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Enhanced Viability of Iron-Doped Titanium Dioxide Nanoparticles with Antibacterial Efficacy
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-27 DOI: 10.1007/s13538-025-01702-3
N. G. Jitha, K. Deepa, N. Ayana

Titanium dioxide nanoparticles (TiO2NPs) exhibit optical, electrical, and magnetic properties and are potential candidates for biomedical uses. The cytotoxicity comparison among undoped as well as iron-doped TiO2NPs is supported by the current study. The antibacterial test was also conducted for five different bacteria. Pure and iron-doped TiO2NPs were synthesized using titanium isopropoxide and iron nitrate nonahydrate as precursors using the co-precipitation method. The synthesized TiO2NPs were characterized by XRD (X-ray diffraction), UV-Vis (UV-visible diffuse reflectance spectroscopy), EDAX (energy dispersive X-ray spectroscopy) analysis, and FTIR (Fourier transform infrared spectroscopy) analysis. XRD examination revealed a shift in peak when TiO2 is doped with iron. EDAX analysis verified that (Fe3+) iron particles were present in the TiO2 crystal structure. Band gap energy was calculated from UV-Vis, and it was confirmed that with an increase in doping concentration, band gap energy seems to decrease. FTIR analysis established the presence of different functional groups within TiO2NPs. The in-vitro cytotoxic effect was determined using the MTT assay method. The study showed that the iron-doped TiO2NPs are comparatively less cytotoxic than pure TiO2NPs.

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引用次数: 0
Correction: Influence of Cobalt on Structural, Morphological, Dielectric, and Magnetic Properties of Barium M-Type Hexagonal Ferrites for Technological Applications
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-25 DOI: 10.1007/s13538-025-01705-0
Muhammad Zahid, Hasan M. Khan, Zunaira Munawar, Shehla Honey, Muhammad A. Assiri, Muhammad Arif Khan, Zia Ur Rehman
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引用次数: 0
The Impact of Deuteron Breakup in the Field of 90Zr and 116Sn Targets
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-24 DOI: 10.1007/s13538-025-01699-9
Zh. Kurmanaliyev, D. Soldatkhan, G. Yergaliuly, R. Akhat, B. Mauyey, K. W. Kemper, Sh. Hamada

The role of continuum coupling to the breakup of the deuteron is clearly shown through microscopic continuum discretized coupled channel (CDCC) calculations carried out with and without this coupling. The analysis was further extended to construct an effective potential (Ueff) from the sum of cluster folding (CF) and dynamical polarization (DPP) potentials that allow the continuum coupling to be more easily visualized. The considered d + 90Zr and 116Sn ADs are reasonably reproduced within the Ueff without any additional adjustments over the wide energy range of this study from ~ 23 to 196 MeV. Both methods clearly show the growth in the influence of coupling to the breakup channel as a function of an increase in deuteron energy. The findings of this study provide evidence supporting the use of the Ueff to describe elastic angular distribution (AD) data across a wide range of energies.

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引用次数: 0
Investigating the Potential of Utilizing Free Standing Bi1−xGdxFeO3 Polymer-Ceramic Nanocomposite Film for Applications in Flexible and Wearable Microwave Devices 研究独立Bi1−xGdxFeO3聚合物-陶瓷纳米复合薄膜在柔性和可穿戴微波器件中的应用潜力
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-22 DOI: 10.1007/s13538-024-01678-6
E. John Alex, B. Gayathri Manju, R. Anlin Golda, K. A. Malar, I. Paulkani

A facile approach was developed for a novel polymer-ceramic nanocomposite, specifically gadolinium-substituted bismuth ferrites (Bi1−xGdxFeO3) for flexible radio-frequency (RF) antenna applications. The polymer-ceramic nanocomposite was developed by synthesizing gadolinium-substituted bismuth ferrite (Bi1−xGdxFeO3) nanoparticles through a methoxy-aided sol–gel process followed by dispersion in PVA polymer. The structural and morphological characteristics of the nanoparticles were extensively examined using X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The study revealed a rhombohedral distorted perovskite structure and increased crystallite size with higher gadolinium concentrations. Dielectric properties of the nanocomposite material was investigated at low and high frequencies to assess the material’s suitability for high-frequency conformal antennas. The PVA/Bi0.9Gd0.1FeO3 nanocomposite films exhibited a relative wave impedance of 0.6 with a miniaturization factor of 1.89 making it eligible for microwave device applications. The microstrip patch antenna modeled and simulated with the PVA/Bi0.9Gd0.1FeO3 composite exhibited a return loss of − 21.9 dB in the X band of the frequency spectrum. The functionality of the antennas was tested for the bending conditions of radius 10 mm and 30 mm, exhibiting a return loss of − 41.2 dB and − 23.5 dB in the X band with an ultrawide bandwidth of 5 GHz. The results of PVA/Bi0.9Gd0.1FeO3 nanocomposite substrate antennas exhibit enhanced performance for application in wireless wearable devices.

