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Degradation Properties of Sustained ReleaseMembrane Composited of Water-BasedCopolymer and Zeolite 水基聚合物和沸石复合缓释膜的降解特性
Pub Date : 2024-04-24 DOI: 10.15244/pjoes/177463
Haonan Sun, Tao Lei, Xianghong Guo, Jianxin Liu, Xihuan Sun, Juanjuan Ma
The self-made slow-release membrane material with water-based copolymer (polyvinyl alcohol PVA, polyvinyl pyrrolidone PVP), zeolite and epoxy resin as raw materials was tested for degradation in buried soil. The effects of soil temperature T ( T 15 , T 25 , T 35 ) and moisture W ( W 60 , W 80 , W 100 ) on the degradability of membrane materials were investigated by a comprehensive experimental design, and a hydrothermal coupling model K ( T , W ) was established. The effects of degradation on the chemical structure, functional groups, and morphology of membrane materials were revealed by infrared spectroscopy and SEM electron microscopy. The results showed that the degradation degree of membrane material was an exponentially positive response to the increase in soil temperature and moisture. The degradation rate of membrane materials under different treatments was 13.7%-17.3%, and the maximum degradation rate was 17.3% under the T 35 W 100 condition. The determination coefficient R 2 of the constructed K ( T , W ) model reached 0.927, and the average relative error of the predicted degradation rate was 1.58%, indicating good accuracy of the model. The infrared spectrum showed that the -OH stretching vibration absorption peak of the degraded membrane becomes wider and the peak intensity increases; the absorption peak intensity of C-H, -CH 2 , and Si-O weakens; and the peak of the C=C absorption peak appears as a continuous staircase after degradation. The SEM electron microscopy showed there were differences in the pores and cracks of the membrane materials under different treatments, and the degradation was the most obvious under the T 35 W 100 condition.
以水性共聚物(聚乙烯醇PVA、聚乙烯吡咯烷酮PVP)、沸石和环氧树脂为原料,对自制的缓释膜材料进行了埋土降解试验。通过综合实验设计研究了土壤温度 T(T 15、T 25、T 35)和湿度 W(W 60、W 80、W 100)对膜材料降解性的影响,并建立了水热耦合模型 K(T,W)。通过红外光谱和 SEM 电子显微镜揭示了降解对膜材料化学结构、官能团和形貌的影响。结果表明,膜材料的降解程度与土壤温度和湿度的增加呈指数正相关。不同处理条件下膜材料的降解率为 13.7%-17.3%,在 T 35 W 100 条件下降解率最大,为 17.3%。构建的 K ( T , W ) 模型的判定系数 R 2 达到 0.927,预测降解率的平均相对误差为 1.58%,表明模型的准确性较好。红外光谱显示,降解膜的-OH伸缩振动吸收峰变宽,峰强度增大;C-H、-CH 2和Si-O的吸收峰强度减弱;降解后C=C吸收峰呈连续阶梯状。SEM 电子显微镜显示,在不同处理条件下,膜材料的孔隙和裂纹存在差异,在 T 35 W 100 条件下降解最为明显。
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引用次数: 0
Analysis of Emulsion Compositionand the Migration and Transformationin Mine Water 矿井水中的乳状液成分及迁移和转化分析
Pub Date : 2024-04-24 DOI: 10.15244/pjoes/177151
Youli Qiu, Chao Yang, Min Wu, Jie Li, Ruimin He, Chunming Hao, Xing Fan
In this study, emulsion and mine water samples were collected from the Daliuta area, and the emulsion composition was analyzed. The typical pollutants in the emulsion were triethanolamine, sodium benzoate, sodium nitrite, and sodium hyponitrotriacetate. Furthermore, migration and transformation studies were conducted with respect to these typical pollutants in the emulsion. When the mine water was passed through the aeration zone of a water accumulation leaching device, the pollutant concentrations considerably decreased, resulting in significant adsorption and migration effects. Subsequently, the adsorption effect was significantly reduced. The adsorption rate of sodium benzoate and sodium hyponitrotriacetate increased with an increase in the emulsion concentration on the 30th day. The adsorption rate of sodium nitrite in 1 L mine water with 20 mL emulsion on the 30 th day was 86.4%. The noncarcinogenic health risk assessment and exposure index (EI) model calculations of the simulated mine water containing emulsion revealed that all the hazard quotient (HQ) and EI values of carcinogens were >1. Furthermore, reference pollutant concentrations under the specific conditions of HQ and EI were obtained. These study findings are expected to provide scientific data support for local governments to strengthen geological environment management in mining areas.
