3积累较少。
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引用次数: 11
American petroleum institute in situ air sparging database 美国石油学会现场空气喷射数据库
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-03-01 DOI: 10.1080/15320389709383555
C. Bruell, M. Marley, Harley H. Hopkins
An evaluation of data detailing in situ air sparging (IAS) systems at 59 sites has been assembled into an American Petroleum Institute in situ Air Sparging Database (API‐IAS Database). The database was developed to provide site managers insights concerning the state‐of‐the‐art of IAS system design, operation, and evaluation. The IAS radius of influence (ROI) is often evaluated based on changes in a number of physical, chemical, or biological monitoring parameters. Measurements of groundwater dissolved oxygen levels was the technique used most often to determine the ROI. Other parameters such as pressure changes in the vadose and saturated zones, groundwater mounding, air bubbling in wells and tracer gases were also used to aid in the determination of the IAS ROI. A review of 37 pilot studies revealed that the IAS ROI is generally between 10 to 26 ft. IAS technology is generally being applied in sandy soils. The application of IAS technology was deemed infeasible at seven sites where soils contained high l...
对59个地点的现场空气喷射(IAS)系统的详细数据进行了评估,并汇编成美国石油学会的现场空气喷射数据库(API‐IAS数据库)。该数据库的开发是为了提供网站管理人员对IAS系统设计,操作和评估的最新状态的见解。IAS影响半径(ROI)通常是根据一些物理、化学或生物监测参数的变化来评估的。测量地下水溶解氧水平是确定ROI最常用的技术。其他参数,如渗透层和饱和层的压力变化、地下水堆积、井中空气鼓泡和示踪气体,也用于帮助确定IAS ROI。对37项试点研究的回顾表明,IAS投资回报率通常在10至26英尺之间。IAS技术通常应用于沙质土壤。在土壤含硫量高的7个地点,IAS技术的应用被认为是不可行的。
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引用次数: 8
Comparison of Soil VOCs measured by soil gas, heated headspace, and methanol extraction techniques 土壤气体、加热顶空和甲醇萃取技术测量土壤挥发性有机化合物的比较
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-03-01 DOI: 10.1080/15320389709383556
M. Minnich, B. Schumacher, John H. Zimmerman
Comparisons of soil volatile organic compound (VOC) measurement techniques and soil properties expected to influence these measurements were performed at two dissimilar sites. A total of 41 soil gas, 52 heated headspace, and 51 methanol extraction/purge‐and‐trap measurements were obtained on collocated samples. Contaminants present at both sites included cis‐1,2‐dichloroethene, 1, 1, 1‐trichloroethane, trichloroethene, and tetrachloroethene. Heated headspace offered the highest sensitivity, as indicated by the greatest percentage of detections per number of analyses. The statistical regression between headspace concentrations and methanol extraction concentrations was highly significant (p < 0.001) with r2 = 0.53. Headspace concentrations (range, 7 to 4250 ng/g) ran approximately 20 to 30% of the methanol extraction concentrations (range, 260 to 7300 ng/g), indicating that the methanol was able to extract significantly more of the chlorinated hydrocarbons (CHCs) than the headspace extraction, even in soil...
在两个不同的地点进行了土壤挥发性有机化合物(VOC)测量技术和预计会影响这些测量的土壤性质的比较。共41个土壤气体,52个加热顶空,51个甲醇提取/吹扫和捕集测量在配置的样品上获得。存在于两个地点的污染物包括顺式1,2‐二氯乙烯、1,1,1‐三氯乙烷、三氯乙烯和四氯乙烯。加热顶空提供了最高的灵敏度,正如每次分析的最大检测百分比所表明的那样。顶空浓度与甲醇萃取浓度之间的统计学回归极显著(p < 0.001), r2 = 0.53。顶空浓度(范围,7至4250 ng/g)约为甲醇提取浓度(范围,260至7300 ng/g)的20%至30%,表明甲醇能够比顶空提取明显更多的氯化碳氢化合物(CHCs),即使在土壤中也是如此。
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引用次数: 5
Soil Gas Modeling: The Need for New Techniques and Better Information 土壤气体模拟:需要新技术和更好的信息
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383541
K. Altshuler, D. Burmaster
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引用次数: 7
Evaluation of residual soil contamination from commercial oil well drilling activities and its impact on the naturally occurring background radiation environment 商业钻井活动对土壤残留污染的评价及其对自然本底辐射环境的影响
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383545
H. Spitz, K. Lovins, C. Becker
Radiation exposure received by individuals living and working on a farmland contaminated with radium was evaluated by measuring the technologically enhanced radiation background using portable survey instruments and a high‐pressure ionization chamber. Analysis of selected organic compounds, metals, and radioactive material in samples of soil and water obtained from the farm demonstrate a potential risk to inhabitants that needs to be evaluated, especially for future generations living and working on this land who may not be aware of the potential hazard. The distribution of radium and several other hazardous waste materials was found to be significantly elevated in areas where sludge ponds and waste pits were formerly located. Transport of these contaminants in soil was detected by in situ measurement of radium, which may be a useful analog for determining the translocation of metals and other contaminants associated with oil well‐drilling activities. Conventional risk assessment models, using default inp...
