首页 > 最新文献

International Journal of Lightweight Materials and Manufacture最新文献

英文 中文
Effect of retrogression and reaging (RRA) on pitting and stress corrosion cracking (SCC) resistance of stir zone of high strength AA7075-T651 alloy joined by friction stir welding 回火和再时效(RRA)对搅拌摩擦焊接高强度AA7075-T651合金搅拌区耐点蚀和应力腐蚀开裂(SCC)性能的影响
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.12.002
P. Prabhuraj , S. Rajakumar , Tushar Sonar , Mikhail Ivanov , I. Rajkumar , D. Elil Raja

The main purpose of this study is to investigate the influence of retrogression and re-aging post weld heat treatment (RRA-PWHT) on potentiodynamic corrosion (PC) and stress corrosion cracking resistance (SCC) of stir zone (SZ) of AA7075-T651 alloy butt joints developed using friction stir welding (FSW). FSW was employed to overcome the problems in fusion welding of AA7075-T651 alloy such as solidification cracking, heat affected zone (HAZ) softening, grain coarsening, dissolution of strengthening precipitates and inferior mechanical performance. The SZ of joints were subjected to potentiodynamic corrosion test in 3.56 wt% NaCl solution. The circumferential notch tensile (CNT) specimens were subjected to SCC test at various conditions of axial stress level in 3.56 wt% NaCl solution. The microstructural features of butt joints SZ were characterized using optical (OM), scanning electron (SEM) and transmission electron microscope (TEM). The results disclosed that RRA-PWHT joints exhibited greater PC and SCC resistance compared to as-welded joints. The threshold stress level for the failure of CNT specimens of parent metal, as-welded joints and RRA-PWHT joints was 242 MPa, 175 MPa and 198 MPa, respectively. The threshold stress level of RRA-PWHT joints and as-welded joints is 81.81% and 72.31% of parent metal threshold stress level. It is correlated to increase in vol% and coarsening of grain boundary precipitates with enrichment of copper at the grain boundaries.

本研究的主要目的是研究倒退和再时效焊后热处理(RRA-PWHT)对搅拌摩擦焊AA7075-T651合金对接接头搅拌区(SZ)的动电位腐蚀(PC)和应力腐蚀开裂(SCC)的影响。针对AA7075-T651合金在熔焊过程中出现的凝固开裂、热影响区(HAZ)软化、晶粒粗化、强化析出物溶解、力学性能差等问题,采用FSW进行了焊接。接头的SZ在3.56wt%的NaCl溶液中进行了动电位腐蚀试验。在3.56wt%NaCl溶液中,在轴向应力水平的各种条件下对周向缺口拉伸(CNT)试样进行SCC测试。利用光学(OM)、扫描电子(SEM)和透射电子显微镜(TEM)对SZ对接接头的微观结构特征进行了表征。结果表明,与焊接接头相比,RRA-PWHT接头表现出更大的PC和SCC阻力。母体金属CNT试样、焊接接头和RRA-PWHT接头的失效阈值应力水平分别为242MPa、175MPa和198MPa。RRA-PWHT接头和焊接接头的阈值应力水平分别为母材阈值应力的81.81%和72.31%。它与体积%的增加和晶界沉淀物的粗化以及晶界处铜的富集有关。
{"title":"Effect of retrogression and reaging (RRA) on pitting and stress corrosion cracking (SCC) resistance of stir zone of high strength AA7075-T651 alloy joined by friction stir welding","authors":"P. Prabhuraj ,&nbsp;S. Rajakumar ,&nbsp;Tushar Sonar ,&nbsp;Mikhail Ivanov ,&nbsp;I. Rajkumar ,&nbsp;D. Elil Raja","doi":"10.1016/j.ijlmm.2022.12.002","DOIUrl":"https://doi.org/10.1016/j.ijlmm.2022.12.002","url":null,"abstract":"<div><p>The main purpose of this study is to investigate the influence of retrogression and re-aging post weld heat treatment (RRA-PWHT) on potentiodynamic corrosion (PC) and stress corrosion cracking resistance (SCC) of stir zone (SZ) of AA7075-T651 alloy butt joints developed using friction stir welding (FSW). FSW was employed to overcome the problems in fusion welding of AA7075-T651 alloy such as solidification cracking, heat affected zone (HAZ) softening, grain coarsening, dissolution of strengthening precipitates and inferior mechanical performance. The SZ of joints were subjected to potentiodynamic corrosion test in 3.56 wt% NaCl solution. The circumferential notch tensile (CNT) specimens were subjected to SCC test at various conditions of axial stress level in 3.56 wt% NaCl solution. The microstructural features of butt joints SZ were characterized using optical (OM), scanning electron (SEM) and transmission electron microscope (TEM). The results disclosed that RRA-PWHT joints exhibited greater PC and SCC resistance compared to as-welded joints. The threshold stress level for the failure of CNT specimens of parent metal, as-welded joints and RRA-PWHT joints was 242 MPa, 175 MPa and 198 MPa, respectively. The threshold stress level of RRA-PWHT joints and as-welded joints is 81.81% and 72.31% of parent metal threshold stress level. It is correlated to increase in vol% and coarsening of grain boundary precipitates with enrichment of copper at the grain boundaries.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 264-277"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50191614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of process parameters on deposition rate and coating roughness of electro discharge deposition on AA7075 aluminium alloy 工艺参数对AA7075铝合金放电沉积速率和涂层粗糙度的影响
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.11.001
K. Nallathambi , C. Senthilkumar , U. Elaiyarasan , M. Seeman

