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Oxygen Measurement in Cuprate Superconductors Using the Dissolved Oxygen/Chlorine Method 使用溶解氧/氯法测量铜氧化物超导体中的氧含量
Pub Date : 2024-07-16 DOI: 10.3390/technologies12070115
Yuliang Wei, Chengcheng Yan, Shiro Kambe
We have developed a dissolved oxygen (DO) method with differential equation (DE) correction. We measured the oxygen content in La-based and Y-based superconductors, and succeeded in measuring the oxygen content simply in one-third of the time required by the iodometric titration method. However, there was a problem with Bi-based superconductors where the measured oxygen content was smaller compared to the iodometric titration method. We hypothesized that not only O2 but also Cl2 gas is generated when dissolving Bi-based superconductors and developed a dissolved oxygen/chlorine (DO/Cl) method with DE correction. This method uses only a dissolved oxygen sensor and a dissolved chlorine sensor to measure the dissolved oxygen and dissolved chlorine content in Bi2Sr2−xLaxCuOy, allowing for the calculation of copper valence and oxygen content. The results from the DO/Cl method with DE correction show that the measured copper valence and oxygen content differ very little from those obtained using the iodometric titration method, with discrepancies within 0.016 and 0.008, respectively. Additionally, this method reduces the measurement time by one-third compared to the iodometric titration method. The results demonstrate that the DO/Cl method with DE correction can effectively measure the copper valence and oxygen content in cuprate superconductors, and using hydrochloric acid as the experimental solution is superior to sulfuric acid and nitric acid.
我们开发了一种带有微分方程校正的溶解氧 (DO) 方法。我们测量了 La 基和 Y 基超导体中的氧含量,并成功地在碘滴定法所需的三分之一时间内测量出了氧含量。然而,在 Bi 基超导体中存在一个问题,与碘滴定法相比,测量的氧含量较小。我们推测,在溶解 Bi 基超导体时,不仅会产生 O2,还会产生 Cl2 气体,因此开发了一种带有 DE 校正功能的溶解氧/氯(DO/Cl)方法。该方法仅使用一个溶解氧传感器和一个溶解氯传感器来测量 Bi2Sr2-xLaxCuOy 中的溶解氧和溶解氯含量,从而计算出铜价和氧含量。采用溶解氧/溶解氯法进行 DE 校正的结果表明,测得的铜价和氧含量与采用碘量滴定法测得的铜价和氧含量相差很小,分别为 0.016 和 0.008。此外,与碘量滴定法相比,这种方法还能将测量时间缩短三分之一。结果表明,带 DE 校正的 DO/Cl 方法能有效测量铜氧化物超导体中的铜价和氧含量,而使用盐酸作为实验溶液则优于硫酸和硝酸。
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引用次数: 0
Probabilistic Confusion Matrix: A Novel Method for Machine Learning Algorithm Generalized Performance Analysis 概率混淆矩阵:机器学习算法通用性能分析的新方法
Pub Date : 2024-07-13 DOI: 10.3390/technologies12070113
Ioannis Markoulidakis, Georgios Markoulidakis
The paper addresses the issue of classification machine learning algorithm performance based on a novel probabilistic confusion matrix concept. The paper develops a theoretical framework which associates the proposed confusion matrix and the resulting performance metrics with the regular confusion matrix. The theoretical results are verified based on a wide variety of real-world classification problems and state-of-the-art machine learning algorithms. Based on the properties of the probabilistic confusion matrix, the paper then highlights the benefits of using the proposed concept both during the training phase and the application phase of a classification machine learning algorithm.
