Pub Date : 2024-12-04DOI: 10.1007/s13538-024-01658-w
Poovitha Kanagaraj, Karthikeyan Balasubramanian
The search for advanced energy storage devices has extensive research into batteries beyond the conventional lithium-ion battery. As we know, now researchers are actively exploring alternative energy storage technologies, focusing on abundant elements such as calcium (Ca), magnesium (Mg), sodium (Na), and zinc (Zn). These alternatives promise to reduce the limitations of lithium resources, offering potentially lower costs, higher resource availability, and diverse chemistries for various applications. This short review provides an overview of recent advancements in next-generation battery storage systems mainly on the alternate to Li-ion battery, focusing on innovations in battery chemistry, energy density, safety, and integration with renewable energy sources. The review explores the significance of enhancing battery technology for various uses like electric vehicles and large-scale energy storage systems. It emphasizes notable advancements and hurdles encountered in this domain. The various types of batteries and their anode, cathode, and electrolyte materials were discussed briefly, in the present review. The present work will be helpful for the budding researchers who work in the field of energy storage systems, to acquire a knowledge on the recent trends and future technology of battery storage systems towards the alternate solution for Li-ion battery.
{"title":"A Short Review on Next-Generation Batteries: Energy Storage System","authors":"Poovitha Kanagaraj, Karthikeyan Balasubramanian","doi":"10.1007/s13538-024-01658-w","DOIUrl":"10.1007/s13538-024-01658-w","url":null,"abstract":"<div><p>The search for advanced energy storage devices has extensive research into batteries beyond the conventional lithium-ion battery. As we know, now researchers are actively exploring alternative energy storage technologies, focusing on abundant elements such as calcium (Ca), magnesium (Mg), sodium (Na), and zinc (Zn). These alternatives promise to reduce the limitations of lithium resources, offering potentially lower costs, higher resource availability, and diverse chemistries for various applications. This short review provides an overview of recent advancements in next-generation battery storage systems mainly on the alternate to Li-ion battery, focusing on innovations in battery chemistry, energy density, safety, and integration with renewable energy sources. The review explores the significance of enhancing battery technology for various uses like electric vehicles and large-scale energy storage systems. It emphasizes notable advancements and hurdles encountered in this domain. The various types of batteries and their anode, cathode, and electrolyte materials were discussed briefly, in the present review. The present work will be helpful for the budding researchers who work in the field of energy storage systems, to acquire a knowledge on the recent trends and future technology of battery storage systems towards the alternate solution for Li-ion battery.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The interaction between aquatic organisms and plants is crucial to maintaining the ecological balance of the marine environment. This study aims to investigate the effects of providing refuge on phytoplankton and the delay in releasing hazardous substances by phytoplankton. To accomplish this, a nutrient-phytoplankton-zooplankton system was developed and analyzed to examine its equilibria and the conditions under which they exist. The model’s stability was also analyzed, both in the absence and presence of time delays. The inclusion of a time delay caused a Hopf bifurcation at the interior equilibrium of the model, resulting in a transition from stability to instability. The study found that as the time delay value increases, the system’s stable dynamics transition into an unstable state. However, because phytoplankton refuge is part of the system, the dynamics temporarily become stable, even though phytoplankton release the toxins over a long time. However, this stable behavior is disrupted when the time required for the toxin liberation process by phytoplankton is further extended.
