Chemical looping hydrogen generation represents a viable technology for high-purity hydrogen production and CO2 capture. Moving bed reactors are considered effective for this process, but the high cost of experiments and the complexity of the biomass gas reaction have hindered the development of hydrogen generation from biomass gas.This investigation employs Computational Fluid Dynamics-Discrete Element Method (CFD-DEM) to simulate gas-solid phase distribution and reactions within a moving bed fuel reactor, aiming to amplify biomass gas and oxygen carrier conversion rates. Findings indicate that enhancing particle flux rate and reaction temperature substantially increases the conversion efficiency of both biomass gas and oxygen carrier. Notably, achieving complete CH4 conversion presents significant challenges in biomass gasification, with CH4 conversion dictating the requisite bed height for total biomass gas conversion. Furthermore, the gas-phase equilibrium conversion rate of Fe3O4 to FeO delineates the operational limit within the moving bed. Under full reaction conditions of biomass gas, the oxygen carrier’s maximum achievable conversion ranges between 29.2 and 31.6 % at 850 °C. These insights substantially advance the application of biomass gas in the chemical looping domain and inform future design and operational strategies for reactors.
{"title":"CFD-DEM simulation of chemical looping hydrogen generation in a moving bed reactor","authors":"Shenglong Teng, Yongxian Zhou, Yun Xv, Zhuang Ke, Kai Zhou, Qian Zhang, JingXin Xv, Dewang Zeng","doi":"10.1515/ijcre-2024-0001","DOIUrl":"https://doi.org/10.1515/ijcre-2024-0001","url":null,"abstract":"\u0000 Chemical looping hydrogen generation represents a viable technology for high-purity hydrogen production and CO2 capture. Moving bed reactors are considered effective for this process, but the high cost of experiments and the complexity of the biomass gas reaction have hindered the development of hydrogen generation from biomass gas.This investigation employs Computational Fluid Dynamics-Discrete Element Method (CFD-DEM) to simulate gas-solid phase distribution and reactions within a moving bed fuel reactor, aiming to amplify biomass gas and oxygen carrier conversion rates. Findings indicate that enhancing particle flux rate and reaction temperature substantially increases the conversion efficiency of both biomass gas and oxygen carrier. Notably, achieving complete CH4 conversion presents significant challenges in biomass gasification, with CH4 conversion dictating the requisite bed height for total biomass gas conversion. Furthermore, the gas-phase equilibrium conversion rate of Fe3O4 to FeO delineates the operational limit within the moving bed. Under full reaction conditions of biomass gas, the oxygen carrier’s maximum achievable conversion ranges between 29.2 and 31.6 % at 850 °C. These insights substantially advance the application of biomass gas in the chemical looping domain and inform future design and operational strategies for reactors.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"9 4","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140747017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dong He, Xiaoyue Bai, Hanzhong Tao, Yanna Li, Shuo Lin
This paper introduces a novel process for decomposing N2O through interstage cooling utilizing a heat pipe heat exchanger. The reactor design involves segmenting the fixed bed reactor into multiple layers and integrating heat pipe heat exchangers between these layers to efficiently dissipate the high heat generated by the upper fixed bed reactor. This innovative approach facilitates the direct decomposition of N2O feedgas with high concentrations, obviating the need for gas dilution. The study conducted in this paper employed Fluent and ASPEN PLUS to investigate N2O decomposition with interstage cooling using heat pipe heat exchangers, as well as decomposition after dilution. A comparison between the two methods was made based on catalyst dosage, temperature uniformity, and reactor energy consumption. The results demonstrate that the proposed method for N2O decomposition via interstage cooling with a heat pipe heat exchanger is a viable option, offering the desired temperature control and enhanced efficiency. Furthermore, this reactor design effectively reduces both catalyst usage and energy consumption, providing substantial advantages over traditional approaches.