本文基于新颖的概率混淆矩阵概念,探讨了分类机器学习算法的性能问题。论文建立了一个理论框架,将提出的混淆矩阵和由此产生的性能指标与常规混淆矩阵联系起来。理论结果基于各种现实世界的分类问题和最先进的机器学习算法得到了验证。基于概率混淆矩阵的特性,论文强调了在分类机器学习算法的训练阶段和应用阶段使用所提概念的好处。
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引用次数: 0
Development and Evaluation of an mHealth App That Promotes Access to 3D Printable Assistive Devices 开发和评估可促进获取 3D 打印辅助设备的移动医疗应用程序
Pub Date : 2024-07-13 DOI: 10.3390/technologies12070114
Jeffrey Bush, S. Benham, Monica Kaniamattam
Three-dimensional printing is an emerging service delivery method for on-demand access to customized assistive technology devices. However, barriers exist in locating and designing appropriate models and having the devices printed. The purpose of this work is to outline the development of an app, 3DAdapt, which allows users to overcome these issues by searching within a curated list of 3D printable assistive devices, customizing models that support it, and ordering the device to be printed by manufacturers linked within the app or shared with local 3D printing operators. The app integrates searching and filters based on the International Classification of Functioning, Disability, and Health, with the available devices including those developed from fieldwork collaborations with multiple professionals and students within clinical, community, and educational settings. It provides users the ability to customize select models to meet their needs. The model can then be shared, downloaded, or ordered from a third-party 3D printing service. This development and expert testing phase to assess feasibility and modify the app based on identified themes then prepared the team for the next phases of beta testing to reach the overall aim of 3DAdapt to connect individuals to affordable and customizable devices to increase independence and quality of life.
三维打印是一种新兴的服务提供方法,可按需提供定制的辅助技术设备。然而,在寻找和设计合适的模型以及打印设备方面存在障碍。这项工作的目的是概述 3DAdapt 应用程序的开发过程,该应用程序允许用户通过在经过策划的三维打印辅助设备列表中进行搜索、定制支持该设备的模型以及订购该设备,然后由应用程序中链接的制造商或与本地三维打印运营商共享的制造商进行打印,从而克服这些问题。该应用程序集成了基于国际功能、残疾和健康分类的搜索和筛选功能,可用设备包括在临床、社区和教育环境中与多位专业人士和学生实地合作开发的设备。用户可以根据自己的需要定制选定的模型。然后,用户可以共享、下载或从第三方 3D 打印服务订购模型。开发和专家测试阶段旨在评估可行性,并根据确定的主题修改应用程序,然后为团队下一阶段的测试做好准备,以实现 3DAdapt 的总体目标,将个人与经济实惠的定制设备联系起来,提高独立性和生活质量。
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引用次数: 0
Improvement of the ANN-Based Prediction Technology for Extremely Small Biomedical Data Analysis 基于 ANN 的预测技术在极小生物医学数据分析中的改进
Pub Date : 2024-07-12 DOI: 10.3390/technologies12070112
I. Izonin, R.O. Tkachenko, O. Berezsky, Iurii Krak, Michal Kováč, M. Fedorchuk
Today, the field of biomedical engineering spans numerous areas of scientific research that grapple with the challenges of intelligent analysis of small datasets. Analyzing such datasets with existing artificial intelligence tools is a complex task, often complicated by issues like overfitting and other challenges inherent to machine learning methods and artificial neural networks. These challenges impose significant constraints on the practical application of these tools to the problem at hand. While data augmentation can offer some mitigation, existing methods often introduce their own set of limitations, reducing their overall effectiveness in solving the problem. In this paper, the authors present an improved neural network-based technology for predicting outcomes when analyzing small and extremely small datasets. This approach builds on the input doubling method, leveraging response surface linearization principles to improve performance. Detailed flowcharts of the improved technology’s operations are provided, alongside descriptions of new preparation and application algorithms for the proposed solution. The modeling, conducted using two biomedical datasets with optimal parameters selected via differential evolution, demonstrated high prediction accuracy. A comparison with several existing methods revealed a significant reduction in various errors, underscoring the advantages of the improved neural network technology, which does not require training, for the analysis of extremely small biomedical datasets.