Nowadays, surface modification techniques are a big part of making metals and alloys better on the outside. Even though various metals and alloys are coated using surface modification techniques, improving the surface properties of the light alloys is difficult. To improve the surface properties of light alloys, electro-thermal techniques, namely electro discharge deposition (EDD), are suitable. Hence, in this investigation, a fly ash (FA)–copper (Cu) composite coating was developed on AA7075 using electro discharge deposition. The FA–Cu composite electrodes were manufactured by the powder metallurgy method. The effects of discharge current, pulse on time, and pulse off time on deposition rate (DR) and coating roughness (CR) have been studied. Tests were carried out according to the design matrix generated by central composite design in response surface methodology (RSM). An ANOVA was performed to determine the optimum parametric conditions for the responses. Pulse off time was the dominating parameter followed by discharge current and pulse on time for attaining the best response. Higher values of current, pulse on time, and pulse off time led to higher DR and CR values. Higher discharge current produced sufficient spark strength that melted both the tool electrode and the workpiece. The lower setting of parameters offered smooth roughness due to the even spark distribution. At a current of 8 A, bigger craters were observed due to the higher spark intensity that made the surface hard. The uneven mass was produced with a deeper shallow crater, resulting in a poor surface.

如今,表面改性技术是使金属和合金外观更好的重要组成部分。即使使用表面改性技术涂覆各种金属和合金,改善轻合金的表面性能也是困难的。为了改善轻合金的表面性能,电热技术,即放电沉积(EDD)是合适的。因此,在本研究中,使用放电沉积在AA7075上开发了粉煤灰(FA)-铜(Cu)复合涂层。采用粉末冶金方法制备了FA–Cu复合电极。研究了放电电流、脉冲开启时间和脉冲关闭时间对沉积速率(DR)和涂层粗糙度(CR)的影响。根据响应面法(RSM)中中央复合材料设计生成的设计矩阵进行测试。进行方差分析以确定响应的最佳参数条件。脉冲关断时间是获得最佳响应的主要参数,其次是放电电流和脉冲接通时间。电流、脉冲接通时间和脉冲断开时间的值越高,DR和CR值越高。较高的放电电流产生足够的火花强度,使工具电极和工件都熔化。由于火花分布均匀,较低的参数设置提供了平滑的粗糙度。在8A的电流下,由于较高的火花强度使表面变硬,观察到了更大的弹坑。不均匀的质量是由一个更深的浅坑产生的,导致表面不平整。
{"title":"Effect of process parameters on deposition rate and coating roughness of electro discharge deposition on AA7075 aluminium alloy","authors":"K. Nallathambi ,&nbsp;C. Senthilkumar ,&nbsp;U. Elaiyarasan ,&nbsp;M. Seeman","doi":"10.1016/j.ijlmm.2022.11.001","DOIUrl":"10.1016/j.ijlmm.2022.11.001","url":null,"abstract":"<div><p>Nowadays, surface modification techniques are a big part of making metals and alloys better on the outside. Even though various metals and alloys are coated using surface modification techniques, improving the surface properties of the light alloys is difficult. To improve the surface properties of light alloys, electro-thermal techniques, namely electro discharge deposition (EDD), are suitable. Hence, in this investigation, a fly ash (FA)–copper (Cu) composite coating was developed on AA7075 using electro discharge deposition. The FA–Cu composite electrodes were manufactured by the powder metallurgy method. The effects of discharge current, pulse on time, and pulse off time on deposition rate (DR) and coating roughness (CR) have been studied. Tests were carried out according to the design matrix generated by central composite design in response surface methodology (RSM). An ANOVA was performed to determine the optimum parametric conditions for the responses. Pulse off time was the dominating parameter followed by discharge current and pulse on time for attaining the best response. Higher values of current, pulse on time, and pulse off time led to higher DR and CR values. Higher discharge current produced sufficient spark strength that melted both the tool electrode and the workpiece. The lower setting of parameters offered smooth roughness due to the even spark distribution. At a current of 8 A, bigger craters were observed due to the higher spark intensity that made the surface hard. The uneven mass was produced with a deeper shallow crater, resulting in a poor surface.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 238-244"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45067258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel triple-layer hot stamping process of titanium alloy TC4 sheet for enhancing formability and its application in a plug socket part 钛合金TC4板三层热冲压成形新工艺及其在插头插座零件中的应用
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.10.003
Yanhong Mu , Xiaoming Yang , Baoyu Wang , Haitao Qu , Fulong Chen