{"title":"Conceptual design of a fixed bed N2O decomposition reactor with a heat pipe heat exchanger","authors":"Dong He, Xiaoyue Bai, Hanzhong Tao, Yanna Li, Shuo Lin","doi":"10.1515/ijcre-2023-0227","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0227","url":null,"abstract":"\u0000 This paper introduces a novel process for decomposing N2O through interstage cooling utilizing a heat pipe heat exchanger. The reactor design involves segmenting the fixed bed reactor into multiple layers and integrating heat pipe heat exchangers between these layers to efficiently dissipate the high heat generated by the upper fixed bed reactor. This innovative approach facilitates the direct decomposition of N2O feedgas with high concentrations, obviating the need for gas dilution. The study conducted in this paper employed Fluent and ASPEN PLUS to investigate N2O decomposition with interstage cooling using heat pipe heat exchangers, as well as decomposition after dilution. A comparison between the two methods was made based on catalyst dosage, temperature uniformity, and reactor energy consumption. The results demonstrate that the proposed method for N2O decomposition via interstage cooling with a heat pipe heat exchanger is a viable option, offering the desired temperature control and enhanced efficiency. Furthermore, this reactor design effectively reduces both catalyst usage and energy consumption, providing substantial advantages over traditional approaches.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"26 17","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140753668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zeng Lingwei, Zhenpeng Li, Li Jun, Dongmei Yan, Fuchuan Huang
When the airlift bioreactor is applied to the field of industrial fermentation, there is a common problem of low mixing and flow efficiency due to its simple structure. In order to expand the application of airlift bioreactor in the field of industrial fermentation, a new type of airlift bioreactor with three-dimensional bumps in the draft tube has been designed to enhance the mixing and flow of gas-liquid two-phase in the reactor. In order to determine the specific influence of the three-dimensional bumps on the internal flow field of the reactor, and to provide technical reference for the improvement of the structure of the airlift bioreactor, in this paper, the CFD simulation of this type of bioreactor is carried out. Based on the Euler multiphase flow, the Realizable k-ε model was used to analyze the flow field of the reactor with average gas-liquid flow linear velocity and temperature as parameters. The results show that under certain conditions, the three-dimensional bumps inside the draft tube can effectively accelerate the gas-liquid two-phase flow and better promotes the mixing of pig manure fermentation broth and air.
{"title":"CFD simulation study of internal mixing and flow of a modified airlift bioreactor","authors":"Zeng Lingwei, Zhenpeng Li, Li Jun, Dongmei Yan, Fuchuan Huang","doi":"10.1515/ijcre-2023-0169","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0169","url":null,"abstract":"\u0000 When the airlift bioreactor is applied to the field of industrial fermentation, there is a common problem of low mixing and flow efficiency due to its simple structure. In order to expand the application of airlift bioreactor in the field of industrial fermentation, a new type of airlift bioreactor with three-dimensional bumps in the draft tube has been designed to enhance the mixing and flow of gas-liquid two-phase in the reactor. In order to determine the specific influence of the three-dimensional bumps on the internal flow field of the reactor, and to provide technical reference for the improvement of the structure of the airlift bioreactor, in this paper, the CFD simulation of this type of bioreactor is carried out. Based on the Euler multiphase flow, the Realizable k-ε model was used to analyze the flow field of the reactor with average gas-liquid flow linear velocity and temperature as parameters. The results show that under certain conditions, the three-dimensional bumps inside the draft tube can effectively accelerate the gas-liquid two-phase flow and better promotes the mixing of pig manure fermentation broth and air.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"129 ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140755833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The rigid-flexible impeller (RF impeller) was used in the mixing process of viscoplastic fluid, and the mixing performance of RF impeller was explored by using numerical simulation and experimental analysis. Results indicated that RF impeller could reduce the power consumption (P) and demonstrate the advantage of energy-saving compared with Rushton turbine (RT). RF impeller demonstrated a more pronounced force coupling effect between the impeller and surrounding fluid, and exhibited superior adaptability in the flow field compared with RT. Meanwhile, the utilization of RF impeller can effectively enhance the expansion of high velocity region, expand the cavern zone, and decrease the mixing efficiency number while maintaining constant P compared with RT, and the size of high velocity region and cavern zone could be increased with an increase in impeller speed. Moreover, the cavern structure was obtained through the visualization experiment, and the results were similar to that in the simulation. The findings suggested that incorporating rigid-flexible combination structure design of impeller blades could effectively expand the cavern zone, reduce the stagnant zone, and enhance the mixing efficiency in the viscoplastic fluid mixing process.