本研究从达柳塔地区采集了乳化液和矿井水样本,并对乳化液成分进行了分析。乳液中的典型污染物是三乙醇胺、苯甲酸钠、亚硝酸钠和次硝基三乙酸钠。此外,还对乳液中的这些典型污染物进行了迁移和转化研究。当矿井水通过积水浸出装置的曝气区时,污染物浓度大大降低,产生了显著的吸附和迁移效应。随后,吸附效果明显降低。在第 30 天,苯甲酸钠和次硝基三乙酸钠的吸附率随着乳液浓度的增加而增加。在含有 20 毫升乳液的 1 升矿井水中,亚硝酸钠在第 30 天的吸附率为 86.4%。对含有乳化液的模拟矿井水进行的非致癌健康风险评估和暴露指数(EI)模型计算显示,所有致癌物质的危害商数(HQ)和暴露指数(EI)值均大于 1。此外,还获得了在 HQ 和 EI 特定条件下的污染物参考浓度。这些研究结果有望为地方政府加强矿区地质环境管理提供科学数据支持。
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引用次数: 0
Characterization of Salt-Tolerant Cultivarsof Date Palm Based on Morphological andBiochemical Responses Under Salinity Stress 基于盐度胁迫下枣椰树形态和生化反应的耐盐栽培品种特性分析
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/177179
Muhammad Yousaf Ali, Irfan Ashraf, Ishtiaq Ahmed, Rashid Iqbal, A. Ditta, Vinoth Kumarasamy, Sayed M. Eldin, Iftikhar Ali, M. Alwahibi, M. Elshikh
Abiotic stress, especially salinization, is considered a major soil problem in arid and semiarid regions. To combat salinization, halophytes such as date palms are grown in these areas. However, less information is available on the morphological and biochemical responses of different date palm cultivars under high salinity. In this regard, eight cultivars of date palm were selected and treated with different salinity levels to check the adaptive capabilities of these cultivars against salt stress in terms of morphological and biochemical attributes. The objective of the current study was to screen these cultivars for tolerance or susceptibility to salt stress (0, 50, 100, and 200 mM NaCl). The results of the morphological parameters revealed the negative impact of salt stress on the morphology. Higher concentrations of salt reduced the plant height (Haleemi, Dahakki, Sanduri, Saghoi, Tarwali, and Hamanwali), the number of leaves (Haleemi, Basrawali, Dhakki, Sanduri, Saghoi, and Gajjar),
非生物胁迫,尤其是盐碱化,被认为是干旱和半干旱地区的一个主要土壤问题。为了应对盐碱化,这些地区种植了枣椰树等盐生植物。然而,关于不同枣椰树栽培品种在高盐度条件下的形态和生化反应的资料较少。为此,研究人员选择了 8 个枣椰树栽培品种,并用不同的盐度水平进行处理,以检测这些栽培品种在形态和生化属性方面对盐胁迫的适应能力。本研究的目的是筛选这些栽培品种对盐胁迫(0、50、100 和 200 mM NaCl)的耐受性或敏感性。形态参数的结果表明,盐胁迫对植物形态有负面影响。较高浓度的盐会降低植株高度(Haleemi、Dahakki、Sanduri、Saghoi、Tarwali 和 Hamanwali)和叶片数量(Haleemi、Basrawali、Dhakki、Sanduri、Saghoi 和 Gajjar)、
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引用次数: 1
Mechanism of Cd Adsorption by SulphurModified Biochar and Its Applicationin Cd-Contaminated Soil 硫改性生物炭吸附镉的机理及其在镉污染土壤中的应用
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/183498
Xiaoli Wang, Sujun Ding, Tong Cheng, Sha Wang, Zhentian Qing, Jiale Hu, Xiaobing Wang
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引用次数: 0
Active Biomonitoring of Atmospheric ElementDeposition in the Heating Period of TangshanUsing Ramalina sinensis 利用中华槐对唐山采暖期大气沉降元素进行主动生物监测
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/183500
Meina Li, Jianwei Meng, Dan Lin, Peng Xu, Lei Wang, Yanqiao Hu, Chong Qin, Liangcheng Zhao, Yu Xia, Liangyu Zhang, Huajie Liu
