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Luminescent Gd2O3:Eu, NaGdF4:Eu, and NaGdF4:Ce/Eu Nanoparticles: Synthesis, Photophysical Properties, and Application for Enhanced Solar Cell Efficiency 发光Gd2O3:Eu、NaGdF4:Eu和NaGdF4:Ce/Eu纳米粒子:合成、光物理性质及其在提高太阳能电池效率中的应用
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714795
K. S. Zimin, R. M. Gataullina, J. R. Shayimova, L. A. Nurtdinova, A. G. Shmelev, D. K. Zharkov, A. N. Solodov, L. M. Amirova, E. O. Mityushkin, A. V. Leontyev, O. Kh. Khasanov, V. G. Nikiforov

Results of the synthesis and comprehensive characterization of rare earth oxide and fluoride nanoparticles Gd2O3:Eu3+, NaGdF4:Eu3+, and NaGdF4:Ce3+/Eu3+ are presented here. All nanoparticles were synthesized by thermal decomposition of organometallic precursors in high-boiling organic solvents. Structure, morphology and phase composition were studied using a wide range of physicochemical methods. It turned out that the introduction of Ce3+ with its allowed 4f–5d transitions promotes broadening of the excitation spectrum and significant enhancement of Eu3+ emission upon irradiation in the 254 nm region. Particular attention was paid to the study of energy transfer mechanisms, including the effect of Eu3+ ion concentration on the efficiency of cascade energy transfer along the Ce3+ → Gd3+ → Eu3+ channel. In order to assess the application potential, synthesized nanoparticles were encapsulated in a polyvinyl alcohol matrix and deposited on the surface of silicon solar cells. Resulting coating made it possible to increase the efficiency of photocurrent generation due to the spectral conversion of radiation from ultraviolet to visible spectral range.

本文介绍了稀土氧化物和氟化物纳米粒子Gd2O3:Eu3+、NaGdF4:Eu3+和NaGdF4:Ce3+/Eu3+的合成和综合表征结果。所有纳米颗粒都是通过在高沸点有机溶剂中热分解有机金属前驱体合成的。采用多种物理化学方法对其结构、形态和相组成进行了研究。结果表明,Ce3+的引入及其允许的4f-5d跃迁促进了激发光谱的拓宽,并在254 nm区域显著增强了Eu3+的辐射。重点研究了能量传递机理,包括Eu3+离子浓度对Ce3+→Gd3+→Eu3+通道级联能量传递效率的影响。为了评估其应用潜力,将合成的纳米颗粒包裹在聚乙烯醇基质中,并沉积在硅太阳能电池表面。由此产生的涂层可以提高光电流产生的效率,因为从紫外线到可见光谱范围的辐射的光谱转换。
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引用次数: 0
Exact Solution for One-Dimensional Spin Models with Markov Property 具有马尔可夫性质的一维自旋模型的精确解
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714655
Yu. D. Panov

For one-dimensional spin and pseudospin models that allow mapping to a Markov chain, the free energy of the system at a finite temperature can be expressed in terms of bond concentrations. Minimizing the free energy function makes it possible to obtain an exact solution of a statistical model. A dilute Ising chain with interacting impurities is considered as an example.

对于允许映射到马尔可夫链的一维自旋和伪自旋模型,系统在有限温度下的自由能可以用键浓度来表示。使自由能函数最小化使统计模型的精确解成为可能。以具有相互作用的杂质的稀伊辛链为例。
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引用次数: 0
Hydroxyapatite with Substitution of Calcium Cations by Magnetic Iron Ions 磁性铁离子取代钙离子的羟基磷灰石
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714679
V. S. Bystrov, E. V. Paramonova, S. V. Makarova, N. V. Bulina

The results of calculations of the calcium cations substitution by iron in hydroxyapatite lattice using density functional theory methods are presented. Changes in the unit cell parameters and unit cell volume, the energy bands, and the magnetic properties with increasing number of substitutions in different calcium positions and for various charge of iron ions were analyzed in comparison with experimental data. The arisen magnetic properties of Fe-HAP are proportional to the amount of Fe introduced and energy levels Ei, filled by spin-up and spin-down electrons in different ratios.

