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Geometric control and memory in networks of bistable elements 双稳态元素网络中的几何控制和记忆
Pub Date : 2024-09-12 DOI: arxiv-2409.07804
Dor Shohat, Martin van Hecke
The sequential response of driven frustrated media encodes memory effects andhidden computational capabilities. While abstract hysteron models can capturethese effects, they require phenomenologically introduced interactions,limiting their predictive power. Here we introduce networks of bistableelements - physical hysterons - whose interactions are controlled by thenetworks' geometry. These networks realize a wide range of previouslyunobserved exotic pathways, including those that surpass current hysteronmodels. Our work paves the way for advanced microscopic models of memory andthe rational design of (meta)materials with targeted pathways and capabilities.
受驱动的受挫介质的顺序响应包含了记忆效应和隐藏的计算能力。虽然抽象的滞留子模型可以捕捉这些效应,但它们需要从现象学角度引入相互作用,这限制了它们的预测能力。在这里,我们引入了双稳态元件网络--物理滞留子--其相互作用由网络的几何形状控制。这些网络实现了一系列以前未曾观察到的奇异路径,包括那些超越当前滞留子模型的路径。我们的工作为建立先进的记忆微观模型以及合理设计具有目标途径和能力的(元)材料铺平了道路。
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引用次数: 0
Mechanical hysterons with tunable interactions of general sign 具有一般符号可调相互作用的机械滞留器
Pub Date : 2024-09-12 DOI: arxiv-2409.07726
Joseph D. Paulsen
Hysterons are the basic units of hysteresis that underlie many of the complexbehaviors of disordered matter. Recent work has sought to develop designs formechanical hysterons, both to better understand their interactions and tocreate materials that respond to their mechanical environment in novel ways.Elastic structures including slender beams, creased sheets, and shells offerthe requisite bistability for artificial hysterons, but producing andcontrolling interactions between such structures has proven challenging. Herewe report a mechanical hysteron composed of rigid bars and linear springs,which has controllable properties and tunable interactions of general sign. Wederive an approximate mapping from the system parameters to the hysteronproperties, and we show how collective behaviors of multiple hysterons can betargeted by adjusting geometric parameters on the fly. Our results provide abasic step towards hysteron-based materials that can sense, compute, andrespond to their mechanical environment.
滞后子是滞后的基本单位,是无序物质许多复杂行为的基础。最近的研究试图开发机械滞后子的设计,以便更好地理解它们之间的相互作用,并创造出能以新颖方式对机械环境做出反应的材料。弹性结构包括细长的梁、有皱褶的薄片和壳,为人造滞后子提供了必要的双稳态性,但事实证明,制造和控制这些结构之间的相互作用具有挑战性。在此,我们报告了一种由刚性杆和线性弹簧组成的机械滞留器,它具有可控的特性和一般符号的可调相互作用。我们得出了从系统参数到滞留器属性的近似映射,并展示了如何通过即时调整几何参数来瞄准多个滞留器的集体行为。我们的研究成果为实现能感知、计算和响应其机械环境的基底材料迈出了重要的一步。
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引用次数: 0
Reversible Electron-Beam Patterning of Colloidal Nanoparticles at Fluid Interfaces 流体界面胶体纳米粒子的可逆电子束图案化
Pub Date : 2024-09-12 DOI: arxiv-2409.08192
Jonathan G. Raybin, Ethan J. Dunsworth, Veronica Guo, Naomi S. Ginsberg
The directed self-assembly of colloidal nanoparticles (NPs) using externalfields guides the formation of sophisticated hierarchical materials but becomesless effective with decreasing particle size. As an alternative,electron-beam-driven assembly offers a potential avenue for targeted nanoscalemanipulation, yet remains poorly controlled due to the variety and complexityof beam interaction mechanisms. Here, we investigate the beam-particleinteraction of silica NPs pinned to the fluid-vacuum interface of ionic liquiddroplets. In these experiments, scanning electron microscopy of the dropletsurface resolves NP trajectories over space and time while simultaneouslydriving their reorganization. With this platform, we demonstrate the ability todirect particle transport and create transient, reversible colloidal patternson the droplet surface. By tuning the beam voltage, we achieve precise controlover both the strength and sign of the beam-particle interaction, with lowvoltages repelling particles and high voltages attracting them. This responsestems from the formation of well-defined solvent flow fields generated fromtrace radiolysis of the ionic liquid, as determined through statisticalanalysis of single-particle trajectories under varying solvent composition.Altogether, electron-beam-guided assembly introduces a versatile strategy fornanoscale colloidal manipulation, offering new possibilities for the design ofdynamic, reconfigurable systems with applications in adaptive photonics andcatalysis.