Tangshan is known as a typical heavy industrial city with serious atmospheric pollution. It suffers the most serious atmospheric pollution during the winter heating period. This study aims to explore the level and spatial distribution of atmospheric element deposition in the study area and validate the suitability of Ramalina sinensis ( RSI ) as an active biomonitor in North China cities. RSI was transplanted to Tangshan in winter (Dec. 2016-Mar. 2017) and exposed for 17 weeks. The concentration of 51 elements was tested using an ICP-MS (inductively coupled plasma mass spectrometer). The results showed that the exposure concentration of all elements but Ag was significantly higher than the background value. Principal component analysis (PCA) showed that K, P, and Rb were separated into the group G5, and these nutrients have a lower level of bioaccumulation than other groups. The remaining 47 elements were classified into groups G1 (Al, Be, Co, Cr, Cs, Ge, Li, Nb, Ni, Si, Th, Ti, U, V, and 16 rare earth elements La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y, and Sc) of crustal origin, G2 (Ca, Cd, Cu, Mg, Mn, Mo, S, Sb, Sr, and Zn) and G3 (Bi, Pb, and Sn) of atmospheric origin, and G4 (As, Fe, Se, and Tl) of crustal-atmospheric origin. The overall bioaccumulation in Tangshan is moderate (PLI zone = 2.010 for the combined groups G1-4), with the highest bioaccumulation level (high to severe) for the atmospheric group G2. The most concerned elements are Ca and S, which are of high bioaccumulation at the regional scale. All element groups show a similar spatial pattern characterized by decreasing atmospheric deposition from east to west and from rural to urban areas. These results indicate that RSI is a good active biomonitor for most elements, barring some nutrients. The importance of G2 elements should be emphasized as an indicator of anthropogenic emissions in lichen-active biomonitoring techniques in North China cities. The study area experienced a certain degree of atmospheric pollution, contributed mainly by the frequent industrial and agricultural activities and coal combustion for heating in the east of the city and the rural areas around. This study is the first to monitor atmospheric deposition in industrial cities in North China using the active lichen biomonitoring method.
众所周知,唐山是典型的重工业城市,大气污染严重。冬季采暖期的大气污染最为严重。本研究旨在探索研究区大气元素沉积水平和空间分布,验证Ramalina sinensis(RSI)作为华北城市活性生物监测物的适宜性。在冬季(2016年12月-2017年3月)将RSI移植到唐山,并暴露17周。使用 ICP-MS(电感耦合等离子体质谱仪)检测了 51 种元素的浓度。结果显示,除 Ag 外,所有元素的暴露浓度都明显高于背景值。主成分分析(PCA)显示,K、P 和 Rb 被分为 G5 组,这些营养元素的生物累积水平低于其他组别。其余 47 种元素被归入 G1 组(Al、Be、Co、Cr、Cs、Ge、Li、Nb、Ni、Si、Th、Ti、U、V 和 16 种稀土元素 La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y 和 Tm)、G2(Ca、Cd、Cu、Mg、Mn、Mo、S、Sb、Sr 和 Zn)和 G3(Bi、Pb 和 Sn),以及 G4(As、Fe、Se 和 Tl)。唐山的总体生物累积水平为中度(G1-4 组的综合生物累积指数区 = 2.010),其中 G2 大气组的生物累积水平最高(高至重度)。最受关注的元素是 Ca 和 S,这两种元素在区域范围内的生物累积程度较高。所有元素组都呈现出类似的空间模式,即从东到西,从农村到城市地区,大气沉积量不断减少。这些结果表明,除某些营养元素外,RSI 对大多数元素来说都是一个很好的活性生物监测器。在华北城市地衣活性生物监测技术中,G2 元素作为人为排放指标的重要性应得到强调。研究区域存在一定程度的大气污染,主要由频繁的工农业活动和城市东部及周边农村地区的取暖燃煤造成。本研究首次采用地衣活性生物监测方法对华北地区工业城市的大气沉降进行监测。
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引用次数: 0
Methane Emission in Mangrove Forests:Field Study and Environmental Correlations fromXuan Thuy National Park, Vietnam 红树林的甲烷排放:越南宣泰国家公园的实地研究与环境相关性
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/183086
Hanh Thi Minh Pham, Ba The Dang, Cuong Tu Ho, Nghi Thanh Duong, Hanh Thi Nguyen, Quynh Phuong Thi Le, Thuy Thi Duong, Ha Manh Bui
