Abstract With the rapid development of underwater space construction, the theoretical research is at the initial stage. At present, the theoretical research methods mainly include mirror image method and conformal transformation method. At present, almost all the research objects in analytical research are homogeneous soil layers. However, in practical engineering, soil layers are often distributed in layers. In this study, the seepage field of layered soil layers is analyzed, and the analytical derivation method of seepage field in heterogeneous media based on traditional conformal transformation method is given, which is verified by numerical simulation. The hydraulic head loss of the medium with better permeability in shallow layer is very small, and the streamline is vertically distributed. In the weak interlayer, the hydraulic head loss is huge, and the streamline bends greatly, showing a strong horizontal distribution and converging towards the center. It can provide theoretical basis for the design of water and soil pressure in practical engineering.
{"title":"Study on the risk of seepage field of Qiantang River underground space excavated in water-rich rheological rock area","authors":"Tianjiao Zhang","doi":"10.1515/arh-2022-0155","DOIUrl":"https://doi.org/10.1515/arh-2022-0155","url":null,"abstract":"Abstract With the rapid development of underwater space construction, the theoretical research is at the initial stage. At present, the theoretical research methods mainly include mirror image method and conformal transformation method. At present, almost all the research objects in analytical research are homogeneous soil layers. However, in practical engineering, soil layers are often distributed in layers. In this study, the seepage field of layered soil layers is analyzed, and the analytical derivation method of seepage field in heterogeneous media based on traditional conformal transformation method is given, which is verified by numerical simulation. The hydraulic head loss of the medium with better permeability in shallow layer is very small, and the streamline is vertically distributed. In the weak interlayer, the hydraulic head loss is huge, and the streamline bends greatly, showing a strong horizontal distribution and converging towards the center. It can provide theoretical basis for the design of water and soil pressure in practical engineering.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46943741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yanlin Zhao, Xiaguang Wang, Wenyu Tang, Yang Li, Hang Lin, Yixian Wang, Lianyang Zhang
Abstract This paper presents an extensive laboratory investigation of layered salt rocks under triaxial loading and unloading cycles aiming to better understand their viscoelastic plasticity strain characteristics. Specifically, creep curves were obtained from the triaxial loading and unloading tests and analyzed using the Burgers model. The microstructure of the layered salt rocks before and after the creep test was comparatively analyzed using the dry grinding optical diagram. The results show that the creep deformation of layered salt rocks is mainly viscoelastic under a low deviatoric stress and contains both viscoelastic and viscoplastic deformations when the deviatoric stress is high. With the increase of deviatoric stress, both the instantaneous elastic and plastic strains increase, and the increasing rate becomes lower as the deviatoric stress increases. The creep curves of layered salt rocks can be well represented with the Burgers model. Since the creep leads to fracturing and interlayer rupturing and producing new fluid seepage channels in layered salt rocks, this study has great value for understanding the long-term performance of gas and hydrocarbon liquid storage caverns in layered salt rock formation.
{"title":"Creep behavior of layered salt rock under triaxial loading and unloading cycles","authors":"Yanlin Zhao, Xiaguang Wang, Wenyu Tang, Yang Li, Hang Lin, Yixian Wang, Lianyang Zhang","doi":"10.1515/arh-2023-0103","DOIUrl":"https://doi.org/10.1515/arh-2023-0103","url":null,"abstract":"Abstract This paper presents an extensive laboratory investigation of layered salt rocks under triaxial loading and unloading cycles aiming to better understand their viscoelastic plasticity strain characteristics. Specifically, creep curves were obtained from the triaxial loading and unloading tests and analyzed using the Burgers model. The microstructure of the layered salt rocks before and after the creep test was comparatively analyzed using the dry grinding optical diagram. The results show that the creep deformation of layered salt rocks is mainly viscoelastic under a low deviatoric stress and contains both viscoelastic and viscoplastic deformations when the deviatoric stress is high. With the increase of deviatoric stress, both the instantaneous elastic and plastic strains increase, and the increasing rate becomes lower as the deviatoric stress increases. The creep curves of layered salt rocks can be well represented with the Burgers model. Since the creep leads to fracturing and interlayer rupturing and producing new fluid seepage channels in layered salt rocks, this study has great value for understanding the long-term performance of gas and hydrocarbon liquid storage caverns in layered salt rock formation.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135401221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Traditional rigorous limit equilibrium methods satisfy all equilibrium conditions and usually have high accuracy, however, which are less efficient for slope reliability analysis. The main reason is that the limit state functions are highly nonlinear implicit functions of safety factor. Complex numerical iterations are required, which may sometimes lead to computational convergence problems. A new method for computing slope reliability calculation with high efficiency and accuracy was proposed. This method was based on the rigorous limit equilibrium method by modifying normal stresses over the slip surface. The critical horizontal acceleration factor K c {K}_{c} , which can be expressed explicitly, was used to replace the implicit safety factor as a representation of slope stability. The difference between K c {K}_{c} and the known value K c 0 {K}_{c0} was used as the limit state function. Two slope examples were analyzed. The results showed that the calculation results of this method were in good agreement with those of the traditional Morgenstern–Price limit equilibrium method, but the computational efficiency was significantly improved. When this method was combined with the subset simulation method, the calculation time was only a few seconds. Therefore, this method can be used for rapid calculation of slope reliability.