胶体纳米颗粒(NPs)的定向自组装是利用外场引导形成复杂的分层材料,但随着颗粒尺寸的减小,其效果也会减弱。作为一种替代方法,电子束驱动的组装为定向纳米操纵提供了一条潜在的途径,但由于电子束相互作用机制的多样性和复杂性,这种方法的可控性仍然很差。在这里,我们研究了钉在离子液体液滴的流体-真空界面上的二氧化硅 NPs 的光束-粒子相互作用。在这些实验中,液滴表面的扫描电子显微镜可以解析 NP 在空间和时间上的轨迹,同时驱动它们重组。利用这一平台,我们展示了引导粒子传输并在液滴表面形成瞬时、可逆胶体模式的能力。通过调节光束电压,我们实现了对光束与粒子相互作用的强度和符号的精确控制,低电压排斥粒子,高电压吸引粒子。总之,电子束引导组装为纳米尺度胶体操纵引入了一种多功能策略,为设计动态可重构系统提供了新的可能性,可应用于自适应光子学和催化等领域。
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引用次数: 0
Self-organization and memory in a cyclically driven elasto-plastic model of an amorphous solid 无定形固体循环驱动弹塑性模型中的自组织和记忆
Pub Date : 2024-09-11 DOI: arxiv-2409.07621
Dheeraj Kumar, Muhittin Mungan, Sylvain Patinet, Damien Vandembroucq
The mechanical behavior of disordered materials such as dense suspensions,glasses or granular materials depends on their thermal and mechanical past.Here we report the memory behavior of a quenched mesoscopic elasto-plastic(QMEP) model. After prior oscillatory training, a simple read-out protocolgives access to both the training protocol's amplitude and the last sheardirection. The memory of direction emerges from the development of a mechanicalpolarization during training. The analysis of sample-to-sample fluctuationsgives direct access to the irreversibility transition. Despite the quadrupolarnature of the elastic interactions in amorphous solids, a behavior close toReturn Point Memory (RPM) is observed. The quasi RPM property is used to builda simple Preisach-like model of directional memory.
无序材料(如致密悬浮液、玻璃或颗粒材料)的机械行为取决于它们的热和机械过去。在此,我们报告了淬火介观弹塑性(QMEP)模型的记忆行为。经过事先的振荡训练后,一个简单的读出协议就能获得训练协议的振幅和最后的方向。方向记忆来自于训练过程中机械极化的发展。对样本间波动的分析可直接获取不可逆转换。尽管无定形固体中的弹性相互作用具有四重性质,但仍可观察到接近于回转点记忆(RPM)的行为。利用准 RPM 特性建立了一个简单的类似普雷萨赫的定向记忆模型。
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引用次数: 0
Anomalous behavior of electric-field Fréedericksz transitions 电场弗雷德里克兹转换的反常行为
Pub Date : 2024-09-11 DOI: arxiv-2409.07654
Eugene C. Gartland Jr
Fr'eedericksz transitions in nematic liquid crystals are re-examined with afocus on differences between systems with magnetic fields and those withelectric fields. A magnetic field can be treated as uniform in a liquid-crystalmedium; while a nonuniform director field will in general cause nonuniformityof the local electric field as well. Despite these differences, the widely heldview is that the formula for the threshold of local instability in anelectric-field Fr'eedericksz transition can be obtained from that for themagnetic-field transition in the same geometry by simply replacing the magneticparameters by their electric counterparts. However, it was shown in [Arakelyan,Karayan, and Chilingaryan, Sov. Phys. Dokl., 29 (1984) 202-204] that in two ofthe six classical electric-field Fr'eedericksz transitions, thelocal-instability threshold should be strictly greater than that predicted bythis magnetic-field analogy. Why this elevation of the threshold occurs iscarefully examined, and a simple test to determine when it can happen is given.This "anomalous behavior" is not restricted to classical Fr'eedericksztransitions and is shown to be present in certain layered systems (planarcholesterics, smectic-A) and in certain nematic systems that exhibit periodicinstabilities.
