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Assessment of Possibly Toxic Elements in Landfill Soils and Their Impacts on the Ecosystem in Alice, South Africa 评估南非艾丽丝垃圾填埋场土壤中可能有毒的元素及其对生态系统的影响
Pub Date : 2024-06-03 DOI: 10.3390/pollutants4020019
Nontobeko Gloria Maphuhla, O. Oyedeji
Soil contamination by metallic components is an obscure, detrimental, protracted, and irreparable predicament. Dumping of waste containing heavy metals into landfills, fertilizer and pesticide application, and coal combustion results in high toxicity of metallic elements, and their continuous accumulation in soil pollutes the environment, which, in turn, poses a threat to human health. The specimens were subsequently dehydrated, processed for mineralization, and carefully examined microscopically by scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDX), which examined their mineral substance, crystalline configuration, and chemical composition. Thirteen (13) elements were detected, and only eight (8) metals were discovered (K, Mg, Na, Ca, Al, Fe, Au, Ba), including non-metals (C, O, Cl, P) and a metalloid (Si). The concentrations of possibly toxic elements obtained showed no consistent succession, as they fluctuated across the examined sites. The Al concentration ranged from 3.78 ± 0.23 wt% to 10.23 ± 0.31 wt%, while the Fe concentration fluctuated from 4.14 ± 0.40 wt% to 13.13 ± 1.07 wt%. Na and Mg levels were present in all samples, but their availability was minimal, at less than 2.0 wt%, ranging between 1.44 ± 0.20 wt% and 0.31 ± 0.08 wt%. The concentrations of Ca and K were low in all soil samples, ranging from 0.91 ± 0.14 wt% to 5.56 ± 0.47 wt% for Ca and from 1.32 ± 0.25 wt% to 4.87 ± 0.18 wt% for K. During the investigation at the designated and control areas, it was discovered that the concentrations of potentially hazardous metals exceeded the accepted limits established by the World Health Organization (WHO) > 100 ppm. The findings provide proof of metallic contaminants in the study region, which calls for proper monitoring, management, and remedial measures of metal-tainted sites, since the residents of this locality are at a significantly elevated risk of experiencing adverse effects due to their heightened exposure to these elements. As a result of that, there is an imperative need to monitor and regulate this area regularly and appropriately. The study recommends sustainable farming practices, where farmers could use natural fertilizers and compost, as well as, the implementation of proper waste management, effective recycling techniques, and proper disposal of substances containing heavy metals as byproducts. Further implement remediation techniques that effectively and safely restore soils contaminated by metals in an environmentally sustainable and economically efficient manner.
金属成分对土壤的污染是一个隐蔽的、有害的、长期的和无法弥补的困境。向垃圾填埋场倾倒含有重金属的废物、施用化肥和农药以及燃烧煤炭导致金属元素的高毒性,它们在土壤中的持续积累污染了环境,进而对人类健康构成威胁。随后,对标本进行脱水、矿化处理,并通过扫描电子显微镜和能量色散 X 射线光谱仪(SEM/EDX)对其进行仔细的显微镜检查,检查其矿物物质、晶体结构和化学成分。检测到 13 种元素,仅发现 8 种金属(K、Mg、Na、Ca、Al、Fe、Au、Ba),包括非金属(C、O、Cl、P)和一种类金属(Si)。所获得的可能有毒元素的浓度没有显示出一致的连续性,因为它们在所考察的地点之间有波动。铝的浓度从 3.78 ± 0.23 wt% 到 10.23 ± 0.31 wt% 不等,而铁的浓度从 4.14 ± 0.40 wt% 到 13.13 ± 1.07 wt% 不等。所有样本中都含有 Na 和 Mg,但含量极低,不到 2.0 wt%,在 1.44 ± 0.20 wt% 和 0.31 ± 0.08 wt% 之间。所有土壤样本中的钙和钾含量都很低,钙含量在 0.91 ± 0.14 wt% 到 5.56 ± 0.47 wt% 之间,钾含量在 1.32 ± 0.25 wt% 到 4.87 ± 0.18 wt% 之间。这些发现证明研究区域存在金属污染物,因此需要对受金属污染的地点进行适当的监测、管理并采取补救措施,因为该地区的居民由于接触这些元素的机会增多,遭受不良影响的风险大大增加。因此,亟需对该地区进行定期和适当的监测和监管。研究建议采用可持续的耕作方式,农民可以使用天然肥料和堆肥,同时实施适当的废物管理、有效的回收技术,并妥善处理含有重金属的物质副产品。进一步实施补救技术,以环境可持续和经济高效的方式有效、安全地恢复受金属污染的土壤。