In this paper, a novel method was proposed to improve the production efficiency and formability of titanium alloy, which was named triple-layer sheet hot stamping with a cold die cooling (THF). The titanium alloy sheet was clamped by two steel sheets with no adhesive added, then heated, transferred and formed together. In order to verify the ability in enhancing formability of this process, spherical part forming tests were carried out to study the formability under the single-layer sheet hot stamping (SHF) and THF. Finally, a plug socket part was formed to verify the practicability of the novel forming process. The finite element (FE) model was established to analyze the forming process finding that the formability of the parts were significantly improved after using THF process. Comparing with SHF process, the stamping depth increases by 135.7% at 900 °C in the THF process. The forming limit strain increases from 0.18 of the single-layer sheet to 0.51 of the triple-layer sheet. The forming limit strain obtained by the THF process is close to that of isothermal forming. The friction state is one of the main reason for improving formability. Moreover, for plug socket parts, there is almost no thinning of the part in the THF process at 900 °C. In conclusion, it has great advantages in improving the formability of titanium alloy using the THF process.

本文提出了一种提高钛合金生产效率和成形性的新方法,即冷模冷却三层薄板热冲压(THF)。钛合金片由两块不添加粘合剂的钢板夹持,然后加热、转移并形成在一起。为了验证该工艺提高成形性的能力,进行了球形零件成形试验,研究了单层片材热冲压(SHF)和THF下的成形性。最后,对插头插座零件进行了成形,验证了该成形工艺的实用性。通过建立有限元模型对成形过程进行分析,发现采用THF工艺后,零件的成形性得到了显著改善。与SHF工艺相比,THF工艺在900°C时的冲压深度增加了135.7%。成形极限应变从单层片材的0.18增加到三层片材的0.51。通过THF工艺获得的成形极限应变接近于等温成形的极限应变。摩擦状态是提高成形性的主要原因之一。此外,对于插头插座零件,在900°C的THF工艺中,零件几乎没有变薄。总之,使用THF工艺在改善钛合金的成形性方面具有很大的优势。
{"title":"A novel triple-layer hot stamping process of titanium alloy TC4 sheet for enhancing formability and its application in a plug socket part","authors":"Yanhong Mu ,&nbsp;Xiaoming Yang ,&nbsp;Baoyu Wang ,&nbsp;Haitao Qu ,&nbsp;Fulong Chen","doi":"10.1016/j.ijlmm.2022.10.003","DOIUrl":"https://doi.org/10.1016/j.ijlmm.2022.10.003","url":null,"abstract":"<div><p>In this paper, a novel method was proposed to improve the production efficiency and formability of titanium alloy, which was named triple-layer sheet hot stamping with a cold die cooling (THF). The titanium alloy sheet was clamped by two steel sheets with no adhesive added, then heated, transferred and formed together. In order to verify the ability in enhancing formability of this process, spherical part forming tests were carried out to study the formability under the single-layer sheet hot stamping (SHF) and THF. Finally, a plug socket part was formed to verify the practicability of the novel forming process. The finite element (FE) model was established to analyze the forming process finding that the formability of the parts were significantly improved after using THF process. Comparing with SHF process, the stamping depth increases by 135.7% at 900 °C in the THF process. The forming limit strain increases from 0.18 of the single-layer sheet to 0.51 of the triple-layer sheet. The forming limit strain obtained by the THF process is close to that of isothermal forming. The friction state is one of the main reason for improving formability. Moreover, for plug socket parts, there is almost no thinning of the part in the THF process at 900 °C. In conclusion, it has great advantages in improving the formability of titanium alloy using the THF process.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 189-197"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50191554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of post-processing CO2 laser cutting and FFF 3D printing parameters on the surface morphology of PLAs: Statistical modelling and RSM optimisation 后处理CO2激光切割和FFF 3D打印参数对PLAs表面形态的影响:统计建模和RSM优化
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2023.01.004
M. Karamimoghadam , M. Lalegani Dezaki , A. Zolfagharian , M. Bodaghi

This study investigates the optimization of 3D printing and CO2 laser cutting parameters by the design of experiments (DOE) and response surface methodology (RSM). In fused filament fabrication (FFF) process, the surface quality of printed curves is poor due to the stairstep defects. The aim is to determine how the laser cutting parameters affect the surface morphology of surface finishing polylactic acid (PLA) samples. A total of 13 cube shape samples are 3D-printed with a cone-shaped hole in the middle. Then, post-processing CO2 laser cutting with a maximum power of 1 kW is used to cut the 3D-printed products. Infill percentage (IP) and extruder temperature (ET) in 3D printing, and laser power (LP), scanning speed (SS), and top edge in CO2 laser cutting are the main parameters in this study. Regression equations are obtained by doing an analysis of the experimental findings using statistical software to examine the impacts of process factors on surface conditions. Results show that the infill percentage and extruder temperature have an extraordinary effect on 3D-printed products' surface quality. 30% infill percentage and 190 °C extruder temperature result in the lowest surface quality with a value of 2.151 μm using DOE and RSM optimization. Also, the lowest value of the top edge is achieved at 275 μm with 300 W laser power and a 5 mm/s cutting speed. The proposed methods can be used to reduce material consumption in the product development.