: This study investigates methane emissions in the mangrove forests of Xuan Thuy National Park in Vietnam, examining seasonal variations and the influence of environmental factors. Data from the field measurements present methane flux rates ranging from 0.01 to 10.42 mg m−2 day−1, are substantially lower than the default estimations recommended by IPCC guidelines. The study highlights discrepancies between actual field measurements and suggested default values, emphasizing the necessity for site-specific monitoring to avoid overestimating greenhouse gas emissions, particularly in mangrove areas. The analysis reveals strong correlations between methane flux and environmental parameters. Factors such as water pH, turbidity, temperature, and nitrogen content significantly influence methane emissions. The study emphasizes the interconnectedness of various greenhouse gas emissions within mangrove ecosystems and underlines the importance of accurate, location-specific data in environmental assessments and policy-making
:本研究调查了越南 Xuan Thuy 国家公园红树林的甲烷排放情况,研究了季节性变化和环境因素的影响。实地测量数据显示甲烷通量率为 0.01 至 10.42 毫克/平方米-2 天-1,大大低于 IPCC 指南建议的默认估计值。该研究强调了实际实地测量值与建议默认值之间的差异,强调有必要针对具体地点进行监测,以避免高估温室气体排放量,尤其是在红树林地区。分析表明,甲烷通量与环境参数之间存在很强的相关性。水的 pH 值、浑浊度、温度和氮含量等因素对甲烷排放有显著影响。这项研究强调了红树林生态系统中各种温室气体排放的相互关联性,并强调了准确的、针对具体地点的数据在环境评估和政策制定中的重要性。
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引用次数: 0
The Evolution of Sloping Cultivated LandAbandonment in Karst Mountainous Areas – A Caseof Huajiang Canyon in Guizhou Province, China 岩溶山区坡耕地围垦的演变--以贵州花江峡谷为例
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/182884
Limin Yu, Yangbing Li, Linyu Yang, Yiyi Zhang, Shanshan Li, Mei Chen
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引用次数: 0
Research on the Impact of Digital Economyon Environmental Pollution Management– A Quasi-Natural Experimentfrom the “Broadband China” Pilot Policy 数字经济对环境污染治理的影响研究--来自 "宽带中国 "试点政策的准自然实验
Pub Date : 2024-04-22 DOI: 10.15244/pjoes/177161
Liang Qu, Yueting Shao, Pengzhen Liu
Based on panel data from 286 cities at the prefecture level and above in China spanning from 2010 to 2020 and utilizing the digital economy development objectives advanced by the “Broadband China” strategy in 2014 as a natural experiment, we employed the double-difference method to examine the impact of digital economy development on urban environmental pollution management and its underlying mechanisms. The study reveals that the “Broadband China” pilot policy significantly influences the level of environmental pollution control when compared to non-demonstration cities. This conclusion still holds after a series of robustness tests. The mechanism analysis demonstrates that the “Broadband China” pilot policy affects the level of environmental pollution control by enhancing regional innovation capacity and upgrading the industrial structure. Moreover, heterogeneity analysis indicates that the influence of the “Broadband China” pilot policy on environmental pollution control varies depending on location choice, city size, and degree of urbanization. Notably, the impact of constructing demonstration cities is particularly pronounced in the eastern region, larger cities, and areas with higher urbanization rates. This study holds significant implications for enhancing the urban ecological environment and achieving high-quality development.