开发了一种新型聚合物-陶瓷纳米复合材料,特别是用于柔性射频(RF)天线应用的钆取代铋铁氧体(Bi1−xGdxFeO3)。采用甲氧基辅助溶胶-凝胶法制备钆取代铋铁氧体(Bi1−xGdxFeO3)纳米粒子,并在PVA聚合物中分散,制备了聚合物-陶瓷纳米复合材料。利用x射线衍射、扫描电子显微镜和能量色散x射线光谱学对纳米颗粒的结构和形态特征进行了广泛的研究。研究发现,随着钆浓度的增加,钙钛矿呈菱面体扭曲结构,晶体尺寸增大。研究了纳米复合材料在低频和高频下的介电性能,以评估该材料在高频共形天线中的适用性。PVA/Bi0.9Gd0.1FeO3纳米复合膜的相对波阻抗为0.6,小型化系数为1.89,适合微波器件应用。用PVA/Bi0.9Gd0.1FeO3复合材料模拟的微带贴片天线在X波段回波损耗为- 21.9 dB。在半径为10 mm和30 mm的弯曲条件下测试了天线的功能,在5 GHz的超宽带带宽下,X波段的回波损耗分别为- 41.2 dB和- 23.5 dB。结果表明,PVA/Bi0.9Gd0.1FeO3纳米复合衬底天线在无线可穿戴设备中的应用性能有所提高。
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引用次数: 0
Preparation of Er,Nd Codoped Y2O3 Transparent Ceramics and their Upconversion and Downconversion Mechanisms Er、Nd共掺Y2O3透明陶瓷的制备及其上、下转换机理
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-20 DOI: 10.1007/s13538-025-01694-0
Srimathy B,  Ramesh Babu P, Rachana Selvamani,  Veeramanikandasamy T,  Devendiran S,  Maniammal K

Transparent ceramics nowadays finds applications in infrared windows, lamps covers, optoelectronic devices, smart phone screens and especially as host materials for solid-state lasers. One such ceramic material, Y2O3 was considered in the present investigation and the effect of neodymium (Nd) and erbium (Er) at different concentrations (0.5, 1.0, 1.5 and 2.0 at%) was studied. Transparent ceramic pellets were synthesized by co-precipitation method, sintered at high vacuum and finally polished. Structural characterizations confirmed the presence of cubic phase and scanning electron micrographs established the compactness of the samples with no secondary phase. The ceramics were found to have good transparency around 75%. Refractive index measurements showed least absorption at higher wavelengths which ensures good transmission properties. The upconversion and downconversion mechanisms are discussed in detail with varying Er concentration for different excitation wavelengths. The observations clearly indicate green and red emissions which ensure the effective utilization of these transparent ceramics as dual mode emitters.

透明陶瓷如今被应用于红外窗、灯罩、光电器件、智能手机屏幕,特别是作为固态激光器的主体材料。本文以其中一种陶瓷材料Y2O3为研究对象,研究了不同浓度(0.5、1.0、1.5和2.0 at%)的钕(Nd)和铒(Er)对陶瓷性能的影响。采用共沉淀法合成透明陶瓷球团,在高真空下烧结,最后抛光。结构表征证实了立方相的存在,扫描电镜证实了样品的致密性,没有二次相。研究发现,这种陶瓷的透明度在75%左右。折射率测量表明,在较高的波长吸收最小,这保证了良好的传输性能。详细讨论了不同激发波长下铒浓度变化时的上转换和下转换机理。观察结果清楚地表明,绿色和红色的发射保证了这些透明陶瓷作为双模发射体的有效利用。
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引用次数: 0
Form Factor and New Mean Fields in Bubble Nuclei 气泡核的形状因子和新平均场
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-18 DOI: 10.1007/s13538-025-01697-x
S. Berbache, A. Bouldjedri

Bubble nuclei are an exotic class of nuclear systems showing a central region of reduced nucleon density. The occurrence of such depletion (a bubble)is an interesting nuclear phenomenon, whose underlying microscopic origin provides a rapidly developing field of research in nuclear structure. In the present work, the properties of (medium) bubble nuclei are analyzed using shell model calculations. We addressed the question of deriving a criterion that allows identifying experimentally bubble nuclei using the form factor. As an extension of the seminal work of Wong in the 70 s, different mean fields have been proposed and their properties discussed. In addition, the effect of a bubble structure on the charge density distribution, the form factor and the single-particle levels, is discussed through their dependence on the inner-to-outer radius ratio p. In this way, level crossing and inversion have been obtained. Such results lead to the magic numbers 18 and 32, low angular momentum state occupancy reduction, and hence to candidates for bubble structure in exotic nuclei.

