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Probing Electrochemical Interfaces with X‐Rays 用X射线探测电化学界面
Pub Date : 2007-03-14 DOI: 10.1002/9780470141267.CH5
Héaector D. Abruña
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引用次数: 7
Equilibrium and dynamical Fourier path integral methods 平衡和动态傅立叶路径积分方法
Pub Date : 2007-03-14 DOI: 10.1002/9780470141274.CH2
J. Doll, D. Freeman, T. Beck
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引用次数: 158
Structure of the electric double layer 双电层结构
Pub Date : 2007-03-14 DOI: 10.1002/9780470141274.CH4
L. Blum
Abstract : The general problem of the interface between two phases which are charged and or conducting is of relevance to a number of systems which occur in nature: colloids, micelles, membranes, solid-solution interfaces in general and metal solution interfaces in particular, form a bewildering array of systems of enormous complexity. The investigation of the structure of these systems poses considerable difficulties, both experimentally as well as theoretically. The experimental problem is that the interface has 10 to the minus 8th power particles relative to the bulk, solid or liquid phases. For this reason one needs a surface specific method, which is able to discriminate between the signal from the surface structure of solids. However they must be used in vacuum and that precludes their use in the study of the liquid solid interface. The study of electrode surfaces removed from the liquid cell under various conditions has provided an enormous wealth of useful data which we will not try to review here. The only way to understand the relation between the ex-situ and is to measure both. (rh)
摘要:带电或导电的两相之间界面的一般问题与自然界中出现的许多系统有关:胶体,胶束,膜,一般的固溶界面,特别是金属溶液界面,形成了一系列令人眼花缭乱的极其复杂的系统。研究这些系统的结构在实验上和理论上都有相当大的困难。实验问题是,相对于体积、固相或液相,界面有10 ^(- 8)次方的粒子。由于这个原因,需要一种表面特定的方法,它能够区分固体表面结构的信号。然而,它们必须在真空中使用,这就妨碍了它们在研究液固界面中的应用。在各种条件下对从液体电池中取出的电极表面的研究已经提供了大量有用的数据,我们在此不作回顾。了解迁地和移地之间关系的唯一方法是测量两者。(rh)
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引用次数: 14
Chemistry Induced by Core Electron Excitation 核心电子激发诱导的化学
Pub Date : 2007-03-14 DOI: 10.1002/9780470141267.CH1
D. M. Hanson
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引用次数: 66
Semiclassical Approach to Charge‐Transfer Processes in Ion‐Molecule Collisions 离子-分子碰撞中电荷转移过程的半经典方法
Pub Date : 2007-03-14 DOI: 10.1002/9780470141403.CH5
Hiroki Nakamura
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引用次数: 9
Relaxation Theory of Nonlinear Processes in the Smoluchowski Rotational Diffusion Approximation Smoluchowski旋转扩散近似中非线性过程的松弛理论
Pub Date : 2007-03-14 DOI: 10.1002/9780470141434.CH1
W. Alexiewicz, B. Kasprowicz-Kielich
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引用次数: 2
Photon statistics of nonclassical fields 非经典场的光子统计
Pub Date : 2007-03-14 DOI: 10.1002/9780470141434.CH10
J. Peřina, J. Bajer, Vlasta Peřinová, Z. Hradil
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引用次数: 0
Melting and Liquid Structure in two Dimensions 二维熔融和液体结构
Pub Date : 2007-03-14 DOI: 10.1002/9780470141410.CH7
M. Glaser, N. Clark
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引用次数: 67
Molecular Theory of Liquid‐Phase Vibrational Energy Relaxation 液相振动能量弛豫的分子理论
Pub Date : 2007-03-14 DOI: 10.1002/9780470141427.CH2
S. Adelman, R. Ravi, R. Muralidhar, R. Stote
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引用次数: 3
Laser and Pulsed‐Laser NMR Spectroscopy 激光和脉冲激光核磁共振光谱学
Pub Date : 2007-03-14 DOI: 10.1002/9780470141441.CH2
M. Evans
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引用次数: 1
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