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Effect of Benzoyl Chloride and Fiber Loading on Mechanical Properties and Biodegradation of Poly Lactic Acid/Sugarcane Bagasse Fibre Composites 苯甲酰氯和纤维负载对聚乳酸/甘蔗渣纤维复合材料机械性能和生物降解的影响
Pub Date : 2024-01-01 DOI: 10.59324/ejaset.2023.1(1).05
Zubairu Zulyadain, J. M. Yelwa, Shuaibu Abdullahi, Ibrahim Umar Gwangwazo, Omolade Ojo
This study aimed to investigate the properties of benzoyl chloride modified and unmodified poly lactic acid and sugarcane bagasse fibre composites (PLA/SCBF), as well as the impact of chemical treatment on the mechanical and biodegradation properties of these composites. In this study, Fourier Transform Infrared (FTIR) Spectroscopy was employed to examine the benzoyl chloride modified and unmodified fibre samples. Additionally, Scanning Electron Microscope (SEM) and Thermal Gravimetric Analysis (TGA) techniques were utilised to investigate the morphology and thermal behaviour of the Poly lactic/SCBF composites. The results indicate that the use of benzoyl chloride treatment resulted in an increase in the tensile, flexural characteristics, impact strength, and hardness strength. The treatment with benzoyl chloride resulted in a reduction in both water absorption and biodegradability. The research also elucidated the impact of increasing the quantity of sugar cane bagasse on the aforementioned qualities. The addition of SCBF at higher loading resulted in a decrease in the tensile strength, biodegradability, flexural strength, and impact strength. The water absorption and hardness exhibited a positive correlation with the increase in fibre loading. The observed improvement in mechanical characteristics indicates that the treatment effectively enhanced the interfacial adhesion between SCBF and the PLA matrix. The enhancement of the interfacial adhesive forces was observed by the examination of scanning electron microscopy (SEM) micrographs. The Fourier Transform Infrared (FTIR) spectrum of the treated solvent-cast bamboo fibre (SCBF) exhibited the presence of a benzoyl group attached to the fibre, indicating successful benzoyl chloride treatment. Additionally, a modest reduction in hemicellulose content was seen following the treatment. The thermal characteristics of the modified PLA/SCBF composites were found to be enhanced based on the results obtained from the TGA-DTA analysis.
本研究旨在调查苯甲酰氯改性和未改性聚乳酸与甘蔗渣纤维复合材料(PLA/SCBF)的特性,以及化学处理对这些复合材料的机械和生物降解特性的影响。本研究采用傅立叶变换红外光谱法(FTIR)检测苯甲酰氯改性和未改性纤维样品。此外,还利用扫描电子显微镜(SEM)和热重力分析(TGA)技术研究了聚乳酸/SCBF 复合材料的形态和热性能。结果表明,使用苯甲酰氯处理可提高拉伸、弯曲特性、冲击强度和硬度。使用苯甲酰氯处理后,吸水性和生物降解性均有所降低。研究还阐明了增加甘蔗渣数量对上述质量的影响。添加更多的 SCBF 会导致拉伸强度、生物降解性、抗弯强度和冲击强度降低。吸水性和硬度与纤维添加量的增加呈正相关。所观察到的机械特性的改善表明,这种处理方法有效地增强了 SCBF 与聚乳酸基质之间的界面粘附力。通过扫描电子显微镜(SEM)显微照片可以观察到界面粘附力的增强。经处理的溶剂铸造竹纤维(SCBF)的傅立叶变换红外光谱显示,纤维上附着有苯甲酰基,表明苯甲酰氯处理成功。此外,处理后半纤维素含量略有减少。根据 TGA-DTA 分析得出的结果,改性聚乳酸/SCBF 复合材料的热特性得到了增强。
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引用次数: 0
Passenger Flow Prediction Method based on Hybrid Algorithm: Intelligent Transportation System 基于混合算法的客流预测方法智能交通系统
Pub Date : 2024-01-01 DOI: 10.59324/ejaset.2024.2(1).02
Ahmed Raza, Guangjie Liu, J. M. Adeke, Jie Cheng, Danish Attique
Forecasting passenger flow at metro transit stations is a useful method for optimizing the organization of passenger transportation and enhancing operational safety and transportation efficiency. Aiming at the problem that the traditional ARIMA model has poor performance in predicting passenger flow, a hybrid prediction method based on ARIMA-Kalman filtering is proposed. In this regard, ARIMA model training experimental samples are integrated with Kalman filter to create a prediction recursion equation, which is then utilized to estimate passenger flow. The simulation experiment results based on the inbound passenger flow data of Nanjing metro station show that compared with the single ARIMA model, the root mean square error of the prediction results of the proposed ARIMA-Kalman filter hybrid algorithm is reduced by 257.106, and the mean absolute error decreased by 145. 675, the mean absolute percentage error dropped by 5. 655%, proving that the proposed hybrid algorithm has higher prediction accuracy. The experiment results based on the passenger flow data of Nanjing metro station show that compared to a single ARIMA model, the proposed ARIMA Kalman filtering hybrid algorithm reduces the root mean square error of the prediction results by 257.106, the average absolute error by 145.675, and the average absolute percentage error by 5.655%. It has been proven that the proposed hybrid algorithm has higher prediction accuracy.