泡核是一类奇特的核系统,其中心区域的核子密度降低。这种耗竭(气泡)的发生是一种有趣的核现象,其潜在的微观起源为核结构的研究提供了一个迅速发展的领域。本文采用壳层模型计算分析了(介质)泡核的性质。我们解决了导出一个标准的问题,该标准允许使用形状因子在实验中识别泡核。作为黄在70年代开创性工作的延伸,提出了不同的平均场并讨论了它们的性质。此外,还讨论了气泡结构对电荷密度分布、形状因子和单粒子能级的影响,通过它们与内外半径比p的关系,从而获得了水平交叉和反转。这些结果导致了幻数18和32,低角动量状态占用减少,从而成为奇异核中气泡结构的候选者。
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引用次数: 0
A Systematic DFT Study on the Optoelectronic and Elastic Characteristics of H-Induced KMnF3 Perovskite 氢致KMnF3钙钛矿光电和弹性特性的系统DFT研究
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-16 DOI: 10.1007/s13538-024-01683-9
Hussein A. Miran, Zainab N. Jaf

Perovskite based compounds have demonstrated unique performance in range of applications. Particularly, KMnF3 has gained much importance in recent years. However, loading various contents of H ion to be situated at F site would improve the desired physical properties of the pristine KMnF3. This account carries out density functional theory (DFT) calculations via using CASTEP code. GGA approximation and PW91 functional were adopted to investigate the structural, optoelectronic, and mechanical properties of KMnHxF3-x at (x = 0.25 and 0.50). The optimized lattice constants of the pure configuration were in good agreements with the published literature. Moreover, KMnF3 exhibits a semiconducting nature with a direct electronic band gap of 2.177 eV. The modelled configurations demonstrate negative values of formation energies indicating the possibility of experimental synthesis. The analysed band structure reveals reducing tendency after H insertion. Furthermore, Optical results show an enhancement in the absorption spectra after the insertion of Hydrogen toward visible region of the electromagnetic radiation. Finally, elastic properties have been recorded and suggested that these compounds are mechanically stable. The current findings would significantly contribute in the field of solar cell applications and optoelectronic devices.