本研究通过实验设计(DOE)和响应面方法(RSM)研究了3D打印和CO2激光切割参数的优化。在熔融丝制造(FFF)工艺中,由于台阶缺陷,印刷曲线的表面质量较差。目的是确定激光切割参数如何影响表面处理聚乳酸(PLA)样品的表面形态。共有13个立方体形状的样本被3D打印,在中间有一个锥形孔。然后,使用最大功率为1kW的后处理CO2激光切割来切割3D打印产品。3D打印中的填充百分比(IP)和挤出机温度(ET),以及CO2激光切割中的激光功率(LP)、扫描速度(SS)和顶部边缘是本研究的主要参数。回归方程是通过使用统计软件对实验结果进行分析来获得的,以检验工艺因素对表面条件的影响。结果表明,填充率和挤出机温度对3D打印产品的表面质量有着显著的影响。使用DOE和RSM优化,30%的填充百分比和190°C的挤出机温度导致最低的表面质量,其值为2.151μm。此外,在300 W激光功率和5 mm/s切割速度的情况下,顶部边缘的最低值在275μm处实现。所提出的方法可用于降低产品开发中的材料消耗。
{"title":"Influence of post-processing CO2 laser cutting and FFF 3D printing parameters on the surface morphology of PLAs: Statistical modelling and RSM optimisation","authors":"M. Karamimoghadam ,&nbsp;M. Lalegani Dezaki ,&nbsp;A. Zolfagharian ,&nbsp;M. Bodaghi","doi":"10.1016/j.ijlmm.2023.01.004","DOIUrl":"https://doi.org/10.1016/j.ijlmm.2023.01.004","url":null,"abstract":"<div><p>This study investigates the optimization of 3D printing and CO<sub>2</sub> laser cutting parameters by the design of experiments (DOE) and response surface methodology (RSM). In fused filament fabrication (FFF) process, the surface quality of printed curves is poor due to the stairstep defects. The aim is to determine how the laser cutting parameters affect the surface morphology of surface finishing polylactic acid (PLA) samples. A total of 13 cube shape samples are 3D-printed with a cone-shaped hole in the middle. Then, post-processing CO<sub>2</sub> laser cutting with a maximum power of 1 kW is used to cut the 3D-printed products. Infill percentage (IP) and extruder temperature (ET) in 3D printing, and laser power (LP), scanning speed (SS), and top edge in CO<sub>2</sub> laser cutting are the main parameters in this study. Regression equations are obtained by doing an analysis of the experimental findings using statistical software to examine the impacts of process factors on surface conditions. Results show that the infill percentage and extruder temperature have an extraordinary effect on 3D-printed products' surface quality. 30% infill percentage and 190 °C extruder temperature result in the lowest surface quality with a value of 2.151 μm using DOE and RSM optimization. Also, the lowest value of the top edge is achieved at 275 μm with 300 W laser power and a 5 mm/s cutting speed. The proposed methods can be used to reduce material consumption in the product development.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 285-295"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50191613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
A short review on high strain rate superplasticity in magnesium-based composites materials 镁基复合材料的高应变速率超塑性研究进展
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.10.004
Abdul Malik , Yangwei Wang

Magnesium composites are next-generation lightweight materials for aerospace and military industries. However, the complex shape components of magnesium composites cannot be designed at ambient temperature, therefore, they need to be processed at elevated temperatures. Generally, material at elevated temperatures displays superplasticity. It is more interesting that magnesium composites exhibite high strain rate superplasticity compared to aluminum alloys. Therefore, this review article sheds light on the superplastic deformation behavior of magnesium composites fabricated by different routes. Further, the stress-energy, cavitation nucleation and its impact on the elongation to fracture have been explored. At the end of the review article, some terrifying unresolved subjects have been addressed, so that their potential use can be enhanced as complex shape components.

镁复合材料是用于航空航天和军事工业的下一代轻质材料。然而,镁复合材料的复杂形状部件不能在环境温度下设计,因此需要在高温下进行加工。通常,材料在高温下表现出超塑性。更令人感兴趣的是,与铝合金相比,镁复合材料表现出高应变速率超塑性。因此,本文对不同工艺路线制备的镁基复合材料的超塑性变形行为进行了研究。此外,还探讨了应力能、空穴形核及其对断裂伸长率的影响。在这篇综述文章的最后,我们讨论了一些可怕的尚未解决的主题,以便作为复杂的形状组件来增强它们的潜在用途。
{"title":"A short review on high strain rate superplasticity in magnesium-based composites materials","authors":"Abdul Malik ,&nbsp;Yangwei Wang","doi":"10.1016/j.ijlmm.2022.10.004","DOIUrl":"10.1016/j.ijlmm.2022.10.004","url":null,"abstract":"<div><p>Magnesium composites are next-generation lightweight materials for aerospace and military industries. However, the complex shape components of magnesium composites cannot be designed at ambient temperature, therefore, they need to be processed at elevated temperatures. Generally, material at elevated temperatures displays superplasticity. It is more interesting that magnesium composites exhibite high strain rate superplasticity compared to aluminum alloys. Therefore, this review article sheds light on the superplastic deformation behavior of magnesium composites fabricated by different routes. Further, the stress-energy, cavitation nucleation and its impact on the elongation to fracture have been explored. At the end of the review article, some terrifying unresolved subjects have been addressed, so that their potential use can be enhanced as complex shape components.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 214-224"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49255660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
A review on flexibility of free bending forming technology for manufacturing thin-walled complex-shaped metallic tubes 薄壁复杂形状金属管自由弯曲成形技术柔性综述
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.09.007
Ali Abd El-Aty , Xunzhong Guo , Myoung-Gyu Lee , Jie Tao , Yong Hou , Shenghan Hu , Tao Li , Cong Wu , Qiucheng Yang