{"title":"The Effect of Time Delay on the Dynamics of a Plankton-Nutrient System with Refuge","authors":"Kaushik Dehingia, Anusmita Das, Evren Hinçal, Kamyar Hosseini","doi":"10.1007/s13538-024-01670-0","DOIUrl":"10.1007/s13538-024-01670-0","url":null,"abstract":"<div><p>The interaction between aquatic organisms and plants is crucial to maintaining the ecological balance of the marine environment. This study aims to investigate the effects of providing refuge on phytoplankton and the delay in releasing hazardous substances by phytoplankton. To accomplish this, a nutrient-phytoplankton-zooplankton system was developed and analyzed to examine its equilibria and the conditions under which they exist. The model’s stability was also analyzed, both in the absence and presence of time delays. The inclusion of a time delay caused a Hopf bifurcation at the interior equilibrium of the model, resulting in a transition from stability to instability. The study found that as the time delay value increases, the system’s stable dynamics transition into an unstable state. However, because phytoplankton refuge is part of the system, the dynamics temporarily become stable, even though phytoplankton release the toxins over a long time. However, this stable behavior is disrupted when the time required for the toxin liberation process by phytoplankton is further extended.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142761967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study examines the head-on collision of ion-acoustic solitons in a one-dimensional, hot, collisionless electron-positron-ion (e-p-i) plasma, incorporating mobile ions, (kappa )-distributed trapped electrons, and Maxwellian positrons. Using the modified Poincare-Lighthill-Kuo (PLK) method, we derive modified Korteweg-de Vries (mKdV) equations and analyze phase shifts in soliton trajectories post-interaction. Results reveal that only rarefactive electrostatic nonlinear waves can propagate within the range of parameters relevant to experiments, showing symmetrical soliton behavior during head-on collisions, with identical amplitude and width. Additionally, soliton amplitude is found to decrease as the electron spectral index ((kappa _e)) and positron-to-electron temperature ratio ((beta _e)) increase, with a sharp decline observed within the range (0<kappa _e<5). Phase shift analysis shows that smaller (kappa _e) values result in a steady increase in phase shifts, which becomes asymptotic as (kappa _e) grows, while phase shifts decrease with rising (sigma _i) (temperature ratio of ions to electrons). These results have practical applications in astrophysical and laboratory plasma environments where soliton interactions play a crucial role. Understanding head-on soliton collisions helps predict plasma behavior in environments such as the interstellar medium, fusion devices, and space plasmas, where wave stability, energy transport, and plasma heating are influenced by nonlinear interactions in systems with trapped particles and nonthermal distributions.
{"title":"Head-on Collision of Ion Acoustic Waves in Electron-Ion-Positron Plasmas with Trapped-Distributed Electrons","authors":"Alireza Abdikian, Uday Narayan Ghosh, Mohamad Eghbali","doi":"10.1007/s13538-024-01662-0","DOIUrl":"10.1007/s13538-024-01662-0","url":null,"abstract":"<div><p>This study examines the head-on collision of ion-acoustic solitons in a one-dimensional, hot, collisionless electron-positron-ion (e-p-i) plasma, incorporating mobile ions, <span>(kappa )</span>-distributed trapped electrons, and Maxwellian positrons. Using the modified Poincare-Lighthill-Kuo (PLK) method, we derive modified Korteweg-de Vries (mKdV) equations and analyze phase shifts in soliton trajectories post-interaction. Results reveal that only rarefactive electrostatic nonlinear waves can propagate within the range of parameters relevant to experiments, showing symmetrical soliton behavior during head-on collisions, with identical amplitude and width. Additionally, soliton amplitude is found to decrease as the electron spectral index (<span>(kappa _e)</span>) and positron-to-electron temperature ratio (<span>(beta _e)</span>) increase, with a sharp decline observed within the range <span>(0<kappa _e<5)</span>. Phase shift analysis shows that smaller <span>(kappa _e)</span> values result in a steady increase in phase shifts, which becomes asymptotic as <span>(kappa _e)</span> grows, while phase shifts decrease with rising <span>(sigma _i)</span> (temperature ratio of ions to electrons). These results have practical applications in astrophysical and laboratory plasma environments where soliton interactions play a crucial role. Understanding head-on soliton collisions helps predict plasma behavior in environments such as the interstellar medium, fusion devices, and space plasmas, where wave stability, energy transport, and plasma heating are influenced by nonlinear interactions in systems with trapped particles and nonthermal distributions.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-30DOI: 10.1007/s13538-024-01664-y
Mário J. de Oliveira
We propose a stochastic dynamics to be associated to a deterministic motion defined by a set of first order differential equation. The transitions that defined the stochastic dynamics are unidirectional, and the rates are equal to the absolute value of the velocity vector field associate to the deterministic motion. From the stochastic dynamics, we determine the entropy production and the entropy flux. This last quantity is found to be the negative of the divergence of the velocity vector field. In the case of a Hamiltonian dynamics, it vanishes identically.