{"title":"Study on mixing characteristics of viscoplastic fluid in a rigid-flexible impeller stirred tank","authors":"Deyin Gu, Yinghua Song, Li Wen, Mei Ye","doi":"10.1515/ijcre-2023-0219","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0219","url":null,"abstract":"\u0000 The rigid-flexible impeller (RF impeller) was used in the mixing process of viscoplastic fluid, and the mixing performance of RF impeller was explored by using numerical simulation and experimental analysis. Results indicated that RF impeller could reduce the power consumption (P) and demonstrate the advantage of energy-saving compared with Rushton turbine (RT). RF impeller demonstrated a more pronounced force coupling effect between the impeller and surrounding fluid, and exhibited superior adaptability in the flow field compared with RT. Meanwhile, the utilization of RF impeller can effectively enhance the expansion of high velocity region, expand the cavern zone, and decrease the mixing efficiency number while maintaining constant P compared with RT, and the size of high velocity region and cavern zone could be increased with an increase in impeller speed. Moreover, the cavern structure was obtained through the visualization experiment, and the results were similar to that in the simulation. The findings suggested that incorporating rigid-flexible combination structure design of impeller blades could effectively expand the cavern zone, reduce the stagnant zone, and enhance the mixing efficiency in the viscoplastic fluid mixing process.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"12 10","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140077890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Self-similarity impeller (SS impeller) was applied to enlarge the cavern region for the mixing of pseudoplastic fluid. The mixing characteristics of pseudoplastic fluid in an SS impeller stirred tank were explored by employing experimental and numerical simulation. The results indicated that the utilization of SS impeller resulted in significant improvement in the largest Lyapunov exponent of mixing system, as well as reduced mixing time and decreased mixing efficiency number compared with pitched-blade impeller (PB impeller) operating at an equivalent power consumption per unit volume. A reduction in power consumption was obtained through the application of self-similar configuration for the impeller blades. Meanwhile, SS impeller could enhance the fluidity of pseudoplastic fluid, minimize the stagnation regions, and enlarge the cavern region. This phenomenon was even more pronounced as the increase in self-similar iteration number of SS impeller. It was found that the design of self-similar structure for impeller blades could expand the cavern region and enhance the mixing efficiency for the mixing of pseudoplastic fluid, particularly as the self-similar iteration number increased.
