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Evaluation of plume-induced continental crust growth rate in early Earth: Insight from integrated petrological-thermo-mechanical modeling 早期地球上羽状诱导的大陆地壳增长率评估:岩石力学-热力学综合建模的启示
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-07 DOI: 10.1016/j.precamres.2024.107506
Xinyi Zhong, Zhong-Hai Li, Yang Wang

The origin of Earth’s felsic continental crust remains a mystery. The generation of felsic continental crust requires a two-stage partial melting from original mantle sources. There are two hypotheses for the continental crust generation in the early Earth. One is the subduction-related magmatism, e.g., island arcs, which produces intermediate to felsic magma that constitutes the early buoyant continental crust. The other is the magmatism induced by the mantle plume that creates thick basaltic crust and finally the continental crust. However, there is controversy about the origin of plate tectonics, which is an obstacle for simply applying the subduction-induced model in the early Earth. On the other hand, the efficiency of mantle plume-induced continental crust growth remains unknown. In this study, we develop a new numerical model, integrating the petrological-thermo-mechanical model with melt migration and crystallization, to evaluate the efficiency of continental crust production by mantle plumes in Earth’s history. Our results indicate that mantle plumes are considerably more effective for continental crust generation in the hot early Earth than that in the present Earth. The contribution of plume-induced continental crust growth may be greatly promoted by the possible high frequency of mantle plume generation in the early Earth than the present.

地球长岩大陆地壳的起源仍然是一个谜。长岩大陆地壳的生成需要从原始地幔源经过两个阶段的部分熔融。早期地球大陆地壳的生成有两种假说。一种是与俯冲有关的岩浆活动,如岛弧,它产生的中间岩浆到炽热岩浆构成了早期的浮力大陆地壳。另一种是由地幔羽流诱发的岩浆活动,形成厚玄武岩地壳,最后形成大陆地壳。然而,关于板块构造的起源存在争议,这是在早期地球简单应用俯冲诱导模型的障碍。另一方面,地幔羽流诱导大陆地壳生长的效率仍然未知。在本研究中,我们建立了一个新的数值模型,将岩石-热力学模型与熔融迁移和结晶相结合,以评估地球历史上地幔羽流产生大陆地壳的效率。我们的研究结果表明,在炽热的早期地球,地幔羽流对大陆地壳生成的作用要比现在的地球大得多。由于早期地球地幔羽流生成的频率可能比现在的地球高,这可能大大促进了羽流诱导的大陆地壳生长。
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引用次数: 0
An unusual occurrence of carbonatites derived from the crust in the UHT granulite facies metamorphic terrain of Sri Lanka 斯里兰卡超高温花岗岩变质地形中出现的不寻常的地壳衍生碳酸盐岩
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-06 DOI: 10.1016/j.precamres.2024.107502
W.A.G.K. Wickramasinghe , T.B.N.S. Madugalla , Bhathiya Athurupana , Lei Zhao , Mingguo Zhai , Xianhua Li , H.M.T.G.A. Pitawala

The special calcite bodies (CBs) exposed within the ultrahigh temperature (UHT) granulite facies terrain in the Balangoda area of Sri Lanka preserve shreds of evidence for the generation of crust-derived carbonatite in the crust. The CBs are exclusively made up of massive calcites and appear as concordant bands extending tens of meters or as meso-scale isolated pockets hosting the massive dolomitic marble band. Various sizes of mafic and calc-silicate enclaves occur as rotated or tilted structures within the CBs. The contact between the CBs and the host marble is texturally and mineralogically gradational, while the contact between the enclaves and the CBs is sharp. The large-ion lithophile elements and rare earth element contents of the CBs show enrichment compared to the host marble, while depletion compared to typical carbonatites. Furthermore, the Sr content and C-O isotope values in CBs differ from those found in known carbonatites, hydrothermal carbonates, or metasomatic carbonates. We suggested that the crustal anatexis of marble should be hypothesized as the possible mechanism for the origin of the CBs. Microtexural evidence of the calcite grains shows indications of the melting of the host marble. The release of CO2-rich fluids from the collision and thrusting of HC over VC, or related metamorphic events, likely lowered the solidus of carbonates, triggering crustal anatexis of marble during UHT granulite facies metamorphism. The generated low viscous carbonate melt may have moved rapidly, resulting in a low degree of mixing of silicates and fragmentation and dislocation of enclaves. The results of the present study reflect the existence of anatexis of carbonates under extreme crustal conditions and provide a better understanding of the sources, migration paths and reservoirs of the carbon recycling processes.