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引用次数: 0
Impact of Artisanal Gold Mining in Community Conserved Areas with High Biodiversity Using a Multi-Criteria Approach: A Case Study in Colombia 采用多重标准方法研究手工开采金矿对生物多样性丰富的社区保护区的影响:哥伦比亚案例研究
Pub Date : 2024-06-03 DOI: 10.3390/pollutants4020018
F. Gomez, Natalia Pelegri, Juan Guillermo Lopez, Kelly Cristina Torres, M. Vaccari
Artisanal small-scale gold mining (ASGM) using mercury affects community agreements for the conservation of forests (CoS) and lakes (CoH), which have a high level of biodiversity in the Peasant Reserve Zone of the Cimitarra River Valley (ZRC-VRC) in Colombia. In this research, a multi-criteria approach (MCA) was applied to analyze the impact of ASGM. This analysis is based on the community environmental agreements to preserve CoS and CoH areas, the ecological importance of these areas, as well as the results of mercury dispersion in the Cimitarra river basin, with concentrations found 40 km downstream of the mining area of 0.09 µgTHg L−1 in the Cimitarra river, 0.07 µgTHg L−1 in the CoH, and 0.01 mgTHg kg−1 in the tissues of macrophytes, as well as the increase in deforestation since 2020 in the CoS, due to a 1.8% (990 ha) loss of forest cover, with 693 ha of the forest cover loss coinciding with areas related to the opening of new mines. The MCA showed that the main impact is found within the criterion Social and armed conflict, followed by Deforestation. This research offers recommendations to reduce impact scores, such as the implementation of a sustainable development plan (PDS) of the ZRC-VRC, and it highlights the urgent need to safeguard the community conservation areas.
使用汞的手工小规模采金业(ASGM)影响了哥伦比亚西米塔拉河谷农民保护区(ZRC-VRC)中具有高度生物多样性的森林(CoS)和湖泊(CoH)的社区保护协议。本研究采用多重标准方法 (MCA) 分析手工和小规模采金业的影响。该分析基于保护 CoS 和 CoH 区域的社区环境协议、这些区域的生态重要性以及 Cimitarra 河流域的汞散布结果,在采矿区下游 40 公里处的 Cimitarra 河中发现的汞浓度为 0.09 µgTHg L-1,Cimitarra 河中发现的汞浓度为 0.07 µgTHg L-1,Cimitarra 河中发现的汞浓度为 0.07 µgTHg L-1。此外,自 2020 年以来,CoS 地区的森林砍伐量增加,森林覆盖面积减少了 1.8%(990 公顷),其中 693 公顷的森林覆盖面积减少与新矿区的开设有关。多重标准分析表明,主要影响来自社会和武装冲突标准,其次是森林砍伐。这项研究提出了降低影响分数的建议,如实施 ZRC-VRC 的可持续发展计划 (PDS),并强调迫切需要保护社区保护区。
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引用次数: 0
A Comprehensive Analysis of Risk Assessment of Particulate Matter in Five Health Centers in Akure, Nigeria 尼日利亚阿库雷市五家医疗中心颗粒物风险评估综合分析
Pub Date : 2024-02-08 DOI: 10.3390/pollutants4010006
F. Abulude, S. Oluwagbayide, A. Akinnusotu, K. M. Arifalo, Ademola Adamu, A. M. Kenni