传统的严格极限平衡法满足所有平衡条件，精度较高，但在边坡可靠度分析中效率较低。主要原因是极限状态函数是安全系数的高度非线性隐式函数。需要复杂的数值迭代，这有时可能导致计算收敛问题。提出了一种高效、准确的边坡可靠度计算新方法。该方法基于修正滑移面法向应力的严格极限平衡法。用可显式表示的临界水平加速度系数K c {K}_{c}代替隐式安全系数作为边坡稳定性的表征。取K c {K}_{c}与已知值K c0 {K}_{c}之差作为极限状态函数。分析了两个斜率算例。结果表明，该方法的计算结果与传统的Morgenstern-Price极限均衡法的计算结果吻合较好，但计算效率明显提高。当该方法与子集模拟方法相结合时，计算时间仅为几秒。因此，该方法可用于边坡可靠度的快速计算。
{"title":"An efficient method for computing slope reliability calculation based on rigorous limit equilibrium","authors":"Juxiang Chen, Da-yong Zhu, Yalin Zhu","doi":"10.1515/arh-2022-0147","DOIUrl":"https://doi.org/10.1515/arh-2022-0147","url":null,"abstract":"Abstract Traditional rigorous limit equilibrium methods satisfy all equilibrium conditions and usually have high accuracy, however, which are less efficient for slope reliability analysis. The main reason is that the limit state functions are highly nonlinear implicit functions of safety factor. Complex numerical iterations are required, which may sometimes lead to computational convergence problems. A new method for computing slope reliability calculation with high efficiency and accuracy was proposed. This method was based on the rigorous limit equilibrium method by modifying normal stresses over the slip surface. The critical horizontal acceleration factor K c {K}_{c} , which can be expressed explicitly, was used to replace the implicit safety factor as a representation of slope stability. The difference between K c {K}_{c} and the known value K c 0 {K}_{c0} was used as the limit state function. Two slope examples were analyzed. The results showed that the calculation results of this method were in good agreement with those of the traditional Morgenstern–Price limit equilibrium method, but the computational efficiency was significantly improved. When this method was combined with the subset simulation method, the calculation time was only a few seconds. Therefore, this method can be used for rapid calculation of slope reliability.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44996915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract It is favorable to re-evaluate the seismic hazard for a given territory, since in the course of time new methods are developed and new data are gathered that can enable more sophisticated (physically sound) and reliable assessment of the seismic hazard. Therefore, it is mandatory to re-evaluate the seismic hazard for Kosovo, considering the seismic sources in Kosovo. The data of this article influence the reduction of seismic risk for the territory of Kosovo.
{"title":"Seismic hazard analysis by neo-deterministic seismic hazard analysis approach (NDSHA) for Kosovo","authors":"Nazmi Hasi, Latif Hasi, N. Syla, Arber Zeqiraj","doi":"10.1515/arh-2022-0137","DOIUrl":"https://doi.org/10.1515/arh-2022-0137","url":null,"abstract":"Abstract It is favorable to re-evaluate the seismic hazard for a given territory, since in the course of time new methods are developed and new data are gathered that can enable more sophisticated (physically sound) and reliable assessment of the seismic hazard. Therefore, it is mandatory to re-evaluate the seismic hazard for Kosovo, considering the seismic sources in Kosovo. The data of this article influence the reduction of seismic risk for the territory of Kosovo.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42485715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract According to the deep foundation pit project of Xiaoxihu station on Lanzhou subway Line 1, the three-dimensional finite-element model of the half-cover excavation method of retaining structure is established to simulate the construction of the excavation of the foundation pit. This article analyzes the settling of the surrounding surface, the horizontal displacement and vertical displacement of the retaining pile, the vertical displacement of the shoring column, and the change of the axial force of the inner support and compares them with the actual monitoring data. The results show that for the collapsible loess strata in Lanzhou, the design of retaining pile and inner support is viable. The support form has a good control effect on the deformation of the foundation pit. It keeps the foundation pit stable. The numerical simulation results are more consistent with the actual monitoring data. It provides a basis for the scientific design and construction of a deep foundation pit in the Lanzhou metro station.