斯里兰卡巴兰戈达地区超高温花岗岩面地层中出露的特殊方解石体(CBs)为地壳中碳酸盐岩的生成保留了一些证据。碳酸盐岩完全由块状方解石组成,以延伸数十米的和谐带状或中尺度孤立袋状形式出现在块状白云石大理岩带中。不同大小的黑云母和钙硅酸盐飞地作为旋转或倾斜结构出现在 CBs 内。CBs与寄主大理岩之间的接触在纹理和矿物学上是渐变的,而飞地与CBs之间的接触则是尖锐的。与寄主大理岩相比,CBs 的大离子亲岩元素和稀土元素含量呈富集态,而与典型的碳酸盐岩相比则呈贫化态。此外,CBs 中的锶含量和 C-O 同位素值与已知碳酸盐岩、热液碳酸盐岩或变质碳酸盐岩中的锶含量和 C-O 同位素值不同。我们认为,大理岩的地壳无性化应被假定为 CBs 的可能起源机制。方解石颗粒的显微氧化证据显示了寄主大理岩熔化的迹象。在超高温花岗岩变质过程中,HC对VC的碰撞和推移或相关变质事件释放出富含二氧化碳的流体,很可能降低了碳酸盐的固结度,引发了大理岩的地壳膨胀。生成的低粘度碳酸盐熔体可能快速移动,导致硅酸盐的低度混合以及飞地的破碎和错位。本研究的结果反映了极端地壳条件下碳酸盐岩的无性化现象,有助于更好地了解碳循环过程的来源、迁移路径和储层。
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引用次数: 0
Neoproterozoic tungsten mineralization and associated granitic magmatism in the western Yangtze Block, South China: Mineralization age, petrogenesis and geodynamic implications 华南扬子地块西部新近新生代钨矿化及相关花岗岩岩浆活动:成矿时代、岩石成因和地球动力学影响
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-05 DOI: 10.1016/j.precamres.2024.107496
Zhongyuan Liu , Fuhao Xiong , Hui Li , Han Zhao , Tingting Gong , Jie Gan , Junqing Mu , Xiaohui Zeng

Neoproterozoic granitic magmatism and associated mineralization in the western Yangtze Block (WYB), South China, records the assembly and breakup of the Rodinia supercontinent, making it a key window for understanding the tectonic evolution and associated dynamic process of the Rodinia supercontinent. In this paper, we present an integrated study on petrology, petrography, geochemistry, zircon U-Pb-Hf isotope, vesuvianite U-Pb and muscovite Rb-Sr geochronology for the W-rich granitic plutons (Xiacun and Shunhe plutons) and ore-bearing granitic dikes from the newly discovered Neoproterozoic Huili tungsten deposit in the WYB. Our objective is to provide vital constraint on the mineralization age and metallogenic geodynamic setting of the Neoproterozoic Huili tungsten deposit in the WYB. The ore body is characterized by skarn-type and quartz vein-type mineralization with main ore mineral of scheelite and gangue minerals of vesuvianite, muscovite and diopside. Zircon U-Pb dating indicates the granitic plutons and granitic dikes emplaced at ca. 845 Ma and 824 Ma, respectively. The vesuvianite U-Pb age and muscovite Rb-Sr isochron age are ca. 826–818 Ma and 822 Ma, respectively, indicating the tungsten mineralization was coeval with the crystallization of the granitic dikes. Petrology and geochemical studies reveal that the granitic dikes and the Shunhe pluton are highly fractionated S-type granite, while the Xiacun pluton belongs to unfractionated S-type granite. The granitic plutons have uniform and weakly enriched zircon Lu-Hf isotopes (εHf(t) = -3.08 ∼ -0.22), while the granitic dikes have varied zircon Hf isotopes (εHf(t) = -10.57 ∼ 4.64). Zircon Lu-Hf isotopes, as well as their varied whole-rock geochemical compositions, indicate that the Xiacun and Shunhe granitic plutons mainly originate from partial melting of Middle Paleoproterozoic crust, while the ore-bearing granitic dikes are mainly derived from the melting of heterogeneous Middle Paleoproterozoic crust, followed by significant fractional crystallization of feldspar, biotite and accessory minerals. Petrological, geochronological and geochemical data compilation reveals that the studied ca. 845 Ma granitic plutons and ca. 824 Ma W-mineralized granitic dikes were formed in a progressive subduction and a back-arc extension setting, respectively, and the Neoproterozoic back-arc extension-related granitic magmatism during the breakup of Rodinia supercontinent may be beneficial for the tungsten mineralization.