This study presents a comprehensive assessment of indoor particulate matter (PM) concentrations, focusing on PM1, PM2.5, and PM10 in five primary health centers (PHCs): Arakale (Urban), the Federal College of Agriculture (FECA) (Urban), Iju (semi-urban), Oba-Ile (semi-urban), and Owode (Rural) within Akure local government areas in Nigeria. The primary novelty of this research lies in its detailed exploration of the toxicity potential of these PM fractions, providing valuable insights into the local air quality and associated health risks. This study assesses the health implications by calculating the toxicity potential (TP), relative risk (RR), excess risk (ER), and attributable fractions (Afs) for cardiopulmonary and lung cancer mortality. The results reveal varying RR values for all-cause mortality, with Arakale showing a slight elevation (RR: 1.061), indicating potential health risks. ER values for cardiopulmonary mortality range from 14.728 ± 7.25 to 19.04 ± 0.38, emphasizing the substantial excess risk associated with long-term PM2.5 exposure. The study also uncovers Afs for cardiopulmonary mortality ranging between 11.03 ± 0.31 and 19.22 ± 0.04, underscoring the significant contribution of PM to cardiovascular and respiratory health risks. Similarly, Afs for lung cancer mortality range from 10.03 ± 0.012 to 17.13 ± 0.10, highlighting the substantial association between PM2.5 exposure and lung cancer risk. These findings underscore the urgent need for targeted air quality management strategies and public health interventions in the studied locations to mitigate the heightened health risks associated with particulate matter pollution. The calculated RR, ER, and AF values offer crucial insights into the complex relationship between PM exposure and adverse health outcomes, providing a foundation for informed decision-making and future research endeavors.
本研究全面评估了五个初级保健中心(PHC)的室内颗粒物(PM)浓度,重点是 PM1、PM2.5 和 PM10:Arakale(城市)、联邦农业学院(FECA)(城市)、Iju(半城市)、Oba-Ile(半城市)和 Owode(农村)。这项研究的主要创新之处在于详细探讨了这些可吸入颗粒物馏分的潜在毒性,为了解当地空气质量和相关健康风险提供了宝贵的见解。本研究通过计算心肺癌和肺癌死亡率的毒性潜力(TP)、相对风险(RR)、超额风险(ER)和可归因分数(Afs)来评估对健康的影响。结果显示,全因死亡率的 RR 值各不相同,阿拉卡莱的 RR 值略有上升(RR:1.061),表明存在潜在的健康风险。心肺死亡率的 ER 值从 14.728 ± 7.25 到 19.04 ± 0.38 不等,强调了与长期暴露于 PM2.5 相关的巨大超额风险。研究还发现,心肺死亡率的 Afs 值介于 11.03 ± 0.31 和 19.22 ± 0.04 之间,强调了 PM 对心血管和呼吸系统健康风险的重大影响。同样,肺癌死亡率的Afs从10.03 ± 0.012到17.13 ± 0.10不等,突显了PM2.5暴露与肺癌风险之间的重大关联。这些研究结果突出表明,迫切需要在研究地点采取有针对性的空气质量管理策略和公共卫生干预措施,以降低与颗粒物污染相关的更高健康风险。计算得出的RR、ER和AF值为了解PM暴露与不良健康后果之间的复杂关系提供了重要依据,为知情决策和未来的研究工作奠定了基础。
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引用次数: 0
A Comprehensive Analysis of Risk Assessment of Particulate Matter in Five Health Centers in Akure, Nigeria 尼日利亚阿库雷市五家医疗中心颗粒物风险评估综合分析
Pub Date : 2024-02-08 DOI: 10.3390/pollutants4010006
F. Abulude, S. Oluwagbayide, A. Akinnusotu, K. M. Arifalo, Ademola Adamu, A. M. Kenni
This study presents a comprehensive assessment of indoor particulate matter (PM) concentrations, focusing on PM1, PM2.5, and PM10 in five primary health centers (PHCs): Arakale (Urban), the Federal College of Agriculture (FECA) (Urban), Iju (semi-urban), Oba-Ile (semi-urban), and Owode (Rural) within Akure local government areas in Nigeria. The primary novelty of this research lies in its detailed exploration of the toxicity potential of these PM fractions, providing valuable insights into the local air quality and associated health risks. This study assesses the health implications by calculating the toxicity potential (TP), relative risk (RR), excess risk (ER), and attributable fractions (Afs) for cardiopulmonary and lung cancer mortality. The results reveal varying RR values for all-cause mortality, with Arakale showing a slight elevation (RR: 1.061), indicating