钙钛矿基化合物在广泛的应用中表现出独特的性能。特别是,KMnF3近年来得到了越来越多的重视。然而,在F位点加载不同含量的氢离子会改善原始KMnF3的期望物理性质。该帐户通过使用CASTEP代码进行密度泛函理论(DFT)计算。采用GGA近似和PW91泛函对KMnHxF3-x在(x = 0.25和0.50)下的结构、光电性能和力学性能进行了研究。优化后的纯构型晶格常数与已发表的文献基本一致。此外,KMnF3具有半导体性质,其直接电子带隙为2.177 eV。模型构型的地层能为负值,表明实验合成的可能性。分析的能带结构显示插入H后有减小的趋势。此外,光学结果表明,在电磁辐射可见区插入氢后,吸收光谱增强。最后,弹性性能的记录表明,这些化合物是机械稳定的。目前的研究结果将在太阳能电池应用和光电子器件领域做出重大贡献。
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引用次数: 0
Influence of Cobalt on Structural, Morphological, Dielectric, and Magnetic Properties of Barium M-Type Hexagonal Ferrites for Technological Applications 钴对钡m型六方铁氧体结构、形态、介电和磁性能的影响及其技术应用
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-16 DOI: 10.1007/s13538-025-01698-w
Muhammad Zahid, Hasan M. Khan, Zunaira Munawar, Shehla Honey, Muhammad A. Assiri, Muhammad Arif Khan, Zia Ur Rehman
<div><p>Hexagonal ferrites have gained considerable attention due to their promising applications in electronic fields. Herein, the synthesis of M-type hexaferrites with nominal composition Ba<sub>1-x</sub>Co<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> at x = (0.0, 0.2, 0.4, 0.6) was successfully prepared by the facile and cost-effective sol–gel auto-combustion technique. The synthesized samples were characterized by a variety of techniques, and dielectric properties were investigated by impedance analyzer. Structural, morphological, magnetic, and dielectric characteristics of the synthesized samples were explored. The objectives of the present study are to enhance the magnetic and dielectric characteristics that were obtained by the variation of cobalt. X-ray diffraction analysis was applied to verify the single-phase hexagonal ferrites. Physical properties such as bulk density, X-ray density, and porosity of the Ba<sub>1-x</sub>Co<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> at x = (0.0, 0.2, 0.4, 0.6) M-type hexagonal ferrites were calculated. As a result of internal stress induced by the alteration in ionic radii of the dopant ion (Co<sup>2+</sup> with ionic radii 0.72 Å) and base element (Ba<sup>2+</sup> with ionic radii 1.49 Å), lattice parameters were decreased. The prepared materials were analyzed using scanning electron microscopy (SEM), which showed the hexagonal platelet structure. The dielectric constant gradually increased with the increase of dopant concentration. It is found that these characteristics are beneficial for high-frequency technologies such as phase shifters and modulators, as well as magnetic recording media. The saturation magnetization was found to be in the range of 58.27–64.26 (emu/g), and coercivity was found to be from 208.95–568.46 Oe. The dielectric and magnetic properties of Ba<sub>1-x</sub>Co<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> at x = (0.0, 0.2, 0.4, 0.6) M-type hexagonal ferrites with the cobalt variation suggested that the prepared materials are excellent candidates for modern gadgets.</p><h3>Graphical Abstract</h3><p>X-ray diffraction pattern of the cobalt-substituted M-type hexaferrites with composition Ba<sub>1-x</sub>Co<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> x = (0.0, 0.2, 0.4, 0.6) is shown in the figure. The pattern of the synthesized nanoparticles exhibits a single-phase homogeneous structure. It is found that each sample had no impurity phase and was hexagonally crystallized to the P63/mmc space group. All the peaks matched with the JCPDS card number (43–0002). The prepared samples exhibited well-matched intensity peaks with the miller indices of the peaks (006), (110), (008), (114), (205), (206), (1011), (209), (2010), (218), (0014), and (0016) in the diffraction planes. The cell software determined the lattice parameters (a and c). Lattice parameter “a” was found to be in the range of (5.888–5.857) Å and “c” was found to be in the range of (23.152–23.119) Å. Crystallite size ranges from 39.08 to 4
六方铁氧体由于在电子领域中具有广阔的应用前景而受到广泛的关注。本文采用溶胶-凝胶自燃烧技术,在x =(0.0, 0.2, 0.4, 0.6)处成功合成了标称成分为Ba1-xCoxFe12O19的m型六铁体。用各种技术对合成的样品进行了表征,并用阻抗分析仪对样品的介电性能进行了研究。研究了合成样品的结构、形态、磁性和介电特性。本研究的目的是提高磁性和介电特性,得到了变化的钴。采用x射线衍射分析对单相六方铁氧体进行了验证。计算了Ba1-xCoxFe12O19在x = (0.0, 0.2, 0.4, 0.6) m型六方铁氧体的体积密度、x射线密度和孔隙率等物理性能。由于掺杂离子(离子半径为0.72 Å的Co2+)和碱元素(离子半径为1.49 Å的Ba2+)的离子半径发生变化所引起的内应力,导致晶格参数降低。用扫描电镜对制备的材料进行了分析,发现材料呈六角形片状结构。介电常数随掺杂剂浓度的增加而逐渐增大。研究发现,这些特性对移相器、调制器等高频技术以及磁记录介质都是有利的。饱和磁化强度为58.27 ~ 64.26 (emu/g),矫顽力为208.95 ~ 568.46 Oe。在x = (0.0, 0.2, 0.4, 0.6) m时,Ba1-xCoxFe12O19的介电和磁性能随钴含量的变化而变化,表明所制备的材料是现代器件的优良候选材料。图1为成分Ba1-xCoxFe12O19 x =(0.0, 0.2, 0.4, 0.6)的钴取代m型六铁素体的x射线衍射图。合成的纳米颗粒呈单相均匀结构。结果表明,各样品均无杂质相,呈P63/mmc空间基六边形结晶。所有峰值与JCPDS卡号(43-0002)相匹配。制备的样品与衍射平面上的峰(006)、(110)、(008)、(114)、(205)、(206)、(1011)、(209)、(2010)、(218)、(0014)、(0016)的米勒指数具有较好的匹配强度峰。细胞软件确定了晶格参数(a和c),晶格参数“a”的取值范围为(5.888-5.857)Å,“c”的取值范围为(23.152-23.119)Å。晶粒尺寸为39.08 ~ 44.70 nm,具有良好的信噪比。
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引用次数: 0
Phase Shifts Due to Head-on Collision of Electron Acoustic Waves and Production of Rogue Waves: Kappa-Deformed Kaniadakis Electrons 电子声波正面碰撞引起的相移和异常波的产生:kappa变形的Kaniadakis电子
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-16 DOI: 10.1007/s13538-025-01700-5
Umma Imon, M. S. Bhuyan, M. S. Alam