对向列液晶中的 Fr'eedericksz 转变进行了重新研究,重点是有磁场的系统与有电场的系统之间的差异。在液晶介质中,磁场可以被视为均匀的;而非均匀的导演场一般也会导致局部电场的非均匀性。尽管存在这些差异,但人们普遍认为,只需将磁参数替换为电参数,就能从相同几何形状的磁场转换中得到电场-弗里德里希茨转换的局部不稳定性阈值公式。然而,[Arakelyan、Karayan 和 Chilingaryan,Sov. Phys. Dokl.这种 "反常行为 "并不局限于经典的 Fr'eedericksz 转变,它还被证明存在于某些层状体系(planarcholesterics,smectic-A)和某些表现出周期不稳定性的向列体系中。
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引用次数: 0
Phase separation bursting and symmetry breaking inside an evaporating droplet; formation of a flower-like pattern 蒸发液滴内部的相分离迸发和对称性破坏;形成花朵状图案
Pub Date : 2024-09-11 DOI: arxiv-2409.07095
Vahid Nasirimarekani
Pattern formation inside a liquid phase is a phenomenon involved in manydifferent aspects of life on our planet. The droplet form of a liquid thatevaporates can reveal patterns that depend on the chemistry of the droplet andthe physical parameters involved. We observed a flower-like deposition patternof micrometer-sized particles as a result of the evaporation of a dropletcontaining salt and a non-ionic polymer. We show experimentally that the phaseseparation of the polymer due to the salting-out effect causes a strongentropic flow, which manifests as vortices. The flow is called phase separationbursting flow, which leads to the axial symmetry breaking and the formation ofa radially aligned flower-like pattern. We foresee that understanding theobserved flow can provide insights into the fluid physics aspects of phaseseparation and may have implications for technical applications.
液相内部的图案形成是一种涉及地球上许多不同生活方面的现象。液体蒸发后形成的液滴可以显示出取决于液滴化学性质和相关物理参数的图案。我们观察到,在含有盐和非离子聚合物的液滴蒸发过程中,微米大小的颗粒呈花朵状沉积。我们的实验表明,由于盐析效应,聚合物的相分离会导致强烈的熵流,表现为涡流。这种流动被称为 "相分离爆发流",它导致轴向对称性被打破,并形成径向排列的花朵状图案。我们预计,理解所观察到的流动可以深入了解相分离的流体物理学方面,并可能对技术应用产生影响。
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引用次数: 0
Hydrodynamic Spin-Pairing and Active Polymerization of Oppositely Spinning Rotors 对向旋转转子的水动力自旋配对和主动聚合作用
Pub Date : 2024-09-11 DOI: arxiv-2409.07554
Mattan Gelvan, Artyom Chirko, Jonathan Kirpitch, Yahav Lavie, Noa Israel, Naomi Oppenheimer
Rotors are common in nature - from rotating membrane-proteins tosuperfluid-vortices. Yet, little is known about the collective dynamics ofheterogeneous populations of rotors. Here, we show experimentally, numerically,and analytically that at small but finite inertia, a mixed population ofoppositely spinning rotors spontaneously self-assembles into active chains,which we term gyromers. The gyromers are formed and stabilized by fluid motionand steric interactions alone. A detailed analysis of pair interaction showsthat rotors with the same spin repel and orbit each other while opposite rotorsspin-pair and propagate together as bound dimers. Rotor dimers interact withindividual rotors, each other, and the boundaries to form chains. A minimalmodel predicts the formation of gyromers in numerical simulations and theirpossible subsequent folding into secondary structures of lattices and rings.This inherently out-of-equilibrium polymerization process holds promise forengineering self-assembled metamaterials such as artificial proteins.