{"title":"Deformation rules of deep foundation pit of a subway station in Lanzhou collapsible loess stratum","authors":"Yaxiong Liang, Shuaihua Ye, Yiguan Huang","doi":"10.1515/arh-2023-0107","DOIUrl":"https://doi.org/10.1515/arh-2023-0107","url":null,"abstract":"Abstract According to the deep foundation pit project of Xiaoxihu station on Lanzhou subway Line 1, the three-dimensional finite-element model of the half-cover excavation method of retaining structure is established to simulate the construction of the excavation of the foundation pit. This article analyzes the settling of the surrounding surface, the horizontal displacement and vertical displacement of the retaining pile, the vertical displacement of the shoring column, and the change of the axial force of the inner support and compares them with the actual monitoring data. The results show that for the collapsible loess strata in Lanzhou, the design of retaining pile and inner support is viable. The support form has a good control effect on the deformation of the foundation pit. It keeps the foundation pit stable. The numerical simulation results are more consistent with the actual monitoring data. It provides a basis for the scientific design and construction of a deep foundation pit in the Lanzhou metro station.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":"16 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136209824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guangchen Sun, Wen-chen Fan, Helin Fu, Shan He, Hao Shen, S. Yin, Peng Yin, Xueyi Wang
Abstract In order to investigate the dynamic response characteristics and damage mechanism of the tunnel lining at the tunnel portal in the bridge–tunnel overlapping section in soft rock strata, a physical model with the scale ratio of 1:50 was made based on the similarity theory for shaking table tests. The acceleration and strain results of the tunnel lining under EL Centro seismic waves with different acceleration peak values were studied. Test results show that most of the acceleration values have significant amplification effects compared to input seismic waves, which increased significantly with greater peak values and elevations. Tensile deformations appear along the longitudinal and the circumferential directions of the tunnel lining. The tunnel spandrel and tunnel vault are the maximum deformation parts, respectively, at the standard section and the enlarged section of the tunnel lining. Therefore, it is suggested that the longitudinal anti-tensile design of the tunnel lining at the tunnel portal in such sensitive environments should be strengthened. And the anti-seismic design standard and durability requirement of the standard section of the tunnel lining adjacent to the enlarged section should be improved, so as to meet the requirements for stress deformation and overall stability when subjected to severe earthquakes.
{"title":"Seismic response and damage mechanism of tunnel lining in sensitive environment of soft rock stratum","authors":"Guangchen Sun, Wen-chen Fan, Helin Fu, Shan He, Hao Shen, S. Yin, Peng Yin, Xueyi Wang","doi":"10.1515/arh-2022-0141","DOIUrl":"https://doi.org/10.1515/arh-2022-0141","url":null,"abstract":"Abstract In order to investigate the dynamic response characteristics and damage mechanism of the tunnel lining at the tunnel portal in the bridge–tunnel overlapping section in soft rock strata, a physical model with the scale ratio of 1:50 was made based on the similarity theory for shaking table tests. The acceleration and strain results of the tunnel lining under EL Centro seismic waves with different acceleration peak values were studied. Test results show that most of the acceleration values have significant amplification effects compared to input seismic waves, which increased significantly with greater peak values and elevations. Tensile deformations appear along the longitudinal and the circumferential directions of the tunnel lining. The tunnel spandrel and tunnel vault are the maximum deformation parts, respectively, at the standard section and the enlarged section of the tunnel lining. Therefore, it is suggested that the longitudinal anti-tensile design of the tunnel lining at the tunnel portal in such sensitive environments should be strengthened. And the anti-seismic design standard and durability requirement of the standard section of the tunnel lining adjacent to the enlarged section should be improved, so as to meet the requirements for stress deformation and overall stability when subjected to severe earthquakes.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41764642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yating Mao, M. Tan, T. Kohs, J. Sylman, A. Ngo, C. Puy, O. McCarty, T. Walker
Abstract The maintenance of hemostasis to ensure vascular integrity is dependent upon the rapid conversion of zymogen species of the coagulation cascade to their enzymatically active forms. This process culminates in the generation of the serine protease thrombin and polymerization of fibrin to prevent vascular leak at sites of endothelial cell injury or loss of cellular junctions. Thrombin generation can be initiated by the extrinsic pathway of coagulation through exposure of blood to tissue factor at sites of vascular damage, or alternatively by the coagulation factor (F) XII activated by foreign surfaces with negative charges, such as glass, through the contact activation pathway. Here, we used transient particle tracking microrheology to investigate the mechanical properties of fibrin in response to thrombin generation downstream of both coagulation pathways. We found that the structural heterogeneity of fibrin formation was dependent on the reaction kinetics of thrombin generation. Pharmacological inhibition of FXII activity prolonged the time to form fibrin and increased the degree of heterogeneity of fibrin, resulting in fibrin clots with reduced mechanical properties. Taken together, this study demonstrates a dependency of the physical biology of fibrin formation on activation of the contact pathway of coagulation.
