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Mathematical modelling of the vitamin C clock reaction: a study of two kinetic regimes 维生素 C 时钟反应的数学建模:两种动力学机制的研究
Pub Date : 2024-08-07 DOI: arxiv-2408.04108
Aliya Alsaleh, David J. Smith, Sara Jabbari
Chemically reacting systems exhibiting a repeatable delay period before avisible and sudden change are referred to as clock reactions; they have a longhistory in education and provide an idealisation of various biochemical andindustrial processes. We focus on a purely substrate-depletive clock reactionutilising vitamin C, hydrogen peroxide, iodine and starch. Building on a recentstudy of a simplified two-reaction model under high hydrogen peroxideconcentrations, we develop a more detailed model which breaks the slow reactioninto two steps, one of which is rate-limiting unless hydrogen peroxide levelsare very high. Through asymptotic analysis, this model enables the effect ofhydrogen peroxide concentration to be elucidated in a principled way, resolvingan apparent discrepancy with earlier literature regarding the order of the slowreaction kinetics. The model is analysed in moderate- and high-hydrogenperoxide regimes, providing approximate solutions and expressions for theswitchover time which take into account hydrogen peroxide concentration. Thesolutions are validated through simultaneously fitting the same set ofparameters to several experimental series, then testing on independentexperiments across widely varying hydrogen peroxide concentration. The studythereby presents and further develops a validated mechanistic understanding ofa paradigm chemical kinetics system.
化学反应系统在发生明显的突变之前会出现一个可重复的延迟期,这种反应被称为时钟反应;时钟反应在教育领域有着悠久的历史,是各种生物化学和工业过程的理想化产物。我们将重点放在利用维生素 C、过氧化氢、碘和淀粉的纯底物消耗性时钟反应上。在最近对高过氧化氢浓度下的简化双反应模型研究的基础上,我们建立了一个更详细的模型,该模型将缓慢反应分成两个步骤,除非过氧化氢浓度非常高,否则其中一个步骤将限制反应速率。通过渐近分析,该模型能够以一种原则性的方式阐明过氧化氢浓度的影响,解决了与早期文献中关于缓慢反应动力学顺序的明显差异。该模型在中度和高度过氧化氢条件下进行了分析,提供了考虑到过氧化氢浓度的切换时间近似解和表达式。通过对多个实验序列同时拟合同一组参数,然后在不同过氧化氢浓度的独立实验中进行测试,验证了这些解决方案。因此,该研究提出并进一步发展了对典型化学动力学系统的有效机理理解。
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引用次数: 0
Permutations of periodic points of Weierstrass Prym eigenforms 魏尔斯特拉斯-普赖姆特征形式周期点的排列
Pub Date : 2024-08-07 DOI: arxiv-2408.03832
Rodolfo Gutiérrez-Romo, Angel Pardo
A Weierstrass Prym eigenform is an Abelian differential with a single zero ona Riemann surface possessing some special kinds of symmetries. Such surfacescome equipped with an involution, known as a Prym involution. They wereoriginally discovered by McMullen and only arise in genus 2, 3 and 4. Moreover,they are classified by two invariants: discriminant and spin. We study how the fixed points for the Prym involution of Weierstrass Prymeigenforms are permuted. In previous work, the authors computed the permutationgroup induced by affine transformations in the case of genus 2, showing thatthey are dihedral groups depending only on the residue class modulo 8 of thediscriminant $D$. In this work, we complete this classification by settling thecase of genus 3, showing that the permutation group induced by the affine groupon the set of its three (regular) fixed points is isomorphic to$mathrm{Sym}_2$ when $D$ is even and a quadratic residue modulo 16, and to$mathrm{Sym}_3$ otherwise. The case of genus 4 is trivial as the Pyrminvolution fixes a single (regular) point. In both cases, these same groupsarise when considering only parabolic elements of the affine group. By recent work of Freedman, when the Teichm"uller curve induced byWeierstrass Prym eigenform is not arithmetic, the fixed points of the Pryminvolution coincide with the periodic points of the surface. Hence, in thiscase, our result also classifies how periodic points are permuted.
