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A lab experiment on metals separation and recovery from waste ink-jet cartridges as a non-formal appealing learning activity for students of secondary schools 从废弃喷墨墨盒中分离和回收金属的实验室实验,作为面向中学生的非正规吸引力学习活动
Pub Date : 2024-05-13 DOI: 10.1515/cti-2023-0063
A. Rossi, Angela Serpe
Since 2004, the Italian Ministry of Education, University and Research (MIUR), the Conference of Science and Technology Headmasters, and Confindustria, have been promoting the National Plan for Scientific Degrees (PLS) aimed at supporting students in acquiring scientific skills better responding to contemporary society challenges and increasing vocations in basic sciences. This paper describes a successful experience of the University of Cagliari together with selected local secondary schools, in which the hot topic of technological waste valorization was selected to create an orientation laboratory for students towards chemistry disciplines. Specifically, students and teachers were guided into the challenging world of e-waste production and treatment through the practical activity of noble metals recovery from real waste ink-jet cartridges. A specific emphasis was placed on fundamental chemical aspects – separation and recovery of metals driven by redox processes favored by a complexing agent – as well as on the chance to play on coordination chemistry to promote a green chemistry approach. The close collaboration between school and university teachers in planning and implementing laboratory activities is the element that characterizes PLS actions and promotes the development and strengthening of relations between secondary school and university courses in science, technology, engineering, and mathematics (STEM).
自 2004 年以来,意大利教育、大学和研究部 (MIUR)、科技校长会议和 Confindustria 一直在推动国家科学学位计划 (PLS),旨在支持学生掌握科学技能,更好地应对当代社会的挑战,增加基础科学领域的就业机会。本文介绍了卡利亚里大学与当地部分中学合作的成功经验,其中选择了技术废物价值化这一热门话题,为学生创建一个化学学科定向实验室。具体而言,通过从真正的废弃喷墨墨盒中回收惰性金属的实践活动,引导学生和教师进入具有挑战性的电子废物生产和处理领域。重点特别放在基础化学方面--在络合剂的氧化还原过程驱动下进行金属的分离和回收,以及利用配位化学的机会推广绿色化学方法。学校和大学教师在规划和实施实验室活动方面的密切合作是 PLS 行动的特点,也促进了中 学和大学科学、技术、工程和数学(STEM)课程之间关系的发展和加强。
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引用次数: 0
Analysis of undergraduate chemistry students’ responses to substitution reaction mechanisms: a road to mastery 分析本科化学学生对取代反应机理的反应:通向掌握的道路
Pub Date : 2024-05-08 DOI: 10.1515/cti-2023-0075
Esther Nartey, Ernest Koranteng, Emmanuel Kyame Oppong, Ruby Hanson
This study analyzed third-year undergraduate Chemistry major students’ drawings and written explanations of substitution reactions. Seventy (70) students were purposively selected for this study. The main data collection instrument was a diagnostic test and students’ responses were analyzed using deductive coding. The study aimed to unearth students’ conceptual understanding and difficulties on substitution reactions to provide significant insights into improving teaching strategies and learning outcomes. The findings revealed that: 1. Students were more familiar with SN2 reaction mechanisms and could answer questions on SN2 reaction mechanisms better than SN1 reaction mechanisms; 2. Students’ use of ‘chemical vocabulary’ did not translate into an understanding of electron movement and causal mechanistic explanation; 3. About 97 % of the students who gave a correct/partially correct description provided a description of what was happening in the reaction without any further explanation of why the reaction occurred; 4. Students had a slightly better understanding of drawing the correct mechanisms than providing accurate explanations. This study recommends that, in teaching organic reaction mechanisms, instructors should emphasize on electron-pushing formalisms and explain how and why reactions occur to encourage mechanistic thinking in students. Also, students should be given ample practice in organic reaction mechanisms to improve mastery.