华南西部扬子地块的新近新生代花岗岩岩浆活动及相关成矿作用记录了罗迪尼亚超大陆的组装和解体过程,是了解罗迪尼亚超大陆构造演化及相关动力过程的重要窗口。在本文中,我们综合研究了WYB新近发现的新元古代会理钨矿床中富W花岗质柱岩(下村柱岩和顺河柱岩)和含矿花岗岩岩脉的岩石学、岩相学、地球化学、锆石U-Pb-Hf同位素、蛭石U-Pb和蕈云母Rb-Sr地质年代。我们的目标是为瓦屋湾新新生代会理钨矿床的成矿时代和成矿地球动力学环境提供重要的约束。该矿体以矽卡岩型和石英脉型矿化为特征,主要矿石矿物为白钨矿,夹杂矿物为白钨矿、黝帘石和透辉石。锆石 U-Pb 测定结果表明,花岗岩柱岩和花岗岩尖晶石的形成年代分别约为 845 Ma 和 824 Ma。845 Ma 和 824 Ma。蛭石的 U-Pb 年龄和黝帘石的 Rb-Sr 等时线年龄分别约为 826-818 Ma 和 822 Ma。分别为 826-818 Ma 和 822 Ma,表明钨矿化与花岗岩尖晶石的结晶同时发生。岩石学和地球化学研究表明,花岗质岩峰和顺河岩体属于高度分馏的 S 型花岗岩,而下村岩体则属于未分馏的 S 型花岗岩。花岗质岩体的锆石Lu-Hf同位素均匀且富集程度较弱(εHf(t) = -3.08 ∼ -0.22),而花岗质岩体的锆石Hf同位素变化较大(εHf(t) = -10.57 ∼ 4.64)。锆石Lu-Hf同位素及其不同的全岩地球化学成分表明,下村和顺河花岗岩柱岩主要源于中古生界地壳的部分熔融,而含矿花岗岩尖晶岩则主要源于中古生界异质地壳的熔融,其次是长石、斜长石和附属矿物的大量分块结晶。岩石学、地质年代学和地球化学数据汇编显示,所研究的约 845 Ma 花岗岩柱岩和约 824 Ma W 矿化花岗岩埂岩分别形成于渐进俯冲和弧后延伸环境中,罗迪尼亚超大陆解体过程中与新元古代弧后延伸相关的花岗岩岩浆活动可能有利于钨矿化。
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引用次数: 0
Late Tonian (ca. 770-720 Ma) arc activity in the Wuyi domain of the West Cathaysia terrane, South China 华南西华夏地层武夷域的晚砺石期(约 770-720 Ma)弧活动
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-05 DOI: 10.1016/j.precamres.2024.107505
Huan Liu , Lijun Wang , Shoufa Lin , Xilin Zhao

The late Tonian tectonic setting of the West Cathaysia terrane in South China is highly controversial and is key to better understanding the timing of amalgamation between the Yangtze Block and the West Cathaysia terrane and the positions of these two terranes in Rodinia and Gondwana. A detailed field-based study was conducted on the petrology, zircon U-Pb geochronology and Lu-Hf isotopes, and whole-rock geochemistry of a series of Neoproterozoic meta-volcanic and meta-sedimentary rocks in the Wuyi domain in the northeastern West Cathaysia terrane. The results indicate that the meta-volcanic rocks formed in an arc setting at 756-740 Ma, and the meta-sedimentary rocks were developed in an arc-related basin with single zircon age peaks of 765-728 Ma. We propose that the late Tonian arc in the Wuyi domain was part of a major arc system in the West Cathaysia terrane. An arc setting for the West Cathaysia terrane is distinct from the continental rift setting for the southeastern margin of the Yangtze Block at the time, supporting an interpretation that the two terranes were not amalgamated until after the late Tonian and occupied separate positions in Rodinia.

华南西国泰地层的晚砺石期构造背景极具争议,它是更好地理解长江地块与西国泰地层的混杂时间以及这两个地层在罗迪尼亚和冈瓦纳的位置的关键。该研究以野外为基础,对国泰西地层东北部武夷域一系列新新生代元火山岩和元沉积岩的岩石学、锆石U-Pb地质年代学和Lu-Hf同位素以及全岩地球化学进行了详细研究。结果表明,元火山岩形成于756-740Ma的弧环境中,元沉积岩则发育于与弧有关的盆地中,锆石年龄峰值为765-728Ma。我们认为武夷山域的晚砺石期弧系是西国泰地层中主要弧系的一部分。西国泰阶地的弧形环境与当时扬子地块东南缘的大陆裂谷环境截然不同,支持这两个阶地直到晚通年之后才合并并在罗迪尼亚占据不同位置的解释。
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引用次数: 0
Localized geochemical variability produced by depositional and diagenetic processes in a 2.8 Ga Ca-carbonate system: A cautionary paradigm 2.8 Ga Ca-碳酸盐系统中沉积和成岩过程产生的局部地球化学变异:警示范例
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107499
Philip Fralick , Tobias Himmler , Stefan V. Lalonde , Robert Riding