potential health risks. ER values for cardiopulmonary mortality range from 14.728 ± 7.25 to 19.04 ± 0.38, emphasizing the substantial excess risk associated with long-term PM2.5 exposure. The study also uncovers Afs for cardiopulmonary mortality ranging between 11.03 ± 0.31 and 19.22 ± 0.04, underscoring the significant contribution of PM to cardiovascular and respiratory health risks. Similarly, Afs for lung cancer mortality range from 10.03 ± 0.012 to 17.13 ± 0.10, highlighting the substantial association between PM2.5 exposure and lung cancer risk. These findings underscore the urgent need for targeted air quality management strategies and public health interventions in the studied locations to mitigate the heightened health risks associated with particulate matter pollution. The calculated RR, ER, and AF values offer crucial insights into the complex relationship between PM exposure and adverse health outcomes, providing a foundation for informed decision-making and future research endeavors.
本研究全面评估了五个初级保健中心(PHC)的室内颗粒物(PM)浓度,重点是 PM1、PM2.5 和 PM10:Arakale(城市)、联邦农业学院(FECA)(城市)、Iju(半城市)、Oba-Ile(半城市)和 Owode(农村)。这项研究的主要创新之处在于详细探讨了这些可吸入颗粒物馏分的潜在毒性,为了解当地空气质量和相关健康风险提供了宝贵的见解。本研究通过计算心肺癌和肺癌死亡率的毒性潜力(TP)、相对风险(RR)、超额风险(ER)和可归因分数(Afs)来评估对健康的影响。结果显示,全因死亡率的 RR 值各不相同,阿拉卡莱的 RR 值略有上升(RR:1.061),表明存在潜在的健康风险。心肺死亡率的 ER 值从 14.728 ± 7.25 到 19.04 ± 0.38 不等,强调了与长期暴露于 PM2.5 相关的巨大超额风险。研究还发现,心肺死亡率的 Afs 值介于 11.03 ± 0.31 和 19.22 ± 0.04 之间,强调了 PM 对心血管和呼吸系统健康风险的重大影响。同样,肺癌死亡率的Afs从10.03 ± 0.012到17.13 ± 0.10不等,突显了PM2.5暴露与肺癌风险之间的重大关联。这些研究结果突出表明,迫切需要在研究地点采取有针对性的空气质量管理策略和公共卫生干预措施,以降低与颗粒物污染相关的更高健康风险。计算得出的RR、ER和AF值为了解PM暴露与不良健康后果之间的复杂关系提供了重要依据,为知情决策和未来的研究工作奠定了基础。
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引用次数: 0
Assessing the Bioaccumulation of Heavy Metals in Cabbage Grown under Five Soil Amendments 评估在五种土壤改良剂下种植的卷心菜中重金属的生物累积性
Pub Date : 2024-02-02 DOI: 10.3390/pollutants4010005
Anjan Nepal, G. Antonious, B. Gyawali, Thomas C. Webster, Frederick Bebe
Increased heavy metal pollution worldwide necessitates urgent remediation measures. Phytoremediation stands as an eco-friendly technique that addresses this issue. This study aimed to investigate the applicability of phytoremediation in agricultural practices. Specifically, to evaluate the impact of five soil amendments (chicken manure, sewage sludge, leaf compost, cow manure, and vermicompost) on three cabbage (Brassica oleracea var. capitata) varieties (Capture, Primo vantage, and Tiara) yield, quality, and the accumulation of Cd, Cu, Mo, Ni, Pb, and Zn in cabbage heads. The bioaccumulation efficiency of cabbage was determined using an inductively coupled plasma–optical emission spectrometer (ICP-OES). Analysis revealed that soil enriched with chicken manure exhibited the highest cabbage yield. Each cabbage variety demonstrated very high bioaccumulation factor (BAF) indicating substantial heavy metal accumulation. These findings underscore the potential of utilizing crops for phytoremediation to mitigate heavy metal pollution. Additionally, the concentrations of metals below the permissible limits suggest that employing crops for phytoremediation can simultaneously ensure food productivity. This study emphasizes the necessity for further research into the use of crops for remediation strategies.