如今,生物医学工程领域横跨众多科学研究领域,这些领域都面临着对小型数据集进行智能分析的挑战。利用现有的人工智能工具分析这些数据集是一项复杂的任务,而过拟合等问题以及机器学习方法和人工神经网络所固有的其他挑战往往使这项任务变得更加复杂。这些挑战严重制约了这些工具在实际应用中解决手头问题的能力。虽然数据扩增可以提供一些缓解措施,但现有方法往往会引入自身的一系列局限性,降低解决问题的整体效率。在本文中,作者提出了一种基于神经网络的改进技术,用于在分析小型和超小型数据集时预测结果。这种方法以输入加倍法为基础,利用响应面线性化原理来提高性能。本文提供了改进技术操作的详细流程图,同时还介绍了拟议解决方案的新准备和应用算法。建模使用了两个生物医学数据集,并通过微分进化选择了最佳参数,结果显示预测准确率很高。与现有的几种方法进行比较后发现,各种误差明显减少,这凸显了改进后的神经网络技术在分析极小的生物医学数据集方面的优势,而且无需训练。
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引用次数: 0
Optimizing Speech Emotion Recognition with Machine Learning Based Advanced Audio Cue Analysis 利用基于机器学习的高级音频线索分析优化语音情感识别
Pub Date : 2024-07-11 DOI: 10.3390/technologies12070111
Nuwan Pallewela, D. Alahakoon, A. Adikari, John E. Pierce, ML Rose
In today’s fast-paced and interconnected world, where human–computer interaction is an integral component of daily life, the ability to recognize and understand human emotions has emerged as a crucial facet of technological advancement. However, human emotion, a complex interplay of physiological, psychological, and social factors, poses a formidable challenge even for other humans to comprehend accurately. With the emergence of voice assistants and other speech-based applications, it has become essential to improve audio-based emotion expression. However, there is a lack of specificity and agreement in current emotion annotation practice, as evidenced by conflicting labels in many human-annotated emotional datasets for the same speech segments. Previous studies have had to filter out these conflicts and, therefore, a large portion of the collected data has been considered unusable. In this study, we aimed to improve the accuracy of computational prediction of uncertain emotion labels by utilizing high-confidence emotion labelled speech segments from the IEMOCAP emotion dataset. We implemented an audio-based emotion recognition model using bag of audio word encoding (BoAW) to obtain a representation of audio aspects of emotion in speech with state-of-the-art recurrent neural network models. Our approach improved the state-of-the-art audio-based emotion recognition with a 61.09% accuracy rate, an improvement of 1.02% over the BiDialogueRNN model and 1.72% over the EmoCaps multi-modal emotion recognition models. In comparison to human annotation, our approach achieved similar results in identifying positive and negative emotions. Furthermore, it has proven effective in accurately recognizing the sentiment of uncertain emotion segments that were previously considered unusable in other studies. Improvements in audio emotion recognition could have implications in voice-based assistants, healthcare, and other industrial applications that benefit from automated communication.
在当今这个快节奏、互联互通的世界里,人机交互已成为日常生活不可或缺的组成部分,因此识别和理解人类情绪的能力已成为技术进步的一个重要方面。然而,人类的情感是生理、心理和社会因素的复杂交织,即使是人类也难以准确理解。随着语音助手和其他基于语音的应用的出现,改进基于音频的情感表达变得至关重要。然而,目前的情感注释实践缺乏具体性和一致性,许多人类注释的情感数据集对相同语音片段的标签相互矛盾就是证明。以往的研究不得不过滤掉这些冲突,因此收集到的数据中有很大一部分被认为是不可用的。在本研究中,我们旨在利用 IEMOCAP 情感数据集中的高置信度情感标签语音片段,提高不确定情感标签的计算预测准确度。我们使用音频词编码袋(BoAW)实现了基于音频的情感识别模型,从而通过最先进的递归神经网络模型获得了语音中情感音频方面的表征。我们的方法改进了最先进的基于音频的情感识别,准确率达到 61.09%,比 BiDialogueRNN 模型提高了 1.02%,比 EmoCaps 多模态情感识别模型提高了 1.72%。与人工注释相比,我们的方法在识别正面和负面情绪方面取得了相似的结果。此外,我们的方法还能准确识别不确定情绪片段的情感,这在其他研究中被认为是不可用的。音频情感识别的改进可能会对基于语音的助手、医疗保健和其他受益于自动通信的行业应用产生影响。
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引用次数: 0
The Measurement of Contrast Sensitivity in Near Vision: The Use of a Digital System vs. a Conventional Printed Test 近视对比敏感度的测量:数字系统与传统印刷测试的对比使用
Pub Date : 2024-07-09 DOI: 10.3390/technologies12070108
Kevin J Mena-Guevara, D. Piñero, María José Luque, D. de Fez