A plethora of proxies has been developed over the preceding two decades in attempts to investigate the geochemistry of the Archean ocean–atmosphere system, and in particular oxygen levels. Unfortunately the necessary parallel investigations of the effects that localized ocean chemistry and diagenesis can have on Archean sediments have commonly not kept pace. We used micro-analytical techniques (LA-ICP-MS and XRF scanning), to distinguish the effects of changes in water composition during precipitation and diagenesis on marine limestone precipitates at the margin and interior of a 2.8 Ga carbonate platform (Mosher Carbonate, Steep Rock Group) in western Superior Province, Canada. Platform margin meter-scale hybrid giant domes consist of centimetric interlayered couplets of (1) Sr-rich crystal fan fabric and cuspate fenestral microbialite, both with pronounced negative Ce-anomalies, and (2) net-like fenestral microbialite, rich in diagenetic cement with diminished concentrations of Sr and lacking negative Ce anomalies. The elevated Sr in the crystal fan fabric and cuspate fenestral microbialite is a general sign of less diagenetic alteration, as is preservation of millimeter-scale chemical differences. XRF mapping revealed that samples that otherwise appear pristine from a second site on the platform rim, near a zone of alteration in the limestone, have ferroan dolomite-filled micro-fractures with Mn flooding of the surrounding calcite and lack Ce anomalies. Platform interior silicified and ferroan dolomitized columnar stromatolites have some calcite laminae, but exceptionally low Sr contents indicate that they formed by dedolomitization. In several horizons REE patterns identical to those of offshore iron formation, replacement of calcite by iron carbonate, and the presence of iron oxides all suggest that short term flooding of the platform by offshore seawater episodically introduced ferroan dolomitizing fluids. Overall, these data indicate a restricted marine environment subject to periodic flooding by offshore waters that caused seafloor diagenetic alteration and precipitation of iron hydroxides. In this system the least altered limestone was the lithotype most likely to retain evidence of free oxygen. Samples with abundant phreatic cement and/or Mn alteration associated with micro-fractures were liable to have experienced REE mobilization. Detailed studies that integrate both depositional and diagenetic information are critical for the correct interpretation of geochemical data from sedimentary rocks.

在过去的二十年里,为了研究阿新世海洋-大气系统的地球化学,特别是氧气含量,已经开发了大量的代用指标。遗憾的是,对局部海洋化学和成岩作用对阿全新统沉积物的影响进行的必要平行研究通常跟不上步伐。我们利用微分析技术(LA-ICP-MS 和 XRF 扫描),在加拿大苏必利尔省西部的一个 2.8 Ga 碳酸盐平台(Mosher Carbonate,陡岩组)的边缘和内部,区分了沉淀和成岩过程中水成分变化对海洋石灰岩沉淀物的影响。平台边缘米级混合巨型穹窿由以下几部分组成:(1)富含 Sr 的晶体扇状结构和尖状栅栏状微粒岩,两者都具有明显的负 Ce 异常;(2)网状栅栏状微粒岩,富含成岩胶结物,Sr 浓度降低,缺乏负 Ce 异常。晶体扇状结构和尖晶石栅栏状微闪长岩中的硒含量升高,是成岩蚀变较少的总体迹象,同时也保留了毫米尺度的化学差异。XRF 图谱显示,在平台边缘靠近石灰岩蚀变带的第二个地点采集的样品,在其他方面看起来是原生态的,但在周围的方解石中却有铁质白云石填充的微裂隙和锰充填,而且没有铈异常。平台内部硅化和铁质白云石化的柱状叠层石有一些方解石层,但 Sr 含量极低,表明它们是通过反渗滤形成的。在几个地层中,与近海铁形成过程相同的 REE 模式、方解石被碳酸铁置换以及铁氧化物的存在都表明,近海海水对平台的短期淹没偶尔会引入铁白云石化流体。总之,这些数据表明,受限的海洋环境受到近海海水的周期性淹没,导致海底成岩蚀变和铁氢氧化物沉淀。在这一系统中,蚀变最少的石灰岩是最有可能保留自由氧证据的岩型。与微裂隙相关的大量相生胶结物和/或锰蚀变的样品很可能经历了 REE 迁移。综合沉积和成岩信息的详细研究对于正确解释沉积岩的地球化学数据至关重要。
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引用次数: 0
Temporal constraints on gold mineralisation at the world-class Jundee deposit: Insights into the episodic nature of orogenic gold mineralisation in the Neoarchean Yilgarn Craton 世界级 Jundee 矿床金矿化的时间限制:对新元古代伊尔加恩克拉通造山金矿化偶发性质的启示
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107479
Sumail , Nicolas Thébaud , Quentin Masurel , Christopher M. Fisher , Hugh Smithies , Ravi Schreefel