Weierstrass Prym 特征形式是黎曼曲面上具有单个零点的阿贝尔微分,它具有某些特殊的对称性。这种曲面带有一个内卷,称为 Prym 内卷。它们最初由麦克马伦发现,只出现在属 2、3 和 4 中。此外,它们还被分为两个不变式:判别式和自旋式。我们将研究魏尔斯特拉斯 Prymeigenforms 的 Prym 卷积的定点是如何被置换的。在之前的工作中,作者计算了在属 2 的情况下仿射变换引起的置换群,结果表明它们是二面体群,只取决于判别式 $D$ 的残差类 modulo 8。在这项工作中,我们通过解决属 3 的情况完成了这一分类,证明了当 $D$ 为偶数且为模为 16 的二次残差时,仿射组在其三个(正则)定点集合上诱导的置换群与 $mathrm{Sym}_2$ 同构,否则与 $mathrm{Sym}_3$ 同构。属数为 4 的情况是微不足道的,因为 Pyrminvolution 只固定了一个(正则)点。在这两种情况下,如果只考虑仿射群的抛物线元素,也会出现同样的群。根据弗里德曼(Freedman)的最新研究,当韦尔斯特拉斯 Prym 特征形式诱导的 Teichm"uller 曲线不是算术曲线时,Pryminvolution 的固定点与曲面的周期点重合。因此,在这种情况下,我们的结果也对周期点的排列方式进行了分类。
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引用次数: 0
Monochromatic nonuniform hyperbolicity 单色非均匀双曲性
Pub Date : 2024-08-07 DOI: arxiv-2408.03878
Jairo Bochi
We construct examples of continuous $mathrm{GL}(2,mathbb{R})$-cocycleswhich are not uniformly hyperbolic despite having the same non-zero Lyapunovexponents with respect to all invariant measures. The base dynamics can be anynon-trivial subshift of finite type. According to a theorem of DeWitt--Gogolevand Guysinsky, such cocycles cannot be H"older-continuous. Our constructionuses the nonuniformly hyperbolic cocycles discovered by Walters in 1984.
我们构造了连续 $mathrm{GL}(2,mathbb{R})$ 循环的例子,这些循环尽管相对于所有不变度量具有相同的非零 Lyapunovexponents,却不是均匀双曲的。基动力学可以是有限类型的任何非三维子移动。根据DeWitt--Gogolevand Guysinsky的定理,这样的cocycles不可能是连续的。我们的构造使用了沃尔特斯在 1984 年发现的非均匀双曲循环。
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引用次数: 0
Force-Motion Control For A Six Degree-Of-Freedom Robotic Manipulator 六自由度机器人机械手的力-运动控制
Pub Date : 2024-08-07 DOI: arxiv-2408.04106
Sagar Ojha, Karl Leodler, Lou Barbieri, TseHuai Wu
This paper presents a unified algorithm for motion and force control for asix degree-of-freedom spatial manipulator. The motion-force controller performstrajectory tracking, maneuvering the manipulator's end-effector through desiredposition, orientations and rates. When contacting an obstacle or target object,the force module of the controller restricts the manipulator movements with anovel force exertion method, which prevents damage to the manipulator, theend-effector, and the objects during the contact or collision. The corestrategy presented in this paper is to design the linear acceleration for theend-effector which ensures both trajectory tracking and restriction of anycontact force at the end-effector. The design of the controller is validatedthrough numerical simulations and digital twin validation.
本文介绍了六自由度空间机械手运动和力控制的统一算法。运动-力控制器执行轨迹跟踪,操纵机械手的末端执行器通过所需的位置、方向和速率。当接触到障碍物或目标物体时,控制器的力模块会通过一种水平施力方法限制机械手的运动,从而防止机械手、末端执行器和物体在接触或碰撞过程中受损。本文提出的核心策略是为末端执行器设计线性加速度,既能确保轨迹跟踪,又能限制末端执行器的任何接触力。控制器的设计通过数值模拟和数字孪生验证进行了验证。
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引用次数: 0
Tangent Space of the Stable And Unstable Manifold of Anosov Diffeomorphism on 2-Torus 2-Torus 上阿诺索夫衍射的稳定与不稳定漫域的切线空间
Pub Date : 2024-08-07 DOI: arxiv-2408.03607
Federico Bonneto, Jack Wang, Vishal Kumar
In this paper we describe the tangent vectors of the stable and unstablemanifold of a class of Anosov diffeomorphisms on the torus $mathbb{T}^2$ usingthe method of formal series and derivative trees. We start with linearautomorphism that is hyperbolic and whose eigenvectors are orthogonal. Then westudy the perturbation of such maps by trigonometric polynomial. It is knownthat there exist a (continuous) map $H$ which acts as a change of coordinatebetween the perturbed and unperturbed system, but such a map is in general, notdifferentiable. By "re-scaling" the parametrization $H$, we will be able toobtain the explicit formula for the tangent vectors of these maps.