本文介绍了用密度泛函方法计算羟基磷灰石晶格中钙离子被铁取代的结果。通过与实验数据的比较,分析了随着不同钙离子位置取代次数的增加和不同铁离子电荷的增加,单元胞参数、单元胞体积、能带和磁性能的变化。Fe- hap的磁性与Fe的引入量和Ei的能级成正比,由不同比例的自旋向上和自旋向下的电子填充。
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引用次数: 0
Creation of the Cogged Charged Domain Wall by Local Switching in Lithium Niobate 利用铌酸锂的局部开关产生锯齿状带电畴壁
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714722
A. P. Turygin, E. D. Greshnyakov, A. R. Akhmatkhanov, V. Ya. Shur

We have studied experimentally the shape evolution of the interacting initial head-to-head (h2h) and tail-to-tail (t2t) charged domain walls (CDW) and growing isolated domain in the Y-cut LiNbO3 plates. The wedge-like domains were created and grew by electric field application using biased tip of scanning probe microscope. Two h2h and one t2t initial CDWs have been produced during phase transition in the crystal with composition gradients created by in-diffusion and out-diffusion of Li. The formation and growth of cogged CDW has been revealed for domain interaction with t2t CDW in contrast to h2h CDW. Near the t2t CDW domain elongation is slowed down, while the widening of the domain part with neutral walls continues. The growth anisotropy leads to formation of the region with increased local tilt and formation of cogged CDW by generation of additional spikes. The obtained effects were considered in terms of kinetic approach to domain wall motion considering abnormal local field distribution in the vicinity of initial CDW with effectively screened depolarization field. The discovered effect can be considered for domain wall engineering thus paving the way for manufacturing of the nanoelectronics devices based on the CDWs.

实验研究了y型切割LiNbO3板中初始头对头(h2h)和尾对尾(t2t)带电畴壁(CDW)和生长隔离畴的形状演变。利用扫描探针显微镜的偏置针尖施加电场,形成并生长楔形畴。在晶体相变过程中产生了两个h2h和一个t2t初始CDWs,其组成梯度由Li的内扩散和外扩散引起。与h2h CDW相比,cogged CDW的形成和生长与t2t CDW的结构域相互作用已被揭示。在t2t附近,CDW区域的伸长率减慢,而中性壁区域的加宽仍在继续。生长各向异性导致局部倾斜增加区域的形成,并通过产生额外的尖峰形成锯齿状的CDW。在有效筛选退极化场的情况下,考虑初始CDW附近异常的局部场分布,用动力学方法考虑畴壁运动的影响。该效应可用于畴壁工程,从而为基于cdw的纳米电子器件的制造铺平道路。
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引用次数: 0
Near-Electrode Processes in LiNbO3 Crystals with Different Domain Structures 不同畴结构LiNbO3晶体的近电极工艺
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714680
V. E. Umylin, N. S. Kozlova, E. V. Zabelina, A. A. Mololkin, A. V. Korchagin, D. A. Kiselev, T. S. Ilina

The influence of conductive coating materials on the magnitude of short-circuit currents (SCC) in single-domain and polydomain Z-cut polar lithium niobate (LiNbO3) crystals is investigated. The domain structure of the samples was determined by piezoresponse force microscopy (PFM) using a probe microscope. Indium and silver symmetrical (identical) coatings were used for the study. Temperature dependences of SCC were measured using a hardware complex with special software in the temperature range from room to 350°C at a rate of 2 deg/min in air without applying an external electric field. Even at room temperature the SCC are observed on all investigated samples. The direction of the SCC flow depends on the conductive coating material, and the domain structure influences the current magnitude during heating. The current flow was in the positive direction for In conductive coatings and in the negative direction for Ag conductive coatings. In the single-domain samples observed higher currents than those in polydomain ones. The surface of the conductive coatings before and after heating was investigated using an optical microscope. Significant changes in the structure and color of the conductive coatings are observed. The obtained data demonstrate a significant dependence of SCC on the type of domain structure and the material of conductive coatings, which is important to consider when developing stable piezoelectric devices operating in a wide temperature range.