The proposed genetic model for orogenic gold deposits hosted in Archean cratons worldwide has long assumed a single, late-orogenic mineralisation event. Recent geochronological developments and their application to gold deposits, however, have challenged this conventional view and indicate that gold endowment in several world-class Archean systems developed over distinct mineralisation stages. Here, we present U-Pb geochronological data from igneous zircons extracted from pre-, syn-, and post-mineralisation intrusions from the world-class Jundee gold deposit in the Yilgarn Craton of Western Australia. The crystallisation age obtained for a syn-mineralisation lamprophyre indicates that gold mineralisation occurred at ca. 2670 Ma, which is ca. 30 Ma older than the previously proposed gold episode (ca. 2640 – 2630 Ma) for the region. When integrated with fast-emerging, high-quality geochronological data from other major gold deposits across the Yilgarn Craton, our results highlight the occurrence of an early, syn-orogenic mineralisation event between ca. 2675 – 2655 Ma, which pre-dated the ca. 2640 – 2630 Ma late-orogenic gold event identified across the Kalgoorlie Terrane. This older gold mineralisation event was concurrent with the onset of the Neoarchean Kalgoorlie Orogeny in the Yilgarn Craton, which also coincided with a peak in mantle-derived magmatism (e.g., lamprophyres and sanukitoids). The younger gold event was coeval with intra-crustal granite plutonism and peak metamorphic conditions that occurred during the late- to post-collisional evolution of the Yilgarn Craton at ca. 2640 – 2630 Ma. Comparison between the Yilgarn Craton in Western Australia and the Superior Craton in Canada demonstrates that both record multiple gold events that occurred during protracted orogenesis. This study underscores the importance of tectonic processes in shaping the episodic nature of gold mineralisation in these ancient cratons.

长期以来,人们一直假定世界范围内阿基坦环形山所蕴藏的成岩金矿床的成因模式是单一的、晚期成岩成矿事件。然而,最近的地质年代学发展及其在金矿床中的应用对这一传统观点提出了挑战,并表明在几个世界级的Archean系统中,金的赋存经历了不同的成矿阶段。在这里,我们展示了从西澳大利亚伊尔加恩克拉通世界级 Jundee 金矿床的成矿前、同步和成矿后侵入体中提取的火成锆石的 U-Pb 地球时序学数据。同步成矿灯泡岩获得的结晶年龄表明,金矿化发生在大约 2670 Ma,比该地区之前提出的金矿时期(大约 2640 - 2630 Ma)早大约 30 Ma。当与来自整个伊尔加恩克拉通地区其他主要金矿床的快速涌现的高质量地质年代数据相结合时,我们的研究结果突出表明,在约2675-2655Ma之间发生了早期的同步成矿事件,早于约2640-2630Ma的晚期成矿事件。我们的研究结果突显了在约 2675 - 2655 Ma 之间出现的早期同成因金矿化事件,它早于在整个卡尔古利地层发现的约 2640 - 2630 Ma 晚成因金矿化事件。这一较早的金矿化事件与伊尔加恩克拉通的新元古代卡尔古利造山运动同时发生,也与地幔岩浆活动(如灯石和萨努基托岩)的高峰期相吻合。较年轻的金事件与发生在约2640-2630Ma的伊尔加恩克拉通晚期至碰撞后演化过程中的壳内花岗岩柱状构造和变质高峰条件同时发生。对西澳大利亚的伊尔加恩克拉通和加拿大的苏必利尔克拉通进行比较后发现,两者都记录了在漫长的造山过程中发生的多次金事件。这项研究强调了构造过程在塑造这些古老克拉通金矿化的偶发性质方面的重要性。
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引用次数: 0
Clay mineral geochemistry and paleoenvironmental reconstruction across the Cryogenian Sturtian Snowball glaciation 整个冰期斯图尔特雪球冰川的粘土矿物地球化学和古环境重建
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107498
Jalila Al Bahri , Olabode Bankole , Duncan Muir , Abderrazzak El Albani , Anthony Oldroyd , Diana Contreras , Morten Andersen , Ernest Chi Fru