本研究分析了化学专业三年级本科生对置换反应的图画和书面解释。本研究有目的性地选取了七十(70)名学生。主要数据收集工具是一个诊断测试,学生的回答采用演绎编码法进行分析。研究旨在发现学生对置换反应的概念理解和困难,为改进教学策略和提高学习效果提供重要启示。研究结果表明1.2. 学生对 "化学词汇 "的使用并没有转化为对电子运动和因果机理解释的理解;3. 在给出正确/部分正确描述的学生中,约 97% 只描述了反应中发生的情况,而没有进一步解释反应发生的原因;4. 学生对绘制正确机理图的理解略好于提供准确解释。本研究建议,在教授有机反应机理时,教师应强调电子推动形式主义,并解释反应发生的过程和原因,以鼓励学生的机理思维。此外,应让学生进行充分的有机反应机理练习,以提高其掌握程度。
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引用次数: 0
Students’ perceptions towards the use of computer simulations in teaching and learning of chemistry in lower secondary schools 学生对初中化学教学中使用计算机模拟的看法
Pub Date : 2024-04-15 DOI: 10.1515/cti-2023-0064
Jane Batamuliza, Gonzague Habinshuti, Jean Baptiste Nkurunziza
The study aims to explore how students perceive the use of interactive computer simulations (ICS). The mixed-method approach under a converging design was employed to collect quantitative and qualitative data. A sample of 160 participants were purposively selected. The questionnaire consisted of four sections, including Behavioral Intention to Use, Attitude Toward Usage, Usefulness, and Perceived Ease of Use. The collected data was analyzed in MS Excel. 83 % of participants believed that their learning experience has improved and become easier. Moreover, a significant number of students 79 % expressed high perceptions towards the ease-of-use ICS in the teaching and learning process, and 77 % demonstrated a strong positive attitude towards the usage. Additionally, 76 % had a highly positive perception of their behavioral intention to use ICS in their chemistry learning. However, 39 % of students expressed low perceptions of ease of use of ICSs due to a lack of basic computer skills. In general, the findings show positive significance in students’ perceptions toward the use of ICSs in teaching and learning chemistry. The study recommends that ICSs should be used to supplement chemistry education.
本研究旨在探讨学生如何看待交互式计算机模拟(ICS)的使用。本研究采用了融合设计下的混合方法来收集定量和定性数据。研究有目的性地选取了 160 名参与者作为样本。问卷由四个部分组成,包括使用行为意向、使用态度、有用性和感知易用性。收集到的数据用 MS Excel 进行了分析。83% 的参与者认为他们的学习体验得到了改善,变得更加轻松。此外,79%的学生对综合控制系统在教学过程中的易用性表示高度认可,77%的学生对使用综合控制系统持积极态度。此外,76%的学生对在化学学习中使用综合控制系统的行为意向持非常积极的态度。然而,由于缺乏基本的计算机技能,39%的学生对综合学科系统的易用性评价较低。总的来说,研究结果表明,学生对在化学教学中使用综合布线系统的看法具有积极意义。研究建議應使用綜合系統輔助化學教學。
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引用次数: 0
Fractionating microplastics by density gradient centrifugation: a novel approach using LuerLock syringes in a low-cost density gradient maker 通过密度梯度离心分离微塑料:在低成本密度梯度离心机中使用 LuerLock 注射器的新方法
Pub Date : 2024-04-11 DOI: 10.1515/cti-2023-0079
Alina Majcen, J. Gohla, Anna S. Steinhoff, Lena Meißner, Sebastian Tassoti, Philipp Spitzer
Microplastics are now ubiquitous in the environment and are even considered “technofossils” of the Anthropocene. Given their omnipresence and potential impact, identifying and analyzing these particles becomes increasingly crucial. Novel approaches suggest density gradient centrifugation for simultaneous extraction and fractionation of microplastic particles based on their plastic-specific densities. In this article we describe a cheap and harmless experimental setting to fractionate microplastic particles by density gradient centrifugation. An innovative low-cost Do-It-Yourself (DIY) gradient maker using Luer-Lock syringes is presented. With this gradient maker it is possible to produce density gradients with water and sucrose solutions, covering a density range of 1.00–1.32 g/cm3, as well as with water and saturated potassium carbonate solutions, covering a density range of 1.06–1.53 g/cm3. The separation performance was tested with the most broadly used plastics polyamide, polyurethane, polycarbonate, polyethylene terephthalate and polyvinylchloride. Both density gradients show centrifugation stability and clear banding patterns after centrifugation. Due to its cheap and easy-to-build-easy-to-use nature, this experimental setting for microplastic fractionation by density gradient centrifugation offers an approach for schools not only to address the microplastic problems, but also to integrate new methods of microplastic analysis in upper secondary school laboratories.