转子在自然界中很常见--从旋转的膜蛋白到超流体旋涡。然而,人们对异质转子群的集体动力学知之甚少。在这里,我们通过实验、数值和分析表明,在较小但有限的惯性条件下,正向旋转转子的混合群体会自发地自组装成活性链,我们称之为回旋体。回旋体的形成和稳定仅靠流体运动和立体相互作用。对相互作用的详细分析显示,具有相同自旋的转子相互排斥并绕行,而相反的转子自旋配对并以结合二聚体的形式一起传播。转子二聚体与单个转子、彼此以及边界相互作用形成链。一个最小模型预测了数值模拟中回旋体的形成,以及它们随后可能折叠成晶格和环状的二级结构。这种固有的非平衡聚合过程有望设计出自组装超材料,如人造蛋白质。
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引用次数: 0
Programmable self-assembly of core-shell ellipsoids at liquid interfaces 液体界面上核-壳椭圆体的可编程自组装
Pub Date : 2024-09-11 DOI: arxiv-2409.07443
Jack Eatson, Susann Bauernfeind, Benjamin Midtvedt, Antonio Ciarlo, Johannes Menath, Giuseppe Pesce, Andrew B. Schofield, Giovanni Volpe, Paul S. Clegg, Nicolas Vogel, D. Martin. A. Buzza, Marcel Rey
Ellipsoidal particles confined at liquid interfaces exhibit complexself-assembly behaviour due to quadrupolar capillary interactions induced bymeniscus deformation. These interactions cause particles to attract each otherin either tip-to-tip or side-to-side configurations. However, controlling theirinterfacial self-assembly is challenging because it is difficult to predictwhich of these two states will be preferred. In this study, we demonstrate thatintroducing a soft shell around hard ellipsoidal particles provides a means tocontrol the self-assembly process, allowing us to switch the preferredconfiguration between these states. We study their interfacial self-assemblyand find that pure ellipsoids without a shell consistently form a "chain-like"side-to-side assembly, regardless of aspect ratio. In contrast, core-shellellipsoids transition from "flower-like" tip-to-tip to "chain-like"side-to-side arrangements as their aspect ratios increase. The critical aspectratio for transitioning between these structures increases with shell-to-coreratios. Our experimental findings are corroborated by theoretical calculationsand Monte Carlo simulations, which map out the phase diagram ofthermodynamically preferred self-assembly structures for core-shell ellipsoidsas a function of aspect ratio and shell-to-core ratios. This study shows how toprogram the self-assembly of anisotropic particles by tuning theirphysicochemical properties, allowing the deterministic realization of distinctstructural configurations.
由于四极毛细管的相互作用,被限制在液体界面上的椭圆形颗粒在流体变形的诱导下表现出复杂的自组装行为。这些相互作用导致颗粒在顶端到顶端或侧面到侧面的配置中相互吸引。然而,控制它们的界面自组装具有挑战性,因为很难预测这两种状态中哪一种更受青睐。在本研究中,我们证明了在硬椭圆形粒子周围引入软壳可以控制自组装过程,从而在这两种状态之间切换首选配置。我们对它们的界面自组装进行了研究,发现不带外壳的纯椭圆体无论长宽比如何,都能始终如一地形成 "链状 "侧对侧组装。相反,随着长宽比的增加,有核有壳的椭圆体会从 "花状 "的顶端到顶端排列过渡到 "链状 "的侧面到侧面排列。在这些结构之间过渡的临界长宽比随着壳对壳长宽比的增加而增加。我们的实验结果得到了理论计算和蒙特卡罗模拟的证实,这些计算和模拟绘制出了核壳椭圆体的热力学优选自组装结构相图,它是高宽比和壳核比的函数。这项研究展示了如何通过调整各向异性粒子的物理化学特性来对其自组装进行编程,从而确定性地实现不同的结构构型。
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引用次数: 0
Curvature induces and enhances transport of spinning colloids through narrow channels 曲率诱导并增强旋转胶体在狭窄通道中的传输
Pub Date : 2024-09-11 DOI: arxiv-2409.07661
Eric Cereceda-López, Marco De Corato, Ignacio Pagonabarraga, Fanlong Meng, Pietro Tierno, Antonio Ortiz-Ambriz
The effect of curvature and how it induces and enhances the transport ofcolloidal particles driven through narrow channels represent an unexploredresearch avenue. Here we combine experiments and simulations to investigate thedynamics of magnetically driven colloidal particles confined through a narrow,circular channel. We use an external precessing magnetic field to induce a nettorque and spin the particles at a defined angular velocity. Due to thespinning, the particle propulsion emerges from the different hydrodynamiccoupling with the inner and outer walls and strongly depends on the curvature.The experimental findings are combined with finite element numericalsimulations that predict a positive rotation translation coupling in themobility matrix. Further, we explore the collective transport of many particlesacross the curved geometry, making an experimental realization of a drivensingle file system. With our finding, we elucidate the effect of curvature onthe transport of microscopic particles which could be important to understandthe complex, yet rich, dynamics of particle systems driven through curvedmicrofluidic channels.