Recent evidence from marine sedimentary rocks suggests that clay minerals were important in the supply of bioessential nutrients to seawater at the end of the Sturtian Snowball Earth glaciation that occurred ∼ 717–660 million years ago. However, little is known about the identity of these clay minerals, their abundance and distribution in the pre-glacial, glacial and post-glacial deposits. Here, high resolution petrographic scanning electron microscopy-energy dispersive x-ray spectroscopy, combined with bulk and < 2µ clay-size fraction X-ray diffraction mineralogical analysis and trace and major element geochemistry, point to dominant enrichment of illite in shallow marine platform sediments preserved across Sturtian Snowball Earth facies on Islay and the Garvellachs Island, Scotland. The glacial till is enriched with detrital chlorite, while pore-filling authigenic kaolinite is observed in the pre-glacial and post-glacial greenhouse facies, but scarce in the glaciogenic tillites. Discriminant binary plots of Th/Sc vs Zr/Sc ratios, indicative of insignificant modification of primary sediment composition by hydraulic sorting and recycling processes, together with chemical weathering indices, point to moderate to intense chemical weathering of the pre-glacial and post-glacial source rocks. Low Chemical Index of Alternation (CIA) values, coupled to the distinct chlorite composition of the glacial till, is consistent with mechanical tillage of continental landmass by the terminal Snowball melting ice sheets. The moderate to intense chemical weathering indices in the pre- and post-glacial deposits correspond with greenhouse conditions of elevated atmospheric CO2 content and temperature. Overall, the predominantly detrital origin of the clay minerals implies enhanced post-glacial nutrient supply bound to clay minerals in lower pH river water during transportation, followed by release in higher pH saline seawater.

最近从海洋沉积岩中获得的证据表明,在距今 7.17-6.6 亿年前的斯图尔特雪球地球冰川末期,粘土矿物对海水中生物必需营养物质的供应非常重要。然而,人们对这些粘土矿物的特征、它们在冰川前、冰川期和冰川后沉积物中的丰度和分布知之甚少。在这里,高分辨率岩相扫描电子显微镜-能量色散 X 射线光谱分析,结合大块和 2µ 粘土尺寸分数 X 射线衍射矿物学分析以及痕量和主要元素地球化学分析,表明在苏格兰艾莱岛和加维尔拉克斯岛保存的整个斯特尔蒂雪球地层的浅海平台沉积物中主要富含伊利石。冰川沉积物中富含绿泥石,而在冰川前和冰川后温室面层中观察到孔隙填充自生高岭石,但在冰川成因沉积物中却很少见。Th/Sc与Zr/Sc比率的二元判别图表明,水力分选和循环过程对原始沉积物成分的改变不大,再加上化学风化指数,表明前冰期和后冰期源岩的化学风化程度为中等至强烈。较低的化学交替指数(CIA)值,加上冰川淤积物中明显的绿泥石成分,与雪球末期融化冰原对大陆地块的机械耕作是一致的。冰川前和冰川后沉积物的中等至强烈化学风化指数与大气中二氧化碳含量和温度升高的温室条件相吻合。总体而言,粘土矿物主要来源于碎屑岩,这意味着冰川期后的营养物质供应增强,在运输过程中与 pH 值较低的河水中的粘土矿物结合,然后在 pH 值较高的盐海水中释放出来。
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引用次数: 0
High-pressure mafic granulite and supracrustal rocks in the southern Hengshan area, North China Craton: Metamorphic P-T-t evolution and geotectonic significance 华北克拉通恒山南部地区的高压黑云母花岗岩和超基性岩:变质P-T-t演化及其大地构造意义
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107501
Guo-Dong Wang , Xiao-Lei Wang , Zhen M.G. Li , Yue Guan , Juan Wang , Feng-Li Shao , Chun-Ming Wu

Amphibolite- to granulite-facies rocks are widely distributed in the Hengshan Complex, middle Trans-North China Orogen, and the high-pressure (HP) mafic granulite has been recently identified in the southern Hengshan area. The HP mafic granulite and amphibolite occur as rootless tectonic boudins/lenses within the TTG (tonalite–trondhjemite–granodiorite) gneiss/metapelite, indicative of typical “block-in-matrix” texture of metamorphic-tectonic mélange. Three to four generations of metamorphic mineral assemblages that correspond to the prograde (M1), peak (M2), and retrograde (M3-M4) stages, are recognized in these rocks. Conventional geothermobarometry and phase equilibrium modeling yield peak P–T conditions of 10.8–13.8 kbar/754–799 °C for the HP mafic granulite and 7.3–9.0 kbar/690–725 °C for the supracrustal rocks, respectively. A clockwise P–T path with near-isothermal decompression (ITD) and subsequent near-isobaric cooling (IBC) segments is reconstructed for the HP mafic granulite, indicating a dynamic subduction–collision–exhumation process that unfolded during an orogenic event. Secondary ion mass spectrometry (SIMS) U-Pb dating of zircon yields metamorphic ages of ca. 1.91–1.83 Ga, representing the long-lived tectono-metamorphic event caused by collision between the Eastern and Western Blocks along the Trans-North China Orogen. It is hypothesized that the tectono-metamorphic mélange in the area originated from the tectonically juxtaposition of metamorphic rocks that had diverse protoliths, different peak P–T conditions and discrepant metamorphic ages. This complexity may be a hallmark of Paleoproterozoic orogens, drawing intriguing parallels with the intricate characteristics observed in Phanerozoic orogenic belts.