Free bending forming (FBF) is a flexible forming technology that gained significant attention recently because of its broad applications in critical industries such as the automotive, aerospace, and nuclear industries. Thus, this paper aims to present a comprehensive review of FBF technology and its flexibility in manufacturing thin-walled complex-shaped metallic tubes with variable curvatures. First, the historical development and state of the art of FBF technology were reviewed and discussed its importance in tube forming recently. Then, the fundamental principles, theoretical modelling, deformation mechanisms during complex bending, critical process parameters, and forming defects with a discussion of the recent research and technological developments of FBF technology under three-, five- and six-axis processes were explained. After that, the system dies and tools design of the FBF machines and the trajectory control of the bending die were presented. Afterwards, the mechanisms of manufacturing spiral and involute hollow metallic tubes and outstanding solutions for critical issues during tube manufacturing, such as springback, cross-section deformation, over-thinning (even cracking), and wrinkling instability were introduced. Finally, the paper is concluded by providing the discussions on the system, die and tool design methodology, and outlook of the FBF technology.

自由弯曲成形(FBF)是一种柔性成形技术,由于其在汽车、航空航天和核工业等关键行业的广泛应用,近年来备受关注。因此,本文旨在全面综述FBF技术及其在制造变曲率薄壁复杂形状金属管方面的灵活性。首先,回顾了FBF技术的历史发展和技术现状,并讨论了其在管材成型中的重要性。然后,阐述了FBF技术在三轴、五轴和六轴工艺下的基本原理、理论建模、复杂弯曲变形机制、关键工艺参数和成形缺陷,并讨论了FBF工艺的最新研究和技术发展。然后,介绍了FBF机床的系统模具和工具设计以及弯曲模具的轨迹控制。然后,介绍了螺旋和渐开线中空金属管的制造机理,以及在管制造过程中关键问题(如回弹、截面变形、过薄(甚至开裂)和起皱不稳定性)的突出解决方案。最后,本文对FBF技术的系统、模具和工具设计方法以及展望进行了讨论。
{"title":"A review on flexibility of free bending forming technology for manufacturing thin-walled complex-shaped metallic tubes","authors":"Ali Abd El-Aty ,&nbsp;Xunzhong Guo ,&nbsp;Myoung-Gyu Lee ,&nbsp;Jie Tao ,&nbsp;Yong Hou ,&nbsp;Shenghan Hu ,&nbsp;Tao Li ,&nbsp;Cong Wu ,&nbsp;Qiucheng Yang","doi":"10.1016/j.ijlmm.2022.09.007","DOIUrl":"10.1016/j.ijlmm.2022.09.007","url":null,"abstract":"<div><p>Free bending forming (FBF) is a flexible forming technology that gained significant attention recently because of its broad applications in critical industries such as the automotive, aerospace, and nuclear industries. Thus, this paper aims to present a comprehensive review of FBF technology and its flexibility in manufacturing thin-walled complex-shaped metallic tubes with variable curvatures. First, the historical development and state of the art of FBF technology were reviewed and discussed its importance in tube forming recently. Then, the fundamental principles, theoretical modelling, deformation mechanisms during complex bending, critical process parameters, and forming defects with a discussion of the recent research and technological developments of FBF technology under three-, five- and six-axis processes were explained. After that, the system dies and tools design of the FBF machines and the trajectory control of the bending die were presented. Afterwards, the mechanisms of manufacturing spiral and involute hollow metallic tubes and outstanding solutions for critical issues during tube manufacturing, such as springback, cross-section deformation, over-thinning (even cracking), and wrinkling instability were introduced. Finally, the paper is concluded by providing the discussions on the system, die and tool design methodology, and outlook of the FBF technology.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 165-188"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45603225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Machinability and surface integrity investigation during helical hole milling in AZ31 magnesium alloy AZ31镁合金螺旋孔铣削加工的可加工性和表面完整性研究
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.09.006
Raviraja Adhikari , Gururaj Bolar , Ragavanantham Shanmugam , Ugur Koklu

Conventional drilling has been widely used for making holes in structural materials. However, drawbacks like high cutting forces, poor surface finish, high cutting temperatures, excessive tool wear, and undesirable burr formation while drilling magnesium alloys have necessitated the development of alternative hole-making methods. Lately, the helical milling process has attracted interest in facilitating hole-making for assembly applications. However, the machinability of magnesium alloys using the helical milling process needs more investigation. Therefore, the presented work analyzed the influence of axial pitch, tangential feed, and spindle speed on cutting forces and surface integrity while milling AZ31 magnesium alloy. Axial feed was the most crucial factor contributing to the thrust force (71.8%), followed by tangential feed (13.2%). All three process variables impacted the radial force. Spindle speed was the most influential variable affecting the surface roughness (48.7%), followed by axial pitch (31.4%) and tangential feed (12.5%). Microhardness closer to the free surface of the hole was higher than the subsurface hardness. Moreover, microhardness showed an upward trend with the rise in axial pitch and tangential feed; however, it reduced with increased spindle speed.