{"title":"Entropy Production Along a Deterministic Motion","authors":"Mário J. de Oliveira","doi":"10.1007/s13538-024-01664-y","DOIUrl":"10.1007/s13538-024-01664-y","url":null,"abstract":"<div><p>We propose a stochastic dynamics to be associated to a deterministic motion defined by a set of first order differential equation. The transitions that defined the stochastic dynamics are unidirectional, and the rates are equal to the absolute value of the velocity vector field associate to the deterministic motion. From the stochastic dynamics, we determine the entropy production and the entropy flux. This last quantity is found to be the negative of the divergence of the velocity vector field. In the case of a Hamiltonian dynamics, it vanishes identically.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-29DOI: 10.1007/s13538-024-01651-3
Eman Mohammed El-Bayoumi, M. Abd-Elzaher, Kottakkaran Sooppy Nisar, Mona Mahmoud, A. Atteya
The overtaking collision of dust acoustic waves (DAWs) featuring electrons distributed according to a hybrid Cairns-Tsallis model and Boltzmann-distributed ions is investigated in this paper. The Korteweg de Vries (KdV) equation, which permits rarefactive DAWs, is the result of nonlinear research of the plasma system utilizing the reductive perturbation approach. Using Hirota’s bilinear method, the overtaking interaction between two and three-soliton solutions is examined. Physical factors that affect the overtaking collisions and change the dynamics of the solitons include electron density, dust radius ratio, and nonextensive parameters. Interestingly, the solitons amplitude and width grow when the electron density and dust radius ratio rise or the nonextensivity falls. In addition, the system’s properties have an impact on the phase alterations of the solitons. The information offered here may be useful for the investigation of DAWs in dusty space plasmas, including cometary environments, the F and G rings of Saturn, and laboratory plasmas with nonthermal nonextensive electrons.
研究了以Cairns-Tsallis混合分布的电子和玻尔兹曼分布离子为特征的粉尘声波的超车碰撞。Korteweg de Vries (KdV)方程是利用约化微扰方法对等离子体系统进行非线性研究的结果。利用Hirota的双线性方法,研究了两孤子解和三孤子解之间的超车相互作用。影响超车碰撞和改变孤子动力学的物理因素包括电子密度、尘埃半径比和非扩展参数。有趣的是,当电子密度和尘埃半径比增大或非广泛性减小时,孤子的振幅和宽度增大。此外,系统的性质对孤子的相位变化也有影响。这里提供的信息可能对研究尘埃空间等离子体中的daw有用,包括彗星环境,土星的F和G环,以及具有非热非扩展电子的实验室等离子体。
{"title":"Variable-Sized Dust Grains and Hybrid Cairns-Tsallis-Distributed Electron Effects on Collision Dynamics of Dust Acoustic Waves in Saturn’s Dusty Plasma","authors":"Eman Mohammed El-Bayoumi, M. Abd-Elzaher, Kottakkaran Sooppy Nisar, Mona Mahmoud, A. Atteya","doi":"10.1007/s13538-024-01651-3","DOIUrl":"10.1007/s13538-024-01651-3","url":null,"abstract":"<div><p>The overtaking collision of dust acoustic waves (DAWs) featuring electrons distributed according to a hybrid Cairns-Tsallis model and Boltzmann-distributed ions is investigated in this paper. The Korteweg de Vries (KdV) equation, which permits rarefactive DAWs, is the result of nonlinear research of the plasma system utilizing the reductive perturbation approach. Using Hirota’s bilinear method, the overtaking interaction between two and three-soliton solutions is examined. Physical factors that affect the overtaking collisions and change the dynamics of the solitons include electron density, dust radius ratio, and nonextensive parameters. Interestingly, the solitons amplitude and width grow when the electron density and dust radius ratio rise or the nonextensivity falls. In addition, the system’s properties have an impact on the phase alterations of the solitons. The information offered here may be useful for the investigation of DAWs in dusty space plasmas, including cometary environments, the F and G rings of Saturn, and laboratory plasmas with nonthermal nonextensive electrons.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142753956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-27DOI: 10.1007/s13538-024-01654-0