全球重金属污染日益严重,迫切需要采取补救措施。植物修复是解决这一问题的生态友好型技术。本研究旨在调查植物修复在农业实践中的适用性。具体而言,评估五种土壤改良剂(鸡粪、污水污泥、叶堆肥、牛粪和蛭石堆肥)对三个甘蓝(Brassica oleracea var. capitata)品种(Capture、Primo vantage 和 Tiara)的产量、品质以及甘蓝头中镉、铜、钼、镍、铅和锌的积累的影响。使用电感耦合等离子体-光发射光谱分析仪(ICP-OES)测定了白菜的生物累积效率。分析表明,富含鸡粪的土壤白菜产量最高。每个卷心菜品种的生物累积系数(BAF)都非常高,表明重金属累积量很大。这些发现强调了利用作物进行植物修复以减轻重金属污染的潜力。此外,金属浓度低于允许限值表明,利用作物进行植物修复可同时确保粮食产量。这项研究强调,有必要进一步研究利用作物进行修复的策略。
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引用次数: 0
Assessing the Bioaccumulation of Heavy Metals in Cabbage Grown under Five Soil Amendments 评估在五种土壤改良剂下种植的卷心菜中重金属的生物累积性
Pub Date : 2024-02-02 DOI: 10.3390/pollutants4010005
Anjan Nepal, G. Antonious, B. Gyawali, Thomas C. Webster, Frederick Bebe
Increased heavy metal pollution worldwide necessitates urgent remediation measures. Phytoremediation stands as an eco-friendly technique that addresses this issue. This study aimed to investigate the applicability of phytoremediation in agricultural practices. Specifically, to evaluate the impact of five soil amendments (chicken manure, sewage sludge, leaf compost, cow manure, and vermicompost) on three cabbage (Brassica oleracea var. capitata) varieties (Capture, Primo vantage, and Tiara) yield, quality, and the accumulation of Cd, Cu, Mo, Ni, Pb, and Zn in cabbage heads. The bioaccumulation efficiency of cabbage was determined using an inductively coupled plasma–optical emission spectrometer (ICP-OES). Analysis revealed that soil enriched with chicken manure exhibited the highest cabbage yield. Each cabbage variety demonstrated very high bioaccumulation factor (BAF) indicating substantial heavy metal accumulation. These findings underscore the potential of utilizing crops for phytoremediation to mitigate heavy metal pollution. Additionally, the concentrations of metals below the permissible limits suggest that employing crops for phytoremediation can simultaneously ensure food productivity. This study emphasizes the necessity for further research into the use of crops for remediation strategies.