微塑料如今在环境中无处不在,甚至被视为人类世的 "技术化石"。鉴于其无处不在和潜在影响,识别和分析这些微粒变得越来越重要。新方法建议采用密度梯度离心法,根据塑料的特异性密度对微塑料颗粒进行同步提取和分馏。在本文中,我们介绍了一种通过密度梯度离心分离微塑料颗粒的廉价、无害的实验装置。文章介绍了一种使用鲁尔锁注射器的创新型低成本自助梯度仪(DIY)。使用这种梯度仪,可以利用水和蔗糖溶液(密度范围为 1.00-1.32 g/cm3)以及水和饱和碳酸钾溶液(密度范围为 1.06-1.53 g/cm3)制作密度梯度。对聚酰胺、聚氨酯、聚碳酸酯、聚对苯二甲酸乙二酯和聚氯乙烯等最常用塑料的分离性能进行了测试。两种密度梯度在离心后都显示出离心稳定性和清晰的带状图案。密度梯度离心法的微塑料分馏实验装置价格便宜,易于制造和使用,不仅为学校解决微塑料问题提供了一种方法,而且为高中实验室整合微塑料分析的新方法提供了一种途径。
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引用次数: 0
EDITORIAL for Volume 6_1 第 6_1 卷编辑
Pub Date : 2024-03-28 DOI: 10.1515/cti-2024-2002
Mustafa Sözbilir
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引用次数: 0
List of reviewers contributing to volume 5, 2023 为 2023 年第 5 卷撰稿的审稿人名单
Pub Date : 2024-03-12 DOI: 10.1515/cti-2024-2001
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引用次数: 0
Consequences of the incorrect disposal of electronic waste when growing flower seedlings 种植花苗时错误处理电子垃圾的后果
Pub Date : 2024-02-29 DOI: 10.1515/cti-2023-0061
Karen Ouverney dos Santos, Cauã Paes de Almeida Martins, Maurício Luzetti de Oliveira Leite, Michel Alves Moura Andrade, Sophia da Cruz Augusto
The improper disposal of batteries has numerous consequences for the environment, since they contain potentially toxic metals that can be leached, infiltrating, and contaminating the soil layers, the groundwater, as well as the fauna and flora of nearby regions. Therefore, studies were conducted to simulate and analyze soil contamination by the release of potentially toxic metals from the incorrect disposal of alkaline batteries in the environment, in similar natural conditions, by doing leaching tests in fertilized soil resembling a landfill. Therefore, in this paper a simple experiment is proposed for sensitizing students toward the consequences of an incorrect disposal of batteries in the environment.
电池处理不当会对环境造成许多后果,因为电池中含有潜在的有毒金属,这些金属可能会浸出、渗入和污染土壤层、地下水以及附近地区的动植物。因此,通过在类似垃圾填埋场的肥沃土壤中进行沥滤试验,研究模拟和分析在类似自然条件下,碱性电池在环境中的错误处理所释放的潜在有毒金属对土壤造成的污染。因此,本文提出了一个简单的实验,让学生了解在环境中不正确处理电池的后果。
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引用次数: 0
Design of Jacob’s ladder-based teaching aids for illustrating the dualities of benzene derivatives 设计基于雅各布天梯的教具,用于说明苯衍生物的二元性
Pub Date : 2024-02-22 DOI: 10.1515/cti-2023-0038
R. Horikoshi, Hiroki Nakajima
The dualities of benzene derivatives often make basic organic chemistry challenging for students. This includes the relationship between full structural and line-angle formulas, the distinctions between preferred and systematic IUPAC names for benzene derivatives, and the nuances between ortho-, para-, and meta-directors. To effectively demonstrate these dualities of benzene derivatives, we have designed a range of teaching aids rooted in the folk toy, Jacob’s ladder. This paper presents lectures designed for advanced placement high school students and nonchemistry majors, employing this innovative series of Jacob’s ladder-based teaching aids. The majority of students found the lecture engaging, and many developed a comprehensive understanding of the dualities of benzene derivatives.