曲率效应及其如何诱导和增强胶体颗粒在狭窄通道中的传输是一个尚未探索的研究领域。在这里,我们结合实验和模拟来研究磁驱动胶体粒子在狭窄圆形通道中的动力学。我们使用外部预处理磁场来诱导净转矩,并以确定的角速度旋转粒子。实验结果与有限元数值模拟相结合,预测了流动矩阵中的正旋转平移耦合。此外,我们还探索了许多粒子穿越弯曲几何体的集体传输,在实验中实现了驱动单文件系统。我们的发现阐明了曲率对微观粒子输运的影响,这对理解通过弯曲微流体通道驱动的粒子系统复杂而丰富的动力学非常重要。
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引用次数: 0
Protocol dependence for avalanches under constant stress in elastoplastic models 弹塑性模型中恒定应力下雪崩的协议依赖性
Pub Date : 2024-09-09 DOI: arxiv-2409.05444
Tristan Jocteur, Eric Bertin, Romain Mari, Kirsten Martens
Close to the yielding transition, amorphous solids exhibit a jerky dynamicscharacterized by plastic avalanches. The statistics of these avalanches havebeen measured experimentally and numerically using a variety of differenttriggering protocols, assuming that all of them were equivalent for thispurpose. In particular two main classes of protocols have been studied,deformation under controlled strain or under controlled stress. In this work,we investigate different protocols to generate plasticity avalanches andconduct twodimensional simulations of an elastoplastic model to examine theprotocol dependence of avalanche statistics in yield-stress fluids. Wedemonstrate that when stress is controlled, the value and even the existence ofthe exponent governing the probability distribution function of avalanche sizesstrongly depend on the protocol chosen to initiate avalanches. This confirms infinite dimensions a scenario presented in a previous mean-field analysis. Weidentify a consistent stress-controlled protocol whose associated avalanchesdiffer from the quasi-static ones in their fractal dimension and dynamicalexponent. Remarkably, this protocol also seems to verify the scaling relationsamong exponents previously proposed. Our results underscores the necessity fora cautious interpretation of avalanche universality within elastoplasticmodels, and more generally within systems where several control parametersexist.
在接近屈服转变时,无定形固体会表现出以塑性雪崩为特征的生涩动态。这些雪崩的统计数据已通过实验和数值方法,使用各种不同的触发协议进行了测量,并假定所有协议在此方面都是等效的。特别是对两大类协议进行了研究:受控应变下的变形和受控应力下的变形。在这项工作中,我们研究了产生塑性雪崩的不同协议,并对弹塑性模型进行了二维模拟,以检验屈服应力流体中雪崩统计的协议依赖性。我们证明,当应力受到控制时,雪崩大小概率分布函数的指数值甚至存在与否,在很大程度上取决于启动雪崩时所选择的协议。这证实了之前平均场分析中提出的无限大方案。我们确定了一种一致的应力控制协议,其相关雪崩的分形维数和动态指数与准静态雪崩不同。值得注意的是,该协议似乎还验证了之前提出的指数之间的比例关系。我们的研究结果强调了在弹塑性模型中谨慎解释雪崩普遍性的必要性,以及在存在多个控制参数的系统中谨慎解释雪崩普遍性的必要性。
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引用次数: 0
期刊
arXiv - PHYS - Soft Condensed Matter
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