{"title":"Transient particle tracking microrheology of plasma coagulation via the intrinsic pathway","authors":"Yating Mao, M. Tan, T. Kohs, J. Sylman, A. Ngo, C. Puy, O. McCarty, T. Walker","doi":"10.1515/arh-2022-0129","DOIUrl":"https://doi.org/10.1515/arh-2022-0129","url":null,"abstract":"Abstract The maintenance of hemostasis to ensure vascular integrity is dependent upon the rapid conversion of zymogen species of the coagulation cascade to their enzymatically active forms. This process culminates in the generation of the serine protease thrombin and polymerization of fibrin to prevent vascular leak at sites of endothelial cell injury or loss of cellular junctions. Thrombin generation can be initiated by the extrinsic pathway of coagulation through exposure of blood to tissue factor at sites of vascular damage, or alternatively by the coagulation factor (F) XII activated by foreign surfaces with negative charges, such as glass, through the contact activation pathway. Here, we used transient particle tracking microrheology to investigate the mechanical properties of fibrin in response to thrombin generation downstream of both coagulation pathways. We found that the structural heterogeneity of fibrin formation was dependent on the reaction kinetics of thrombin generation. Pharmacological inhibition of FXII activity prolonged the time to form fibrin and increased the degree of heterogeneity of fibrin, resulting in fibrin clots with reduced mechanical properties. Taken together, this study demonstrates a dependency of the physical biology of fibrin formation on activation of the contact pathway of coagulation.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":"33 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41720626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In this study, the feasibility of the trigeneration system, which is one of the on-site energy production methods, was determined for Kocaeli University Umuttepe Campus, exergy and energy analyses were made for each point of the system and exergy destruction in the lines was found. The key point of the gains, losses, and efficiency analyses in the lines are presented with engineering solutions and thermodynamic proofs. The seasonal mathematical models covering the whole of the feasibility of the trigeneration system were carried out and the energy and equilibrium equations of the entire system were established. In addition, energy and exergy analysis, 2nd law efficiency, coefficient of performance (COP), and thermal efficiency were calculated for all the systems. The seasonal numerical analyses of the system have been prepared so that it can work effectively in two different working disciplines separately for summer and winter seasons. Thanks to these numerical analyses that are mentioned, the seasonal exergic destructions of the system are found, seasonal working methods are shown, and working conditions and operating load values suitable for the current season are determined. In addition, in the light of the technical studies mentioned above, both the hourly energy capacities and hourly consumption values that the university will produce after trigeneration have been compared by performing separate mathematical models for summer and winter modes. Thus, it has been aimed to reduce the energy production costs by selling the excess energy to the mains. It is for this reason that it is aimed to reduce the energy production costs of the country, to reduce foreign dependency to meet energy demand, to present both a ready to apply feasibility report to investors and a ready to use design of a medium-sized power plant that will set an example of trigeneration studies in academic terms. In today’s practical applications, it is known that the system efficiency of trigeneration systems can be between 70 and 80%. In the light of the studies, 66% exergic efficiency in winter, thermal efficiency of 0.87411 with 2.05 MW thermal capacity, 63% exergic efficiency in summer, COP of 0.82 with 1.5 MW cooling capacity, and 2.02 MWe instantaneous electrical power was found in summer and winter. It was decided that the system could be a facility that is technically open to development and worth establishing in the light of the exergic and energetic analyses results obtained in this study and the exergic system efficiency comparisons made in the literature. In this study, attention was drawn to the importance of exergy and energy analyses in deciding the installation of a trigeneration system, and it was shown that exergic and energetic analyses played a key role in the verification of decision mechanisms. In order to give an idea for other studies in the literature, it is aimed to draw attention to the need to perform seasonal exergy and energy analyses of th