In recent years, there has been intense development of digital diagnostic tests for vision. All of these tests must be validated for clinical use. The current study enrolled 51 healthy individuals (age 19–72 years) in which achromatic contrast sensitivity function (CSF) in near vision was measured with the printed Vistech VCTS test (Stereo Optical Co., Inc., Chicago, IL, USA) and the Optopad-CSF (developed by our research group to be used on an iPad). Likewise, chromatic CSF was evaluated with a digital test. Statistically significant differences between tests were only found for the two higher spatial frequencies evaluated (p = 0.012 and <0.001, respectively). The mean achromatic index of contrast sensitivity (ICS) was 0.02 ± 1.07 and −0.76 ± 1.63 for the Vistech VCTS and Optopad tests, respectively (p < 0.001). The ranges of agreement between tests were 0.55, 0.76, 0.78, and 0.69 log units for the spatial frequencies of 1.5, 3, 6, and 12 cpd, respectively. The mean chromatic ICS values were −20.56 ± 0.96 and −0.16 ± 0.99 for the CSF-T and CSF-D plates, respectively (p < 0.001). Furthermore, better achromatic, red–green, and blue–yellow CSF values were found in the youngest groups. The digital test allows the fast measurement of near-achromatic and chromatic CSF using a colorimetrically calibrated iPad, but the achromatic measures cannot be used interchangeably with those obtained with a conventional printed test.
近年来,数字视力诊断测试得到了大力发展。所有这些测试都必须经过验证才能用于临床。本次研究共招募了 51 名健康人(年龄 19-72 岁),使用印刷版 Vistech VCTS 测试(立体光学公司,美国伊利诺斯州芝加哥市)和 Optopad-CSF(由我们的研究小组开发,可在 iPad 上使用)测量近视的消色差对比敏感度功能(CSF)。同样,色度 CSF 也是通过数字测试进行评估的。只有在评估的两个较高空间频率上,测试之间才存在统计学意义上的显著差异(分别为 p = 0.012 和 <0.001)。Vistech VCTS 和 Optopad 测试的平均消色差对比敏感度指数(ICS)分别为 0.02 ± 1.07 和 -0.76 ± 1.63(p < 0.001)。在空间频率为 1.5、3、6 和 12 cpd 时,测试间的一致性范围分别为 0.55、0.76、0.78 和 0.69 对数单位。CSF-T 和 CSF-D 平板的平均色度 ICS 值分别为 -20.56 ± 0.96 和 -0.16 ± 0.99(p < 0.001)。此外,最年轻组的消色差、红-绿和蓝-黄 CSF 值更好。数字测试可使用经过色度校准的 iPad 快速测量近消色差和色差 CSF,但消色差测量值不能与传统打印测试值互换使用。
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引用次数: 0
Numerical Simulation and Design of a Mechanical Structure of an Ankle Exoskeleton for Elderly People 老年人踝关节外骨骼机械结构的数值模拟与设计
Pub Date : 2024-07-09 DOI: 10.3390/technologies12070107
Ammir Rojas, Julio Ronceros, Carlos Raymundo, Gianpierre Zapata, Leonardo Vinces, Gustavo Ronceros
This article presents the numerical simulation and design of an ankle exoskeleton oriented to elderly users. For the design, anatomical measurements were taken from a user of this age group to obtain an ergonomic, resistant, and exceptionally reliable mechanical structure. In addition, the design was validated to support a “weight range” of users between 50 and 80 kg in order to evaluate the reaction of the mechanism within the range of loads generated in relation to the first principal stress, the safety coefficient, the Von Mises stress, and principal deformations, for which the 3D CAD software Autodesk Inventor and theoretical correlations were used to calculate the displacement and rotation angles of the ankle in the structure. Likewise, two types of materials were evaluated: ABS (acrylonitrile butadiene styrene) and a polymer reinforced with carbon fiber. Finally, the designed pieces were assembled with the guarantee that the mobility of the system had been validated through the numerical simulation environment, highlighting that by being generated through 3D printing, manufacturing costs are reduced, allowing them to be accessible and ensuring that more people can benefit from this ankle exoskeleton.