G. Vinod, M. Bhanu, D. Mallesh, K. Rajashekhar, D. Ravinder, Noha Ahmed Elayah, A. Nagarjuna, G. Sunitha, J. Laxman Naik
Mg0.5Cu0.8ErxFe2−xO4 (through x = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030) A series of rare earth (Er3+)-doped magnesium-copper nanoparticles with the general chemical compositions of Mg0.5Cu0.8ErxFe2−xO4 (through x = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030) was fabricated by citrate sol–gel auto combustion technique. The fabricated materials are investigated through XRD, FE-SEM, EDS, TEM, FTIR, UV–Vis, DC resistivity, and TEP properties. The crystallite size of the samples was determined to be 33–40 nm with increased Er3+ concentration, and the XRD investigations validated the spinel cubic structure of the samples with the space group Fd-3 m. The lattice constant was found to decrease from 8.403 to 8.356 Å. The morphology of FE-SEM micrographs was found to be spherical shape. TEM micrographs show that average particle size decreases from 64 to 48 nm. The nanoparticles’ FTIR examination revealed that their ʋ1 and ʋ2 absorption bands were between 401–412 cm−1 and 547–562 cm−1. The optical band gap was measured using UV–vis spectroscopy and found between 1.81 and 2.38 eV. In Mg–Cu nano-ferrites with Er-doping, there was no noticeable increase in the elasticity moduli. With increasing Er-doping and composition, it has been found that the thermal energy needed to change the p-type Mg–Cu nano-ferrites’ behavior from semiconducting to n-type semiconducting behavior increases. Er-doped Mg–Cu ferrites demonstrate a metal–semiconductor behavior according to DC resistivity exploration.
Mg0.5Cu0.8ErxFe2-xO4 (through x = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030) 一系列掺杂稀土 (Er3+) 的镁铜纳米粒子,其一般化学成分为 Mg0.5Cu0.8ErxFe2-xO4 (through x = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030)。5Cu0.8ErxFe2-xO4(x = 0.000、0.005、0.010、0.015、0.020、0.025 和 0.030)。通过 XRD、FE-SEM、EDS、TEM、FTIR、UV-Vis、直流电阻率和 TEP 特性对制备的材料进行了研究。经测定,随着 Er3+ 浓度的增加,样品的晶体尺寸为 33-40 nm,XRD 研究验证了样品的尖晶石立方结构,空间群为 Fd-3 m,晶格常数从 8.403 Å 下降到 8.356 Å。TEM 显微照片显示,平均粒径从 64 纳米减小到 48 纳米。纳米颗粒的傅立叶变换红外光谱分析显示,它们的ʋ1 和ʋ2 吸收带介于 401-412 cm-1 和 547-562 cm-1 之间。光带隙通过紫外可见光谱进行测量,结果显示在 1.81 和 2.38 eV 之间。在掺有 Er 的 Mg-Cu 纳米铁氧体中,弹性模量没有明显增加。随着掺铒量和成分的增加,发现将 p 型 Mg-Cu 纳米铁氧体从半导体行为转变为 n 型半导体行为所需的热能也在增加。根据直流电阻率探测,掺铒镁铜铁氧体表现出金属半导体行为。
{"title":"Er–Mg–Cu Ferrite Nanoparticles: a Synergetic Effect of Rare Earth RE-Er3+ on Enhanced Surface Morphological, Optical, and High-Temperature Electrical Properties","authors":"G. Vinod, M. Bhanu, D. Mallesh, K. Rajashekhar, D. Ravinder, Noha Ahmed Elayah, A. Nagarjuna, G. Sunitha, J. Laxman Naik","doi":"10.1007/s13538-024-01654-0","DOIUrl":"10.1007/s13538-024-01654-0","url":null,"abstract":"<div><p>Mg<sub>0.5</sub>Cu<sub>0.8</sub>Er<sub><i>x</i></sub>Fe<sub>2−<i>x</i></sub>O<sub>4</sub> (through <i>x</i> = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030) A series of rare earth (Er<sup>3+</sup>)-doped magnesium-copper nanoparticles with the general chemical compositions of Mg0.5Cu0.8ErxFe2−xO4 (through x = 0.000, 0.005, 0.010, 0.015, 0.020, 0.025 and 0.030) was fabricated by citrate sol–gel auto combustion technique. The fabricated materials are investigated through XRD, FE-SEM, EDS, TEM, FTIR, UV–Vis, DC resistivity, and TEP properties. The crystallite size of the samples was determined to be 33–40 nm with increased Er<sup>3+</sup> concentration, and the XRD investigations validated the spinel cubic structure of the samples with the space group Fd-3 m. The lattice constant was found to decrease from 8.403 to 8.356 Å. The morphology of FE-SEM micrographs was found to be spherical shape. TEM micrographs show that average particle size