应用自相似性叶轮（SS 叶轮）扩大空腔区域，以混合假塑性流体。通过实验和数值模拟探讨了假塑性流体在 SS 叶轮搅拌槽中的混合特性。结果表明，与单位体积功耗相同的投叶式叶轮（PB 叶轮）相比，使用 SS 叶轮显著提高了混合系统的最大 Lyapunov 指数，缩短了混合时间，降低了混合效率。通过对叶轮叶片进行自相似配置，降低了功耗。同时，SS 叶轮可以增强假塑性流体的流动性，减少停滞区，扩大空腔区。随着 SS 叶轮自相似迭代次数的增加，这一现象更加明显。研究发现，叶轮叶片的自相似结构设计可以扩大空腔区域，提高假塑性流体的混合效率，尤其是随着自相似迭代次数的增加。
{"title":"Modifications in impeller blades for high efficiency mixing of pseudoplastic fluid in a stirred tank","authors":"Deyin Gu, Linjie Yan, Hui Xu","doi":"10.1515/ijcre-2023-0235","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0235","url":null,"abstract":"\u0000 Self-similarity impeller (SS impeller) was applied to enlarge the cavern region for the mixing of pseudoplastic fluid. The mixing characteristics of pseudoplastic fluid in an SS impeller stirred tank were explored by employing experimental and numerical simulation. The results indicated that the utilization of SS impeller resulted in significant improvement in the largest Lyapunov exponent of mixing system, as well as reduced mixing time and decreased mixing efficiency number compared with pitched-blade impeller (PB impeller) operating at an equivalent power consumption per unit volume. A reduction in power consumption was obtained through the application of self-similar configuration for the impeller blades. Meanwhile, SS impeller could enhance the fluidity of pseudoplastic fluid, minimize the stagnation regions, and enlarge the cavern region. This phenomenon was even more pronounced as the increase in self-similar iteration number of SS impeller. It was found that the design of self-similar structure for impeller blades could expand the cavern region and enhance the mixing efficiency for the mixing of pseudoplastic fluid, particularly as the self-similar iteration number increased.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"1 3","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139958624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To increase the specific surface area of corn starch and remove the anion contaminant in water, STP-OGG-DD, which is composed of porous corn starch (Stp), methylpropenoxyethyl trimethyl ammonium chloride (DMC) and dimethyldiallyl ammonium chloride (DMDAAC), was prepared and used for the flocculation of humic acid (HA). In this preparation, ferrous sulfate and hydrogen peroxide act as initiators for free radicals that attract cationic monomers to gather on starch chains. The effects of reaction time, reaction temperature, dosage of cationic monomer, and initiator on the reaction performance were investigated. The results showed that the conversion rate of starch monomer was 97.69 %, the grafting rate was 96.47 %, and the grafting efficiency was 95.85 %. Stp-OG-DD was characterized by scanning electron microscopy, and its structure was characterized by X-ray diffraction and infrared spectroscopy. In the flocculation test. The flocculation effect of 30 mg/L flocculants with different grafting rates on 30 mg/L humic acid was investigated, and the relationship between the two was studied. The results showed that the flocculant with a high starch grafting rate had a better removal effect on humic acid and was positively correlated. Different from the traditional gelatinization method, the enzymatic hydrolysis method is used to pretreat starch, which not only saves energy but also enlarges the specific surface area of molecules. In addition, adding two cationic monomers improved the grafting effect of starch. DMC and DMDAAC could be polymerized alternately onto the starch backbone, providing long molecular chains and abundant positive charge for enzymatic hydrolysis of starch molecular chains. In addition to exploring the grafting of samples under reaction conditions, flocculants prepared under different conditions were used to flocculate 30 mg/L humic acid to further determine the role of grafting rate in the removal effect.
{"title":"Preparation and flocculation performance of a cationic starch based flocculant","authors":"Yuhui Shi, Yi Zheng","doi":"10.1515/ijcre-2023-0220","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0220","url":null,"abstract":"\u0000 To increase the specific surface area of corn starch and remove the anion contaminant in water, STP-OGG-DD, which is composed of porous corn starch (Stp), methylpropenoxyethyl trimethyl ammonium chloride (DMC) and dimethyldiallyl ammonium chloride (DMDAAC), was prepared and used for the flocculation of humic acid (HA). In this preparation, ferrous sulfate and hydrogen peroxide act as initiators for free radicals that attract cationic monomers to gather on starch chains. The effects of reaction time, reaction temperature, dosage of cationic monomer, and initiator on the reaction performance were investigated. The results showed that the conversion rate of starch monomer was 97.69 %, the grafting rate was 96.47 %, and the grafting efficiency was 95.85 %. Stp-OG-DD was characterized by scanning electron microscopy, and its structure was characterized by X-ray diffraction and infrared spectroscopy. In the flocculation test. The flocculation effect of 30 mg/L flocculants with different grafting rates on 30 mg/L humic acid was investigated, and the relationship between the two was studied. The results showed that the flocculant with a high starch grafting rate had a better removal effect on humic acid and was positively correlated. Different from the traditional gelatinization method, the enzymatic hydrolysis method is used to pretreat starch, which not only saves energy but also enlarges the specific surface area of molecules. In addition, adding two cationic monomers improved the grafting effect of starch. DMC and DMDAAC could be polymerized alternately onto the starch backbone, providing long molecular chains and abundant positive charge for enzymatic hydrolysis of starch molecular chains. In addition to exploring the grafting of samples under reaction conditions, flocculants prepared under different conditions were used to flocculate 30 mg/L humic acid to further determine the role of grafting rate in the removal effect.