传统钻孔已被广泛用于在结构材料中钻孔。然而,在钻镁合金时,存在切削力高、表面光洁度差、切削温度高、刀具过度磨损和不希望形成毛刺等缺点,因此需要开发替代的制孔方法。最近,螺旋铣削工艺吸引了人们对促进组装应用的孔制造的兴趣。然而,使用螺旋铣削工艺的镁合金的可加工性需要更多的研究。因此,本文分析了在铣削AZ31镁合金时,轴向螺距、切向进给和主轴速度对切削力和表面完整性的影响。轴向进给是影响推力的最关键因素(71.8%),其次是切向进给(13.2%)。所有三个过程变量都影响径向力。主轴转速是影响表面粗糙度的最大变量(48.7%),其次是轴向螺距(31.4%)和切向进给(12.5%)。接近孔自由表面的显微硬度高于表面下硬度。显微硬度随轴向螺距和切向进给量的增加呈上升趋势;然而,它随着主轴速度的增加而减小。
{"title":"Machinability and surface integrity investigation during helical hole milling in AZ31 magnesium alloy","authors":"Raviraja Adhikari ,&nbsp;Gururaj Bolar ,&nbsp;Ragavanantham Shanmugam ,&nbsp;Ugur Koklu","doi":"10.1016/j.ijlmm.2022.09.006","DOIUrl":"10.1016/j.ijlmm.2022.09.006","url":null,"abstract":"<div><p>Conventional drilling has been widely used for making holes in structural materials. However, drawbacks like high cutting forces, poor surface finish, high cutting temperatures, excessive tool wear, and undesirable burr formation while drilling magnesium alloys have necessitated the development of alternative hole-making methods. Lately, the helical milling process has attracted interest in facilitating hole-making for assembly applications. However, the machinability of magnesium alloys using the helical milling process needs more investigation. Therefore, the presented work analyzed the influence of axial pitch, tangential feed, and spindle speed on cutting forces and surface integrity while milling AZ31 magnesium alloy. Axial feed was the most crucial factor contributing to the thrust force (71.8%), followed by tangential feed (13.2%). All three process variables impacted the radial force. Spindle speed was the most influential variable affecting the surface roughness (48.7%), followed by axial pitch (31.4%) and tangential feed (12.5%). Microhardness closer to the free surface of the hole was higher than the subsurface hardness. Moreover, microhardness showed an upward trend with the rise in axial pitch and tangential feed; however, it reduced with increased spindle speed.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 149-164"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42694873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Evolution of segregation, microstructure and mechanical properties of a semisolid die casting Al–6Si–3Cu–0.4Mg alloy Al-6Si-3Cu-0.4Mg半固态压铸合金偏析、显微组织及力学性能演变
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.11.002
Jian Feng , Zikang Liu , Daquan Li , Jiahui Zhu , Song Chen , Fan Zhang , Fan Zhang , Xianchao Hao

Study on segregation, microstructure and mechanical properties of Al–6Si–3Cu–0.4Mg alloy was achieved by controlling the filling length in semisolid die casting. Results show that the microstructure is comprised of globular α–Al, eutectic Si, θ–Al2Cu, Q–Al5Cu2Mg8Si6 and Fe–rich phase. After solution–ageing treatment, abundant θ–Al2Cu and Q–Al5Cu2Mg8Si6 phases dissolve into the matrix. The liquid difference between the edge and middle area is 21.3% for 1/3 filling length, which is much higher than that of 15.0% for full filling length. As the filling length decreases, the increment of segregation degree at the bottom of the sample is detected. This segregation behavior leads to the strength and ductility both decreases from 425.0 MPa and 6.5% for 1/3 filling length to 405.3 MPa and 4.4% for full filling length, respectively. Besides, along with the formation of abundant fine θ–Al2Cu phase and higher liquid fraction at the edge area, the ultimate tensile strength and elongation reaches 443.5 MPa and 5.2%. While in center area, the occurrence of coarsen θ–Al2Cu phases leads to the tensile properties dramatically reducing to 378.7 MPa and 1.9%.