研究了导电涂层材料对单畴和多畴z切割极性铌酸锂晶体中短路电流(SCC)大小的影响。采用探针显微镜压响应力显微镜(PFM)测定了样品的畴结构。铟和银对称(相同)涂层用于研究。在室温至350℃的温度范围内,在空气中以2度/分钟的速率测量SCC的温度依赖性,而不施加外电场。即使在室温下,在所有被调查的样品上也观察到SCC。导电涂层材料决定了SCC的流动方向,畴结构影响了加热过程中电流的大小。in导电镀层的电流为正方向,Ag导电镀层的电流为负方向。在单畴样品中观察到的电流比在多畴样品中观察到的电流高。用光学显微镜观察了导电涂层加热前后的表面形貌。观察到导电涂层的结构和颜色发生了显著变化。得到的数据表明,SCC与畴结构的类型和导电涂层的材料有很大的关系,这是开发在宽温度范围内工作的稳定压电器件时需要考虑的重要因素。
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引用次数: 0
Density Dependent Hyperonic Interactions in Neutron Stars 中子星中依赖密度的超子相互作用
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714801
S. A. Mikheev, D. E. Lanskoy, A. I. Nasakin, S. V. Sidorov, T. Yu. Tretyakova

Influence of density dependent hyperon–nucleon forces on characteristics of neutron stars is investigated. In particular, the role of the exponent γ, determining the dependence of interaction on the nucleon density, in the description of the matter of neutron stars is studied. It is also shown that the hyperon–nucleon forces proportional to the nucleon density and three-body hyperon–nucleon–nucleon forces can lead to qualitatively different results in neutron stars.

研究了密度相关的超子-核子力对中子星特性的影响。特别地,研究了γ指数在描述中子星物质时的作用,它决定了相互作用对核子密度的依赖。结果还表明,与核子密度成正比的超子-核子力和三体超子-核子-核子力在中子星中会导致质量不同的结果。
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引用次数: 0
Current Issues in Nuclear Physics, Elementary Particle Physics, and Nuclear Physical Technologies (Report on the Nucleus 2025 International Conference) 核物理、基本粒子物理与核物理技术的现状(核2025国际会议报告)
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-02-02 DOI: 10.1134/S1062873825714771
G. A. Feofilov, S. Yu. Torilov, A. K. Vlasnikov, V. I. Zherebchevsky

We provided an overview of the reports presented at the 75th International Conference “Nucleus-2025: Nuclear Physics, Elementary Particle Physics, and Nuclear Technologies,” which took place in St. Petersburg from July 1 to 6, 2025. The program covered nuclear structure, nuclear reactions, astrophysics, neutrino, high energy and particle physics, nuclear technologies. Emphasis was placed on medical, energy, radioecology and materials applications, demonstrating the growing interdisciplinary impact of nuclear science.

我们提供了在2025年7月1日至6日在圣彼得堡举行的第75届国际会议“核子-2025:核物理学,基本粒子物理学和核技术”上提交的报告的概述。该计划涵盖核结构、核反应、天体物理学、中微子、高能和粒子物理、核技术。重点放在医疗、能源、放射生态学和材料应用上,显示出核科学日益增长的跨学科影响。
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引用次数: 0
Influence of an Axial Magnetic Field on the Charged Particle Flow from a Conical Cathode in a Gas under Space-Charge-Limited Current Conditions 轴向磁场对空间电荷限制条件下气体中锥形阴极带电粒子流动的影响
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-01-13 DOI: 10.1134/S1062873825714345
M. A. Belyaev, N. M. Zubarev, O. V. Zubareva

The influence of a uniform axial magnetic field on the drift of charged particles from the apex of a conical cathode in the surrounding gas is studied. A self-consistent analytical model is developed to describe this influence within the space-charge-limited current regime. Assuming the shape of the drift region to be conical, it is possible to determine the dependence of its opening angle on the electrode angle, the magnitude of the applied magnetic field, and the mobility of charge carriers.

