Pub Date : 2024-05-10DOI: 10.1007/s40999-024-00980-3
Penglong Zhao, Zheng Si, Lingzhi Huang, Xiaoqi Du, Yanlan He, Yi Ren, Meiwei Ke
With the advances in infrastructure construction in various countries around the world, extensive requirements have been promoted for the mechanical properties and durability of concrete. In this article, the effects of single and compound additions of nano-SiO2 (NS) and nano-Fe2O3 (NF) on the mechanical properties and durability of concrete were evaluated through different experiments. Moreover, the optimal contents of these additions corresponding to their different properties were explored. The macroscopic test results indicated that the addition of nanomaterials had a perceptible effect on the mechanical properties and durability of concrete. The concrete mixed with 1.0% NS and 0.5% NF achieved optimal performance. With this composition, the compressive strength, flexural strength, water absorption rate, and chloride ion diffusion coefficient (corrosion resistance) of the 28 days concrete were 52.94 MPa, 7.27 MPa, 4.82%, and 4.52 × 10–12 m2/s, respectively, which were 21.5%, 23.0%, 29.4%, and 37.2% higher than those of ordinary concrete at the same age. Microscopic observation and elemental analysis of the ITZ (interfacial transition zone) interface in concrete revealed that NS and NF contributed to nucleation. The two components reacted chemically with Ca (OH)2 grains, resulting in the synergistic effect of the spatial morphology of the hydration products, thus increasing the density of the internal structure of the concrete. To facilitate the application of nanomaterials in engineering, functional relationships between the content of nanomaterials in concrete and the improvements in various properties of concrete were constructed with high accuracy. In addition, the time-dependent correlation coefficients of apparent chloride ion concentration and chloride ion diffusion were introduced based on Fick’s second law, and this model was applied to multiple long-term monitoring experiments to verify its accuracy under various exposure conditions, such as tidal zones, splash zones, and atmospheric zones. The improved Fick model was used to predict the service life of concrete. By taking the splash zone as an example, it was reported that under the same conditions, the expected lives of S2F0, S0F2, and S2F1 increased by 31.8%, 25.7%, and 50.2%, respectively, compared to that of OPC. The research results could provide a reference for the development of high-performance concrete.
{"title":"Optimal Content and Lifespan Prediction of Nanomaterials in Nano-modified Concrete","authors":"Penglong Zhao, Zheng Si, Lingzhi Huang, Xiaoqi Du, Yanlan He, Yi Ren, Meiwei Ke","doi":"10.1007/s40999-024-00980-3","DOIUrl":"https://doi.org/10.1007/s40999-024-00980-3","url":null,"abstract":"<p>With the advances in infrastructure construction in various countries around the world, extensive requirements have been promoted for the mechanical properties and durability of concrete. In this article, the effects of single and compound additions of nano-SiO<sub>2</sub> (NS) and nano-Fe<sub>2</sub>O<sub>3</sub> (NF) on the mechanical properties and durability of concrete were evaluated through different experiments. Moreover, the optimal contents of these additions corresponding to their different properties were explored. The macroscopic test results indicated that the addition of nanomaterials had a perceptible effect on the mechanical properties and durability of concrete. The concrete mixed with 1.0% NS and 0.5% NF achieved optimal performance. With this composition, the compressive strength, flexural strength, water absorption rate, and chloride ion diffusion coefficient (corrosion resistance) of the 28 days concrete were 52.94 MPa, 7.27 MPa, 4.82%, and 4.52 × 10<sup>–12</sup> m<sup>2</sup>/s, respectively, which were 21.5%, 23.0%, 29.4%, and 37.2% higher than those of ordinary concrete at the same age. Microscopic observation and elemental analysis of the ITZ (interfacial transition zone) interface in concrete revealed that NS and NF contributed to nucleation. The two components reacted chemically with Ca (OH)<sub>2</sub> grains, resulting in the synergistic effect of the spatial morphology of the hydration products, thus increasing the density of the internal structure of the concrete. To facilitate the application of nanomaterials in engineering, functional relationships between the content of nanomaterials in concrete and the improvements in various properties of concrete were constructed with high accuracy. In addition, the time-dependent correlation coefficients of apparent chloride ion concentration and chloride ion diffusion were introduced based on Fick’s second law, and this model was applied to multiple long-term monitoring experiments to verify its accuracy under various exposure conditions, such as tidal zones, splash zones, and atmospheric zones. The improved Fick model was used to predict the service life of concrete. By taking the splash zone as an example, it was reported that under the same conditions, the expected lives of S2F0, S0F2, and S2F1 increased by 31.8%, 25.7%, and 50.2%, respectively, compared to that of OPC. The research results could provide a reference for the development of high-performance concrete.</p>","PeriodicalId":50331,"journal":{"name":"International Journal of Civil Engineering","volume":"215 1","pages":""},"PeriodicalIF":1.7,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140939457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-10DOI: 10.1007/s40999-024-00981-2
Hongyan Ma, Chenglin Pei, Sihan Li, Song Xu
Red clay exhibits characteristics such as softening owing to water absorption and cracking because of water loss, which can lead to slope instability, road cracking, and compromised structural integrity when used directly in roadbed filling. Although the addition of industrial materials such as cement is a common engineering treatment, it severely impairs soil renewability. Lignosulfonate (LS) extracted from paper plant waste fluids is a natural bio-based polymer with promising applications as a soil improver. In this study, the boundary moisture content and mechanical properties of LS-treated red clay were investigated using Atterberg, unconfined compressive strength, and direct shear strength tests. Additionally, the LS-treated red clay modification mechanism was explored at multiple scales using zeta potential analysis, X-ray diffraction, scanning electron microscopy coupled with energy dispersive spectroscopy, and Fourier transform infrared spectroscopy. The results indicated that the LS dosage significantly affected both the water content and mechanical strength of the red clay boundaries. The optimal dosage of LS for red clay was 3 wt. %, at which the liquid limit was reduced by 32.97%, the plastic limit by 19.33%, and the plasticity index by 48.37%. The 28-day compressive strength of LS-treated red clay was increased by 378.4%, and the direct shear strength was increased by 136%. Analysis of the microstructure and mineral composition revealed that the LS-treated red clay did not form new minerals, but primarily filled pores and connected soil particles. Through the combined effects of hydrogen bonds, electrostatic interactions, and cation exchange, the LS-treated red clay reduced the size of the mineral particles and the thickness of the mineral double electric layer, resulting in increased structural densification. These results are of great scientific significance for the ecological modification of soils.