decreases from 64 to 48 nm. The nanoparticles’ FTIR examination revealed that their <i>ʋ</i><sub>1</sub> and <i>ʋ</i><sub>2</sub> absorption bands were between 401–412 cm<sup>−1</sup> and 547–562 cm<sup>−1</sup>. The optical band gap was measured using UV–vis spectroscopy and found between 1.81 and 2.38 eV. In Mg–Cu nano-ferrites with Er-doping, there was no noticeable increase in the elasticity moduli. With increasing Er-doping and composition, it has been found that the thermal energy needed to change the p-type Mg–Cu nano-ferrites’ behavior from semiconducting to <i>n</i>-type semiconducting behavior increases. Er-doped Mg–Cu ferrites demonstrate a metal–semiconductor behavior according to DC resistivity exploration.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142736934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, LaF3–LaOF:Yb3+/Tm3+ upconversion phosphors were synthesized using a solid-state reaction method, and the effects of annealing conditions on their crystal structure and optical properties were examined. The crystal structure, analyzed using an X-ray diffractometer, revealed a transition from LaF3 to LaOF as the annealing temperature and time increased. The photoluminescence (PL) characteristics revealed emission peaks at wavelengths of 477, 485, 795, and 803 nm. In addition, the PL intensity increased under annealing conditions of 1150℃ for 1–3 h. The pump-power dependence of the PL intensity suggested potential thermal quenching. Finally, the temperature characteristics were analyzed, yielding an absolute sensitivity of 0.0081 K−1 and a relative sensitivity of 0.65% K−1.
{"title":"Optical Properties of LaF3–LaOF:Yb3+/Tm3+ Upconversion Phosphors: Influence of Annealing Temperature and Time","authors":"Toshihiro Nonaka, Yutaro Inoue, Mutsuto Yamamoto, Shin-Ichi Yamamoto","doi":"10.1007/s13538-024-01665-x","DOIUrl":"10.1007/s13538-024-01665-x","url":null,"abstract":"<p>In this study, LaF<sub>3</sub>–LaOF:Yb<sup>3+</sup>/Tm<sup>3+</sup> upconversion phosphors were synthesized using a solid-state reaction method, and the effects of annealing conditions on their crystal structure and optical properties were examined. The crystal structure, analyzed using an X-ray diffractometer, revealed a transition from LaF<sub>3</sub> to LaOF as the annealing temperature and time increased. The photoluminescence (PL) characteristics revealed emission peaks at wavelengths of 477, 485, 795, and 803 nm. In addition, the PL intensity increased under annealing conditions of 1150℃ for 1–3 h. The pump-power dependence of the PL intensity suggested potential thermal quenching. Finally, the temperature characteristics were analyzed, yielding an absolute sensitivity of 0.0081 K<sup>−1</sup> and a relative sensitivity of 0.65% K<sup>−1</sup>.</p>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142736933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The structural and luminescence properties of akermanite type compound Sr2MgSi2O7:Sm3+ have been investigated. The crystal structure of Sr2MgSi2O7 has been obtained from the X-ray diffraction data. Sr2MgSi2O7 possesses tetragonal symmetry with space group P (overline{4 }) 21 m (No. 113). Judd Ofelt (J-O) analysis of akermanite structured Sm3+-doped Sr2MgSi2O7 phosphor synthesized by combustion synthesis followed by a solid-state reaction process is presented. SEM confirms the morphology. The photoluminescence emission (PL) spectra indicate that the phosphor gives orange red emission at 601 nm attributed to transitions 4G5/2(to)6H5/2. Optimum concentration is found to be 7.0 mol.%. The CIE chromaticity coordinates are (0.57, 0.43). The branching ratio for the transition, 4G5/2(to)6H7/2, is found to be around 53%, suggesting it as a potential laser material in addition to its use for fabrication of white LED phosphors.