在本文中,我们用形式数列和导数树的方法描述了环$mathbb{T}^2$上一类阿诺索夫差分形的稳定和不稳定manifold的切向量。我们从双曲且特征向量正交的线性自形变开始。然后用三角多项式研究这种映射的扰动。众所周知,存在一个(连续的)映射 $H$,它在扰动系统和未扰动系统之间起着改变坐标的作用,但这种映射一般是不可分的。通过 "重新缩放 "参数 H$,我们将能得到这些映射的切向量的明确公式。
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引用次数: 0
On orbit complexity of dynamical systems: intermediate value property and level set related to a Furstenberg problem 论动力系统的轨道复杂性:与弗斯滕伯格问题有关的中间值特性和水平集
Pub Date : 2024-08-07 DOI: arxiv-2408.04010
Yuanyang Chang, Bing Li, Meng Wu
For symbolic dynamics with some mild conditions, we solve the loweringtopological entropy problem for subsystems and determine the Hausdorffdimension of the level set with given complexity, where the complexity isrepresented by Hausdorff dimension of orbit closure. These results can beapplied to some dynamical systems such as $beta$-transformations, conformalexpanding repeller, etc. We also determine the dimension of the Furstenberglevel set, which is related to a problem of Furstenberg on the orbits under twomultiplicatively independent maps.
对于具有一些温和条件的符号动力学,我们求解了子系统的降低拓扑熵问题,并确定了具有给定复杂度的水平集的 Hausdorff 维度,其中复杂度用轨道闭合的 Hausdorff 维度表示。这些结果可以应用于一些动力学系统,如 $beta$-变换、保形膨胀排斥器等。我们还确定了弗斯滕伯格水平集的维度,这与弗斯滕伯格关于两乘法独立映射下轨道的问题有关。
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引用次数: 0
Holomorphic foliations tangent to Rolle-pfaffian hypersurfaces 与罗尔-普法非超曲面相切的全形叶面
Pub Date : 2024-08-07 DOI: arxiv-2408.03914
Arturo Fernández-Pérez, Rogério Mol, Rudy Rosas
In this paper we study germs of holomorphic foliations, at the origin of thecomplex plane, tangent to Pfaffian hypersurfaces - integral hypersurfaces ofreal analytic 1-forms - satisfying the Rolle-Khovanskii condition. Thishypothesis leads us to conclude that such a foliation is defined by a closedmeromorphic 1-form, also allowing the classification of the simple models inits reduction of singularities.
在本文中,我们研究了在复平面原点,与满足罗尔-霍凡斯基(Rolle-Khovanskii)条件的普法超曲面--真实解析 1 形的积分超曲面--相切的全形叶状的胚芽。这一假设使我们得出结论,这种叶形是由封闭的meromorphic 1-form定义的,也允许对其奇点还原中的简单模型进行分类。
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引用次数: 0
Contraction and Synchronization in Reservoir Systems 储层系统的收缩与同步
Pub Date : 2024-08-07 DOI: arxiv-2408.04058
Adrian S. Wong, Robert S. Martin, Daniel Q. Eckhardt
This work explores the conditions under which global contraction manifests inthe leaky continuous time reservoirs, thus guaranteeing GeneralizedSynchronization. Results on continuous time reservoirs make use of thelogarithmic norm of the connectivity matrix. Further analysis yields somesimple guidelines on how to better construct the connectivity matrix in thesesystems. Additionally, we outline how the Universal Approximation Property ofdiscrete time reservoirs is readily satisfied by virtue of the activationfunction being contracting, and how continuous time reservoirs may inherit alimited form of universal approximation by virtue of them overlapping withNeural Ordinary Differential Equations. The ability of the Reservoir Computingframework to universally approximate topological conjugates, along with theirfast training, make them a compelling data-driven, black-box surrogate ofdynamical systems, and a potential mechanism for developing digital twins.