{"title":"Exergy–energy analysis for a feasibility trigeneration system at Kocaeli University Umuttepe Campus","authors":"Ebru Kolay Kadıoğlu, M. Altınay","doi":"10.1515/arh-2022-0146","DOIUrl":"https://doi.org/10.1515/arh-2022-0146","url":null,"abstract":"Abstract In this study, the feasibility of the trigeneration system, which is one of the on-site energy production methods, was determined for Kocaeli University Umuttepe Campus, exergy and energy analyses were made for each point of the system and exergy destruction in the lines was found. The key point of the gains, losses, and efficiency analyses in the lines are presented with engineering solutions and thermodynamic proofs. The seasonal mathematical models covering the whole of the feasibility of the trigeneration system were carried out and the energy and equilibrium equations of the entire system were established. In addition, energy and exergy analysis, 2nd law efficiency, coefficient of performance (COP), and thermal efficiency were calculated for all the systems. The seasonal numerical analyses of the system have been prepared so that it can work effectively in two different working disciplines separately for summer and winter seasons. Thanks to these numerical analyses that are mentioned, the seasonal exergic destructions of the system are found, seasonal working methods are shown, and working conditions and operating load values suitable for the current season are determined. In addition, in the light of the technical studies mentioned above, both the hourly energy capacities and hourly consumption values that the university will produce after trigeneration have been compared by performing separate mathematical models for summer and winter modes. Thus, it has been aimed to reduce the energy production costs by selling the excess energy to the mains. It is for this reason that it is aimed to reduce the energy production costs of the country, to reduce foreign dependency to meet energy demand, to present both a ready to apply feasibility report to investors and a ready to use design of a medium-sized power plant that will set an example of trigeneration studies in academic terms. In today’s practical applications, it is known that the system efficiency of trigeneration systems can be between 70 and 80%. In the light of the studies, 66% exergic efficiency in winter, thermal efficiency of 0.87411 with 2.05 MW thermal capacity, 63% exergic efficiency in summer, COP of 0.82 with 1.5 MW cooling capacity, and 2.02 MWe instantaneous electrical power was found in summer and winter. It was decided that the system could be a facility that is technically open to development and worth establishing in the light of the exergic and energetic analyses results obtained in this study and the exergic system efficiency comparisons made in the literature. In this study, attention was drawn to the importance of exergy and energy analyses in deciding the installation of a trigeneration system, and it was shown that exergic and energetic analyses played a key role in the verification of decision mechanisms. In order to give an idea for other studies in the literature, it is aimed to draw attention to the need to perform seasonal exergy and energy analyses of th","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47457079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sabrina Benmebarek, Sabiha Anas Boussaa, Imad Eddine Benmebarek, M. Boudraa, H. Merazig
Abstract It is well known that sulfonamide derivatives, through exchange of different functional groups without modification of the –S(O)2N(H)– function, can exhibit a wide variety of pharmacological activities. In addition, some metal complexes of these ligands have been prepared to promote rapid healing of burns in humans and animals, for example, the complex of Zn(ii) sulfadiazine. Their effectiveness does not depend solely on the slow release of the metal ion, but rather strongly on the nature of the material to which the metal is bound. Given the ability of sulfonamide derivatives to coordinate with metal atoms in different ways, considerable interest in the synthesis and structural aspects of new complexes has arisen. These results confirm that the significant chemical capacity of sulfonamides to act as ligands is based on the acidity of its –S(O)2N(H)– function, which gives a donor anionic ligand, allied to the presence of atoms vicinal to nitrogen, sulfur or oxygen of the heterocyclic ring, which provide the stereochemical requirements for the realization of complexes with monodentate ligand, chelating agent or bridging ligand, providing monomeric structures, dimeric arrangements and polymers. In addition, the aromatic amino group is responsible for the chemical versatility of the sulfonamides, since it can act as a coordination site, as well as a reactive site for chemical modifications of sulfonamide complexes with very interesting biological purposes. In the present work, the synthesis and structure of a novel sulfanilamide complex: nitro (4-aminobenzenesulfonamide) zirconium was presented. Characterization of the complex was performed by infrared spectroscopic, thermogravimetric and X-ray diffraction analysis.