{"title":"Photoluminescence Analysis and Judd–Ofelt Studies in Sr2MgSi2O7:Sm3+ Phosphor","authors":"Akshay Pimpalkar, Nilesh Ugemuge, Ashok Mistry, Shruti Dhale, Anil Muke, Rujuta Barve Joshi, Sarika Khapre, Sanjiv Moharil","doi":"10.1007/s13538-024-01661-1","DOIUrl":"10.1007/s13538-024-01661-1","url":null,"abstract":"<div><p>The structural and luminescence properties of akermanite type compound Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub>:Sm<sup>3+</sup> have been investigated. The crystal structure of Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub> has been obtained from the X-ray diffraction data. Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub> possesses tetragonal symmetry with space group P <span>(overline{4 })</span> 2<sub>1</sub> m (No. 113). Judd Ofelt (J-O) analysis of akermanite structured Sm<sup>3+</sup>-doped Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub> phosphor synthesized by combustion synthesis followed by a solid-state reaction process is presented. SEM confirms the morphology. The photoluminescence emission (PL) spectra indicate that the phosphor gives orange red emission at 601 nm attributed to transitions <sup>4</sup>G<sub>5/2</sub> <span>(to)</span> <sup>6</sup>H<sub>5/2</sub>. Optimum concentration is found to be 7.0 mol.%. The CIE chromaticity coordinates are (0.57, 0.43). The branching ratio for the transition, <sup>4</sup>G<sub>5/2</sub> <span>(to)</span> <sup>6</sup>H<sub>7/2</sub>, is found to be around 53%, suggesting it as a potential laser material in addition to its use for fabrication of white LED phosphors.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142714196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-23DOI: 10.1007/s13538-024-01660-2
Haifa A. Alyousef, Rasool Shah, C. G. L. Tiofack, Alvaro H. Salas, Weaam Alhejaili, Sherif M. E. Ismaeel, S. A. El-Tantawy
This investigation examines fractional higher-order evolution and fundamental wave equations, namely the third- and fifth-order fractional Korteweg-de Vries (KdV)-type equations, which regulate diverse nonlinear physical processes, especially those occurring in fluids and plasmas. For this purpose, the Aboodh/Laplace residual power series method (ARPSM) and the Aboodh/Laplace transform iterative method (ATIM) are carried out to derive high-accurate approximations. These methods are applied in conjunction with the Caputo operator, which effectively handles the fractional derivatives. The results illustrate the efficacy of both ARPSM and ATIM in analyzing third- and fifth-order time fractional KdV-type equations, providing valuable insights and potential applications in fractional calculus and its applications to complicated physical and engineering issues. The derived approximations are investigated graphically and numerically to understand the effect of the fractional parameter on the properties of the nonlinear phenomena characterized by this family. Furthermore, the precision and efficacy of the suggested techniques are verified by comparing the derived approximations to the exact solutions for the integer-order cases. The findings of this investigation have the potential to benefit a wide range of researchers who are interested in optical physics, fluid physics, and plasma physics. They can be employed to analyze and comprehend the results of their laboratory and space observations.