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"32 7","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139773858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Due to the substantial volume of waste produced and the potential for high-value bioactive compounds to be extracted from potato peel, the valorization of industrial waste of potato processing industry is the subject of this research. The study presents an innovative technique for efficient extraction of 4-hydroxybenzoic acid (P-HBA), a valuable bioactive molecule, from potato peel extract by utilizing molecularly imprinted chitosan beads (MICB). The MICB was synthesized using environmentally benign cross-linkers such as Tetraethyl orthosilicate (TEOS), Sodium triphosphate (STPP), while P-HBA was is used as a template. The MICB was investigated using FTIR, SEM, and EDAX. Adsorption studies were conducted to optimize parameters like adsorbent dose, solution concentration, time and pH. A recovery rate of 95.07 % is recorded from a synthetic P-HBA solution when measured by HPLC while from the actual potato processing industrial effluent the same is 40 %. The adsorption capacity of MICB is 67.5 mg g−1 and specific binding capacity is 20.62 mg g−1 which remained unchanged for six consecutive cycle reuse. This is the first study to report uptake of a bioactive molecule from actual potato processing industry waste.
{"title":"Extraction of 4-hydroxy benzoic acid from potato processing industrial waste","authors":"Praful S. Dadhe, S. Mandavgane, Anupama Kumar","doi":"10.1515/ijcre-2023-0153","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0153","url":null,"abstract":"\u0000 Due to the substantial volume of waste produced and the potential for high-value bioactive compounds to be extracted from potato peel, the valorization of industrial waste of potato processing industry is the subject of this research. The study presents an innovative technique for efficient extraction of 4-hydroxybenzoic acid (P-HBA), a valuable bioactive molecule, from potato peel extract by utilizing molecularly imprinted chitosan beads (MICB). The MICB was synthesized using environmentally benign cross-linkers such as Tetraethyl orthosilicate (TEOS), Sodium triphosphate (STPP), while P-HBA was is used as a template. The MICB was investigated using FTIR, SEM, and EDAX. Adsorption studies were conducted to optimize parameters like adsorbent dose, solution concentration, time and pH. A recovery rate of 95.07 % is recorded from a synthetic P-HBA solution when measured by HPLC while from the actual potato processing industrial effluent the same is 40 %. The adsorption capacity of MICB is 67.5 mg g−1 and specific binding capacity is 20.62 mg g−1 which remained unchanged for six consecutive cycle reuse. This is the first study to report uptake of a bioactive molecule from actual potato processing industry waste.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"52 50","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139961585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To increase the specific surface area of corn starch and remove the anion contaminant in water, STP-OGG-DD, which is composed of porous corn starch (Stp), methylpropenoxyethyl trimethyl ammonium chloride (DMC) and dimethyldiallyl ammonium chloride (DMDAAC), was prepared and used for the flocculation of humic acid (HA). In this preparation, ferrous sulfate and hydrogen peroxide act as initiators for free radicals that attract cationic monomers to gather on starch chains. The effects of reaction time, reaction temperature, dosage of cationic monomer, and initiator on the reaction performance were investigated. The results showed that the conversion rate of starch monomer was 97.69 %, the grafting rate was 96.47 %, and the grafting efficiency was 95.85 %. Stp-OG-DD was characterized by scanning electron microscopy, and its structure was characterized by X-ray diffraction and infrared spectroscopy. In the flocculation test. The flocculation effect of 30 mg/L flocculants with different grafting rates on 30 mg/L humic acid was investigated, and the relationship between the two was studied. The results showed that the flocculant with a high starch grafting rate had a better removal effect on humic acid and was positively correlated. Different from the traditional gelatinization method, the enzymatic hydrolysis method is used to pretreat starch, which not only saves energy but also enlarges the specific surface area of molecules. In addition, adding two cationic monomers improved the grafting effect of starch. DMC and DMDAAC could be polymerized alternately onto the starch backbone, providing long molecular chains and abundant positive charge for enzymatic hydrolysis of starch molecular chains. In addition to exploring the grafting of samples under reaction conditions, flocculants prepared under different conditions were used to flocculate 30 mg/L humic acid to further determine the role of grafting rate in the removal effect.