本文介绍了面向老年用户的踝关节外骨骼的数值模拟和设计。在设计过程中,对这一年龄段的用户进行了解剖学测量,以获得符合人体工程学、耐磨且异常可靠的机械结构。此外,还对设计进行了验证,以支持 "体重范围 "在 50 至 80 公斤之间的用户,从而评估机械装置在第一主应力、安全系数、Von Mises 应力和主变形等相关载荷范围内的反应,并使用三维 CAD 软件 Autodesk Inventor 和理论相关性来计算结构中脚踝的位移和旋转角度。同样,还对两种材料进行了评估:ABS(丙烯腈-丁二烯-苯乙烯)和碳纤维增强聚合物。最后,在通过数值模拟环境对系统的移动性进行验证的保证下,对设计的部件进行了组装,突出强调了通过三维打印生成,降低了制造成本,使其能够普及,并确保更多人能够受益于这种踝关节外骨骼。
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引用次数: 0
HUB3D: Intelligent Manufacturing HUB System HUB3D:智能制造 HUB 系统
Pub Date : 2024-07-09 DOI: 10.3390/technologies12070109
Antonio Trejo-Morales, E. Franco-Urquiza, Hansell David Devilet-Castellanos, Darío Bringas-Posadas
HUB3D represents a cutting-edge solution for managing and operating a 3D printer farm through the integration of advanced hardware and software. It features intuitive, responsive interfaces that support seamless interaction across various devices. Leveraging cloud services ensures the system’s stability, security, and scalability, enabling users from diverse locations to effortlessly upload and manage their 3D printing projects. The hardware component includes a purpose-built rack capable of housing up to four 3D printers, each synchronized and managed by a manipulator arm controlled via Raspberry Pi technology. This setup facilitates continuous operation and high automation, optimizing production efficiency and reducing downtime significantly. This integrated approach positions HUB3D at the forefront of additive manufacturing management. By combining robust hardware capabilities with sophisticated software functionalities and cloud integration, the system offers unparalleled advantages. It supports continuous manufacturing processes, enhances workflow efficiency, and enables remote monitoring and management of printing operations. Overall, HUB3D’s innovative design and comprehensive features cater to both individual users and businesses seeking to streamline 3D printing workflows. With scalability, automation, and remote accessibility at its core, HUB3D represents a pivotal advancement in modern manufacturing technology, promising increased productivity and operational flexibility in the realm of additive manufacturing.
HUB3D 是通过集成先进的硬件和软件来管理和操作 3D 打印机农场的尖端解决方案。它具有直观、反应灵敏的界面,支持各种设备之间的无缝交互。利用云服务确保了系统的稳定性、安全性和可扩展性,使来自不同地点的用户能够轻松上传和管理他们的三维打印项目。硬件组件包括一个专用机架,可容纳多达四台 3D 打印机,每台打印机都由一个通过 Raspberry Pi 技术控制的机械臂进行同步和管理。这种设置有利于连续运行和高度自动化,优化了生产效率,大大减少了停机时间。这种集成方法使 HUB3D 站在了快速成型制造管理的最前沿。通过将强大的硬件功能与复杂的软件功能和云集成相结合,该系统具有无与伦比的优势。它支持连续生产流程,提高了工作流程效率,并实现了对打印操作的远程监控和管理。总之,HUB3D 的创新设计和全面功能既能满足个人用户的需求,也能满足企业简化 3D 打印工作流程的需求。HUB3D 以可扩展性、自动化和远程可访问性为核心,代表了现代制造技术的重要进步,有望提高增材制造领域的生产率和操作灵活性。
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引用次数: 0
Securing Blockchain-Based Supply Chain Management: Textual Data Encryption and Access Control 确保基于区块链的供应链管理安全:文本数据加密和访问控制
Pub Date : 2024-07-09 DOI: 10.3390/technologies12070110
Imran Khan, Qazi Ejaz Ali, Hassan Jalil Hadi, Naveed Ahmad, Gauhar Ali, Yue Cao, M. Alshara
A supply chain (SC) encompasses a network of businesses, individuals, events, data, and resources orchestrating the movement of goods or services from suppliers to customers. Leveraging a blockchain-based platform, smart contracts play a pivotal role in aligning business logic and tracking progress within supply chain activities. Employing two distinct ledgers, namely Hyperledger and Ethereum, introduces challenges in handling the escalating volume of data and addressing the technical expertise gap related to supply chain management (SCM) tools in blockchain technology. Within the domain of blockchain-based SCM, the growing volume of data activities introduces challenges in the efficient regulation of data flow and the assurance of privacy. To tackle these challenges, a straightforward approach is recommended to manage data growth and thwart unauthorized entries or spam attempts within blockchain ledgers. The proposed technique focuses on validating hashes to ensure blockchain integrity. Emphasizing the authentication of sensitive data on the blockchain to bolster SCM, this approach compels applications to shoulder increased accountability. The suggested technique involves converting all data into textual format, implementing code encryption, and establishing permission-based access control. This strategy aims to address inherent weaknesses in blockchain within SCM. The results demonstrate the efficacy of the proposed technique in providing security and privacy for various types of data within SCM. Overall, the approach enhances the robustness of blockchain-based SCM, offering a comprehensive solution to navigate evolving challenges in data management and privacy assurance.