全球重金属污染日益严重,迫切需要采取补救措施。植物修复是解决这一问题的生态友好型技术。本研究旨在调查植物修复在农业实践中的适用性。具体而言,评估五种土壤改良剂(鸡粪、污水污泥、叶堆肥、牛粪和蛭石堆肥)对三个甘蓝(Brassica oleracea var. capitata)品种(Capture、Primo vantage 和 Tiara)的产量、品质以及甘蓝头中镉、铜、钼、镍、铅和锌的积累的影响。使用电感耦合等离子体-光发射光谱分析仪(ICP-OES)测定了白菜的生物累积效率。分析表明,富含鸡粪的土壤白菜产量最高。每个卷心菜品种的生物累积系数(BAF)都非常高,表明重金属累积量很大。这些发现强调了利用作物进行植物修复以减轻重金属污染的潜力。此外,金属浓度低于允许限值表明,利用作物进行植物修复可同时确保粮食产量。这项研究强调,有必要进一步研究利用作物进行修复的策略。
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引用次数: 0
Long-Term Effects of Plastic Mulch in a Sandy Loam Soil Used to Cultivate Blueberry in Southern Portugal 塑料覆盖物对葡萄牙南部种植蓝莓的沙质壤土的长期影响
Pub Date : 2024-01-11 DOI: 10.3390/pollutants4010002
Filipe Pedra, M. Inácio, Paula Fareleira, Pedro Oliveira, Pablo Pereira, Corina Carranca
Numerous plastic products are used in agriculture, including containers, packaging, tunnels, drip irrigation tubing, and mulches. Large amounts of plastics are used as mulches on the soil surface for vegetable and fruit production (tomato, cucumber, watermelon, strawberry, and vine) to reduce weed competition, increase water and fertilizer use efficiency, and enhance crop yield. Portugal uses around 4500 t/year of polyethylene to cover approximately 23,000 ha of agricultural land, and only a small amount is recovered for recycling or secondary uses because of issues of contamination with the soil, vegetation, pesticides, and fertilizers. Cleaning and decontaminating polyethylene mulch are costly, and commercial technology is often not accessible or economical. Most plastic mulch is composed of polyethylene that degrades slowly and produces a large quantity of residues in the soil, with a negative impact on the environment. In the present study, the effects of long-term cultivation of blueberry using green 100% high-density polyethylene mulch in the south Portugal were evaluated for soil chemical and biological changes. High-density green plastic mulch did not contaminate the topsoil with di(2-ethylhexyl) phthalate, and heavy metals, buttotal nitrogen, organic carbon concentrations, electric conductivity, and microbial activity were significantly reduced in the planting row compared with the bare soil without mulching. Furthermore, the presence of plastic mulch did not negatively affect the presence of nematodes, and the number of Rhabditida (bacterial feeders) increased in the planting and covered row.
农业中使用了大量塑料产品,包括容器、包装、隧道、滴灌管和地膜。大量塑料被用作蔬菜和水果生产(番茄、黄瓜、西瓜、草莓和葡萄)土壤表面的覆盖物,以减少杂草竞争,提高水和肥料的使用效率,并增加作物产量。葡萄牙每年使用约 4500 吨聚乙烯来覆盖约 23000 公顷的农田,但由于土壤、植被、杀虫剂和肥料的污染问题,只有少量聚乙烯被回收用于循环利用或二次利用。清洗和净化聚乙烯地膜的成本很高,而且商业技术往往无法获得或不经济。大多数塑料地膜由聚乙烯组成,降解缓慢,会在土壤中产生大量残留物,对环境造成负面影响。本研究评估了葡萄牙南部长期使用绿色 100% 高密度聚乙烯地膜种植蓝莓对土壤化学和生物变化的影响。与未覆盖地膜的裸露土壤相比,高密度绿色塑料地膜没有污染表层土壤中的邻苯二甲酸二(2-乙基己酯),种植行中的重金属、对接氮、有机碳浓度、电导率和微生物活性都显著降低。此外,塑料覆盖物的存在并没有对线虫的存在产生负面影响,而在种植行和覆盖行中,Rhabditida(细菌取食者)的数量有所增加。
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引用次数: 0
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Pollutants
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