{"title":"Preparation and flocculation performance of a cationic starch based flocculant","authors":"Yuhui Shi, Yi Zheng","doi":"10.1515/ijcre-2023-0220","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0220","url":null,"abstract":"\u0000 To increase the specific surface area of corn starch and remove the anion contaminant in water, STP-OGG-DD, which is composed of porous corn starch (Stp), methylpropenoxyethyl trimethyl ammonium chloride (DMC) and dimethyldiallyl ammonium chloride (DMDAAC), was prepared and used for the flocculation of humic acid (HA). In this preparation, ferrous sulfate and hydrogen peroxide act as initiators for free radicals that attract cationic monomers to gather on starch chains. The effects of reaction time, reaction temperature, dosage of cationic monomer, and initiator on the reaction performance were investigated. The results showed that the conversion rate of starch monomer was 97.69 %, the grafting rate was 96.47 %, and the grafting efficiency was 95.85 %. Stp-OG-DD was characterized by scanning electron microscopy, and its structure was characterized by X-ray diffraction and infrared spectroscopy. In the flocculation test. The flocculation effect of 30 mg/L flocculants with different grafting rates on 30 mg/L humic acid was investigated, and the relationship between the two was studied. The results showed that the flocculant with a high starch grafting rate had a better removal effect on humic acid and was positively correlated. Different from the traditional gelatinization method, the enzymatic hydrolysis method is used to pretreat starch, which not only saves energy but also enlarges the specific surface area of molecules. In addition, adding two cationic monomers improved the grafting effect of starch. DMC and DMDAAC could be polymerized alternately onto the starch backbone, providing long molecular chains and abundant positive charge for enzymatic hydrolysis of starch molecular chains. In addition to exploring the grafting of samples under reaction conditions, flocculants prepared under different conditions were used to flocculate 30 mg/L humic acid to further determine the role of grafting rate in the removal effect.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"331 ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139833391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Siti Juwairiyah A. Rahman, M. A. Rahman, Norhafini Hambali, I. S. Azmi, M. Jalil
Vegetable oils are rich in unsaturated bonds that can be converted to epoxidized oleic acid. They are considered sustainable, renewable, and also environmentally friendly. To date, there is a paucity of studies on production of dihydroxystearic acid (DHSA) using an eco-friendly ion exchange resin as it is not fully utilised. As a result, the aim of this study is to elucidate the mechanism of ring-opening by hydrolysis for the production of DHSA using amberlite IR-120H as a catalyst. The process of epoxidizing oleic acid involved the in situ generation of performic acid, which was then used to convert oleic acid into epoxidized oleic acid. This performic acid was created by combining formic acid, serving as the oxygen carrier, with hydrogen peroxide, acting as the oxygen donor. Under optimal conditions, the maximum relative conversion of oleic acid to oxirane was attained, with up to 85 %. Overall, DHSA with a high hydroxyl value (182 mg KOH/g), was successfully produced from oleic acid using in situ hydrolysis of epoxidized oleic acid.