基于 2010-2020 年中国 286 个地级及以上城市的面板数据,以 2014 年 "宽带中国 "战略推进的数字经济发展目标为自然实验,采用双差分法考察了数字经济发展对城市环境污染治理的影响及其内在机制。研究发现,与非示范城市相比,"宽带中国 "试点政策显著影响了环境污染治理水平。经过一系列稳健性检验,这一结论仍然成立。机制分析表明,"宽带中国 "试点政策通过提升区域创新能力和产业结构升级来影响环境污染治理水平。此外,异质性分析表明,"宽带中国 "试点政策对环境污染治理的影响因区位选择、城市规模和城市化程度而异。值得注意的是,建设示范城市对东部地区、较大城市和城市化率较高地区的影响尤为明显。这项研究对改善城市生态环境、实现高质量发展具有重要意义。
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引用次数: 0
Commercial Bank Expansionand Environmental Pollution: MicroEvidence from Industrial Firms in China 商业银行扩张与环境污染:中国工业企业的微观证据
Pub Date : 2024-04-19 DOI: 10.15244/pjoes/176056
Shengrui Li, Leyi Chen, Pingguo Xu
This paper uses the web crawler method to obtain information on the distribution of commercial bank branches in China and uses the multidimensional fixed-effects model to explore the impact of commercial bank expansion on firm pollution emissions and its mechanism. The findings reveal that commercial bank expansion significantly reduces firms’ pollution emissions and that there is an optimal geographical radius for this suppression effect. The number of commercial bank branches within 20 km of the firm has the biggest inhibiting influence on the firm’s pollution emission, which diminishes as geographical distance increases. This dampening effect remains robust after testing using the instrumental variable method and the Difference-In-Differences method. Examination of heterogeneity demonstrates that the influence of commercial bank expansion on firm pollution emission depends on the degree of regional low-carbon policies and laws, the level of pollution in the industry, and capital intensity of the industry, as well as the firm’s size and ownership. The mechanism test proves that commercial bank expansion reduces firm pollution emissions by promoting technological progress and increasing their investment in pollution reduction.
本文利用网络爬虫法获取了中国商业银行网点分布信息,并利用多维固定效应模型探讨了商业银行扩张对企业污染排放的影响及其机制。研究结果表明,商业银行扩张能明显降低企业的污染排放,而且这种抑制效应存在一个最佳的地理半径。企业周围 20 千米范围内的商业银行网点数量对企业污染排放的抑制作用最大,随着地理距离的增加,抑制作用逐渐减弱。在使用工具变量法和差分法进行检验后,这种抑制效应仍然是稳健的。异质性检验表明,商业银行扩张对企业污染排放的影响取决于地区低碳政策和法律的程度、行业污染水平、行业资本密集度以及企业规模和所有权。机理检验证明,商业银行扩张通过促进技术进步和增加污染减排投资来减少企业污染排放。
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引用次数: 0
Mathematical Approach to Solvingthe Problem of Waste-Free Processingof Metallurgical Wastes 解决冶金废物无废处理问题的数学方法
Pub Date : 2024-04-19 DOI: 10.15244/pjoes/183431
A. Tileuberdi, Altybayev Zhaksylyk, Dana Pazylova, Nurila Sagyndykova, Alibek Tleuov, S. Tleuova
Every year, the problem of environmental pollution from metallurgical waste is gaining momentum. In particular, these are metallurgical wastes containing residual metals. However, with the help of innovative methods of processing lead-containing slags, they can be turned into valuable resources with minimal impact on the environment. This article discusses the importance of recycling lead-containing slag and describes various methods of recycling. The scientific novelty of the article is to analyze the influence of the content of toxic metals, such as lead, chromium, zinc
每年,冶金废物造成的环境污染问题都在日益严重。尤其是含有残余金属的冶金废物。然而,借助创新的含铅炉渣处理方法,可以将其转化为有价值的资源,并将对环境的影响降至最低。本文讨论了回收含铅炉渣的重要性,并介绍了各种回收方法。文章的科学创新之处在于分析了有毒金属(如铅、铬、锌)含量的影响。
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引用次数: 0
期刊
Polish Journal of Environmental Studies
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