通过控制半固态压铸中的填充长度,对Al–6Si–3Cu–0.4Mg合金的偏析、组织和力学性能进行了研究。结果表明,显微组织由球状α–Al、共晶Si、θ–Al2Cu、Q–Al5Cu2Mg8Si6和富Fe相组成。固溶-时效处理后,大量的θ–Al2Cu和Q–Al5Cu2Mg8Si6相溶解到基体中。对于1/3填充长度,边缘和中间区域之间的液体差为21.3%,远高于全填充长度的15.0%。随着填充长度的减小,检测到样品底部偏析程度的增加。这种偏析行为导致强度和延性分别从1/3填充长度的425.0MPa和6.5%下降到全填充长度的405.3MPa和4.4%。此外,随着在边缘区域形成丰富的细θ–Al2Cu相和较高的液体分数,极限抗拉强度和伸长率分别达到443.5MPa和5.2%。而在中心区域,θ–Al2Cu相的出现导致拉伸性能显著降低至378.7MPa和1.9%。
{"title":"Evolution of segregation, microstructure and mechanical properties of a semisolid die casting Al–6Si–3Cu–0.4Mg alloy","authors":"Jian Feng ,&nbsp;Zikang Liu ,&nbsp;Daquan Li ,&nbsp;Jiahui Zhu ,&nbsp;Song Chen ,&nbsp;Fan Zhang ,&nbsp;Fan Zhang ,&nbsp;Xianchao Hao","doi":"10.1016/j.ijlmm.2022.11.002","DOIUrl":"10.1016/j.ijlmm.2022.11.002","url":null,"abstract":"<div><p>Study on segregation, microstructure and mechanical properties of Al–6Si–3Cu–0.4Mg alloy was achieved by controlling the filling length in semisolid die casting. Results show that the microstructure is comprised of globular α–Al, eutectic Si, θ–Al<sub>2</sub>Cu, Q–Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> and Fe–rich phase. After solution–ageing treatment, abundant θ–Al<sub>2</sub>Cu and Q–Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> phases dissolve into the matrix. The liquid difference between the edge and middle area is 21.3% for 1/3 filling length, which is much higher than that of 15.0% for full filling length. As the filling length decreases, the increment of segregation degree at the bottom of the sample is detected. This segregation behavior leads to the strength and ductility both decreases from 425.0 MPa and 6.5% for 1/3 filling length to 405.3 MPa and 4.4% for full filling length, respectively. Besides, along with the formation of abundant fine θ–Al<sub>2</sub>Cu phase and higher liquid fraction at the edge area, the ultimate tensile strength and elongation reaches 443.5 MPa and 5.2%. While in center area, the occurrence of coarsen θ–Al<sub>2</sub>Cu phases leads to the tensile properties dramatically reducing to 378.7 MPa and 1.9%.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 245-253"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48019906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Improvement on the fabrication of SiC materials: Processing, reinforcing phase, fabricating route—A review SiC材料制备的改进:工艺、增强相、制备路线——综述
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.10.005
S.D. Oguntuyi , K. Nyembwe , M.B. Shongwe , O.T. Johnson , J.R. Adewumi , N. Malatji , P.A. Olubambi

The ceaseless exploration for the improvement of ceramic materials has created a lot of techniques, all aimed at producing ceramic materials that can withstand environmental conditions and other factors. Most of thecommon techniques have their advantages and drawbacks. Some of the techniques involve the addition of a reinforcing phase to monolithic ceramic, the application of diverse sintering routes for the fabrication of ceramic products, and the preparatory methods for producing powder materials which cannot be jettisoned. These processes have been evaluated to influence the final ceramic products. Undoped/monolithic/single-phase ceramic has had some limitations in its processing, densification, and mechanical properties limiting its wide application in all circumstances. Hence, the incorporation of reinforcing phase, which can sometimes be called the secondary phase in the ceramic matrix, has significantly evolved into one of the possible means to nullify these challenges posed by undoped ceramics. This review consciously highlights and pinpoints all routes that have been taken to improve the properties of undoped SiC via the introduction of reinforcing phase, processing techniques, sintering techniques, etc. Finally, the possible prospects for future directions, advancement, and opportunities in the production of ceramic materials are concluded.