苯衍生物的双重性往往使基础有机化学对学生来说具有挑战性。这包括全结构式和线角式之间的关系,苯衍生物的首选名称和系统 IUPAC 名称之间的区别,以及正指示剂、副指示剂和元指示剂之间的细微差别。为了有效展示苯衍生物的这些双重性,我们设计了一系列植根于民间玩具雅各布天梯的教具。本文介绍了为高中高年级学生和非化学专业学生设计的讲座,其中采用了这一系列基于雅各布梯子的创新教具。大多数学生认为讲座引人入胜,许多学生对苯衍生物的二元性有了全面的了解。
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引用次数: 0
Learning about Confucian ecological ethics to promote education for sustainable development in Chinese secondary chemistry education 在中国中学化学教育中学习儒家生态伦理以促进可持续发展教育
Pub Date : 2024-02-12 DOI: 10.1515/cti-2023-0037
Baoyu Li, Ingo Eilks
Incorporating cultural aspects into science education has recently been stressed in many non-Western societies. However, Chinese traditional cultures are rarely discussed in Chinese science classrooms. Hence, a teaching intervention integrating Confucian ecological ethics and education for sustainable development in secondary chemistry classrooms was designed, implemented online due to the COVID-19 pandemic, and analyzed. It focuses on discussing aspects of Confucian ecological ethics in the context of a lesson plan on the socio-scientific issue of plastic use. Sixty-five 10th-grade students from an urban key public high school in Beijing voluntarily attended this research. Based on the analysis of their feedback it is suggested that Confucian ecological ethics can improve students’ environmental awareness. Most students acknowledged that Confucian ecological ethics could promote Chinese sustainability-oriented chemistry education with a value-oriented approach.
近来,许多非西方社会都在强调将文化因素纳入科学教育。然而,在中国的科学课堂上却很少讨论中国传统文化。因此,我们设计了一种在中学化学课堂中融入儒家生态伦理和可持续发展教育的教学干预措施,并因 COVID-19 大流行而在线实施和分析。其重点是在有关塑料使用这一社会科学问题的教案中讨论儒家生态伦理的各个方面。来自北京市一所城市重点公立高中的 65 名十年级学生自愿参加了此次研究。根据对学生反馈的分析,我们认为儒家生态伦理能够提高学生的环保意识。大多数学生认为,儒家生态伦理能够以价值为导向,促进中国可持续发展导向的化学教育。
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引用次数: 0
Learning about Confucian ecological ethics to promote education for sustainable development in Chinese secondary chemistry education 在中国中学化学教育中学习儒家生态伦理以促进可持续发展教育
Pub Date : 2024-02-12 DOI: 10.1515/cti-2023-0037
Baoyu Li, Ingo Eilks
Incorporating cultural aspects into science education has recently been stressed in many non-Western societies. However, Chinese traditional cultures are rarely discussed in Chinese science classrooms. Hence, a teaching intervention integrating Confucian ecological ethics and education for sustainable development in secondary chemistry classrooms was designed, implemented online due to the COVID-19 pandemic, and analyzed. It focuses on discussing aspects of Confucian ecological ethics in the context of a lesson plan on the socio-scientific issue of plastic use. Sixty-five 10th-grade students from an urban key public high school in Beijing voluntarily attended this research. Based on the analysis of their feedback it is suggested that Confucian ecological ethics can improve students’ environmental awareness. Most students acknowledged that Confucian ecological ethics could promote Chinese sustainability-oriented chemistry education with a value-oriented approach.
近来,许多非西方社会都在强调将文化因素纳入科学教育。然而,在中国的科学课堂上却很少讨论中国传统文化。因此,我们设计了一种在中学化学课堂中融入儒家生态伦理和可持续发展教育的教学干预措施,并因 COVID-19 大流行而在线实施和分析。其重点是在有关塑料使用这一社会科学问题的教案中讨论儒家生态伦理的各个方面。来自北京市一所城市重点公立高中的 65 名十年级学生自愿参加了此次研究。根据对学生反馈的分析,我们认为儒家生态伦理能够提高学生的环保意识。大多数学生认为,儒家生态伦理能够以价值为导向,促进中国可持续发展导向的化学教育。
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引用次数: 0
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Chemistry Teacher International
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