通过使用便携式测量仪器和高压电离室测量技术增强的辐射本底,评估了在被镭污染的农田生活和工作的个人所受到的辐射暴露。对从农场获得的土壤和水样本中选定的有机化合物、金属和放射性物质的分析表明,对居民的潜在风险需要进行评估,特别是对在这片土地上生活和工作的后代,他们可能没有意识到潜在的危害。在污泥池和废物坑原来所在的地区,镭和其他几种有害废物的分布明显增加。这些污染物在土壤中的迁移是通过镭的原位测量来检测的,这可能是确定与石油钻井活动相关的金属和其他污染物迁移的有用模拟。传统的风险评估模型,使用违约…
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引用次数: 8
Integrating biofiltration with SVE: A case study 生物过滤与SVE的整合:一个案例研究
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383548
Matthew P. Lesley, R. Rangan
An integrated soil vacuum extraction/ biofiltration system has been designed and installed at a gasoline‐contaminated leaking underground storage tank (LUST) site in southern Delaware. The system remediates contaminated moisture entrained in the air stream, employs automatic water level controls in the filters, and achieves maximum vapor extraction and VOC destruction efficiency with an optimum power input. In addition, the valving and piping layout allows the sequence of air flow through the filters to be reversed at given time intervals, which minimizes biofouling, thereby increasing efficiency by decreasing system backpressure. This integrated system achieves VOC destruction rates of up to 69%. The modular design allows for easy mobilization, setup, and demobilization at LUST sites throughout Delaware.
在特拉华州南部的一个汽油污染泄漏地下储罐(LUST)现场,设计并安装了一个集成的土壤真空提取/生物过滤系统。该系统可修复气流中被污染的水分,在过滤器中采用自动水位控制,并在最佳功率输入下实现最大的蒸汽提取和VOC破坏效率。此外,阀门和管道布局允许在给定的时间间隔内通过过滤器的气流顺序颠倒,从而最大限度地减少生物污染,从而通过降低系统反压来提高效率。该集成系统可实现高达69%的VOC破坏率。模块化设计允许在整个特拉华州的LUST站点轻松动员,设置和复员。
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引用次数: 3
Distribution and mobility of lead in soils at an outdoor shooting range 室外射击场土壤中铅的分布和流动性
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383547
K. Murray, A. Bazzi, Crystal Carter, A. Ehlert, A. Harris, Mike Kopec, J. Richardson, Helene Sokol
The distribution of total Pb in surface and subsurface soil horizons at an outdoor shooting range in southeastern Michigan was determined by single extraction elemental analysis (AAS and ICP‐AES). Significant Pb enrichment of the site's soils coincides closely with Pb vapor and particulate matter produced from shot shell primers and the downfall of Pb/Sb pellets associated with the recreational shooting of skeet and trap. Surface concentrations in these locations are 10 to 100 times greater than the background concentration found on adjacent properties. The distribution of Pb in the subsurface soil horizons corresponds to the distribution of Pb at the surface, which suggests the Pb is mobilizing and migrating downward through the vadose zone. This mobilization appears to be occurring despite the clay‐rich nature of the soils, and may be due to the transformation of metallic Pb into soluble Pb compounds of carbonate and sulfate: Both compounds appear to be present in crust material found coating many of th...
采用原子吸收光谱(AAS)和电感耦合等离子体发射光谱(ICP - AES)法测定了密歇根州东南部某户外射击场表层和地下土壤中总Pb的分布。场地土壤中Pb的显著富集与射击弹丸产生的Pb蒸气和Pb颗粒物质以及休闲射击双向飞碟和捕集器产生的Pb/Sb弹丸的沉降密切相关。这些地点的表面浓度比邻近地点的背景浓度高10至100倍。地下土壤层位Pb的分布与地表Pb的分布相对应,表明Pb是通过渗透带向下运移的。尽管土壤富含粘土,但这种动员似乎仍在发生,可能是由于金属Pb转化为可溶的碳酸盐岩和硫酸盐Pb化合物:这两种化合物似乎存在于覆盖在许多土壤表面的地壳物质中。
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引用次数: 90
Sorption and desorption of arsenic from sandy soils: Column studies 砂土对砷的吸附和解吸:柱研究
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383544
P. Kuhlmeier
Rate‐limited sorption/desorption can have a profound effect upon the transport of sorbing contaminants. Numerical and analytical models used to predict chemical movement through the subsurface rarely incorporate the effects of nonlinear sorption and desorption kinetics, resulting in potentially large overestimates of mass extractability. Mass transfer characteristics of arsenic‐contaminated soils at the site of a former arsenical herbicide manufacturer in Houston, Texas, were examined in the laboratory using soil columns. Unaffected soils comprised of silty sands to coarse sands were collected from the uppermost aquifer. Two soil columns were loaded with a known mass of mixed organic and inorganic forms of arsenic resident in site ground water. A third control column was prepared with dry 20 × 30 mesh ASTM silica sand. Leachate samples were collected from each void volume until arsenic breakthrough was achieved. The dynamic test applied a continuing head of water, operating in an upflow mode through 4‐in....
速率限制的吸附/解吸对被吸附污染物的输送有深远的影响。用于预测地下化学运动的数值和分析模型很少考虑非线性吸附和解吸动力学的影响,导致对质量可萃取性的潜在高估。在实验室中,利用土壤柱研究了德克萨斯州休斯顿一家原砷除草剂生产基地砷污染土壤的传质特性。未受影响的土壤由粉砂到粗砂组成,从最上层含水层收集。两个土壤柱装载了已知质量的混合有机和无机形式的砷,这些砷存在于现场地下水中。第三根对照柱用20 × 30目干燥的ASTM硅砂制备。从每个空隙体积中收集渗滤液样本,直到砷突破为止。动态测试采用连续的水头,通过4‐in....以上涌模式运行
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引用次数: 25
Indoor infiltration of volatile organic contaminants: Measured soil gas entry rates and other research results for Canadian houses 挥发性有机污染物的室内渗透:加拿大房屋测量的土壤气体进入率和其他研究结果
IF 2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 1997-01-01 DOI: 10.1080/15320389709383542
D. Fugler, M. Adomait
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引用次数: 11
期刊
Soil & Sediment Contamination
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