闪长岩-花岗岩层位的岩石广泛分布于横断华北造山带中段的衡山复合带,最近在衡山南部地区发现了高压黑云母花岗岩。高压黑云母花岗岩和闪长岩以无根构造拗陷/透镜体的形式出现在TTG(黑云母-透辉石-花岗闪长岩)片麻岩/片麻岩中,显示了变质构造混合体典型的 "块中基质 "质地。在这些岩石中发现了三至四代变质矿物组合,分别对应于顺行阶段(M1)、峰值阶段(M2)和逆行阶段(M3-M4)。根据传统的地温测算法和相平衡模型,高纯黑云母花岗岩的峰值P-T条件分别为10.8-13.8千巴/754-799 °C,超基性岩的峰值P-T条件分别为7.3-9.0千巴/690-725 °C。为HP黑云母花岗岩重建了一条顺时针的P-T路径,其中包括近等温减压(ITD)和随后的近等压冷却(IBC)段,表明在造山运动中发生了一个动态的俯冲-碰撞-膨胀过程。锆石的二次离子质谱(SIMS)U-Pb定年得出的变质年龄约为1.91-1.83 Ga,代表了沿跨华北造山带东西区块之间的碰撞所引起的长周期构造变质事件。据推测,该地区的构造-变质混杂区是由原岩多样、峰值P-T条件不同和变质年龄不一致的变质岩构造并置而形成的。这种复杂性可能是古近纪造山带的特征之一,与新生代造山带的复杂特征具有相似之处。
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引用次数: 0
Genesis of the Neoarchean Algoma-type banded iron formation: constraints from Fe isotope and element geochemistry of the Qian’an iron deposit, eastern North China craton 新元古代阿尔戈马型带状铁矿形成的成因:华北东部克拉通迁安铁矿床铁同位素和元素地球化学的制约因素
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107480
Xin Han , Junlai Liu

The Neoarchean Qian’an BIF deposit in eastern Hebei, eastern North China Craton has attracted extensive attention of study in the last decades, but the genesis, e.g., Fe sources, metallogenic mechanism, as well as tectonic attributes of the BIFs remains highly disputed. Based on field investigations, microscopic observations and geochemical analysis, this study tries to unravel the source characteristics of ore-forming materials in the Qian’an deposit. The results show that the chemical compositions of the BIF ore samples are mainly composed of TFe2O3 and SiO2, with minor Al2O3 and TiO2. The total trace element contents of the samples are relatively low. The PAAS-normalized REE distribution patterns of the ores show LREE depletion and HREE enrichment, with robust positive anomalies of Eu, Y and La. These characteristics indicate that the BIFs are attributed to dominant chemical precipitation originated from paleo-ocean with obvious volcanic hydrothermal contributions and minor clastic input. Their positive to no Ce anomalies and positive δ56Femagnetite values unveil that the iron was precipitated at low oxygen fugacity. These results, in collaboration with evidence from previous lithological, structural geology, metamorphic P-T paths, geochemistry, geochronology and numerical modeling studies, support a mantle plume model to explain the complicated tectono-thermal processes, and the sources of BIFs in Eastern Hebei, eastern North China Craton.