这项研究探讨了在什么条件下全局收缩会在泄漏连续时间水库中表现出来,从而保证广义同步。关于连续时间水库的结果利用了连通性矩阵的对数规范。进一步的分析得出了如何在这些系统中更好地构建连通性矩阵的一些简单指南。此外,我们还概述了离散时间水库的通用逼近特性是如何通过活化函数的收缩而得到满足的,以及连续时间水库是如何通过与神经常微分方程的重叠而继承有限形式的通用逼近的。水库计算框架普遍逼近拓扑共轭物的能力,加上其快速训练,使其成为令人信服的数据驱动、动态系统的黑箱代理,以及开发数字双胞胎的潜在机制。
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引用次数: 0
Slow-fast systems in infinite measure, with or without averaging 有或没有平均值的无限慢-快系统
Pub Date : 2024-08-06 DOI: arxiv-2408.03009
Maxence Phalempin
This paper studies the asymptotic behaviour of the solution of a differentialequation perturbed by a fast flow preserving an infinite measure. This questionis related with limit theorems for non-stationary Birkhoff integrals. Wedistinguish two settings with different behaviour: the integrable setting (noaveraging phenomenon) and the case of an additive "centered" perturbation term(averaging phenomenon). The paper is motivated by the case where theperturbation comes from the Z-periodic Lorentz gas flow or from the geodesicflow over a Z-cover of a negatively curved compact surface. We establish limittheorems in more general contexts.
本文研究的是微分方程解在保持无限度量的快速流扰动下的渐近行为。这个问题与非稳态伯克霍夫积分的极限定理有关。我们区分了具有不同行为的两种情况:可积分情况(无平均现象)和有加法 "居中 "扰动项的情况(平均现象)。本文以扰动来自 Z 周期洛伦兹气体流或来自负弯曲紧凑曲面的 Z 覆盖面上的大地流的情况为出发点。我们建立了更一般情况下的极限定理。
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引用次数: 0
Data-Driven Stochastic Closure Modeling via Conditional Diffusion Model and Neural Operator 通过条件扩散模型和神经运算器建立数据驱动的随机闭合模型
Pub Date : 2024-08-06 DOI: arxiv-2408.02965
Xinghao Dong, Chuanqi Chen, Jin-Long Wu
Closure models are widely used in simulating complex multiscale dynamicalsystems such as turbulence and the earth system, for which direct numericalsimulation that resolves all scales is often too expensive. For those systemswithout a clear scale separation, deterministic and local closure models oftenlack enough generalization capability, which limits their performance in manyreal-world applications. In this work, we propose a data-driven modelingframework for constructing stochastic and non-local closure models viaconditional diffusion model and neural operator. Specifically, the Fourierneural operator is incorporated into a score-based diffusion model, whichserves as a data-driven stochastic closure model for complex dynamical systemsgoverned by partial differential equations (PDEs). We also demonstrate howaccelerated sampling methods can improve the efficiency of the data-drivenstochastic closure model. The results show that the proposed methodologyprovides a systematic approach via generative machine learning techniques toconstruct data-driven stochastic closure models for multiscale dynamicalsystems with continuous spatiotemporal fields.
闭合模型广泛应用于模拟复杂的多尺度动力学系统,如湍流和地球系统。对于那些没有明确尺度划分的系统,确定性模型和局部闭合模型往往缺乏足够的泛化能力,这限制了它们在许多现实世界应用中的性能。在这项工作中,我们提出了一个数据驱动的建模框架,利用条件扩散模型和神经算子构建随机和非局部封闭模型。具体来说,我们将傅立叶神经算子纳入了基于分数的扩散模型,该模型可作为数据驱动的随机闭合模型,用于由偏微分方程(PDE)控制的复杂动态系统。我们还演示了加速采样方法如何提高数据驱动随机闭合模型的效率。结果表明,所提出的方法通过生成式机器学习技术提供了一种系统方法,可为具有连续时空场的多尺度动态系统构建数据驱动随机闭合模型。
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引用次数: 0
期刊
arXiv - MATH - Dynamical Systems
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