预测地铁站的客流量是优化客运组织、提高运营安全和运输效率的有效方法。针对传统的 ARIMA 模型在预测客流方面性能较差的问题,提出了一种基于 ARIMA-Kalman 滤波的混合预测方法。在此基础上,将 ARIMA 模型训练实验样本与卡尔曼滤波相结合,建立预测递推方程,然后利用该方程估算客流量。基于南京地铁站进站客流数据的仿真实验结果表明,与单一的 ARIMA 模型相比,所提出的 ARIMA-Kalman 滤波混合算法预测结果的均方根误差减少了 257.106,平均绝对误差减少了 145.675,平均绝对误差下降了 5. 655%,证明所提出的混合算法具有更高的预测精度。基于南京地铁站客流数据的实验结果表明,与单一ARIMA模型相比,所提出的ARIMA卡尔曼滤波混合算法的预测结果均方根误差降低了257.106,平均绝对误差降低了145.675,平均绝对百分比误差降低了5.655%。事实证明,所提出的混合算法具有更高的预测精度。
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引用次数: 0
Critical Impurity Densities in the Mott Metal-Insulator Transition, Obtained in Three n(p) - Type Degenerate GaAS1-xTex(Sbx,Px)-Crystalline Alloys 在三种 n(p) 型退相 GaAS1-xTex(Sbx,Px)晶体合金中获得的莫特金属-绝缘体转变中的临界杂质密度
Pub Date : 2024-01-01 DOI: 10.59324/ejaset.2024.2(1).05
Huynh Van Cong
By basing on the same physical model and treatment method, as used in our recent works [1, 2, 3, 4, 5], we will investigate the critical impurity densities in the metal-insulator transition (MIT), obtained in three n(p)-type degenerate [GaAs1−xTex,GaAs1−xTex,GaAs1−xTex]- crystalline alloys, 0≤x≤1, being due to the effects of the size of donor (acceptor) d(a)-radius, rd(a), the x-Ge concentration, and finally the high d(a)-density, N, assuming that all the impurities are ionized even at T=0 K. In such n(p)-type degenerate crystalline alloys, we will determine:(i)-the critical impurity densities NCDn(CDp)(rd(a),x) in the MIT, as that given in Eq. (10), by using an empirical Mott parameter
基于我们最近的研究成果[1, 2, 3, 4, 5]中使用的相同物理模型和处理方法,我们将研究在三种 n(p) 型退化[GaAs1-xTex,GaAs1-xTex,GaAs1-xTex]晶体合金(0≤x≤1)中获得的金属-绝缘体转变(MIT)临界杂质密度、GaAs1-xTex、GaAs1-xTex]- 晶体合金(0≤x≤1)中得到的临界杂质密度,这是由于供体(受体)d(a)半径 rd(a)、x-Ge 浓度以及高 d(a)-density N 的影响造成的。在这种 n(p)型退化结晶合金中,我们将通过使用经验莫特参数来确定:(i) MIT 中的临界杂质密度 NCDn(CDp)(rd(a),x),如公式 (10) 所示
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引用次数: 0
European Journal of Applied Science, Engineering and Technology www.ejaset.com 26 Construction of Numerical PVT-Models for the Bulla-Daniz Gas-Condensate Field Based on Laboratory Experiments on Reservoir Fluid Samples 欧洲应用科学、工程和技术期刊》 www.ejaset.com 26 根据储层流体样本实验室实验构建布拉-达尼兹天然气凝析气田数值 PVT 模型
Pub Date : 2024-01-01 DOI: 10.59324/ejaset.2024.2(1).04
Mehdi Huseynov, Natig Hamidov, J. Eyvazov
PVT analysis is important for field-wide optimization and development. This is because we must understand the fluid's overall behavior from the reservoir to the production and processing facilities, and ultimately to the refinery. Modern computer software that uses equation of state (EOS) models to simulate experiments and illustrate fluid phase characteristics has contributed to its growth as a distinct field of study. To find the operating parameters that will maximize the surface liquid content and prolong the production plateau duration at the lowest feasible cost, PVT simulations are run. These simulations employ laboratory-derived data to fine-tune the EOS models, with the outcomes being integrated into reservoir simulation and research. The quality of the data is crucial to getting a good match between EOS and laboratory data, and for retrograde gas condensates, this can be particularly difficult because of their complex phase behavior. When utilized in reservoir simulations, an inadequate match leads to computational mistakes and unrepresentative findings, endangering the reservoir management decisions that depend on it.
PVT 分析对于整个油田的优化和开发非常重要。这是因为我们必须了解流体从储层到生产和加工设施,最终到炼油厂的整体行为。现代计算机软件使用状态方程(EOS)模型来模拟实验并说明流体相位特征,这促使其发展成为一个独特的研究领域。为了找到能以最低可行成本获得最大表面液体含量并延长生产高原持续时间的操作参数,需要进行 PVT 模拟。这些模拟利用实验室数据对 EOS 模型进行微调,并将结果纳入储层模拟和研究中。数据的质量对于 EOS 与实验室数据的良好匹配至关重要,而对于逆行气体凝析物来说,由于其复杂的相态行为,这一点尤为困难。在储层模拟中使用时,不适当的匹配会导致计算错误和不具代表性的结果,从而危及储层管理决策。
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引用次数: 0
期刊
European Journal of Applied Science, Engineering and Technology
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