近几十年来,位于华北克拉通东部河北东部的新元古代迁安BIF矿床引起了人们的广泛关注,但对BIF的成因,如铁的来源、成矿机制以及构造属性等仍存在很大争议。本研究以野外调查、显微观察和地球化学分析为基础,试图揭示乾安矿床成矿物质的来源特征。结果表明,BIF 矿石样品的化学成分主要由 TFe2O3 和 SiO2 组成,少量 Al2O3 和 TiO2。样品的微量元素总含量相对较低。矿石的 PAAS 归一化 REE 分布模式显示 LREE 贫化和 HREE 富集,Eu、Y 和 La 呈强阳性异常。这些特征表明,BIFs 主要是源于古海洋的化学沉淀,有明显的火山热液贡献和少量的碎屑岩输入。它们的铈异常为正值或无异常,δ56铁磁体值为正值,这揭示了铁是在低富氧条件下沉淀的。这些结果与之前的岩石学、构造地质学、变质P-T路径、地球化学、地质年代和数值模拟研究的证据相结合,支持用地幔羽流模型来解释华北克拉通东部河北东部地区复杂的构造热液过程和BIFs的来源。
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引用次数: 0
The significance of Paleoarchean granitoids from the Saglek Block, Labrador, Canada 加拿大拉布拉多萨格尔克区块古新世花岗岩的意义
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1016/j.precamres.2024.107504
Tanmay Keluskar , Monika A. Kusiak , Daniel J. Dunkley , Simon A. Wilde , Martin J. Whitehouse , Keewook Yi , Shinae Lee

The Saglek Block in the Nain Province of northeast Canada is part of the North Atlantic Craton. It comprises Archean gneisses that record magmatic and metamorphic ages between ca. 3.9 and 2.5 Ga. In this study, a grey banded gneiss from Maidmonts Island records an age of 3.72 Ga, which is equated with Uivak I gneisses reported from across the Saglek Block, and contains 3.8 Ga xenocrysts. These rocks were deformed and metamorphosed prior to the intrusion of augen gneiss protoliths on both Maidmonts and Mentzel islands that record U-Pb zircon ages of 3.33 Ga. These rocks are composed of ferroan calc-alkaline granite and granodiorite and were likely generated by partial melting of pre-existing quartzo-feldspathic crust, as attested by the presence of ca. 3.8 Ga xenocrysts. Such augen gneiss was previously classified as ca. 3.6 Ga ‘Uivak II gneiss’, a term we argue should now be abandoned. The final magmatic events recorded on Maidmonts and Mentzel islands took place in the Neoproterozoic with the emplacement of granitic stocks at ca. 2.72 Ga, and sills and dykes at ca. 2.57 Ga. This sequence of magmatic events from the Eoarchean to Neoarchean is very similar to that recorded in the Itsaq Gneiss Complex of southwest Greenland, where, based on the Hf signature, it has been suggested that a change in tectonic environment resulted from the initiation of subduction at ca. 3.2 Ga. Although Lu-Hf and Sm-Nd isotopic signatures from the ca. 3.33 Ga gneisses have been interpreted in the literature as due to partial melting of Hadean mafic crust, alternatively, they can be generated by partial melting of Eoarchean continental crust in a continental arc setting. We argue this is more consistent with the non-TTG geochemistry of the augen gneisses.

加拿大东北部纳恩省的萨格莱克区块是北大西洋克拉通的一部分。它由阿基坦片麻岩组成,记录的岩浆和变质年龄约在 3.9 至 2.5 Ga 之间。在这项研究中,来自梅德蒙茨岛的灰色带状片麻岩记录的年龄为3.72 Ga,与整个萨格莱克地块报告的Uivak I片麻岩相当,并含有3.8 Ga的异晶。这些岩石在麦德蒙茨岛和门采尔岛的奥长片麻岩原岩侵入之前发生了变形和变质,其锆石U-Pb年龄为3.33 Ga。这些岩石由铁质钙碱性花岗岩和花岗闪长岩组成,很可能是由先前存在的石英-长石地壳部分熔融而成,其中存在的约 3.8 Ga 的异晶石证明了这一点。这种奥长片麻岩以前被归类为约 3.6 Ga 的 "Uivak II 片麻岩",我们认为现在应该放弃这个术语。麦德蒙茨岛和门策尔岛记录的最后岩浆事件发生在新元古代,花岗质岩浆在约 2.72 Ga 处形成,而岩柱和岩堤则在约 2.57 Ga 处形成。从新元古代到新元古代的这一岩浆事件序列与格陵兰岛西南部的Itsaq片麻岩复合体所记录的岩浆事件序列非常相似,根据Hf特征,有人认为大约在3.2 Ga时开始的俯冲导致了构造环境的改变。3.2 Ga.尽管来自约 3.33 Ga 片麻岩的 Lu-Hf 和 Sm-Nd 同位素特征表明,格陵兰岛西南部的构造环境发生了变化。3.33Ga片麻岩的Lu-Hf和Sm-Nd同位素特征在文献中被解释为哈代黑云母地壳的部分熔融所致,但它们也可能是在大陆弧环境中由新元古代大陆地壳的部分熔融产生的。我们认为这更符合奥陶纪片麻岩的非TTG地球化学特征。
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