对陶瓷材料改进的不断探索创造了许多技术,所有这些技术都旨在生产能够承受环境条件和其他因素的陶瓷材料。大多数常用技术都有其优点和缺点。其中一些技术涉及在单片陶瓷中添加增强相,应用不同的烧结路线制造陶瓷产品,以及生产不能丢弃的粉末材料的制备方法。已经评估了这些工艺对最终陶瓷产品的影响。未掺杂/单片/单相陶瓷在加工、致密化和机械性能方面存在一些局限性,限制了其在所有情况下的广泛应用。因此,增强相(有时可以称为陶瓷基体中的第二相)的结合已显著发展成为消除未掺杂陶瓷带来的这些挑战的可能手段之一。这篇综述有意识地强调并指出了通过引入增强相、加工技术、烧结技术等来改善未掺杂SiC性能的所有途径。最后,总结了陶瓷材料生产的未来方向、进展和机遇。
{"title":"Improvement on the fabrication of SiC materials: Processing, reinforcing phase, fabricating route—A review","authors":"S.D. Oguntuyi ,&nbsp;K. Nyembwe ,&nbsp;M.B. Shongwe ,&nbsp;O.T. Johnson ,&nbsp;J.R. Adewumi ,&nbsp;N. Malatji ,&nbsp;P.A. Olubambi","doi":"10.1016/j.ijlmm.2022.10.005","DOIUrl":"https://doi.org/10.1016/j.ijlmm.2022.10.005","url":null,"abstract":"<div><p>The ceaseless exploration for the improvement of ceramic materials has created a lot of techniques, all aimed at producing ceramic materials that can withstand environmental conditions and other factors. Most of thecommon techniques have their advantages and drawbacks. Some of the techniques involve the addition of a reinforcing phase to monolithic ceramic, the application of diverse sintering routes for the fabrication of ceramic products, and the preparatory methods for producing powder materials which cannot be jettisoned. These processes have been evaluated to influence the final ceramic products. Undoped/monolithic/single-phase ceramic has had some limitations in its processing, densification, and mechanical properties limiting its wide application in all circumstances. Hence, the incorporation of reinforcing phase, which can sometimes be called the secondary phase in the ceramic matrix, has significantly evolved into one of the possible means to nullify these challenges posed by undoped ceramics. This review consciously highlights and pinpoints all routes that have been taken to improve the properties of undoped SiC via the introduction of reinforcing phase, processing techniques, sintering techniques, etc. Finally, the possible prospects for future directions, advancement, and opportunities in the production of ceramic materials are concluded.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 225-237"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50191555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Influence of auxiliary mold stretch-bend forming on the forming quality for L-section aluminum alloy profile 辅助模具拉弯成形对L型铝合金型材成形质量的影响
Q1 Engineering Pub Date : 2023-06-01 DOI: 10.1016/j.ijlmm.2022.11.003
Guangming Lv , Shengfang Zhang , Laihe Song , Fujian Ma , Ziguang Wang , Yu Liu

To improve the stretch-bend forming precision of aluminum alloy profiles with complex open sections, the relationship stress–strain distribution and the spring-back radius variation were analyzed under different stretch-bend stages. Numerical simulation was performed on the auxiliary mold stretch-bend and spring-back process for the L-section aluminum alloy profile with variable curvature. The effects of cover plate pressure and baffle gap on residual stress, section deformation and spring-back value after forming were investigated. The results show that the stretch-bend warpage can be avoided by setting the cover plate on the straight section of the profile web plate. With the increase of the cover plate pressure, the section distortion of the vertical plate increases by 82%, and the maximum spring-back increases by 71%. A baffle plate was added to the outside of the vertical plate, and the baffle gap is proportional to the amount of section distortion and inversely proportional to the spring-back value. The critical cover force (1 kN) and the critical baffle gap (1 mm) obtained by numerical analysis are used in the stretch-bend forming experiment, and the maximum error between the two results is 2.39%. The numerical simulation has a certain reference value for the rational design of the auxiliary mold stretch-bend process parameters.

为了提高复杂开口铝合金型材的拉弯成形精度,分析了不同拉弯阶段的应力应变分布与回弹半径变化的关系。对变曲率L型铝合金型材的辅助模具拉弯回弹过程进行了数值模拟。研究了盖板压力和隔板间隙对成形后残余应力、截面变形和回弹值的影响。结果表明,将盖板设置在型材腹板的直线段上,可以避免拉弯翘曲。随着盖板压力的增加,垂直板的截面畸变增加了82%,最大回弹增加了71%。在垂直板的外侧增加了一块挡板,挡板间隙与截面变形量成正比,与回弹值成反比。将数值分析得到的临界覆盖力(1kN)和临界挡板间隙(1mm)用于拉伸弯曲成形实验,两个结果之间的最大误差为2.39%。数值模拟对辅助模具拉伸弯曲工艺参数的合理设计具有一定的参考价值。
{"title":"Influence of auxiliary mold stretch-bend forming on the forming quality for L-section aluminum alloy profile","authors":"Guangming Lv ,&nbsp;Shengfang Zhang ,&nbsp;Laihe Song ,&nbsp;Fujian Ma ,&nbsp;Ziguang Wang ,&nbsp;Yu Liu","doi":"10.1016/j.ijlmm.2022.11.003","DOIUrl":"10.1016/j.ijlmm.2022.11.003","url":null,"abstract":"<div><p>To improve the stretch-bend forming precision of aluminum alloy profiles with complex open sections, the relationship stress–strain distribution and the spring-back radius variation were analyzed under different stretch-bend stages. Numerical simulation was performed on the auxiliary mold stretch-bend and spring-back process for the L-section aluminum alloy profile with variable curvature. The effects of cover plate pressure and baffle gap on residual stress, section deformation and spring-back value after forming were investigated. The results show that the stretch-bend warpage can be avoided by setting the cover plate on the straight section of the profile web plate. With the increase of the cover plate pressure, the section distortion of the vertical plate increases by 82%, and the maximum spring-back increases by 71%. A baffle plate was added to the outside of the vertical plate, and the baffle gap is proportional to the amount of section distortion and inversely proportional to the spring-back value. The critical cover force (1 kN) and the critical baffle gap (1 mm) obtained by numerical analysis are used in the stretch-bend forming experiment, and the maximum error between the two results is 2.39%. The numerical simulation has a certain reference value for the rational design of the auxiliary mold stretch-bend process parameters.</p></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"6 2","pages":"Pages 254-263"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49291742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
International Journal of Lightweight Materials and Manufacture
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1