{"title":"Sustainable approach for catalytic epoxidation of oleic acid followed by in situ ring-opening hydrolysis with applied ion exchange resin","authors":"Siti Juwairiyah A. Rahman, M. A. Rahman, Norhafini Hambali, I. S. Azmi, M. Jalil","doi":"10.1515/ijcre-2023-0196","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0196","url":null,"abstract":"\u0000 Vegetable oils are rich in unsaturated bonds that can be converted to epoxidized oleic acid. They are considered sustainable, renewable, and also environmentally friendly. To date, there is a paucity of studies on production of dihydroxystearic acid (DHSA) using an eco-friendly ion exchange resin as it is not fully utilised. As a result, the aim of this study is to elucidate the mechanism of ring-opening by hydrolysis for the production of DHSA using amberlite IR-120H as a catalyst. The process of epoxidizing oleic acid involved the in situ generation of performic acid, which was then used to convert oleic acid into epoxidized oleic acid. This performic acid was created by combining formic acid, serving as the oxygen carrier, with hydrogen peroxide, acting as the oxygen donor. Under optimal conditions, the maximum relative conversion of oleic acid to oxirane was attained, with up to 85 %. Overall, DHSA with a high hydroxyl value (182 mg KOH/g), was successfully produced from oleic acid using in situ hydrolysis of epoxidized oleic acid.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"51 18","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139775528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Siti Juwairiyah A. Rahman, M. A. Rahman, Norhafini Hambali, I. S. Azmi, M. Jalil
Vegetable oils are rich in unsaturated bonds that can be converted to epoxidized oleic acid. They are considered sustainable, renewable, and also environmentally friendly. To date, there is a paucity of studies on production of dihydroxystearic acid (DHSA) using an eco-friendly ion exchange resin as it is not fully utilised. As a result, the aim of this study is to elucidate the mechanism of ring-opening by hydrolysis for the production of DHSA using amberlite IR-120H as a catalyst. The process of epoxidizing oleic acid involved the in situ generation of performic acid, which was then used to convert oleic acid into epoxidized oleic acid. This performic acid was created by combining formic acid, serving as the oxygen carrier, with hydrogen peroxide, acting as the oxygen donor. Under optimal conditions, the maximum relative conversion of oleic acid to oxirane was attained, with up to 85 %. Overall, DHSA with a high hydroxyl value (182 mg KOH/g), was successfully produced from oleic acid using in situ hydrolysis of epoxidized oleic acid.
{"title":"Sustainable approach for catalytic epoxidation of oleic acid followed by in situ ring-opening hydrolysis with applied ion exchange resin","authors":"Siti Juwairiyah A. Rahman, M. A. Rahman, Norhafini Hambali, I. S. Azmi, M. Jalil","doi":"10.1515/ijcre-2023-0196","DOIUrl":"https://doi.org/10.1515/ijcre-2023-0196","url":null,"abstract":"\u0000 Vegetable oils are rich in unsaturated bonds that can be converted to epoxidized oleic acid. They are considered sustainable, renewable, and also environmentally friendly. To date, there is a paucity of studies on production of dihydroxystearic acid (DHSA) using an eco-friendly ion exchange resin as it is not fully utilised. As a result, the aim of this study is to elucidate the mechanism of ring-opening by hydrolysis for the production of DHSA using amberlite IR-120H as a catalyst. The process of epoxidizing oleic acid involved the in situ generation of performic acid, which was then used to convert oleic acid into epoxidized oleic acid. This performic acid was created by combining formic acid, serving as the oxygen carrier, with hydrogen peroxide, acting as the oxygen donor. Under optimal conditions, the maximum relative conversion of oleic acid to oxirane was attained, with up to 85 %. Overall, DHSA with a high hydroxyl value (182 mg KOH/g), was successfully produced from oleic acid using in situ hydrolysis of epoxidized oleic acid.","PeriodicalId":51069,"journal":{"name":"International Journal of Chemical Reactor Engineering","volume":"324 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139835113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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