{"title":"Synthesis and characterization of a new complex based on antibiotic: Zirconium complex","authors":"Sabrina Benmebarek, Sabiha Anas Boussaa, Imad Eddine Benmebarek, M. Boudraa, H. Merazig","doi":"10.1515/arh-2022-0142","DOIUrl":"https://doi.org/10.1515/arh-2022-0142","url":null,"abstract":"Abstract It is well known that sulfonamide derivatives, through exchange of different functional groups without modification of the –S(O)2N(H)– function, can exhibit a wide variety of pharmacological activities. In addition, some metal complexes of these ligands have been prepared to promote rapid healing of burns in humans and animals, for example, the complex of Zn(ii) sulfadiazine. Their effectiveness does not depend solely on the slow release of the metal ion, but rather strongly on the nature of the material to which the metal is bound. Given the ability of sulfonamide derivatives to coordinate with metal atoms in different ways, considerable interest in the synthesis and structural aspects of new complexes has arisen. These results confirm that the significant chemical capacity of sulfonamides to act as ligands is based on the acidity of its –S(O)2N(H)– function, which gives a donor anionic ligand, allied to the presence of atoms vicinal to nitrogen, sulfur or oxygen of the heterocyclic ring, which provide the stereochemical requirements for the realization of complexes with monodentate ligand, chelating agent or bridging ligand, providing monomeric structures, dimeric arrangements and polymers. In addition, the aromatic amino group is responsible for the chemical versatility of the sulfonamides, since it can act as a coordination site, as well as a reactive site for chemical modifications of sulfonamide complexes with very interesting biological purposes. In the present work, the synthesis and structure of a novel sulfanilamide complex: nitro (4-aminobenzenesulfonamide) zirconium was presented. Characterization of the complex was performed by infrared spectroscopic, thermogravimetric and X-ray diffraction analysis.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49573418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Antifreeze design, scientific operation, and maintenance of tunnels with broken surrounding rock in seasonal frozen areas are key factors that affect the safety of tunnel. According to a freezing damage treatment project, theoretical analysis, field monitoring, and numerical simulation are used to study the calculation method of the overall frost-heaving pressure of a tunnel with broken surrounding rock in the seasonal frozen area. Based on the overall frost-heaving model of the broken freeze–thawing lithosphere, a calculation method of the overall frost-heaving pressure of the horseshoe-shaped tunnel with broken surrounding rock in a seasonal frozen area is proposed. The results show that the management grading results based on the freezing depth of the surrounding rock on site are consistent with those based on the minimum safety factor of the lining structure, which indicates that the proposed method for calculating the overall frost-heaving pressure of broken surrounding rock tunnel and management standards for safety monitoring and measurement of tunnel linings can be applied to engineering practice. The research results can provide a reference for the calculation of frost-heaving pressure, operational safety, and prevention of freezing damages in tunnels with broken surrounding rock in a seasonal frozen area.
{"title":"A method of safety monitoring and measurement of overall frost heaving pressure of tunnel in seasonal frozen area","authors":"G. Cui, Yong Xiong","doi":"10.1515/arh-2022-0148","DOIUrl":"https://doi.org/10.1515/arh-2022-0148","url":null,"abstract":"Abstract Antifreeze design, scientific operation, and maintenance of tunnels with broken surrounding rock in seasonal frozen areas are key factors that affect the safety of tunnel. According to a freezing damage treatment project, theoretical analysis, field monitoring, and numerical simulation are used to study the calculation method of the overall frost-heaving pressure of a tunnel with broken surrounding rock in the seasonal frozen area. Based on the overall frost-heaving model of the broken freeze–thawing lithosphere, a calculation method of the overall frost-heaving pressure of the horseshoe-shaped tunnel with broken surrounding rock in a seasonal frozen area is proposed. The results show that the management grading results based on the freezing depth of the surrounding rock on site are consistent with those based on the minimum safety factor of the lining structure, which indicates that the proposed method for calculating the overall frost-heaving pressure of broken surrounding rock tunnel and management standards for safety monitoring and measurement of tunnel linings can be applied to engineering practice. The research results can provide a reference for the calculation of frost-heaving pressure, operational safety, and prevention of freezing damages in tunnels with broken surrounding rock in a seasonal frozen area.","PeriodicalId":50738,"journal":{"name":"Applied Rheology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47539151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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