The effects of electron-acoustic (EA) waves’ head-on collisions and rogue wave (RW) production are studied in a collisionless, unmagnetized plasma composed of stationary ions, deformed Kaniadakis-distributed hot electrons, and cold fluid electrons. The nonlinear Schrödinger equation is generated using the standard reductive perturbation (SRP) approach, and the Korteweg-de Vries (KdV) equations (KdVEs) and modified KdVEs (mKdVEs) are determined via the general case using the extended Poincaré-Lighthill-Kuo (ePLK) perturbation method (ePLKM). In particular, the influence of the density ratio and the deformed Kaniadakis parameter on the RW structure, the creation of EA soliton structures, and phase shifts resulting from head-on collisions are examined. The construction of EA solitons, the generation of RW, and the variations of phase shifts are found to be significantly influenced by the parameters in question. In this work, the collisions of KdV solitons show positive and negative phase shifts. Though both the positive and negative phase shifts result from the interaction of mKdV solitons and the influence of the relevant parameters, only the positive phase shifts are studied here.

在由固定离子、变形kaniadakis分布的热电子和冷流体电子组成的无碰撞非磁化等离子体中,研究了电子声(EA)波的正面碰撞和异常波(RW)的产生。非线性Schrödinger方程采用标准约简摄动(SRP)方法生成,Korteweg-de Vries (KdV)方程(KdV)和修正KdV (mkdv)方程通过一般情况下采用扩展poincar - lighthill - kuo (ePLK)摄动法(ePLKM)确定。特别地,研究了密度比和变形的Kaniadakis参数对RW结构、EA孤子结构的产生以及正面碰撞引起的相移的影响。研究发现,这些参数对EA孤子的构造、RW的产生和相移的变化有显著的影响。在这项工作中,KdV孤子的碰撞表现出正相移和负相移。虽然正相移和负相移都是由mKdV孤子相互作用和相关参数的影响引起的,但这里只研究正相移。
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引用次数: 0
Blazars Jets and Prospects for TeV-PeV Neutrinos and Gamma Rays Through Cosmic-Ray Interactions 耀变体喷流和通过宇宙射线相互作用的TeV-PeV中微子和伽马射线的前景
IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-01-15 DOI: 10.1007/s13538-024-01689-3
Rodrigo Sasse, Rubens Jr. Costa, Luiz A. Stuani Pereira, Rita C. dos Anjos

This study explores the origins of cosmic rays and their secondary messengers, focusing on the potential role of four BL Lacs—W Comae, 1ES 1959+650, PKS 2005-489, and PKS 2155-304—as potential sources of astrophysical neutrinos and gamma rays. We analyzed a single-zone model to understand the interactions between high-energy protons and ambient photons within blazar jets, leading to neutrino production observables and gamma-ray emission. This modeling contextualizes the emissions within multiwavelength observations and evaluates the capabilities of the next-generation Cherenkov Telescope Array Observatory (CTAO) in detecting these emissions. Our estimations suggest that these sources could be effective emitters of CRs, highlighting the need for future multimessenger observations to further investigate and constrain this class of sources.

这项研究探索了宇宙射线及其次级信使的起源,重点关注了四个BL Lacs-W Comae, 1ES 1959+650, PKS 2005-489和PKS 2155-304作为天体物理中微子和伽马射线的潜在来源的潜在作用。我们分析了一个单区域模型,以了解耀变体喷流中高能质子和环境光子之间的相互作用,导致中微子产生和伽马射线发射。该模型将多波长观测中的发射背景化,并评估下一代切伦科夫望远镜阵列天文台(CTAO)探测这些发射的能力。我们的估计表明,这些源可能是CRs的有效发射源,强调未来需要进行多信使观测,以进一步调查和限制这类源。
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引用次数: 0
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Brazilian Journal of Physics
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