{"title":"Novel Approximations to the Third- and Fifth-Order Fractional KdV-Type Equations and Modeling Nonlinear Structures in Plasmas and Fluids","authors":"Haifa A. Alyousef, Rasool Shah, C. G. L. Tiofack, Alvaro H. Salas, Weaam Alhejaili, Sherif M. E. Ismaeel, S. A. El-Tantawy","doi":"10.1007/s13538-024-01660-2","DOIUrl":"10.1007/s13538-024-01660-2","url":null,"abstract":"<div><p>This investigation examines fractional higher-order evolution and fundamental wave equations, namely the third- and fifth-order fractional Korteweg-de Vries (KdV)-type equations, which regulate diverse nonlinear physical processes, especially those occurring in fluids and plasmas. For this purpose, the Aboodh/Laplace residual power series method (ARPSM) and the Aboodh/Laplace transform iterative method (ATIM) are carried out to derive high-accurate approximations. These methods are applied in conjunction with the Caputo operator, which effectively handles the fractional derivatives. The results illustrate the efficacy of both ARPSM and ATIM in analyzing third- and fifth-order time fractional KdV-type equations, providing valuable insights and potential applications in fractional calculus and its applications to complicated physical and engineering issues. The derived approximations are investigated graphically and numerically to understand the effect of the fractional parameter on the properties of the nonlinear phenomena characterized by this family. Furthermore, the precision and efficacy of the suggested techniques are verified by comparing the derived approximations to the exact solutions for the integer-order cases. The findings of this investigation have the potential to benefit a wide range of researchers who are interested in optical physics, fluid physics, and plasma physics. They can be employed to analyze and comprehend the results of their laboratory and space observations.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-23DOI: 10.1007/s13538-024-01647-z
Aka Hyacinthe Aka, Amal Bouich, Sarra Bouazizi, Yassine salhi, Bernabé Mari Soucase, Boko Aka
The quaternary material consisting of copper, zinc, tin and sulfur has long attracted the attention of the scientific world in the development of thin layers for photovoltaic applications. In this work, we proposed to make the junction between the absorbent layer consisting of copper-zinc-tin-sulfur Cu2ZnSnS4 (CZTS) and different buffer layers such as zinc sulfide ZnS, tin disulfide SnS2, and cadmium sulfide CdS for comparison purposes, in using the simple and low-cost technique of spray pyrolysis at 380 °C for all stages. All the films obtained were characterized by X-ray diffraction (XRD), and UV–visible spectroscopy and the morphology and topography of the layers were assessed under the scanning electron microscope (SEM) and EDXA. Characterization results showed the formation of CZTS thin films whose kesterite structure was improved by annealing at 450 °C under sulfur atmosphere. The grain size also improved from 6.7 to 7.9 nm after annealing. Subsequently, a simulation study by SCAPS-1D is made to assess the efficiency of the photovoltaic cell thus produced. It exhibited the highest power conversion efficiency (PCE) for the cell using SnS2 as a buffer layer, i.e., 20.25%, compared to 16.14% for the cell using CdS. This confirmed the possibility of favoring SnS2 in the design of CZTS-based solar cells, suggested in the literature, as a replacement for CdS, and this by the simple technique of spray pyrolysis.
{"title":"Design and Efficiency Enhancement of Heterojunctions Formed by CZTS and S-Based Buffer Layers for Photovoltaic Applications","authors":"Aka Hyacinthe Aka, Amal Bouich, Sarra Bouazizi, Yassine salhi, Bernabé Mari Soucase, Boko Aka","doi":"10.1007/s13538-024-01647-z","DOIUrl":"10.1007/s13538-024-01647-z","url":null,"abstract":"<div><p>The quaternary material consisting of copper, zinc, tin and sulfur has long attracted the attention of the scientific world in the development of thin layers for photovoltaic applications. In this work, we proposed to make the junction between the absorbent layer consisting of copper-zinc-tin-sulfur Cu<sub>2</sub>ZnSnS<sub>4</sub> (CZTS) and different buffer layers such as zinc sulfide ZnS, tin disulfide SnS<sub>2</sub>, and cadmium sulfide CdS for comparison purposes, in using the simple and low-cost technique of spray pyrolysis at 380 °C for all stages. All the films obtained were characterized by X-ray diffraction (XRD), and UV–visible spectroscopy and the morphology and topography of the layers were assessed under the scanning electron microscope (SEM) and EDXA. Characterization results showed the formation of CZTS thin films whose kesterite structure was improved by annealing at 450 °C under sulfur atmosphere. The grain size also improved from 6.7 to 7.9 nm after annealing. Subsequently, a simulation study by SCAPS-1D is made to assess the efficiency of the photovoltaic cell thus produced. It exhibited the highest power conversion efficiency (PCE) for the cell using SnS<sub>2</sub> as a buffer layer, i.e., 20.25%, compared to 16.14% for the cell using CdS. This confirmed the possibility of favoring SnS<sub>2</sub> in the design of CZTS-based solar cells, suggested in the literature, as a replacement for CdS, and this by the simple technique of spray pyrolysis.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}