研究了均匀轴向磁场对锥形阴极顶端带电粒子在周围气体中漂移的影响。建立了一个自洽分析模型来描述空间电荷有限电流状态下的这种影响。假设漂移区域的形状为圆锥形,则可以确定其开口角与电极角度、外加磁场大小和载流子迁移率的关系。
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引用次数: 0
Contraction of Self-Sustained Subnanosecond Discharge 自持续亚纳秒放电的收缩
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-01-13 DOI: 10.1134/S1062873825714382
S. N. Ivanov, V. V. Lisenkov

The glow accompanying a self-sustained subnanosecond discharge in nitrogen in the pressure range from 4 to 15 atm was recorded using the streak method. Breakdown delay time and pulse breakdown voltage of the discharge gap were recorded oscillographically. The experiments were carried out in uniform and non-uniform average electric fields. In these cases, the macro geometry of the discharge gap did not provide an increase in the electric field to the value necessary for the implementation of the electron runaway mode according to the classical runaway criterion. It is shown that at the initial stage of development, the discharge has a volumetric shape, which later turns into a spark. The discharge contraction, as a rule, begins from the cathode and the anode almost simultaneously. The conducted modeling of the dynamics of ionization processes showed that at the stage of the volumetric column formation, a short-term increase in the electric field near the anode occurs. As a result, the ionization of gas in the anode region increases sharply, which initiates the development of a spark channel, including from the anode.

在4 ~ 15atm的压力范围内,用条纹法记录了在氮气中自持续亚纳秒放电的辉光。用示波器记录了放电间隙的击穿延时时间和脉冲击穿电压。实验分别在均匀电场和非均匀电场条件下进行。在这些情况下,放电间隙的宏观几何形状并没有使电场增加到根据经典失控准则实现电子失控模式所必需的值。结果表明,在放电发展的初始阶段,放电具有体积形状,随后转变为火花。通常,放电收缩几乎同时从阴极和阳极开始。对电离过程的动力学模拟表明,在体积柱形成阶段,阳极附近的电场会出现短期的增大。结果,阳极区域的气体电离急剧增加,这引发了火花通道的发展,包括从阳极。
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引用次数: 0
Numerical Simulation of the Shock Wave Propagation in the Discharge Chamber with Megaampere Discharge in High Density Gas 高密度气体中兆安放电腔内冲击波传播的数值模拟
IF 0.48 Q4 Physics and Astronomy Pub Date : 2026-01-13 DOI: 10.1134/S1062873825714527
J. V. Triaskin, A. V. Budin, M. E. Pinchuk, N. V. Tryaskin, A. A. Bogomaz

Numerical simulation of the shock wave propagation in the discharge chamber with the high-current discharge in high density hydrogen at initial pressure of 0.1–32 MPa under non-stationary energy release at current rise of rate of 10 GA/s was carried out by the finite-differences method. The source of the disturbance (shock wave) was a forming discharge channel in the interelectrode gap along the axis of the cylindrical chamber. The power disturbance of the source was given by the experimental power value in near-axis area.

采用有限差分法对初始压力为0.1 ~ 32 MPa、电流上升速率为10 GA/s、能量释放不平稳条件下高密度氢气大电流放电腔内激波传播进行了数值模拟。扰动(激波)的来源是沿圆柱形腔室轴线在电极间隙形成的放电通道。源的功率扰动由近轴区域的实验功率值给出。
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引用次数: 0
期刊
Bulletin of the Russian Academy of Sciences: Physics
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