供应链(SC)包括一个由企业、个人、事件、数据和资源组成的网络,它协调着从供应商到客户的货物或服务的流动。利用基于区块链的平台,智能合约在调整业务逻辑和跟踪供应链活动进展方面发挥着关键作用。采用两个不同的分类账(即超级账本和以太坊),在处理不断增长的数据量和解决与区块链技术中供应链管理(SCM)工具相关的技术专业知识差距方面带来了挑战。在基于区块链的供应链管理(SCM)领域,不断增长的数据活动量给有效监管数据流和确保隐私带来了挑战。为应对这些挑战,建议采用一种直接的方法来管理数据增长,并挫败区块链分类账中的未经授权条目或垃圾邮件企图。所提出的技术侧重于验证哈希值,以确保区块链的完整性。这种方法强调对区块链上的敏感数据进行验证,以加强 SCM,从而迫使应用程序承担更多责任。建议的技术包括将所有数据转换为文本格式、实施代码加密和建立基于权限的访问控制。这一策略旨在解决区块链在单片机中的固有弱点。结果表明,所建议的技术在为供应链管理中的各类数据提供安全性和隐私性方面非常有效。总体而言,该方法增强了基于区块链的 SCM 的稳健性,为应对数据管理和隐私保证方面不断变化的挑战提供了全面的解决方案。
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引用次数: 0
Discovering Data Domains and Products in Data Meshes Using Semantic Blueprints 利用语义蓝图发现数据网格中的数据域和产品
Pub Date : 2024-07-07 DOI: 10.3390/technologies12070105
Michalis Pingos, Andreas S. Andreou
Nowadays, one of the greatest challenges in data meshes revolves around detecting and creating data domains and data products for providing the ability to adapt easily and quickly to changing business needs. This requires a disciplined approach to identify, differentiate and prioritize distinct data sources according to their content and diversity. The current paper tackles this highly complicated issue and suggests a standardized approach that integrates the concept of data blueprints with data meshes. In essence, a novel standardization framework is proposed that creates data products using a metadata semantic enrichment mechanism, the latter also offering data domain readiness and alignment. The approach is demonstrated using real-world data produced by multiple sources in a poultry meat production factory. A set of functional attributes is used to qualitatively compare the proposed approach to existing data structures utilized in storage architectures, with quite promising results. Finally, experimentation with different scenarios varying in data product complexity and granularity suggests a successful performance.
如今,数据网格面临的最大挑战之一是检测和创建数据域和数据产品,以便提供轻松快速地适应不断变化的业务需求的能力。这就需要采用严谨的方法,根据不同数据源的内容和多样性对其进行识别、区分和优先排序。本文针对这一高度复杂的问题,提出了一种将数据蓝图概念与数据网格相结合的标准化方法。从本质上讲,本文提出了一个新颖的标准化框架,利用元数据语义丰富机制创建数据产品,后者还提供数据域就绪和对齐功能。该方法利用一个禽肉生产工厂中多个来源产生的真实世界数据进行了演示。通过一组功能属性,将所提出的方法与存储架构中使用的现有数据结构进行了定性比较,结果相当不错。最后,在数据产品复杂度和粒度不同的情况下进行的实验表明,该方法性能良好。
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引用次数: 0
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