Haonan Sun, Tao Lei, Xianghong Guo, Jianxin Liu, Xihuan Sun, Juanjuan Ma
The self-made slow-release membrane material with water-based copolymer (polyvinyl alcohol PVA, polyvinyl pyrrolidone PVP), zeolite and epoxy resin as raw materials was tested for degradation in buried soil. The effects of soil temperature T ( T 15 , T 25 , T 35 ) and moisture W ( W 60 , W 80 , W 100 ) on the degradability of membrane materials were investigated by a comprehensive experimental design, and a hydrothermal coupling model K ( T , W ) was established. The effects of degradation on the chemical structure, functional groups, and morphology of membrane materials were revealed by infrared spectroscopy and SEM electron microscopy. The results showed that the degradation degree of membrane material was an exponentially positive response to the increase in soil temperature and moisture. The degradation rate of membrane materials under different treatments was 13.7%-17.3%, and the maximum degradation rate was 17.3% under the T 35 W 100 condition. The determination coefficient R 2 of the constructed K ( T , W ) model reached 0.927, and the average relative error of the predicted degradation rate was 1.58%, indicating good accuracy of the model. The infrared spectrum showed that the -OH stretching vibration absorption peak of the degraded membrane becomes wider and the peak intensity increases; the absorption peak intensity of C-H, -CH 2 , and Si-O weakens; and the peak of the C=C absorption peak appears as a continuous staircase after degradation. The SEM electron microscopy showed there were differences in the pores and cracks of the membrane materials under different treatments, and the degradation was the most obvious under the T 35 W 100 condition.
以水性共聚物(聚乙烯醇PVA、聚乙烯吡咯烷酮PVP)、沸石和环氧树脂为原料,对自制的缓释膜材料进行了埋土降解试验。通过综合实验设计研究了土壤温度 T(T 15、T 25、T 35)和湿度 W(W 60、W 80、W 100)对膜材料降解性的影响,并建立了水热耦合模型 K(T,W)。通过红外光谱和 SEM 电子显微镜揭示了降解对膜材料化学结构、官能团和形貌的影响。结果表明,膜材料的降解程度与土壤温度和湿度的增加呈指数正相关。不同处理条件下膜材料的降解率为 13.7%-17.3%,在 T 35 W 100 条件下降解率最大,为 17.3%。构建的 K ( T , W ) 模型的判定系数 R 2 达到 0.927,预测降解率的平均相对误差为 1.58%,表明模型的准确性较好。红外光谱显示,降解膜的-OH伸缩振动吸收峰变宽,峰强度增大;C-H、-CH 2和Si-O的吸收峰强度减弱;降解后C=C吸收峰呈连续阶梯状。SEM 电子显微镜显示,在不同处理条件下,膜材料的孔隙和裂纹存在差异,在 T 35 W 100 条件下降解最为明显。
{"title":"Degradation Properties of Sustained Release\u0000Membrane Composited of Water-Based\u0000Copolymer and Zeolite","authors":"Haonan Sun, Tao Lei, Xianghong Guo, Jianxin Liu, Xihuan Sun, Juanjuan Ma","doi":"10.15244/pjoes/177463","DOIUrl":"https://doi.org/10.15244/pjoes/177463","url":null,"abstract":"The self-made slow-release membrane material with water-based copolymer (polyvinyl alcohol PVA, polyvinyl pyrrolidone PVP), zeolite and epoxy resin as raw materials was tested for degradation in buried soil. The effects of soil temperature T ( T 15 , T 25 , T 35 ) and moisture W ( W 60 , W 80 , W 100 ) on the degradability of membrane materials were investigated by a comprehensive experimental design, and a hydrothermal coupling model K ( T , W ) was established. The effects of degradation on the chemical structure, functional groups, and morphology of membrane materials were revealed by infrared spectroscopy and SEM electron microscopy. The results showed that the degradation degree of membrane material was an exponentially positive response to the increase in soil temperature and moisture. The degradation rate of membrane materials under different treatments was 13.7%-17.3%, and the maximum degradation rate was 17.3% under the T 35 W 100 condition. The determination coefficient R 2 of the constructed K ( T , W ) model reached 0.927, and the average relative error of the predicted degradation rate was 1.58%, indicating good accuracy of the model. The infrared spectrum showed that the -OH stretching vibration absorption peak of the degraded membrane becomes wider and the peak intensity increases; the absorption peak intensity of C-H, -CH 2 , and Si-O weakens; and the peak of the C=C absorption peak appears as a continuous staircase after degradation. The SEM electron microscopy showed there were differences in the pores and cracks of the membrane materials under different treatments, and the degradation was the most obvious under the T 35 W 100 condition.","PeriodicalId":510399,"journal":{"name":"Polish Journal of Environmental Studies","volume":"56 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140662509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}